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Hypoglycaemic effect of Berberis vulgaris *** normal and streptozotocin-induced diabetic rats

Asian Pacific Journal of Tropical Biomedicine 2011年第6期1卷 468-471页

作者： Nawel Meliani Mohamed El Amine Dib Hocine Allali Boufeldja Tabti Laboraloire des Substances Naturelles et Bioactives (LASNABIO) departement de chimie Faculte des SciencesUniversite Aboubekr Belkaid BP 119

Objective:To achieve a primary pharmacological screening contained in the aqueous extract of Berberis vulgaris(***) and to examine the hypoglycaemic effect and biochemical parameters of aqueous and saponins extract on groups of rats rendered diabetic by injection of ***:The phytochemicol tests to detect the presence of different compounds were based on the visual observation of color change or formation of precipitate after the addition of specific *** was induced in rats by intraperitoneal(i.p.) injection of streptozotocin(STZ) at a dose of 65 mg/kg *** fasting blood glucose levels were estimated by glucose oxidase-peroxidase reactive strips(dextrostix,Bayer Diagnostics).Blood samples were taken by cutting the tip of the *** cholesterol and serum triglycerides were estimated by enzymatic DHBS colorimetric ***:Administration of 62.5 and 2S.0 mg/kg of saponins and aqueous extract respectively in normal rats group shows a significant hypoglycemic activity(32.33%and 40.17%respectively) during the first ***,diabetic group treated with saponin extract produced a maximum fall of 73.1%and 76.03%at day 1 and day 21 compared to the diabetics ***,blood glucose levels of the diabetic rats treated with aqueous extract showed decrease of 78.79%on the first day and the effect remains roughly constant during 3 week. Both extracts also declined significantly biochemical parameters(20.77%-49.00%).The control in the loss of body weight was observed in treated diabetic rats as compared to diabetic controls. Conclusions:These results demonstrated significant antidiabetic effects and showed that serum cholesterol and serum triglycerides levels were decreased,significantly,consequently this plant might be of value in diabetes treatment.

关键词： Berberis vulgaris L. Antidiabetic activity Streptozotocin-induced diabetes Saponins Aqueous extract Photochemical screening Hypoglycaemic effect Biochemical parameters Cholesterol Triglycerides Glucose oxidase-peroxidase Colorimetric method

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A quantum cascade laser infrared spectrometer for CO_2 stable isotope analysis：Field implementation at a hydrocarbon contaminated site under bio-remediation

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Journal of Environmental Sciences 2016年第2期28卷 60-74页

作者： Christophe Guimbaud Cécile Noel Michel Chartier Valéry Catoire Michaela Blessing Jean Christophe Gourry Claude Robert Laboratoire de Physique et de chimie de l'Environnement et de l'Espace (LPC2E) CNRS et Universite d'Orleans (UMR 7328)45071 Orleans cedex 2 France Bureau de Recherches Geologiques et Minieres (BRGM) 45060 Orleans cedex 2 France

Real-time methods to monitor stable isotope ratios of CO_2 are needed to identify biogeochemical origins of CO_2 emissions from the soil–air interface. An isotope ratio infra-red spectrometer（IRIS） has been developed to measure CO_2 mixing ratio with δ~13C isotopic signature, in addition to mixing ratios of other greenhouse gases（CH_4, N2_O）. The original aspects of the instrument as well as its precision and accuracy for the determination of the isotopic signature δ~13C of CO_2 are discussed. A first application to biodegradation of hydrocarbons is presented, tested on a hydrocarbon contaminated site under aerobic bio-treatment. CO_2 flux measurements using closed chamber method is combined with the determination of the isotopic signature δ~13C of the CO_2 emission to propose a non-intrusive method to monitor in situ biodegradation of hydrocarbons. In the contaminated area, high CO_2 emissions have been measured with an isotopic signature δ~13C suggesting that CO_2 comes from petroleum hydrocarbon *** first field implementation shows that rapid and accurate measurement of isotopic signature of CO_2 emissions is particularly useful in assessing the contribution of contaminant degradation to the measured CO_2 efflux and is promising as a monitoring tool for aerobic bio-treatment.

关键词： Isotope ratio infrared spectrometry Isotopic signature δ^(13)C of CO_2 Biodegradation monitoring Hydrocarbons BTEX

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Oxidation of propane over substituted Keggin phosphomolybdate salts

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Journal of Natural Gas Chemistry 2009年第3期18卷 319-324页

作者： T.Mazari C.Roch.Marchal S.Hocine N.Salhi C.Rabia Laboratoire de chimie du Gaz Naturel Faculté de ChimieUniversité des Sciences et de la Technologie Houari Boumediéne ILV-UMR 8180 CNRS-Université de Versailles-St Quentin-en-Yvelines Batiment Lavoisier45 avenue des Etats-Unis78035 Versailles CedexFrance

Ammonium salts, （NH4）6HPMo11MO40 （M = Ni, Co, Fe）, have been investigated for the oxidation of propane, with molecular oxygen, at temperature ranging between 380 ℃ and 420 ℃ after in-situ pre-treatment performed at two heating rate of 5 or 9 ℃/min. They were characterized by Bet method, XRD, 31p NMR, UV-Vis and IR techniques. The catalysts were found active in the propane oxidation and selective to propene or acrolein, in particular for samples pre-treated with the heating rate of 9 ℃/min.

关键词： propane oxidation propene acrolein polyoxometalates phosphomolybdate

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Anti-inflammatory and analgesic activities with gastroprotective effect of semi-purified fractions and isolation of pure compounds from Mediterranean gorgonian Eunicella singularis

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Asian Pacific Journal of Tropical Medicine 2015年第8期8卷 598-603页

作者： Monia deghrigue Carmen Festa Lotfi Ghribi Maria Valeria D’Auria Simona de Marino Hichem Ben Jannet Abderrahman Bouraoui Laboratoire de développement chimique galénique et pharmacologique des médicaments (LR12ES09).Equipe de Pharmacologie marineFaculté de pharmacie de MonastirUniversité de Monastir department of Pharmacy University of Naples "Federico II" Laboratoire de chimie hétérocyclique produits naturels et réactivité. Equipe de chimie médicinale et produits naturels (LR11ES39)Faculté des sciences de MonastirUniversité de Monastir Laboratoire de chimie hétérocyclique produits naturels et réactivité.Equipe de chimie médicinale et produits naturels (LR11ES39)Faculté des sciences de MonastirUniversité de Monastir

Objective: To explore anti-inflammatory activities of organic extract and its semi-purified fractions(ethanol, acetone, methanol/dichloromethane) from the Mediterranean gorgonian Eunicella singularis. Methods: The anti-inflammatory and analgesic activities were evaluated, using the carrageenan-induced rat paw edema model and the acetic acid writhing test in mice. The gastroprotective activity was determined using HCl/et OH induced gastric ulcers in rats. The purification and structure elucidation of compound(s) from the more effective fraction were determined by chromatographic and spectroscopic methods and in comparison with data reported in the literature. Results: The fraction F-et OH showed an important antiinflammatory activity associated with significant analgesic and gastroprotective properties. The purification and structure elucidation of compound(s) from this fraction lead to the identification of one diterpenoid and four sterols. Conclusions: These results suggested that components from the active fraction can be used to treat various anti-inflammatory diseases.

关键词： Eunicella singularis Anti-inflammatory activity Analgesic activity Gastroprotective effect Diterpenoid Sterols

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Advantages and Drawbacks of Quantum Mechanical Static and Dynamic Approaches to Modelling Infrared Spectra

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Chinese Journal of Chemical Physics 2009年第2期22卷 123-128页

作者： Claude Pouchan Philippe Carbonniere Groupe chimie Théorique et Réactivité ECP IPREM UMR CNRS 5254 Université de Pau et des Pays de I'Adour 2 Rue Jules Ferry F-54000 Pau France

We present quantum mechanical vibrational computations beyond the harmonic approximation from effective second order perturbative and variation perturbation treatments defined as static approaches, as well as vibrational analysis from density functional theory molecular dynamics trajectories at 300 and 600 K. The four schemes are compared in terms of prediction of fundamental transitions, and simulation of the corresponding medium infrared spectrum at the same level of theory using the B3LYP/6-31＋G（d,p） description of the electronic structure. We summarize conclusions about advantages and drawbacks of these two approaches and report the main results obtained for semi-rigid and flexible molecules.

关键词： Anharmonic vibrations Vibrational configuration interaction Perturbative approach Ab initio molecular dynamic treatment

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Synthesis of 3″-and 4″-deoxy-Lewis^x trisaccharides:A useful tool for study of carbohydrate-carbohydrate interaction

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Science China Chemistry 2010年第9期53卷 1963-1969页

作者： GOURMALA Chafika Université Pierre et Marie Curie-Paris 6 Institut Parisien de Chimie Moléculaire

Synthesis of 3″-deoxy and 4″-deoxy Lewisx trisaccharides is *** 2,3,6-tri-O-benzoyl-4-deoxy-1-thio-β-Dxylo-hexopyranoside was condensed with a diol of glucosamine to give regio-and stereo-selectively a ***-lective fucosylation of this disaccharide provided a protected deoxy Lewisx trisaccharide which was deprotected to give the 4″-deoxy Lewisx *** of the similar synthetic sequence provided the 3″-deoxy Lewisx trisaccharide.

关键词： carbohydrate glycosylation synthesis trisaccharide.

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Synthesis of a novel uridine analogue and its use in attempts to form new cyclonucleosides using ring-closing metathesis

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Science China Chemistry 2010年第9期53卷 1932-1936页

作者： MONDON Martine LEN Christophe UMR 6514 Université de Poitiers CNRS Synthèse et Réactivité des Substances Naturelles EA4297 Université de Technologie de Compiègne UTC-Ecole Supérieure de chimie organique et Minérale ESCOM

One novel nucleoside analogue having a hex-5-enyl group and an allyl group in the 5'-C and 3-N position was synthesized regioand diastereoselectively from D-glucose in twelve *** order to reach a particular conformation of nucleosides the nucleoside formation of restricted cyclonucleoside analogues was studied via Ring-Closing Metathesis.

关键词： nucleoside restrictedconformation metathesis

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Effects of acid treatments on Moroccan Tarfaya oil shale and pyrolysis of oil shale and their kerogen

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燃料化学学报 2009年第6期37卷 659-667页

作者： ABOULKAS A El HARFI K Laboratoire de Recherche sur la Reactivites des Materiaux et IOptimisation des Procedes 《REMATOP》 Departement de chimie Faculte des Sciences Semlalia Universite Cadi Ayyad BP 2390 40001 Marrakech Maroc Laboratoire lnterdisciplinaire de Recherche en Sciences et Techniques Faculte polydisciplinaire de Beni-Mellal Universite Sultan Moulay Slimane BP 592 23000 Beni-Mellal Maroc

In this study,the kerogen of oil shale from Moroccan Tarfaya deposits was isolated and the changes in the initial organic matter during the removal of the mineral matrix were *** extraction of the oil shale increases the intensity of the peaks in the X-ray *** spectra and X-ray diffractograms reveal the presence of mineral,calcite,quartz,kaolinite,and pyrite in the mineral matrix of the oil *** and hydrofluoric acids dissolution do not alter the organic *** nonisothermal weight loss measurements indicate that thermal decomposition of the isolated kerogen can be described by first-order reaction.A single kinetic expression is valid over the temperature range of kerogen pyrolysis between 433K and ***,the results indicate that the removal of mineral matter causes a decrease in the activation energies of the pyrolysis reactions of oil shale.

关键词：页岩矿物方解石氢氟酸

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Conversion of the refractory ammonia and acetic acid in catalytic wet air oxidation of animal byproducts

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Journal of Environmental Sciences 2011年第3期23卷 520-528页

作者： Virginie Fontanier Sofiane Zalouk Stéphane Barbati Aix-Marseille Universite's-CNRS (UMR 6264)-Laboratoire de chimie Provence:quipe chimie de l'Environnement Continental-3 Place Victor Hugo (case 29)-13331 Marseille cedex 3France

Wet air oxidation （WAO） and catalytic wet air oxidation （CWAO） of slaughtered animal byproducts （ABPs） were investigated. Two step experiment was carried out consisting of a non-catalysed WAO run followed by a CWAO run at 170-275 ℃, 20 MPa, and reaction time 180 min. The WAO （lst step） of sample （5 g/L total organic carbon （TOC）） yielded （82.0 ±4）% TOC removal and （78.4 ± 13.2）% conversion of the initial organic-N into NH4＋-N. Four metal catalysts （Pd, Pt, Rh, Ru） supported over alumina have been tested in catalytic WAO （2nd step） at elevated pH to enhance ammonia conversion and organic matter removal, particularly acetic acid. It was found that the catalysts Ru, Pt, and Rh had significant effects on the TOC removal （95.1%, 99.5% and 96.7%, respectively） and on the abatement of ammonia （93.4%, 96.7% and 96.3%, respectively） with high nitrogen selectivity. The catalyst Pd was found to have the less activity while Pt had the best performance. The X-Ray diffraction analysis showed that the support of catalyst was not stable under the experimental conditions since it reacted with phosphate present in solution. Nitrite and nitrate ions were monitored during the oxidation reaction and it was concluded that CWAO of ammonia in real waste treatment framework was in good agreement with the results obtained from the literature for ideal solutions of ammonia.

关键词： wet oxidation, heterogeneous catalysis animal byproducts acetic acid ammonia, nitrite nitrate

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Keggin-type H_4PVMo_(11)O_(40)-based catalysts for the isobutane selective oxidation

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Science China Chemistry 2010年第9期53卷 2039-2046页

作者： PAUL Sébastien SULTAN Manzoor BORdeS-RICHARD Elisabeth Université Lille Nord de France ECLilleUnité de Catalyse et de Chimie du Solide(UMR CNRS 8181)Cité Scientifique Université Lille Nord de France ENSCLUnité de Catalyse et de Chimie du Solide(UMR CNRS 8181)Cité Scientifique

Cesium heteropolysalts Cs3PMo12O40 and HCs3PVMo11O40 were synthesized by modifying the preparation conditions in order to get materials with a much higher surface area than the original Keggin-type heteropolyacids(H3PMo12O40 and H4PVMo11O40).These solids were used as carriers for the dispersion of H4PVMo11O40 heteropolyacid by the incipient wetness impregnation *** textural and structural properties of supports and catalysts were examined by scanning electron microscopy,N2 adsorption-desorption isotherms and Raman *** supported catalysts were studied before and after red/ox pretreatments by X-ray photoelectron spectroscopy,which showed that both the surface composition and oxidized to reduced species ratio depend on the used *** catalytic performances of these novel supported catalysts in the selective oxidation of isobutane to methacrylic acid and methacrolein were *** best catalytic properties were obtained when H4PVMo11O40 was supported on *** isobutane conversion and yield of the desired oxygenates increased along the unsupported H4PVMo11O40

关键词： cesium heteropolysalts supports supported H4PVMo11O40 red/ox XPS isobutane selective oxidation Keggin-type heteropolycompounds

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