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Characterizing occurrence of emerging organic contaminants in Dinaric karst catchment of Jadro andZrnovnica springs,Croatia

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Emerging Contaminants 2024年第3期10卷 158-169页

作者： Ana Selak Jasmina Lukac Reberski Ivana Boljat Josip Terzic HGI-CGS-Croatian Geological Survey Department of Hydrogeology and Engineering GeologySachsova 210000ZagrebCroatia

The occurrence of emerging organic contaminants(EOCs)was investigated in vulnerable Dinaric karst catchment of Jadro andZrnovnica springs in Croatia,under varying flow conditions and across three different water resource types(groundwater,springs,and surface water).The maximal EOCs concentration in both springs were observed following autumn recharge events,while during peak discharge no detection above the limits of detection(LOD)was recorded due to dilution *** to springs,groundwater from deep borehole exhibited highest total EOCs concentration under low flow conditions,underscoring the considerable karst aquifer vulnerability and its oligotrophic *** peak EOCs concentration in karstic Cetina River coincided with the river's lowest *** highest mass flux of 1013 g/day was determined for very mobile pharmaceutical metformin detected in *** presence of potentially persistent to very persistent compounds,like DEET and 1H-benzotriazole,which exhibited highest detection frequencies across all sampling sites,was observed in association with varying hydrological *** regarding the occurrence of identified EOCs include surface contamination infiltrating directly through ponors and highly karstified areas,potential persistence in the epikarst and aquifer matrix,and site-specific contamination sources for compounds such as 1H-benzotriazole,gabapentin,and ketoprofen found in *** evaluate the risk of inadvertent human exposure to EOCs across various age groups,we utilized measured spring concentrations and calculated drinking water equivalent levels(DWEL),which ranged from 1.4 mg/L for cotinine to 503 mg/L for sucralose,both detected in Jadro *** EOCs concentrations in ng/L are unlikely to pose a significant risk to healthy population,long-term exposure to EOCs mixture remains *** scarcity of research on EOCs in karst environments on both global and national levels,our study enhances comp

关键词： Karst groundwater Emerging organic contaminants Pharmaceuticals Human exposure DEET 1H-benzotriazole

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Using neural network modeling to improve the detection accuracy of land subsidence due to groundwater withdrawal

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Journal of Mountain Science 2024年第7期21卷 2320-2333页

作者： Ali M.RAJABI Ali EDALAT Yasaman ABOLGHASEMI Mahdi KHODAPARAST department of engineering geology University of TehranTehran ***Iran department of Civil engineering University of QomQom ***Iran

Despite the high efficiency of remote sensing methods for rapid and large-scale detection of subsidence phenomena,this technique has limitations such as atmospheric impact and temporal and spatial decorrelation that affect the accuracy of the *** paper proposes a method based on an artificial neural network to improve the results of monitoring land subsidence due to groundwater overexploitation by radar interferometry in the Aliabad plain(Central Iran).In this regard,vertical ground deformations were monitored over 18 months using the Sentinel-1A SAR *** model the land subsidence by a multilayer perceptron(MLP)artificial neural network,four parameters,including groundwater level,alluvial thickness,elastic modulus,and transmissivity have been *** model's generalizability was assessed using data derived for 144 *** to the results,the neural network estimates the land subsidence at each ground point with an accuracy of 6.8 mm.A comparison between the predicted and actual values indicated a significant *** MLP model can be used to improve the results of subsidence detection in the study area or other areas with similar characteristics.

关键词： DInSAR Land subsidence Groundwater withdrawal Aliabad plain Artificial neural network

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Revisiting the theoretical prediction of the explosive performance found by the Trauzl test

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Defence Technology（防务技术） 2024年第6期36卷 163-174页

作者： Ivana Dobrilovic Mario Dobrilovic Muhamed Suceska Faculty of Mining Geology and Petroleum EngineeringDepartment of Mining Engineering and GeotechnicsUniversity of ZagrebPierottijeva 6Zagreb10000Croatia

The Trauzl lead block test allows the determination of the approximate performance of explosives in blasting applications by measuring the volume increase(expansion)that is produced by the detonation of an explosive charge in the cavity of a lead *** this paper,we reconsider the possibility of interpreting the Trauzl test results in terms of detonation parameters or *** detonation parameters used in the analysis are calculated using the thermochemical code EXPLO5,while the hydrocode AUTODYN is used to simulate the effect of explosive charge density and reaction rate on the results of the Trauzl *** increase in the volume of the lead block cavity was found to correlate best with the product of the detonation heat and the root of the volume of detonation *** simulation showed that the density of explosive charge and the rate of explosive decomposition affect the dynamics of the interaction of the detonation product and the lead block,and consequently the lead block cavity volume increase.

关键词： Trauzl lead block test Performance of explosives EXPLO5 AUTODYN Detonation heat

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Transport of graphene oxide in the capillary fringe:Insights from sandbox experiments and numerical simulation

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Emerging Contaminants 2024年第3期10卷 103-110页

作者： Taotao Lu Feiyu Chen Xiaochen Liu Xue Bai Hao Peng Shuangcheng Tang College of Hydraulic Science and engineering Yangzhou UniversityYangzhou225009China hydrogeology and engineering geology Institute of Hubei Geological Bureau Jinzhou434020China College of Environment and Civil engineering Chengdu University of TechnologyChengdu610059China

Studying contaminant transport in the capillary fringe(CF),a crucial part of the vadose zone,offers insights into the mechanisms controlling pollution in soils and groundwater *** paper investigated contaminant transport in the CF by continuously injecting a conservative tracer(NaCl)and graphene oxide nanoparticle(GONP),an adsorptive contaminant,into a *** entering the CF from the unsaturated zone,both NaCl and GONP underwent lateral *** breakthrough curves(BTCs)for NaCl and GONP were derived from water samples collected at predetermined sampling ***,contaminant transport in the CF was modeled using a one-dimensionaletwo-dimensional(1D-2D)coupled hydrodynamic *** model incorporated lateral dispersivity(aL=1.198 cm)and longitudinal dispersivity(aT=0.286 cm),calculated using a point-by-point *** hydrodynamic dispersion coefficients obtained were then applied to the Brooks and Corey(BC)and the van Genuchten(VG)parametric *** BC model more accurately simulated the NaCl migration compared to the VG model,leading to its application in simulating GONP transport in the ***,the simulated BTCs for GONP showed a lag behind the measured data,especially at high ionic *** discrepancy was attributed to the variable adsorption partition coefficient of GONP under different ionic *** the experiment,GONP adsorption onto the porous media's surface altered the capillary dynamics,notably increasing capillary rise height,decreasing seepage velocity,and reducing GONP ***,it is necessary to consider the adsorption capacity of the contaminants in order to accurately assess their transport within the vadose zone.

关键词： Capillary fringe Transport Sandbox experiment Numerical simulation

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Hydrochemical Characterization,Controlling Factors and Water Quality of Surface Water in Shandong Province,North China

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Journal of Earth Science 2024年第1期35卷 155-166页

作者： Ran An Jiutan Liu Zongjun Gao Changsuo Li Yuming Peng School of Earth Sciences and Resources China University of GeosciencesBeijing 100083China College of Earth Science and engineering Shandong University of Science and TechnologyQingdao 266590China 801 Institute of hydrogeology and engineering geology Shandong Provincial Bureau of Geology&Mineral ResourcesJinan 250014China Key Laboratory of Groundwater Resources and Environment Shandong Provincial Bureau of Geology&Mineral ResourcesJinan 250014China Shandong engineering Research Center for Groundwater Environmental Protection and Remediation Jinan 250014China

In this study,90 surface water samples were collected from Shandong Province(SDP)in the dry and wet seasons and analyzed using statistical analysis,hydrochemical methods and water quality index(WQI).The content of main ions showed seasonal variations,with a higher average value in the dry season than in the wet *** points exhibiting high contents of the main chemical components were mainly distributed in areas southwest of SDP,north of Weifang,and around *** saturation index of carbonate minerals was greater than zero,while that of evaporite minerals was less than *** hydrochemical characteristics of surface water are mainly dominated by rock weathering as well as cation *** addition,surface water in SDP has significantly been affected by anthropogenic *** of the surface water could be classified as weakly alkaline soft-fresh water,with the hydrochemical types of SO_(4)·Cl-Ca·Mg and SO_(4)·*** terms of WQI,47.88% and 37.88% of the water samples in SDP were classified as poor water in the dry and wet seasons,*** the whole,the water quality is higher in the wet season than in the dry season,and surface water in SDP is generally suitable for agricultural irrigation.

关键词： surface water hydrochemical characteristics controlling factors water quality Shandong Province

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Effect of thermal maturation and organic matter content on oil shale fracturing

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International Journal of Coal Science & Technology 2024年第2期11卷 16-34页

作者： Fatemeh Saberi Mahboubeh Hosseini‑Barzi department of geology and Geological engineering University of North Dakota264 Centennial DriveGrand ForksNDUSA department of geology and Petroleum Basins Shahid Beheshti University of TehranTehranTehran ProvinceIran

The Pabdeh Formation represents organic matter enrichment in some oil fields,which can be considered a source *** study is based on the Rock–Eval,Iatroscan,and electron microscopy imaging results before and after heating the *** discovered this immature shale that undergoes burial and diagenesis,in which organic matter is converted into *** migration is the process that transports hydrocarbons in the source *** investigated this phenomenon by developing a model that simulates hydrocarbon generation and fluid pressure during kerogen-to-hydrocarbon *** initially formed at the tip/edge of kerogen and were filled with hydrocarbons,but as catagenesis progressed,the pressure caused by the volume increase of kerogen decreased due to hydrocarbon *** transformation of solid kerogen into low-density bitumen/oil increased the pressure,leading to the development of damage zones in the source *** Pabdeh Formation’s small porethroats hindered effective expulsion,causing an increase in pore fluid pressure inside the initial *** stress accumulated due to hydrocarbon production,reaching the rock’s fracture strength,further contributed to damage zone *** the expansion process,microfractures preferentially grew in low-strength pathways such as lithology changes,laminae boundaries,and pre-existing *** the porous pressure created by each kerogen overlapped,individual microfractures interconnected,forming a network of microfractures within the source *** research sheds light on the complex interplay between temperature,hydrocarbon generation,and the development of expulsion fractures in the Pabdeh Formation,providing valuable insights for understanding and optimizing hydrocarbon extraction in similar geological settings.

关键词： Oil shale Microfracture Hydrocarbon generation Organic matter Thermal maturation Primary migration

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Upwelling current and its relationship to the enrichment of organic matter in the Lower Silurian Longmaxi Formation, northern Chongqing-western Hubei area, southern China

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Journal of Palaeogeography 2024年第4期13卷 993-1015页

作者： Jun-Jun Shen Jia-Kai Yan Peng-Wan Wang Yu-Man Wang Lin Zhou Yu-Bing Ji Min Xu Hubei Cooperative Innovation Center of Unconventional Oil and Gas of Yangtze University hydrogeology and engineering geology Institute of Hubei Geological Bureau PetroChina Hangzhou Institute of Petroleum geology PetroChina Research Institute of Petroleum Exploration and Development Exploration and Production Research Institute Zhejiang Oilfield Company Integrated Center of Exploration and Development

Upwelling currents play a crucial role in the enrichment of organic matter, yet the mechanisms driving this process remain incompletely understood due to methodological and data resolution limitations. In this paper, we employ a combination of biostratigraphic classification, qualitative methods, and quantitative methods to systematically analyze the sedimentological and geochemical characteristics of the Lower Silurian Longmaxi Formation in the northern Chongqing-western Hubei area, southern China. The relationship between the upwelling currents and organic matter enrichment in the shale of the Longmaxi Formation is investigated. Results indicate that the upwelling currents in the study area were primarily influenced by the foreland flexure process. From the Rhuddanian(flexure-sedimentation stage) to the Aeronian(flexure-migration stage), the more intense tectonic activity led to gradual opening of the barrier between the South Qinling Ocean and the Yangtze Platform, resulting in an increase in the influx of the oceanic current. The upwelling currents significantly contributed to the organic matter production, albeit without substantially affecting the preservation conditions. Throughout the succession of the Longmaxi Formation, the organic matter content decreased gradually from the passive continental margin to the foreland flexural stagnant basin, which was mainly due to deterioration of the preservation conditions as a result of sea level fall and increased terrigenous input. Despite the increase in the upwelling currents, they did not decisively control the organic matter enrichment. Spatially, during the Rhuddanian to Aeronian period, the organic matter content decreased similarly from the passive continental margin to the foreland flexural stagnant basin, influenced by reduced organic matter production caused by weakening of the upwelling currents and the worsening preservation conditions caused by sea-level fall. The terrigenous input had a relatively minor

关键词： Middle–Upper Yangtze Ordovician–Silurian transition Black shale Passive continental margin Foreland flexural stagnant basin Sedimentary paleoenvironment

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Challenges in applying REE-based thermobarometers: Insights from mafic-ultramafic granulites in Indian southern granulite terrain

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Science China Earth Sciences 2024年第11期67卷 3448-3464页

作者： Xiaofei XU Longlong GOU Chengli ZHANG Junsheng LU Yan ZHAO Wenhao AO Yuhua HU Feng ZHOU Faculty of Land Resources engineering Kunming University of Science and Technology State Key Laboratory of Continental Dynamics Department of Geology Northwest University

High-temperature diffusion of major elements may obscure the records of early and peak metamorphic stages in granulites,while trace elements are more likely to preserve these records due to their lower diffusion ***,using calibrated REE-based thermobarometers has proved essential for reconstructing these key stages,drawing considerable attention and application from ***,the precision of these thermobarometers depends on including both major and trace elements from coexisting minerals to define the correlation coefficients（A,B,and D） among mineral pairs,indicating that the elemental composition of these pairs can affect the *** study examines the mafic-ultramafic granulites in the southern granulite terrain,India,employing integrated methods such as petrography,mineral chemistry,phase equilibrium modeling,and REE-based *** aim to determine their metamorphic conditions and evolutionary history and to identify potential challenges in using REE-based *** garnet,clinopyroxene,and orthopyroxene in the mafic-ultramafic granulite samples display homogeneous compositional profiles,with pronounced Fe-Mg diffusion zones at the interfaces between garnet and ***,the profiles of trace elements within garnet and clinopyroxene are better *** into Fe-Mg exchange and randomly selected mineral pairs significantly influence the accuracy of REE-based ***-Mg exchange can increase in coefficient A,while decreasing coefficient B for light rare earth elements（LREEs） and increasing it for heavy rare earth elements（HREEs）,ultimately resulting in overestimations when calculating REE-based *** example,selecting major compositions with an Ex(=(XMgC-XMg0)/XMg0×100%;where XMgCis the value after Fe-Mg exchange,XMg0is the value before Fe-Mg exchange;XMg=Mg/(Fe2++Mg)) value of ～10 for calculation using the REE-in-Grt-Cpx thermobarometer will result in pressures and t

关键词： Granulites REE-based thermobarometer Fe-Mg exchange Randomly selected mineral pairs

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The Upper Jurassic sediments,Marib-Shabwa Basin,Yemen:Lithofacies aspects and sequence stratigraphic analysis

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Energy Geoscience 2024年第1期5卷 342-357页

作者： Mohammed Albaroot Mohamed M.Elhossainy Nabil M.Al-Areeq Emad A.Abdullah Abdelhamid M.Salman department of Applied geology Faculty of Science and EducationUniversity of Saba RegionMaribYemen department of geology Faculty of ScienceKafrelsheikh UniversityKafrelsheikh33516Egypt department of geology and Environment Faculty of Applied SciencesThamar UniversityYemen department of Mineral Developing and Oil&Gas engineering Academy of EngineeringPeoples’Friendship University of Russia(RUDN University)Moscow117198Russia department of geology Faculty of ScienceAssiut UniversityAssiut71516Egypt

The present study is devoted to understanding the evolution of the Upper Jurassic Sab'atayn Formation in the Marib-Shabwa Basin,Yemen,through a sequence stratigraphic analysis based on integrating datasets of sedimentology,seismic sections,and well *** Sab'atayn Formation(Tithonian age)is represented by a series of clastic and evaporites that were deposited under fluvio-deltaic to prodeltaic *** is divided into four members including Yah(at the base),upwards to Seen,Alif,and Safir at the *** third-order depositional sequences were determined for the Tithonian succession which were separated by three sequence *** sequences were classified into their systems tracts signifying several sedimentation patterns of progradational,aggradational,and retrogradational parasequence *** first depositional sequence corresponds to the early-middle Tithonian Yah and Seen units that can be classified into lowstand,transgressive,and highstand systems *** second sequence comprises the late Tithonian Alif unit that can be subdivided into transgressive and highstand systems *** sandy deposits of the Alif Member(highstand deposits)represent the most productive hydrocarbon reservoir in the *** Upper Jurassic sediments in the study area were resulted from a combination of eustatic and tectonic effects.

关键词： Sequence stratigraphy Sandstone reservoir Well logs Upper Jurassic Marib-Shabwa Basin Yemen

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Depositional and Bio-Sequence Stratigraphic Framework of Late Cretaceous Kawagarh Formation,Kala-Chitta Range,Pakistan:Equivalent of Gurpi Formation(Iran)

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Journal of Earth Science 2024年第2期35卷 332-348页

作者： Muhammad Awais Bilal Wadood Muhammad Ishaq Muhammad Bilal Zeeshan Zafar Nasar Khan Aminullah Khan department of geology University of SwabiAnbar-SwabiKhyber PakhtunkhwaSwabi23561Pakistan department of Earth Environmental and Resources SciencesUniversity of Naples FedericoⅡNaples80126Italy State Key Laboratory of Continental Dynamics Department of GeologyNorthwest UniversityXi’an710069China National Centre of Excellence in geology University of PeshawarPeshawarKhyber Pakhtunkhwa25130Pakistan department of Geological engineering School of Earth Sciences and EngineeringXi’an Shiyou UniversityXi’an610500China department of Petroleum geology and engineering School of Earth ResourcesChina University of GeosciencesWuhan430074China department of geology University of MalakandDir Lower18800ChakdaraPakistan department of Earth and Environmental Sciences KU LeuvenLeuven3001Belgium

The present study is focused on evaluation of deep marine pelagic sediments of Late Cretaceous Kawagarh Formation of Kala-Chitta Range in the context of microfacies analysis,paleoenvironmental interpretation,planktonic foraminiferal biostratigraphy,sequence stratigraphy and diversification of species.A total of thirty three rock samples were collected from the measured *** microfacies are interpreted,namely planktonic foraminifera wackestone,planktonic foraminifera mudstone and sandy mudstone indicating low energy depositional environment i.e.,outer *** biostratigraphic studies show plentiful planktonic foraminifera species of Globotruncana,Heterohelix and ***,no association of benthic or siliceous organisms was *** the basis of available species assemblage,a single local planktonic foraminifera biozone i.e.,Globotruncana-Heterohelix-Globotruncanita Assemblage Biozone is *** biozone information is combined with published literature and Lower Santonian to Middle Maastrichtian age has been assigned to the Kawagarh *** trend of species occurrences evinces that species number decreases over time with pulsated rise in the Kawagarh *** Kawagarh Formation carbonates show an overall Transgressive Systems Tract(TST).The Kawagarh Formation of Pakistan evinces analogous characteristics to that of the Late Cretaceous Gurpi Formation of Iran based on the geologic age,outcrop lithology,microfacies,planktonic foraminiferal assemblages,depositional setting and sequence stratigraphy.

关键词： depositional fabric biostratigraphy sequence stratigraphy Late Cretaceous Kawagarh Formation Pakistan Gurpi Formation Iran

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