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Unravelling the role of the combined effect of metallic charge transfer channel and SiO_(x) overlayer in the Zr/Si-Fe_(2)O_(3):Au:SiO_(x) nanorod arrays to boost photoelectrochemical water splitting

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Journal of Energy Chemistry 2024年第3期90卷 370-379,I0009页

作者： Tae Sik Koh Periyasamy Anushkkaran Love Kumar Dhandole Mahadeo A.Mahadik Weon-Sik Chae Hyun Hwi Lee Sun Hee Choi Jum Suk Jang Division of Biotechnology SafetyEnvironment and Life Science InstituteCollege of Environmental and Bioresource SciencesJeonbuk National UniversityIksan 54896Republic of Korea Department of Integrative Environmental Biotechnology College of Environmental and Bioresource SciencesJeonbuk National UniversityIksan 54596Republic of Korea Extreme materials Research Center Korea Institute of Science and Technology(KIST)Seoul 02792Republic of Korea daegu Center Korea Basic Science InstituteDaegu 41566Republic of Korea Pohang Accelerator Laboratory Pohang University of Science and Technology(POSTECH)Pohang 37673Republic of Korea

Hematite(α-Fe_(2)O_(3)) based photoanodes have been extensively studied due to various intriguing features that make them viable candidates for a photoelectrochemical(PEC) water splitting ***,we propose a Zr-doped Fe_(2)O_(3) photoanode decorated with facilely spin-coated Au nanoparticles(NPs) and microwave-assisted attached Si co-doping in conjunction with a SiO_(x) overlayer that displayed a remarkable photocurrent density of 2.01 mA/cm^(2) at 1.23 V *** kinetic dynamics at the photoelectrode/-electrolyte interface was examined by employing systematic electrochemical *** Au NPs played a dual role in increasing PEC water ***,the Schottky interface that was formed between Au NPs and Zr-Fe_(2)O_(3) lectrode ensured the prevention of electron flow from the photoanode to the metal,increasing the number of available charges as well as suppressing surface charge ***,Au extracted photoholes from the bulk of the Zr-Fe_(2)O_(3) and transported them to the outer SiO_(x) overlayer,while the SiO_(x) overlayer efficiently collected the photoholes and promoted the hole injection into the ***,Si co-doping enhanced bulk conductivity by reducing bulk charge transfer resistance and improving charge carrier *** study outlines a technique to design a metallic charge transfer path with an overlayer for solar energy conversion.

关键词： Hematite Microwave attachment Au nanoparticles SiO_(x) overlayer Water splitting

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Giant negative electrocaloric effect measured by indirect method in X-ray irradiated P(VDF-TrFE)films

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Journal of Materiomics 2024年第3期10卷 624-631页

作者： Bo Li Bin Yang Hong Zhang Jiajia Zhang Qianjin Wang Weishu Liu Department of materials Science and Engineering Southern University of Science and TechnologyShenzhenGuangdong 518055China Guangdong Provincial Key Laboratory of Functional Oxide materials and Devices Southern University of Science and TechnologyShenzhenChina College of Physics and Electronic Information Yunnan Normal UniversityYunnan Kunming 650500China The Science and Technology on Reliability Physics and Application of Electronic component Laboratory China Electronic Product Reliability and Environmental Testing Research InstituteGuangzhou 510610China

Flexible solid-state cooling devices with high efficiency are attracted to ferroelectric polymers with excellent negative electrocaloric(EC)*** is challenging to obtain a large negative EC effect in ferroelectric polymers due to the lack of tunable techniques.A giant negative EC response was obtained in the poly(vinylidene fluoride-trifluoroethylene)copolymers(P(VDF-TrFE),70/30,in mole ratio)irra-diated with high-energy *** irradiated P(VDF-TrFE)films showed an adiabatic temperature change of-13.5 K at 40 MV/m under a dose of 5 Mrad(1 Mrad=10^(4) J/kg)obtained by the indirect *** significant negative EC effect is attributed to the enhancement of crystalline due to the entry of polymer molecules into the amorphous to crystalline structure and the reduction of heat ca-pacity due to the increase of *** addition,X-ray irradiation improves the dielectric coefficient from 15 to *** research indicates that irradiation can modify the negative EC properties of ferro-electric polymers for solid-state cooling.

关键词： Negative electrocaloric effects X-rays radiation P(VDF-TrFE)films

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PDOL-Based Solid Electrolyte Toward Practical Application:Opportunities and Challenges

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Nano-Micro Letters 2024年第7期16卷 109-141页

作者： Hua Yang Maoxiang Jing Li Wang Hong Xu Xiaohong Yan Xiangming He institute for Advanced materials School of Materials Science and EngineeringJiangsu UniversityZhenjiang 212013People’s Republic of China institute of Nuclear and New Energy Technology Tsinghua UniversityBeijing 100084People’s Republic of China

Polymer solid-state lithium batteries(SSLB)are regarded as a promising energy storage technology to meet growing demand due to their high energy density and *** conductivity,interface stability and battery assembly process are still the main challenges to hurdle the commercialization of *** the main component of SSLB,poly(1,3-dioxolane)(PDOL)-based solid polymer electrolytes polymerized in-situ are becoming a promising candidate solid elec-trolyte,for their high ion conductivity at room temperature,good battery elec-trochemical performances,and simple assembly *** review analyzes opportunities and challenges of PDOL electrolytes toward practical application for polymer *** focuses include exploring the polymerization mechanism of DOL,the performance of PDOL composite electrolytes,and the application of ***,we provide a perspective on future research directions that need to be emphasized for commercialization of PDOL-based electrolytes in *** exploration of these schemes facilitates a comprehensive and profound understanding of PDOL-based polymer electrolyte and provides new research ideas to boost them toward practical application in solid-state batteries.

关键词： Poly(1,3-dioxolane) Solid electrolyte Polymerization mechanism Composite electrolyte Practical application

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Unveiling the rolling texture variations ofα-Mg phases in a dual-phase Mg-Li alloy

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Journal of Magnesium and Alloys 2024年第6期12卷 2557-2568页

作者： Xiaoyan Li Luyao Jiang Fei Guo Yanlong Ma Hang Yu Qiuyu Chen Haiding Liu Dingfei Zhang College of materials Science and Engineering Chongqing University of TechnologyChongqing 400054China Chongqing materials Research institute Co. Ltd.Chongqing 400707China College of materials Science and Engineering Chongqing UniversityChongqing 400044China

LZ91 Mg-Li alloy plates with three types of initial texture were rolled by 70%reduction at both room temperature and 200℃to explore the rolling texture formation ofα-Mg *** results showed that the rolling texture is largely affected by the initial *** the samples exhibited two main texture components as RD-split double peaks texture and TD-split double peaks texture after large strain *** intensity of the two texture components was strongly influenced by the initial orientation and rolling *** twinning altered the large-split non-basal orientation to a near basal one at low rolling *** basal orientation induced by twinning is unstable,which finally transmitted to the RD-split *** strong TD-split texture formed due to slip-induced orientation transition from its initial *** competition between prismatic and basal slip determined the intensity and tilt angle of the TD-split *** increasing the rolling temperature,the TD-split texture component was enhanced in all three *** of extension twinning behavior and the promotion of prismatic slip at elevated temperature are the main reasons for the difference in hot and cold rolling texture.

关键词： Magnesium-lithium alloys Rolling texture Extension twinning Slip competition

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Phase transition of multi-component(TiZrVNb)C ceramics—Part I:Phase decomposition induced by carbon content

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Journal of Advanced Ceramics 2024年第5期13卷 679-688页

作者： Qingyi Kong Rao Zhang Lei Chen Sijia Huo Wenyu Lu Yujin Wang Boxin Wei Yu Zhou institute for Advanced Ceramics School of Materials Science and EngineeringHarbin Institute of TechnologyHarbin 150080China Key Laboratory of Advanced Structure‒Function Integrated materials and Green Manufacturing Technology Harbin Institute of TechnologyHarbin 150001China School of materials Science and Chemical Engineering Harbin University of Science and TechnologyHarbin 150001China National Key Laboratory of Precision Hot Processing of Metals Harbin Institute of TechnologyHarbin 150001China

Phase decomposition can effectively enhance the mechanical properties of carbide ceramics and can overcome the difficulty of enhancing the mechanical properties of single-phase multicomponent carbide *** this work,a series of nonstoichiometric(TiZrVNb)Cx ceramics were prepared by spark plasma sintering(SPS)at different *** effects of the carbon content on the phase composition,microstructure evolution,and mechanical properties were investigated in *** decomposition occurred with decreasing carbon *** different solid solutions of(Ti,V)-rich and Zr-rich phases formed from the decomposition of equimolar single-phase solid solutions,namely,the Zr-poor phase and Zr-rich phase,*** distribution of Nb element is relatively *** semicoherent interfaces between the Zr-poor phase and the Zr-rich phase can harden and strengthen effectively under the synergistic effect of grain *** with phase decomposition structures have apparent advantages compared to single-phase high-entropy *** work provides an important train of thought for the microstructure tailoring and properties optimization of multi-component carbide ceramics.

关键词： multicomponent ceramics nontoichiometry microstructure evolution phase decomposition mechanical properties

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A review:(Bi,Na)TiO_(3)(BNT)-based energy storage ceramics

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Journal of Materiomics 2024年第1期10卷 86-123页

作者： Wen Zhu Zong-Yang Shen Wei Deng Kai Li Wenqin Luo Fusheng Song Xiaojun Zeng Zhumei Wang Yueming Li Advanced Ceramic materials Research institute China National Light Industry Key Laboratory of Functional Ceramic MaterialsEnergy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi ProvinceSchool of Materials Science and EngineeringJingdezhen Ceramic UniversityJingdezhen333403China

Facing the increasingly serious energy and environmental problems,the research and development of new energy storage technology and environment-friendly energy storage materials are *** a typical lead-free ferroelectric with excellent dielectric properties,(Bi,Na)TiO_(3)(BNT)is supposed to be the most potential and competitive environment-friendly ceramic material and has become a research hotspot for dielectric energy storage in recent *** paper first briefly introduces the basic physical principles and energy storage performance evaluation parameters of dielectric energy storage materials,then summarizes the critical research systems and related progress of BNT-based lead-free energy storage materials(bulk ceramics,films and multilayer ceramics)from the aspects of ions doping modification and multi-component composite optimization,and finally looks forward to the improvement direction and energy storage application prospect of BNT-based lead-free relaxor ferroelectric materials.

关键词： Dielectrics Relaxor ferroelectrics Energy storage ceramics Sodium bismuth titanate Lead free

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Phase transition of multi-component(TiZrVNb)C ceramics—Part II:From single phase to multiple phases via adjusting V content

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Journal of Advanced Ceramics 2024年第5期13卷 689-698页

作者： Qingyi Kong Lei Chen Sijia Huo Kunxuan Li Wenyu Lu Yujin Wang Yu Zhou institute for Advanced Ceramics School of Materials Science and EngineeringHarbin Institute of TechnologyHarbin 150080China Key Laboratory of Advanced Structure‒Function Integrated materials and Green Manufacturing Technology Harbin Institute of TechnologyHarbin 150001China National Key Laboratory of Precision Hot Processing of Metals Harbin Institute of TechnologyHarbin 150001China

To address the relatively mediocre mechanical properties of single-phase multi-component carbide ceramics,a phase transition from a single phase to multiple phases was proposed to achieve superior mechanical properties.A series of(TiZrV_(x)Nb)C_(0.8) ceramics with different V contents were fabricated by spark plasma sintering(SPS).The influence of the V content on the phase composition,microstructural evolution,and mechanical properties was investigated in *** transition behavior from a single phase to multiple phases is discovered and *** formation of the Zr-rich phase and Zr-poor phase can be attributed to the increase in lattice distortion and mixed enthalpy caused by the addition of V.A nanometer lamellar structure with a semi-coherent interface obtained via in situ decomposition is reported for the first time in multi-component carbide *** semi-coherent interfaces with high dislocation density and strain concentration effectively improve the mechanical properties,grain refinement,and multi-phase *** optimal comprehensive mechanical properties of the Vickers hardness(26.3 GPa),flexural strength(369 MPa),and fracture toughness(3.1 MPa·m^(1/2))were achieved for the sample with 20 mol%V.

关键词： multi-component ceramics multiple phases microstructure evolution phase decomposition mechanical properties

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Structural stability estimation of whirling unit

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中国有色金属学会会刊：英文版 2009年第B9期19卷 202-208页

作者： Son-Jae HWAN Han-Chang WOO Lee-Sang RYONG Lee-Young MOON daegu machinery institute of component & materials foundation Department of Automobile Yeungnam College of Science & Technology Department of Mechanical Engineering Kyung pook National University

Whirling is a cutting process in which a series of cutting edges on whirling ring remove material by turning over a rotating workpiece. In this study static and dynamic stability of whirling unit was estimated by using ADAMS and NASTRAN softwares. Each maximum force acting on the bearing attached to the spindle assembly and the cutting tool attached to the whirling ring with the rotating speed of 6 000 r/min was 235 N and 902 N respectively. The maximum stress of 0.74 MPa on the base frame is far smaller than the yield strength of 282 MPa. The calculated natural frequency of 148 Hz of the system is far from the frequency of the driving speed of 6 000 r/min. The experimentally obtained maximum cutting force of 792 N is smaller than that of calculated value. And the experimentally obtained natural frequency of 118 Hz is beyond the driving speed of 6000 r/min. From above results it can be judged that the whirling system is statically and dynamically stable.

关键词：旋转工件稳定性评价 NASTRAN软件动态稳定性结构单元固有频率行车速度

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Facile access to C-N bonds via unexpected side reactions of Knoevenagel condensation and their application in high-efficiency organic solar cells

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Science China Chemistry 2024年第1期67卷 323-329页

作者： Daobin Yang Shuncheng Yang Hongqian Wang Lin Xie Pengyu Yan Ziyi Ge Zhejiang Engineering Research Center for Energy Optoelectronic materials and Devices Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China School of materials Science and Chemical Engineering Ningbo UniversityNingbo 315211China Center of materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

The construction of C-N bonds is of great importance in the fields of biology,medicine,chemistry and materials ***,the replacement of organic base from pyridine to piperidine in the Knoevenagel condensation process unexpectedly yields a series of novel organic molecules containing C-N ***,the synthesis method does not require any external transition-metals catalysis,and photo-/***,when the new compound 1b is added as a third component to a well-known binary system of PM6:Y6,the efficiency of the organic solar cell is significantly improved,resulting in an outstanding efficiency of 18.0%,which is one of the highest values reported to date for PM6:Y6-based ternary organic solar cells.

关键词： C-N bonds Knoevenagel condensation cross-coupling reaction third component organic solar cells

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Phase-engineering modulation of Mn-based oxide cathode for constructing super-stable sodium storage

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Journal of Energy Chemistry 2024年第1期88卷 421-427,I0010页

作者： Quanqing Zhao Ruru Wang Ming Gao Bolin Liu Jianfeng Jia Haishun Wu Youqi Zhu Chuanbao Cao Key Laboratory of Magnetic Molecules and Magnetic Information materials of Ministry of Education School of Chemistry and Materials ScienceShanxi Normal UniversityTaiyuan 030032ShanxiChina Metals and Chemistry Research institute China Academy of Railway Sciences Corporation LimitedBeijing 100081China Research Center of materials Science Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green ApplicationsBeijing Institute of TechnologyBeijing 100081China

The Mn-based oxide cathode with enriched crystal phase structure and component diversity can provide the excellent chemistry structure for Na-ion ***,the broad application prospect is obstructed by the sluggish Na^(+)kinetics and the phase transitions upon ***,we establish the thermodynamically stable phase diagram of various Mn-based oxide composites precisely controlled by sodium content tailoring strategy coupling with co-doping and solid-state *** chemical environment of the P2/P'3 and P2/P3 biphasic composites indicate that the charge compensation mechanism stems from the cooperative contribution of anions and *** from the no phase transition to scavenge the structure strain,P2/P'3 electrode can deliver long cycling stability(capacity retention of 73.8%after 1000 cycles at 10 C)and outstanding rate properties(the discharge capacity of 84.08 mA h g^(-1)at 20 C)than P2/P3 ***,the DFT calculation demonstrates that the introducing novel P'3 phase can significantly regulate the Na^(+)reaction dynamics and modify the local electron configuration of *** effective phase engineering can provide a reference for designing other high-performance electrode materials for Na-ion batteries.

关键词： Sodium ion battery Oxide cathode Phase engineering Phase diagram Na~+kinetic

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