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Journal of Rare Earths 2024年第10期42卷 1995-2002页

作者： Minakshi Koundal Chhaya Sharma A.K.Singh department of Applied Science and Engineering Indian Institute of Technology RoorkeeSaharanpur Campus department of Pulp and paper technology Indian Institute of technology Roorkee Saharanpur Campus

Cerium tartrate（CeTar）,produced in this study by precipitating cerium nitrate with potassium sodium tartrate（KNaTar）,was examined as a corrosion *** loss tests show inhibition efficiency of 71.7% with Ce（NO3）3and 88.7% with CeTar inhibitor for one-month exposure to mild steel in 7 g/L NaCl *** inhibition efficiency drops to 28.6% with the fo rmer and remains around 8 7% with the latter inhibitor after six months of *** results from electrochemical testing indicate that the inhibition efficiency decreases by adding cerium ***,the cerium tartrate inhibitor demonstrates a nearly constant inhibition efficiency for up to 30 d,i.e.,≈90%.Electrochemical impedance spectroscopy（EIS） performed in these cases shows the following results:（ⅰ） with cerium nitrate,a film of iron and cerium oxide,which on prolonged exposure diminishes,and（ⅱ） with cerium tartrate,the formation of a bimetallic film（Fe-tartrate-Ce） and a mixture of cerium hydroxide and iro n oxide that protects steel for a longer *** inferences are based on the analyses of scanning electron microscopy/energydispersive X-ray analysis（SEM/EDAX）,X-ray diffraction（XRD）,Fourier transform infrared spectroscopy（FTIR）,X-ray photoelectron（XPS）,and Raman spectroscopy results.

关键词： Cerium nitrate Cerium tartrate Corrosion inhibition Inhibitor film characterization Mild steel Rare earths

Flexible, thermal processable, self-healing, and fully bio-based starch plastics by constructing dynamic imine network

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Green Energy & Environment 2024年第10期9卷 1610-1618页

作者： Xiaoqian Zhang Haishan Zhang Guowen Zhou Zhiping Su Xiaohui Wang State Key Laboratory of Pulp and paper Engineering South China University of Technology

The serious environmental threat caused by petroleum-based plastics has spurred more researches in developing substitutes from renewable *** is desirable for fabricating bioplastic due to its abundance and renewable ***,limitations such as brittleness,hydrophilicity,and thermal properties restrict its widespread *** overcome these issues,covalent adaptable network was constructed to fabricate a fully bio-based starch plastic with multiple advantages via Schiff base *** strategy endowed starch plastic with excellent thermal processability,as evidenced by a low glass transition temperature （Tg=20.15℃）.Through introducing Priamine with long carbon chains,the starch plastic demonstrated superior flexibility （elongation at break=45.2%） and waterproof capability （water contact angle=109.2°）.Besides,it possessed a good thermal stability and self-adaptability,as well as solvent resistance and chemical *** work provides a promising method to fabricate fully bio-based plastics as alternative to petroleum-based plastics.

关键词： Bioplastic Covalent adaptable networks Schiff base chemistry Thermal processability Self-healing

Optimizing hemicelluloses pre-extraction in eucalyptus kraft pulping:A pathway towards enhancing pulp mill biorefineries

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Chinese Journal of Chemical Engineering 2024年第6期70卷 162-172页

作者： Yuhan Wang Danqi Xue Jingjing Zhuo Zhouyang Xiang State Key Laboratory of Pulp and paper Engineering South China University of TechnologyGuangzhou 510640China

A critical pathway towards enhancing pulp mill biorefineries is to integrate the extraction and utilization of hemicelluloses into the pulping ***,an industrial pre-extraction strategy for hemicelluloses targeting eucalyptus kraft pulping process was *** solution or pulping white liquor was used to pre-extract hemicelluloses before the actual pulping *** response surface methodology(RSM)technique was applied to investigate the most suitable conditions to maximize the yield of these hemicelluloses while simultaneously minimizing the damage to pulp yields and ***(105 to 155℃),alkali concentration(3%to 8%),sulfidity(20%to 30%)and retention time(19 to 221 min)were combined to evaluate their effects on hemicellulose yields and chemical *** optimal pre-extraction conditions identified in this work(5.75%NaOH concentration,25%sulfidity at 135℃for 60 min)successfully allowed recovering 4.8%of hemicelluloses(based on the wood dry mass)and limited damages to pulp yields and *** cellulose content in pulp can even be increased by about 10%.Hemicellulose emulsification properties were also evaluated,which were comparable to synthetic *** study provides an industrial pathway to effectively separate and utilize wood hemicelluloses from the pulping process,which has the potential to improve the economy and material utilization of pulp and paper mills.

关键词： Hemicelluloses Xylan Pre-extraction Kraft pulping Emulsifying Response surface methodology(RSM)

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Exploring the thermophysical properties of natural deep eutectic solvents for gas capture applications: a comprehensive review

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Green Chemical Engineering 2024年第3期5卷 307-338页

作者： Ahmad Al-Bodour Noor Alomari Alberto Guti errez Santiago Aparicio Mert Atilhan department of Chemical and paper Engineering Western Michigan University department of Chemistry University of Burgos Faculty of Sciences

With the intensifying challenge of global warming driven largely by anthropogenic activities, effective greenhouse gas capture techniques are critical. This paper focuses on the role of deep eutectic solvents(DES) as promising agents for such capture at the source. We review the key DES-based methods for greenhouse gas capture, drawing conclusions from a thorough analysis of the existing literature. In particular, we examine the effect of DES structure on gas solubilities and explore the mechanism of gas solubility in DES through molecular simulation. We present a synthesis of state-of-the-art results in this area, assessing the potential of DES as an alternative to current industrial gas capture methods. Furthermore, we propose future research directions for the design of novel DES tailored to more specific applications.

关键词： Global warming Climate change Deep eutectic solvents Gas capture Gas separation

Nickel-catalyzed arylcyanation of alkenes via cyano group translocation:access to 1,n-dinitriles or 4-amino nitriles

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Science China Chemistry 2024年第9期67卷 2975-2981页

作者： Xiaohong Li Shenfan Wang Xiangxiang Fu Donghui Xing Zeyuan Fu Yuanfu Deng Huanfeng Jiang Liangbin Huang State Key Laboratory of Pulp and paper Engineering School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510640China

Herein,a nickel-catalyzed arylcyanation of unactivated alkenes via cyano group translocation with aryl boronic acids has been *** transformations provided a robust approach to constructing structurally diverse 1,n-dinitriles or 4-amino nitriles from easily prepared and commercially available starting *** cyano group translocation was achieved,involving the addition into the intramolecular C–N triple bond followed by the retro-Thorpe *** studies revealed that high temperature and CsHCO_(3) as the base were crucial for the cyano group translocation.

关键词： arylcyanation nickel catalysis cyano group translocation 1 n-dinitriles 4-amino nitriles

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Wood By-Products as UV Protection:A Consequence Review

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Journal of Renewable Materials 2024年第4期12卷 699-720页

作者： Naglaa Salem El‑Sayed Mohamed Hasanin Samir Kamel Cellulose and paper department National Research CentreCairo12622Egypt

In recent decades,the ozone layer has suffered considerable damage,increasing the entry of ultraviolet(UV)light into the atmosphere and reaching the earth’s surface,negatively affecting ***,researchers aimed to solve this problem by synthesizing advanced UV-shielding *** the other hand,developing an easy and green strategy to prepare functional materials with outstanding properties based on naturally abundant and environmentally friendly raw materials is highly desirable for sustainable *** biomass-derived materials are sustainable and biodegradable,they present a promising substitute for petroleum-based *** three main structural constituents of the plant biomass-based materials that are naturally available are cellulose,hemicellulose,and *** review details current developments using wood-based products such as cellulose,hemicellulose,and lignin in UV-shielding *** will start with assembling the structure and chemistry of cellulose,hemicellulose,and lignin,followed by their contributions to preparing UV-shielding ***,it will briefly discuss the different processing methods for the design of UV-shielding *** wood by-products offer additional opportunities to use the whole tree harvest.

关键词： UV-shielding wood cellulose lignin hemicellulose sunlight protection

Starting materials, processes and characteristics of bio-based foams: A review

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Journal of Bioresources and Bioproducts 2024年第2期9卷 160-173页

作者： Xiaohan Wang Jinwon Jang Yanqun Su Jingang Liu Hongjie Zhang Zhibin He Yonghao Ni National Engineering Laboratory for Pulp and paper China National Pulp and Paper Research Institute Co.Ltd.Beijing 100102China Limerick Pulp and paper Centre and department of Chemical Engineering University of New BrunswickNew Brunswick E3B 5A3Canada

Biofoam products have attracted considerable attention lately because there is a growing demand for green/sustainable *** this end,various biobased foams have either been developed or are currently in development,e.g.,bio-based polyurethanes(PUs),polylactic acid(PLA),starch,and polyhydroxyalkanotates(PHAs).Indeed,significant progress has been made;however,chal-lenges still persist,for example,biobased foam products have poor processability,inferior com-patibility,thermal and strength *** this review,we focus on five biofoam products:namely bio-based PUs,PLA,starch,PHAs,and cellulose biofoam products,along with their prop-erties and performance,as well as their manufacturing *** efforts are still needed to unlock the full potential of these bio-based products and meet the goal of complementing and gradually replacing some of their fossil-based ***,the challenges,as well as arising opportunities of future research directions are discussed.

关键词： Biofoam Bio-based polyurethanes Polylactic acid Polyhydroxyalkanotate Starch Cellulose Manufacturing process

Flame Retardant Material Based on Cellulose Scaffold Mineralized by Calcium Carbonate

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Journal of Renewable Materials 2024年第1期12卷 89-102页

作者： Jinshuo Wang Lida Xing Fulong Zhang Chuanfu Liu State Key Laboratory of Pulp and paper Engineering School of Light Industry and EngineeringSouth China University of TechnologyGuangzhou510640China

Wood-based functional materials have developed *** the flammability significantly limits its further *** improve the flame retardancy,the balsa wood was delignified by NaClO2 solution to create a cellulose scaffold,and then alternately immersed in CaCl_(2) ethanol solution and NaHCO3 aqueous solution under *** high porosity and wettability resulting from delignification benefited the following mineralization process,changing the thermal properties of balsa wood *** organic-inorganic wood composite showed abundant CaCO_(3) spherical particles under scanning electron *** peak of the heat release rate of delignified balsa-CaCO_(3) was reduced by 33%compared to the native balsa,according to the cone calorimetric *** flame test demonstrated that the mineralized wood was flame retardant and ***,the mineralized wood also displayed lower thermal *** study developed a feasible way to fabricate a lightweight,fire-retardant,self-extinguishing,and heat-insulating wood composite,providing a promising route for the valuable application of cellulosic biomass.

关键词： Cellulose scaffold delignification CaCO_(3) mineralization fire retardancy

Preparation of a novel lactose-lignin hydrogel catalyst with self-reduction capacity for nitrogenous wastewater treatment

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Frontiers of Chemical Science and Engineering 2024年第9期18卷 25-36页

作者： Fan Zhang Yanzhu Guo Xianhong Wu Ce Gao Qingda An Zhongjian Tian Runcang Sun Key Laboratory of Pulp and paper Science&technology of Ministry of Education Qilu University of TechnologyShandong Academy of SciencesJinan 250353China The Liaoning Province Key Laboratory of paper and Pulp Engineering The Dalian Key Laboratory of High Value Application and Development of Botanical ResourcesThe Key Laboratory of High Value Utilization of Botanical Resources of China Light IndustryDalian Polytechnic UniversityDalian 116034China

A novel carboxylated lactose/sodium lignosulfonate/polyacrylic acid hydrogel composites with self-reduction capacity was successfully synthesized by self-assembly *** hydrogel with well-developed porous structure provided abundant anchoring points and reduction capacity for transforming Ag^(+)into silver *** nanoparticles dispersed among the network of hydrogel and the composites exhibited catalytic *** catalytic performance was evaluated via degradation of p-nitrophenol,rhodamine B,methyl orange and methylene blue,which were catalyzed with corresponding reaction rate constants of 0.04338,0.07499,0.04891,and 0.00628 s^(–1),*** addition,the catalyst exhibited stable performance under fixed-bed condition and the corresponding conversion rate still maintained more than 80%after 540 ***,the catalytic performance still maintained effective in tap water and simulated *** catalytic efficiency still remained 99.7%with no significant decrease after 8 cycles.

关键词： carboxylated lactose Ag NPs self-reduction nitrogenous wastewater

CFD investigation of structural effects of internal gas intake on powder conveying performance in fuel supply systems for aerospace engines

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Particuology 2024年第9期92卷 140-154页

作者： Guanlong Ren Haijun Sun Fangjun Chen Wen Shen Yunzhen Cai Yihua Xu Henrik Ström Bilainu Oboirien Qingang Xiong School of Aircraft Engineering Nanchang Hangkong UniversityNanchang330063China Engineering Research Center of Aero-engine technology for General Aviation Ministry of EducationNanchang330063China State Key Laboratory of Pulp and paper Engineering South China University of TechnologyGuangzhou510640China department of Mechanics and Maritime Sciences Chalmers University of TechnologyGöteborg41296Sweden department of Chemical Engineering University of JohannesburgJohannesburg17011South Africa

Optimal design of gas intake in powder fuel supply systems is crucial for performance of aerospace *** is little research on the impact of intake structure on powder conveying *** novel internal intakes were proposed,which are spherical,cube-shaped,and *** validation,CFD simulations demonstrate that fluctuation of mass flow rate of powders in the dome-shaped intake is reduced by about 73.3%compared with the annular external *** trends of phase velocities are similar for the spherical and cube-shaped intakes,while those are similar for the annular external and dome-shaped internal *** of area of gas zone for the annular external and spherical internal intakes is larger than that for the cube-shaped and dome-shaped internal *** and relative pressure drop in the fluidization chamber have a stable stage,and fluctuation of relative pressure drop is small when dome-shaped internal intake is used.

关键词： Powder supply system Intake structure Dense gas-solid flow Two-fluid model Powder fluidization Pressure drop