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Steam reforming of acetic acid over Ni/biochar of low metal-loading:Involvement of biochar in tailoring reaction intermediates renders superior catalytic performance

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Chinese Journal of Chemical Engineering 2024年第4期68卷 241-252页

作者： Yunyu Guo Yiran Wang Shu Zhang Yi Wang Song Hu Jun Xiang Walid Nabgan Xun Hu School of Material Science and Engineering University of JinanJinan 250022China Joint International Research Laboratory of Biomass Energy and Materials College of Materials Science and EngineeringNanjing Forestry UniversityNanjing 210037China State Key Laboratory of Coal Combustion Huazhong University of Science and TechnologyWuhan 430074China departament d'Enginyeria Química Universitat Rovira i VirgiliTarragona 43007Spain

Biochar is a reactive carrier as it may be partially gasified with steam in steam reforming,which could influence the formation of reaction intermediates and modify catalytic ***,the Ni/biochar as well as two comparative catalysts,Ni/Al_(2)O_(3) and Ni/SiO_(2),with low nickel loading(2%(mass))was conducted to probe involvement of the varied carriers in the steam *** results indicated that the Ni/biochar performed excellent catalytic activity than Ni/SiO_(2) and Ni/Al_(2)O_(3),as the biochar carrier facilitated quick conversion of the -OH from dissociation of steam to gasify the oxygen-rich carbonaceous intermediates like C=O and C-O-C,resulting in low coverage while high exposure of nickel species for maintaining the superior catalytic *** converse,strong adsorption of aliphatic intermediates over Ni/Al_(2)O_(3) and Ni/SiO_(2) induced serious coking with polymeric coke as the main type(21.5%and 32.1%,respectively),which was significantly higher than that over Ni/biochar(3.9%).The coke over Ni/biochar was mainly aromatic or catalytic type with nanotube morphology and high *** high resistivity of Ni/biochar towards coking was due to the balance between formation of coke and gasification of coke and partially biochar with steam,which created developed mesopores in spent Ni/biochar while the coke blocked pores in Ni/Al_(2)O_(3) and Ni/SiO_(2) catalysts.

关键词： Steam reforming Acetic acid Ni/biochar catalyst Property of coke Reaction intermediates

Optimizing magneto-ionic performance in structure/composition-engineered ternary nitrides

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Journal of Materiomics 2024年第4期10卷 870-879页

作者： Zheng Ma P.Monalisha Zhengwei Tan Eva Pellicer Maciej O.Liedke Maik Butterling Ahmed G.Attallah Eric Hirschmann Andreas Wagner Fatima Ibrahim Mairbek Chshiev Enric Menndez Jordi Sort departament de Física Universitat Autònoma de BarcelonaCerdanyola del Vallès08193Spain Institute of Radiation Physics Helmholtz-Zentrum Dresden–RossendorfDresden01328Germany University of Grenoble Alpes CEACNRSSPINTECGrenoble38000France Institut Universitaire de France Paris75231France InstitucióCatalana de Recerca i Estudis Avançats(ICREA) Pg.Lluís Companys 23Barcelona08010Spain

Magneto-ionics,an emerging approach to manipulate magnetism that relies on voltage-driven ion motion,holds the promise to boost energy efficiency in information technologies such as spintronic devices or future non-von Neumann computing *** this purpose,stability,reversibility,endurance,and ion motion rates need to be synergistically *** various ions,nitrogen has demonstrated superior magneto-ionic performance compared to classical species such as oxygen or ***,we show that ternary Co1−xFexN compound exhibits an unprecedented nitrogen magneto-ionic *** substitution of Co by Fe in binary CoN is shown to be favorable in terms of generated magnetization,cyclability and ion motion ***,the Co_(0.3)5Fe_(0.6)5N films exhibit an induced saturation magnetization of 1,500 emu/cm^(3),a magneto-ionic rate of 35.5 emu/(cm^(3)·s)and endurance exceeding 103 *** values significantly surpass those of other existing nitride and oxide *** improvement can be attributed to the larger saturation magnetization of Co_(0.35)Fe_(0.65) compared to individual Co and Fe,the nature and size of structural defects in as-grown films of different composition,and the dissimilar formation energies of Fe and Co with N in the various developed crystallographic structures.

关键词： Voltage control of magnetism Magneto-ionics Electrolyte gating Ternary nitrides Ion transport

BASKETBALL SCORING IN NBA GAMES:AN EXAMPLE OF COMPLEXITY

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Journal of Systems Science & Complexity 2013年第1期26卷 94-103页

作者： DE SA GUERRA Yves MARTíN GONZALEZ Juan Manuel SARMIENTO MONTESDEOCA Samuel RODRIGUEZ RUIZ David ARJONILLA LóPEZ Nieves GARCíA-MANSO Juan Manuel departament of Phisical Education University of Las Palmas de Gran Canaria departament of Physics University of Las Palmas de Gran Canaria

Scoring in a basketball game is a highly dynamic, non-linear process. NBA teams try to be more and more competitive each season. For instance, they incorporate into their rosters the best players in the world. This and other mechanisms concur to make the scoring process in NBA games exciting and rarely predictable. This paper is to study the behavior of timing and scoring in basketball gaines. The authors analyze all the games in five NBA regular seasons （2005-06, 2006-07, 2007-08, 2008-09, 2009-10）, for a total of 6150 games. Scoring does not behave uniformly; therefore, the authors also analyze the distributions of the differences in points in the basketball games. To further analyze the behavior of the tail of the distribution, the authors also carry out a semilog-plot and a log-log plot to verify whether this trend approaches a Poisson distribution or a PL. This paper reveals different areas of behavior related to the score, with specific instances of time that could be considered tipping points of the game. The presence of these critical points suggests that there are phase transitions where the dynamic scoring of the games varies significantly.

关键词： Complexity NBA non-linear Poisson power law.

Prognostic role of selection criteria for liver transplantation in patients with hepatocellular carcinoma:Review and bibliometric

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iLIVER 2024年第1期3卷 52-61页

作者： Pamela Scarlett Espinoza Loyola Diana Laura Muratalla Bautista Karen Adela Hernández Bautista Elizabeth Gil White JoséAntonio González Moreno Daniel Angel Torres del Real Víctor Manuel Páez Zayas Carla Escorza-Molina Fernando Mondragón Rodríguez Omar Vásquez Gómez Luis Jorge Fernández López Paul Santiago Mogrovejo Vázquez Isidoro Aczel Sánchez-Cedillo Víctor Jose Visag Castillo Social Service Internship Universidad Nacional Autónoma de MéxicoMexico City 04510Mexico Social Service Internship Universidad AnahuacMexico City 04510Mexico Department of Surgery Division of Transplantation Surgery Hospital General de MéxicoMexico City 06720Mexico departament of Gastroenterology Division of HepatologyHospital General de MéxicoMexico City 06720Mexico Departmanet of Anesthesiology Hospital General de MéxicoMexico City 06720Mexico

Hepatocellular carcinoma(HCC)is one of the most common cancers in the world and is one of the leading indications for liver transplantation,liver transplantation is the gold standard treatment for end stage liver *** is based up on radiological characteristics and rarely biopsy *** treatment must be individualized to each patient to improve recurrences and *** this article,we focus on the different selection criteria for liver *** study aimed to investigate the distribution laws and research frontiers of international literature,so as to present holistic bibliometric evaluation of the studies on 5-year survival and disease-free recurrence in 5 years,according to hepatocarcinoma criteria for liver *** paper aims to review and analyze 5-year survival and disease-free recurrence based on hepatocarcinoma criteria for liver *** systematically examines and summarizes distribution characteristics and research frontiers through bibliometric analysis.A bibliographic search was implemented in PubMed/Medline,Clinical Key,Science Direct and Index Medicus with MESH terms,from the year 1996–*** selected for transplantation using the Metroticket 2.0(MT2)criteria had the highest overall survival along with patients selected for transplantation using the Milan Criteria had the best 5-year disease-free *** Metroticket 2.0 criteria(MT2)and Milan Criteria(MC)have shown the most favorable post-transplant outcomes for patients with hepatocellular carcinoma(HCC).However,MC demonstrated the best 5-year disease-free recurrence rate,underscoring the significance of taking into account tumor morphology and biology when determining the eligibility of HCC patients for liver *** distribution characteristics and research frontiers by bibliometrics concerning prognostic role of selection criteria for liver transplantation in patients with hepatocellular carcinoma the collaboration

关键词： Hepatocellular carcinoma Liver transplantation Survival Criteria Recurrence Bibliometrics

Real Submanifolds in Complex Spaces

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Acta Mathematica Sinica,English Series 2017年第1期33卷 1-20页

作者： Valentin BURCEA The departament of Mathematics The Federal University of Santa Catarina Brazil

Let （Zll, . . . , Z1N,... , Zml,. . . , ZmN, Wll,. . . , Wmm） be the coordinates in C^mN＋m2. In this note we prove the analogue of the Theorem of Moser in the case of the real-analytic submanifold M defined as follows W=zz-t＋O（3）,where W ={wij}1≤ i,j≤ m and Z ={Zij}1≤i≤ m,1≤j≤N We prove that M is biholomorphically equiva-lent to the model W =zz-tif and only if is formally equivalent to it.

关键词： Real submanifold equivalence problem fischer decomposition

Deciphering the presence of axial-planar veins in tectonites

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Geoscience Frontiers 2019年第6期10卷 2101-2115页

作者： Elena Druguet departament de Geologia Universitat Autonoma de Barcelona

Veins and dikes are often oriented subparallel to the axial surfaces of folds in the adjacent layered or foliated *** implies an awkward situation,since veins would lay in planes close-to-parallel to the maximum stretching axis.A series of geometric models have been conceived in order to gain insight into the possible mechanisms for their *** models are based on the analysis of a varied selection of field structures and on the review of similar structures in the existing literature.A first categorization consists on distinguishing between axial-planar veins achieved by either progressive or polyphase *** models of axial-planar veins resulting from progressive deformation are described and discussed:(1) fold-related veins associated with the standard folding mechanisms,(2) fracture arrays localized along the short limbs of folds(asymmetric fold-related veins),(3) folds associated with rotation of extension veins(vein-related folds),(4) high strain and transposition of early veins,and(5) high strain and late veins parallel to axial planar foliations(axial planar foliation-related veins).The axial planar geometry is achieved through variable amounts of progressive rotational strain,except in model 5,in which the co-planarity is acquired at the time of vein *** possibility for axial-planar veins to have developed in two distinct phases in the context of polyphase or polyorogenic tectonics has also been explored and *** study contributes to a better understanding of the intriguing interplays between deformation,metamorphic and magmatic processes in orogenic belts.

关键词： Dike Fold Fracture Metamorphic rock Migmatite Shear

Combinatorial Dyson-Schwinger equations and inductive data types

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Frontiers of physics 2016年第3期11卷 179-193页

作者： Joachim Kock departament de matemhtiques Universitat Autdnoma de Barcelona Spain

The goal of this contribution is to explain the analogy between combinatorial Dyson-Schwinger equations and inductive data types to a readership of mathematical physicists. The connection relies on an interpretation of combinatorial Dyson-Schwinger equations as fixpoint equations for polynomial functors （established elsewhere by the author, and summarised here）, combined with the now-classical fact that polynomial functors provide semantics for inductive types. The paper is expository, and comprises also a brief introduction to type theory.

关键词： Dyson-Schwinger equations type theory inductive types bialgebras polynomialfunctors

True cicadas (Cicadidae) as prey for the birds of the Western Palearctic: a review

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Avian Research 2020年第2期11卷 174-182页

作者： Pere Pons departament de Ciències Ambientals Universitat de Girona

Background:True cicadas(Cicadidae)are large and temporarily abundant *** availability may produce demographic and behavioural effects on bird populations,as happens with forest avifauna feeding on periodical cicadas in North *** Europe,the Near East and North Africa,knowledge of cicada predation by birds is ***:To help fill this gap,I consulted Cramp’s Birds of the Western Palearctic,conducted a search of online databases and used search engines to generate a database of Western Palearctic birds known to eat ***:A total of 105 species(16%of those occurring in the region)belonging to 13 orders,and comprising 20 of the 33 passerine families,were found to consume cicadas.I estimated that 69 of these bird species are known to consume cicadas within the limits of the Western *** terrestrial birds predate on cicadas,preferably on *** predators include cuckoos,owls,bee-eaters,woodpeckers,falcons,reed-warblers,larks,crows and jays,buntings,shrikes,pipits and wagtails,flycatchers and chats,tits,sparrows,leaf-warblers,starlings,warblers and thrushes,but also terns and *** are consumed by some passerines,owls and *** can make up as much as 70%of food items delivered to *** of stomach contents and neck collar samples are the most common methods used in diet ***:Available knowledge is biased towards species that have been more intensively studied,and often lack proper quantification of prey *** studies about the relative importance of cicadas as prey for birds in the Western Palearctic are needed.I suggest using non-invasive studies based on pellets and droppings and prioritizing declining bird species.

关键词： Bird species Cicadidae Cramp’s handbook Diet studies Predator-prey relationships

Modified Hawking effect from generalized uncertainty principle

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Communications in Theoretical Physics 2021年第1期73卷 62-67页

作者： Jaume Giné departament de Matemàtica Universitat de LleidaCataloniaSpain

We use the generalized uncertainty principle to compute the first correction to the Hawking temperature associated to Hawking *** this value we obtain a new evaporation time and entropy of any Schwarzschild black hole... 详细信息

关键词： Hawking effect quantum fluctuations uncertainty principle