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A dopant-assisted iodide-adduct chemical ionization time-of-flight mass spectrometer based on VUV lamp photoionization for atmospheric low-molecular-weight organic acids analysis

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Journal of Environmental Sciences 2025年第3期149卷 500-511页

作者： Yonglei Zhang Ruidong Liu Mei Li Yingzhe Guo Jichuang Kong Keyong Hou Environment research institute Shandong UniversityQingdao 266237China

Formic and acetic acids are the most abundant gaseous organic acids and play the key role in the atmospheric *** iodine-adduct chemical ionizationmass spectrometry(CIMS),the low utilization efficiency of methyl iodide and humidity interference are two major issues of the vacuum ultraviolet(VUV)lamp initiated CIMS for on-line gaseous formic and acetic acids *** this work,we present a new CIMS based on VUV lamp,and the ion-molecular reactor is separated into photoionization and chemical ionization zones by a reducer *** was added to the photoionization zone,and the VUV photoionization acetone provided low-energy electrons for methyl iodide to generate I−,and the addition of acetone reduced the amount of methyl iodide by 2/*** the chemical ionization zone,a headspace vial containing ultrapure water was added for humidity calibration,and the vial changes the sensitivity as a function of humidity from ambiguity to well linear correlation(R2>0.95).With humidity calibration,the CIMS can quantitatively measure formic and acetic acids in the humidity range of 0%-88%*** this mode,limits of detection of 10 and 50 pptv are obtained for formic and acetic acids,*** the relative standard deviation(RSD)of quantitation stability for 6 days were less than 10.5%.This CIMS was successfully used to determine the formic and acetic acids in the underground parking and ambient environment of the Shandong University campus(Qingdao,China).In addition,we developed a simple model based formic acid concentration to assess vehicular emissions.

关键词： Formic acid Acetic acid Vacuum ultraviolet(VUV)lamp photoionization(PI) Chemical ionization(CI) Time-of-flight mass spectrometry (TOFMS) Trace gases measurement

DDoS Attack Tracking Using Multi-Round Iterative Viterbi Algorithm in Satellite Internet

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China Communications 2025年第03期 148-163页

作者： Guo Wei Xu Jin Pei Yukui Yin Liuguo Feng Wei Department of Electronic Engineering Tsinghua University China Telecom cybersecurity Technology Co. Ltd Operation Center of Network Security Products China Telecom Co. Ltd. Beijing National research Center for Information Science and Technology research institute of Tsinghua Pearl River Delta

Satellite Internet(SI) provides broadband access as a critical information infrastructure in ***, with the integration of the terrestrial Internet, the influx of massive terrestrial traffic will bring significant threats to SI, among which DDoS attack will intensify the erosion of limited bandwidth resources. Therefore, this paper proposes a DDoS attack tracking scheme using a multi-round iterative Viterbi algorithm to achieve high-accuracy attack path reconstruction and fast internal source locking, protecting SI from the source. Firstly, to reduce communication overhead, the logarithmic representation of the traffic volume is added to the digests after modeling SI, generating the lightweight deviation degree to construct the observation probability matrix for the Viterbi algorithm. Secondly, the path node matrix is expanded to multi-index matrices in the Viterbi algorithm to store index information for all probability values, deriving the path with non-repeatability and maximum probability. Finally, multiple rounds of iterative Viterbi tracking are performed locally to track DDoS attack based on trimming tracking results. Simulation and experimental results show that the scheme can achieve 96.8% tracking accuracy of external and internal DDo S attack at 2.5 seconds, with the communication overhead at 268KB/s, effectively protecting the limited bandwidth resources of SI.

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LEGF-DST:LLMs-Enhanced Graph-Fusion Dual-Stream Transformer for Fine-Grained Chinese Malicious SMS Detection

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Computers, Materials & Continua 2025年第2期82卷 1901-1924页

作者： Xin Tong Jingya Wang Ying Yang Tian Peng Hanming Zhai Guangming Ling School of Information and cybersecurity People’s Public Security University of ChinaBeijing100038China Cyber Investigation Technology research and Development Center The Third Research Institute of the Ministry of Public SecurityShanghai201204China Department of cybersecurity Defense Beijing Police CollegeBeijing102202China School of Computer Science Henan Institute of EngineeringZhengzhou451191China

With the widespread use of SMS(Short Message Service),the proliferation of malicious SMS has emerged as a pressing societal *** deep learning-based text classifiers offer promise,they often exhibit suboptimal performance in fine-grained detection tasks,primarily due to imbalanced datasets and insufficient model representation *** address this challenge,this paper proposes an LLMs-enhanced graph fusion dual-stream Transformer model for fine-grained Chinese malicious SMS *** the data processing stage,Large Language Models(LLMs)are employed for data augmentation,mitigating dataset *** the data input stage,both word-level and character-level features are utilized as model inputs,enhancing the richness of features and preventing information loss.A dual-stream Transformer serves as the backbone network in the learning representation stage,complemented by a graph-based feature fusion *** the output stage,both supervised classification cross-entropy loss and supervised contrastive learning loss are used as multi-task optimization objectives,further enhancing the model’s feature *** results demonstrate that the proposed method significantly outperforms baselines on a publicly available Chinese malicious SMS dataset.

关键词： Transformers malicious SMS multi-task learning large language models

Design and Application of Turbine Cascade Partitioned Endwall Profiling

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Journal of Thermal Science 2025年第1期34卷 110-128页

作者： ZENG Fei JIANG Ruiqi XUE Xingxu DU Wei LUO Lei ZHOU Xun AECC Hunan Aviation Powerplant research institute Zhuzhou 412002China School of Energy Science and Technology Harbin Institute of TechnologyHarbin 150001China Science and Technology on Diesel Engine Turbocharging Laboratory China North Engine Research InstituteTianjin 300270China

The influence of partitioned profiling design based on a large-pitch highly loaded cascade is studied by numerical *** partitioned profile is mainly composed of a pressure-side convex structure near the leading edge and a suction-side convex structure at the midstream and downstream sides of the *** influence of the change in the vertex axial position and peak value of the B-line on the secondary flow control is *** this paper,air(ideal gas)is selected as the flow *** average static pressure at the outlet and the average total temperature at the inlet are kept *** γ-θ is used as the turbulence *** results show that the pressure-side convex structure suppresses the spanwise and pitchwise migration of the inlet flow by adjusting the static pressure distribution of the flow field,so the development of the pressure-side leg of the horseshoe vortex is effectively *** suction-side convex structure adjusts the static pressure distribution of the flow field and increases the included angle between the cross-flow and suction surface,so the accumulation of low-momentum fluid,the development of a corner vortex and the flow separation at the trailing edge of the suction-side surface are all suppressed near the endwall-suction ***,the energy loss coefficient of the large-pitch highly loaded cascade is decreased from 0.0564 to 0.0485,representing a 25% reduction in secondary flow losses.

关键词： large-pitch highly loaded cascade highly loaded design non-axisymmetrical endwall design secondary flow control partitioned endwall profiling

Tackling the microlensing wave effects of strong lensing gravitational waves with TAAH

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Science China(Physics,Mechanics & Astronomy) 2025年第1期68卷 253-254页

作者： Zuhui Fan South-Western institute for Astronomy research Yunnan UniversityKunming 650500China

The rapid development of gravitational wave(GW) observations since their first detection in 2015 [1] has opened a completely new window for exploring the Universe. Consequently, astronomical research has entered the multimessenger era, allowing us to use different tracers to view the cosmos from various perspectives. Among others, the appealing application of gravitational wave events from compact binary mergers is that they can act as standard sirens to determine absolute cosmic distances entirely independent of standard candles. This approach is one of the most promising means to solve the current H0tension problem.

关键词： problem. app wave

Higher abundance of DLD protein in buffalobull spermatozoa causes elevated ROSproduction leading to early sperm capacitationand reduction in fertilizing ability

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Journal of Animal Science and Biotechnology 2025年第1期16卷 107-120页

作者： Seema Karanwal Ankit Pal Fanny Josan Aditya Patel Jatinder Singh Chera Sonam Yadav Vikrant Gaur Preeti Verma Shiva Badrhan Vitika Chauhan Mukesh Bhakat Tirtha Kumar Datta Rakesh Kumar Animal Genomics Laboratory Animal Biotechnology DivisionICAR-National Dairy Research InstituteKarnalHaryanaIndia NBGC Laboratory National Bureau of Animal Genetics ResourcesKarnalHaryanaIndia Artificial Breeding research Centre LPM DivisionICAR-National Dairy Research InstituteKarnalHaryanaIndia ICAR-Central institute of research On Goat MakhdoomMathuraUttar PradeshIndia ICAR-Central institute for research On Buffaloes HisarHaryanaIndia

Backgroud Before fertilization,spermatozoa undergo a crucial maturation step called capacitation,which is a unique event regulates the sperm’s ability for successful *** capacitation process takes place as the spermatozoa pass through the female reproductive tract(FRT).Dihydrolipoamide dehydrogenase(DLD)protein is a post-pyruvate metabolic enzyme,exhibiting reactive oxygen species(ROS)production which causes ***,other vital functions of DLD in buffalo spermatozoa are hyperactivation and acrosome *** produces the optimum amount of ROS required to induce capacitation process in *** on physiological or patho-physiological conditions,DLD can either enhance or attenuate the production of reactive oxygen species(ROS).Aim of this study was to investigate whether changes in the production of ROS in sperm cells can impact their ability to fertilize by triggering the capacitation and acrosome *** In this study,abundance of DLD protein was quantified between high(n=5)and low fertile bull(n=5)*** was found that compared to high-fertile(HF)bulls,low-fertile(LF)bulls exhibited significantly(P<0.05)higher DLD ***,we optimised the MICA concentration to inhibit DLD function,spermatozoa were treated with MICA in time(0,1,2,3,4,and 5 h)and concentrations(1,2.5,5,and 10 mmol/L)dependent *** DLD inhibition was found to be at 4 h in 10 mmol/L MICA concentration,which was used for further exper-imentation in HF and *** on DLD inhibition it was seen that LF bull spermatozoa exhibited significantly(P<0.05)higher ROS production and acrosome reaction in comparison to the HF bull *** kinematic parameters of the spermatozoa such as percent total motility,velocity parameters(VCL,VSL,and VAP)and other parameters(BCF,STR,and LIN)were also decreased in MICA treated spermatozoa in comparison to the control(capacitated)*** The present study provides an initial

关键词： Acrosome reaction Capacitation High fertile bull Low fertile bull Protein Reactive oxygen species Spermatozoa

Site-specific patterns of fine root biomass formation across European coniferous forests

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Forest Ecosystems 2025年第1期12卷 104-111页

作者： Yury Karpechko Anna Karpechko Andrej Tuyunen Forest research institute of the Karelian research Centre of the Russian Academy of Sciences 11 Pushkinskaya StPetrozavodskKarelia185910Russia

Fine roots play a crucial role in the biogeochemical cycles of terrestrial *** of fine roots biomass formation for broad geographical areas are still *** use published estimates of characteristics of European pine and spruce stands to determine their productivity and calculate the needle ***,the relationship between the fine-root:needle biomass ratio of European pine and spruce forests and the stand quality index,which is a proxy of soil fertility,was *** show that a rise in soil fertility is accompanied by a decrease in this *** from the northern edge of the boreal zone southwards,with the related rise in air and soil temperatures,we see a decline in the mass ratio of fine roots and *** change in the fine-root:needle biomass ratio is controlled by the change in specific water uptake by roots,which is related to the osmotic pressure of the solution in the absorbing root's central vascular *** fine-root:needle ratio does not vary among stands of the same age if the stand quality index and the geographical latitude(a proxy of air and soil temperatures)are *** findings may be useful for further in-depth analysis of forest ecosystem functioning in Europe.

关键词： Fine-root:needle biomass ratio Stand quality class Soil fertility Latitudinal variation Allometric equation

Managing virus diseases in citrus:Leveraging high-throughput sequencing for versatile applications

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Horticultural Plant Journal 2025年第1期11卷 57-68页

作者： Hongming Chen Zhiyou Xuan Lu Yang Song Zhang Mengji Cao Integrative Science Center of Germplasm Creation in Western China(Chongqing)Science City Citrus Research InstituteSouthwest UniversityChongqing 400712China National Citrus Engineering research Center Citrus Research InstituteSouthwest UniversityChongqing 400712China

In this review,the advantages and advances in applying high-throughput sequencing(HTS)in the management of viral diseases in citrus,along with some challenges,are discussed to provide perspectives on future *** the initial implementation of HTS in citrus virology,a substantial number of citrus viruses have been identified,with a notable increase in the last 7 *** acquisition of viral genomes and various HTS-based omics analyses serve as crucial pillars for advancing research in the etiology,epidemiology,pathology,evolution,ecology,and biotechnology of citrus *** has notably contributed to disease diagnosis,such as the diagnoses of concave gum and impietratura,as well as to the surveillance of new virus risks and the preparation of virus-free ***,certain inherent defects in HTS and coupled bioinformatics analysis,such as challenges with sequence assembly and the detection of viral dark matter,require improvement to enhance practical *** addition,the utilization of HTS for the systematic management of citrus viral diseases remains limited,and drawing insights from other virus-plant pathosystems while integrating emerging compatible techniques and ideas may broaden its specific applications.

关键词： Deep sequencing Virus epidemics Functional genomics CRISPR/Cas Virus-host interactions

Information Security, Ethics, and Integrity in LLM Agent Interaction

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Journal of Information Security 2025年第1期16卷 184-196页

作者： Ying-Jung Chen Vijay K. Madisetti College of Computing Georgia Institute of Technology Atlanta GA USA School of cybersecurity & Privacy Georgia Institute of Technology Atlanta GA USA

This study addresses security and ethical challenges in LLM-based Multi-Agent Systems, as exemplified in a blockchain fraud detection case study. Leveraging blockchain’s secure architecture, the framework involves specialized LLM Agents—ContractMining, Investigative, Ethics, and PerformanceMonitor, coordinated by a ManagerAgent. Baseline LLM models achieved 30% accuracy with a threshold method and 94% accuracy with a random-forest method. The Claude 3.5-powered LLM system reached an accuracy of 92%. Ethical evaluations revealed biases, highlighting the need for fairness-focused refinements. Our approach aims to develop trustworthy and reliable networks of agents capable of functioning even in adversarial environments. To our knowledge, no existing systems employ ethical LLM agents specifically designed to detect fraud, making this a novel contribution. Future work will focus on refining ethical frameworks, scaling the system, and benchmarking it against traditional methods to establish a robust, adaptable, and ethically grounded solution for blockchain fraud detection.

关键词： Multi LLM Agents Systems Blockchain Cooperative Interactions Fraud Detection Ethics and Safety