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Journal of Rare Earths 2024年第6期42卷 1182-1186,I0007页

作者： Dongwei Zhang Wenli Lu Minglei Xu Dehong Chen Xiaowei Zhang Chuang Yu Wensheng Yang Ruifeng Dong Zhiqiang Wang Liguo Han Zengdong Pang GRIREM Hi-Tech co. Ltd.Langfang065201China National Engineering Research Center for Rare Earth China GRINM Group Co.Ltd.Beijing100088China GRIREM Advanced Materials co. Ltd.Beijing100088China

In light of the difficult removal of harmful impurity tungsten(W)in Ce metal,in this paper a co.bined vacuum gravity sedimentation-directional solidification method was innovatively designed and the W separation behavior was *** reducing the electron beam power instantly and gradually at reduction rates of 1,3 and 5 kW/min,it is found that W is enriched at the bottom of ingots as the melt *** enrichment effect is much better than that of single purification method and the enrichment degree increases as the beam reduction rate decreases,attributed to the k0(W)>1 andρ(W)>ρ(Ce).Overall,the minimum co.tent of W impurity can decrease from 630 to 0.1 ppm at the top of the ingot,and the purity of Ce increases from 99.932 wt%to 99.995 wt%by this co.bined ***,this paper provides a new method for the removal of high density and low evaporation co.fficient impurities in low vapor pressure rare earth metals.

关键词： Cerium Electron beam melting Directional solidification Gravity sedimentation Rare earths

Understanding the co.bustion behavior of electric bicycle batteries and unveiling its relationship with fire extinguishing

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Journal of Energy Chemistry 2024年第4期91卷 609-618页

作者： Zhanglong Yu Xueling Shen Ran Xu Zheng Wang Zengming Wan Mingyang Chen Yi Cui Yanyan Fang Xiaoli Ma China Automotive Battery Research Institute co. Ltd.Beijing 101407China China Grinm Group co. Ltd.Beijing 100088China Ministry of Industry and Information Technology Equipment Industry Development CenterBeijing 100846China Hefei Guoxuan High-tech Power energy co. Ltd.Hefei 230000AnhuiChina

In this study,a detailed analysis of the co.bustion behaviors of the lithium iron phosphate(LFP)and lithium manganese oxide(LMO)batteries used in electric bicycles was *** research included quantitative measurements of the co.bustion duration,flame height,co.bustion temperature,heat release rate,and total heat *** results indicated that LMO batteries exhibited higher co.bustion temperatures of 600–700°C,flame heights of 70–75 cm,a significantly higher heat release rate of40.1 k W(12 Ah),and a total heat release of 1.04 MJ(12 Ah)co.pared to LFP batteries with the same *** on these experimental results,a normalized total heat release(NORTHR)parameter was proposed,demonstrating good universality for batteries with different *** this parameter,quantitative calculations and optimization of the extinguishing agent dosage were co.ducted for fires involving these two types of batteries,and the method was validated by extinguishing fires for these two types of battery packs with water-based extinguishing fluids.

关键词： co.bustion behavior Electric bicycle Lithium-ion battery Fire extinguishing Normalized total heat release

co.stitutive model of visco.lastic dynamic damage for the material of gas obturator in modular-charge howitzer

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Defence Technology（防务技术） 2024年第9期39卷 203-216页

作者： Zhonggang Li Longmiao Chen Yifan Li Yufeng Jia Quan Zhang School of Mechanical Engineering Nanjing University of Science and TechnologyNanjing 210094China Technology Center Shanxi North Machine-building Co.Ltd.Taiyuan 030009China Research and development Department Kelong New Material Technology Co.Ltd.Xianyang 712000China

In order to investigate the mechanical response behavior of the gas obturator of the breech mechanism,made of polychloroprene rubber(PCR), uniaxial co.pression experiments were carried out by using a universal testing machine and a split Hopkinson pressure bar(SHPB), obtaining stress-strain responses at different temperatures and strain rates. The results revealed that, in co.parison to other polymers, the gas obturator material exhibited inco.spicuous strain softening and hardening effects;meanwhile, the mechanical response was more affected by the strain rate than by temperature. Subsequently, a succinct visco.lastic damage co.stitutive model was developed based on the ZWT model, including ten undetermined parameters, formulated with inco.porating three parallel co.ponents to capture the visco.lastic response at high strain rate and further enhanced by integrating a three-parameter Weibull function to describe the damage. co.pared to the ZWT model, the modified model co.ld effectively describe the mechanical response behavior of the gas obturator material at high strain rates. This research laid a theoretical foundation for further investigation into the influence of chamber sealing issues on artillery firing.

关键词： Breech mechanism Gas obturator Polychloroprene rubber co.stitutive model Strain rate Damage

Solidification behaviour and hot cracking susceptibility of a novel Ni-based superalloy

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Journal of Iron and Steel Research International 2024年第4期31卷 956-966页

作者： Yue Chen Shao-min Lv Xing-fei Xie Xiao-can Wen Jng-long Qu Jin-hui Du High-Temperature Materials Institute China Iron and Steel Research Institute Group Co.Ltd.Beijing 100081China Beijing GAONA Materials and Technology co. Ltd.Beijing 100081China Sichuan CISRI-GAONA Forging co. Ltd.Deyang 610000SichuanChina

A novel Ni-based superalloy GH4151,with a γ′ volume fraction of about 55%and a service temperature capability up to 8oo oC,was *** to the different co.ling co.ditions of various regions during the solidification of ingots,significant co.ling rate variations may lead to the occurrence of hot *** scanning laser microsco.e was utilised to investigate the solidification process and phase precipitation behaviour of the GH4151 under wide range co.ling *** characteristics of L→γ transformation were analysed,and the growth rates of at each stage were *** segregation behaviour was predicted using the Scheil equation,and the predicted results match well with the experimental *** sensitivity co.fficient for hot cracking was modified,and cracking sensitivity co.fficient values for the alloy under different co.ling rates were co.puted,revealing that the alloy is most susceptible to hot cracking at 10℃/min co.ling ***,co.trolling the co.ling rate can reduce the possibility of hot cracking in ingot.

关键词： Ni-based superalloy Solidification behaviour In-situ observation Clyne and Davies's criterion:Hot cracking susceptibility

Occurrence and vertical distribution of aluminum and rare earths in weathered crust elution-deposited rare earth ore:Effect of soil solution pH and clay minerals

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Journal of Rare Earths 2024年第7期42卷 1394-1402,I0007页

作者： Jiaxin Pan Longsheng Zhao Zheng Li Xiaowei Huang Zongyu Feng Jun Chen National Engineering Research Center for Rare Earth China GRINM Group Co.Ltd.Beijing100088China School of Metallurgical and Eco.ogical Engineering University of Science and Technology Beijing(USTB)Beijing100083China GRIREM Hi–Tech co. Ltd.Langfang065201China GRIREM Advanced Materials co. Ltd.Beijing100088China GRIMAT Engineering Institute co. Ltd.Beijing101407China

Weathered crust elution-deposited rare earth ore is crucial source of medium and heavy rare earths,with in-situ leaching being the most co.mon mining *** high co.tents of impurity of aluminum in the leach solution are a significant challenge for the subsequent enrichment process of rare earths.A co.prehensive understanding of the occurrences and vertical distribution of aluminum and rare earths within typical vertical profiles can provide valuable insights into entire design of the in-situ *** paper improves a five-step sequential extraction method to analyze the occurrence and vertical distribution of rare earths and aluminum in vertical profiles from Chongzuo and *** results demonstrate that soil solution pH is the main factor affecting the vertical distribution of ionexchangeable rare *** samples have distinct areas of enrichment for ion-exchangeable rare earths or ***-exchangeable rare earths are primary co.centrated in the middle and lower parts of the ore layer(4-13 m in Chongzuo,14-22 m in Longyan),while the ion-exchangeable aluminum is mainly enriched in the upper part of the ore layer(1-5 m in Chongzuo,and 2-14 m in Longyan).The vertical distribution of inorganic hydroxy aluminum is likely influenced by the micromorphology and particle size of the clay *** inorganic hydroxy aluminum co.centration in Chongzuo samples decreases co.tinuously from 415.65 to 120.95 mg/kg with increasing sampling depth,whereas the co.centration in Longyan samples(110.55-171.27 mg/kg)is almost independence with sampling *** results provide direct guidance for the entire design of the injection well depth and the leaching parameters,thereby inhibiting the leaching of impurity of aluminum and lower the co.sumption of leaching agent.

关键词： Weathered crust elution-deposited rare earth ore Sequential extraction Occurrence Aluminum Rare earth elements

A Two-co.or Single-molecule Sequencing Platform and Its Clinical Applications

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Genomics, Proteomics & Bioinformatics 2024年第1期22卷 169-175页

作者： Fang Chen Bin Liu Meirong Chen Zefei Jiang Zhiliang Zhou Ping Wu Meng Zhang Huan Jin Linsen Li Liuyan Lu Huan Shang Lei Liu Weiyue Chen Jianfeng Xu Ruitao Sun Guangming Wang Jiao Zheng Jifang Qi Bo Yang Lidong Zeng Yan Li Hui Lv Nannan Zhao Wen Wang Jinsen Cai Yongfeng Liu Weiwei Luo Juan Zhang Yanhua Zhang Jicai Fan Haitao Dan Xuesen He Wei Huang Lei Sun Qin Yan GeneMind Biosciences co. Ltd.Shenzhen 518000China

DNA sequencers have beco.e increasingly important research and diagnostic tools over the past 20 *** this study,we developed a single-molecule desktop sequencer,GenoCare 1600(GenoCare),which utilizes amplification-free library preparation and two-co.or sequencing-by-synthesis chemistry,making it more user-friendly co.pared with previous single-molecule sequencing platforms for clinical *** the GenoCare platform,we sequenced an Escherichia co.i standard sample and achieved a co.sensus accuracy exceeding 99.99%.We also evaluated the sequencing performance of this platform in microbial mixtures and co.onavirus disease 2019(co.ID-19)samples from throat *** findings indicate that the GenoCare platform allows for microbial quantitation,sensitive identification of the severe acute respiratory syndrome co.onavirus 2(SARS-co.-2)virus,and accurate detection of virus mutations,as co.firmed by Sanger sequencing,demonstrating its remarkable potential in clinical application.

关键词： GenoCare Single-molecule sequencing SARS-co.-2 Microbial quantitation Variant detection

Current status and development of CMOS SiPM for scintillator-based radiation detectors toward all-digital sensors[Invited]

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Chinese Optics Letters 2024年第2期22卷 17-27页

作者： Nico.a D'Ascenzo 胡文韬劳慧华越轩张博房磊奚道明郑睿邱奥 Emanuele Antonecchia 凌怡清刘雨晴李琰俞航肖鹏谢庆国 Wuhan National Laboratory for Optoelectronics Wuhan 430074China Biomedical Engineering Department Huazhong University of Science and TechnologyWuhan 430074China RAYQUANT Technology co. Ltd.Ezhou 436044China RAYSOLUTION Healthcare co. Ltd.Hefei 230000China RAYMEASURE Technology co. Ltd.Suzhou 215000China RAYCAN Technology co. Ltd.Suzhou 215000China co.lege of co.puter Science and Software Engineering Shenzhen UniversityShenzhen 518060China

Modern scintillator-based radiation detectors require silico. photomultipliers(Si PMs)with photon detection efficiency higher than 40%at 420 nm,possibly extended to the vacuum ultraviolet(VUV)region,single-photon time resolution(SPTR)co.nt rate(DCR)co.centrations at low CMOS scales,deep-level carrier generation in shallow trench isolation fabrication,and power co.sumption,among *** advances at 350 and 110 nm CMOS nodes are benchmarked against available Si PMs obtained in CMOS and co.mercial customized *** co.cept of digital multithreshold Si PMs with a single microcell readout is finally reported,proposing a possible direction toward fully digital scintillator-based radiation detectors.

关键词： silico. photomultiplier co.plementary metal-oxide semico.ductor digital SiPM

Atomistic mechanism of high ionic co.ductivity in lithium ytterbium-based halide solid electrolytes:A first-principles study

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Journal of Rare Earths 2024年第1期42卷 155-162,I0006页

作者： Limin Wang Wei Xiao Lu Sun Rong Yang Jinqiu Yu Ligen Wang State Key Laboratory of Nonferrous Metals and Processes China GRINM Group Co.Ltd.Beijing100088China GRIMAT Engineering Institute co. Ltd.Beijing101407China General Research Institute for Nonferrous Metals Beijing100088China China Automotive Battery Research Institute co. Ltd.Beijing101407China Rare Earth Functional Materials(Xiong'an)Innovation Center co. Ltd.Xiong'an071700China

As the next generation of co.mercial automotive power batteries begins replacing liquid lithium batteries,many look towards all-solid-state batteries to pioneer the ***-so lid-state batteries have attracted the attention of co.ntless researchers around the world because of their high safety and high energy *** recent times,halide solid-state electrolytes have beco.e a research hotspot within solid-state electrolytes because of their potentially superior *** this paper,in the framework of DFT,we investigated the atomic mechanisms of improving the ionic co.ductivity and stability of Li_(3)YbCl_(6).Our calculations show that both trigonal and orthorhombic Li_(3)YbCl_(6) exhibit wide electrochemical windows and metastable properties(100 meV/atom>Ehull>0 meV/atom).However,the orthorhombic Li_(3)YbCl_(6) can be stabilized at high temperatures by taking the vibrational entropy into acco.nt,which is supported by the experimental ***,it is expected that because of the Yb/Li synergistic interactions that,due to their strong mutual co.lomb repulsion,influence the Li^(+)transport behavior,the orthorhombic Li_(3)YbCl_(6) might have superior ionic co.ductivities with appropriate Li+migration paths determined by the Yb^(3+) ***,higher ionic co.ductivities can be obtained by regulating the random distribution of Li^(+) *** Li^(+)-deficiency can also largely increase the ionic co.ductivity by invoking *** study helps gain a deeper understanding of the laws that govern ionic co.ductivities and stabilities and provides a certain theoretical reference for the experimental development and design of halide solid-state electrolytes.

关键词： Halide solid-state electrolytes Phase stability Ionic co.ductivity First-principles calculations Rare earths

An Image Fingerprint and Attention Mechanism Based Load Estimation Algorithm for Electric Power System

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co.puter Modeling in Engineering & Sciences 2024年第7期140卷 577-591页

作者： Qing Zhu Linlin Gu Huijie Lin Electricity Technology Branch Nari Technology Co.Ltd.Nanjing211106China NARI-TECH Nanjing co.trol Systems co. Ltd.Nanjing211106China

With the rapid development of electric power systems,load estimation plays an important role in system operation and ***,load estimation techniques co.tain traditional,time series,regression analysis-based,and machine learning-based *** the machine learning-based method can lead to better performance,in this paper,a deep learning-based load estimation algorithm using image fingerprint and attention mechanism is ***,an image fingerprint co.struction is proposed for training *** the data preprocessing,the training data matrix is co.structed by the cyclic shift and cubic spline ***,the linear mapping and the gray-co.or transformation method are proposed to form the co.or image ***,a co.volutional neural network(CNN)co.bined with an attentionmechanism is proposed for training performance *** last,an experiment is carried out to evaluate the estimation *** with the support vector machine method,CNN method and long short-term memory method,the proposed algorithm has the best load estimation performance.

关键词： Load estimation deep learning attention mechanism image fingerprint co.struction

A Gel-Based Solidification Technology for Large Fracture Plugging

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Fluid Dynamics & Materials Processing 2024年第3期20卷 563-578页

作者： Kunjian Wang Ruibin He Qianhua Liao Kun Xu Wen Wang Kan Chen Tianjin Branch of CNOOC(China)co. Ltd.Tianjin300450China Jingzhou Jiahua Technology co. Ltd.Jingzhou434001China

Fault fractures usually have large openings and co.siderable extension. Acco.dingly, cross-linked gel materials aregenerally co.sidered more suitable plugging agents than water-based gels because the latter often undergo co.taminationvia formation water, which prevents them from being effective over long times. Hence, in this study, aset of oil-based co.posite gels based on waste grease and epoxy resin has been developed. These materials havebeen observed to possess high co.pressive strength and resistance to the aforementioned co.tamination, therebyleading to notable increase in plugging success rate. The co.pressive strength, thickening time, and resistance toformation water pollution of these gels have been evaluated indoors. The results show that the co.pressivestrength of the gel can reach 11 MPa;additionally, the related gelation time can be co.trolled to be more than3 h, thereby providing a safe co.struction time;Invasion of formation water has a small effect on the gel strengthand does not shorten the thickening time. All co.sidered performance indicators of the oil-based gel co.firm itssuitability as a plugging agent for fault fractures.

关键词： Drilling loss fault fracture oil-based gel co.pressive strength gel plugging