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Ru-doped functional porous materials for electrocatalytic water splitting

Nano Research 2024年第3期17卷 982-1002页

作者： Chongao Tian Rui Liu Yu Zhang Wenxiu Yang Bo Wang Beijing Key Laboratory of Photoelectronic/Electrophotonic conversion Materials Advanced Technology Research Institute(Jinan)Advanced Research Institute of Multidisciplinary ScienceSchool of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 100081China Beijing institute of Technology Library Beijing Institute of TechnologyBeijing 100081China

Electrolytic water splitting(EWS)is an attractive and promising technique for the production of hydrogen ***,the sluggish kinetic rate of hydrogen/oxygen evolution reactions leads to a high overpotential and low energy *** to date,Pt/Ir-based nanocatalysts have become the state-of-the-art EWS catalysts,but disadvantages such as high cost and low earth abundance greatly limit their applications in EWS *** an attractive candidate for the Pt/Ir catalysts,series of Ru-based nanomaterials have aroused much attention for their low price,Pt-like hydrogen bond strength,and high EWS *** particular,Ru-doped functional porous materials have been becoming one of the most representative EWS catalysts,which can not only achieve the dispersion and adjustment for active Ru sites,but also simultaneously solve the problems of mass transfer and catalytic conversion in *** this review,the design and preparation strategies of Ru-doped functional porous materials toward EWS in recent years are summarized,including Ru-doped metal organic frameworks(MOFs),Ru-doped porous organic polymers(POPs),and their ***,detailed structure–activity relationships induced by the tuned geometric/electronic structures of Ru-doped functional porous materials are further depicted in this *** but not least,the challenges and perspectives of Ru-doped functional porous materials catalysts are reasonably proposed to provide fresh ideas for the design of Ru-based EWS catalysts.

关键词： Ru-based catalyst functional porous materials electrolytic water splitting oxygen evolution reaction hydrogen evolution reaction

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An improved model combining machine learning and Kalman filtering architecture for state of charge estimation of lithium-ion batteries

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Green energy and Intelligent Transportation 2024年第4期3卷 1-11页

作者： Yan Li Min Ye Qiao Wang Gaoqi Lian Baozhou Xia National Engineering Research Center for Highway Maintenance Equipment Chang'an UniversityXi'an710064China Chair for Electrochemical energy conversion and Storage Systems Institute for Power Electronics and Electrical Drives(ISEA)RWTH Aachen UniversityAachen52062Germany

Accurate state of charge(SOC)estimation of lithium-ion batteries is a fundamental prerequisite for ensuring the normal and safe operation of electric vehicles,and it is also a key technology component in battery management *** recent years,lithium-ion battery SOC estimation methods based on data-driven approaches have gained significant ***,these methods commonly face the issue of poor model generalization and limited *** address such issues,this study proposes a closed-loop SOC estimation method based on simulated annealing-optimized support vector regression(SA-SVR)combined with minimum error entropy based extended Kalman filter(MEE-EKF)***,a probability-based SA algorithm is employed to optimize the internal parameters of the SVR,thereby enhancing the precision of original SOC ***,utilizing the framework of the Kalman filter,the optimized SVR results are incorporated as the measurement equation and further processed through the MEE-EKF,while the ampere-hour integral physical model serves as the state equation,effectively attenuating the measurement noise,enhancing the estimation accuracy,and improving generalization *** proposed method is validated through battery testing experiments conducted under three typical operating conditions and one complex and random operating condition with wide temperature variations under only one condition *** results demonstrate that the proposed method achieves a mean absolute error below 0.60%and a root mean square error below 0.73%across all operating conditions,showcasing a significant improvement in estimation accuracy compared to the benchmark *** high precision and generalization capability of the proposed method are evident,ensuring accurate SOC estimation for electric vehicles.

关键词： Lithium-ion battery State of charge estimation Support vector regression Simulated annealing optimization Kalman filter

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光响应有机模块自组装导致的氧自由基转化及其光催化应用

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Science China Materials 2024年第3期67卷 833-841页

作者：姚娴雅于胜胜张荣震王发栋刘辉牛凯凯邢令宝李培洲 School of Chemistry and Chemical Engineering Shandong University of TechnologyZibo 255000China School of Chemistry and Chemical Engineering Shandong Provincial Key Laboratory for Science of Material Creation and Energy ConversionScience Center for Material Creation and Energy ConversionInstitute of Frontier and Interdisciplinary ScienceShandong UniversityJinan 250100China

在光催化反应中实现对活性氧物种的单线态氧和超氧阴离子自由基的有效控制仍然是一个巨大挑战.本工作报道了一个从光敏模块构筑主客体超分子有机框架(SOF)策略,有效地实现了单线态氧到超氧阴离子自由基的转化.该TPA-BP-SOF结构中的光敏... 详细信息

在光催化反应中实现对活性氧物种的单线态氧和超氧阴离子自由基的有效控制仍然是一个巨大挑战.本工作报道了一个从光敏模块构筑主客体超分子有机框架(SOF)策略,有效地实现了单线态氧到超氧阴离子自由基的转化.该TPA-BP-SOF结构中的光敏模块由四个4,4′-联吡啶盐(BP)单元修饰的苯基桥接双(三苯胺)衍生物(TPA-BP)构成.来自于不同的TPA-BP中的两个BP单元通过与葫芦[8]脲(CB[8])发生首尾相连的强络合作用,形成了具有周期性孔结构和均匀溶解度的二维超分子有机框架纳米片结构.与单体TPA-BP中检测到的生成单线态氧的能量转移机制不同,通过主客体相互作用形成的TPA-BP-SOF能够有效促进电子转移高效产生超氧阴离子自由基.同时,该TPA-BP-SOF生成的超氧阴离子自由基能有效地用于水相芳基硼酸的氧化羟基化和N-苯基四氢异喹啉的氧化,收率分别高达88%和83%.本研究提出了一种利用SOF实现II型光敏剂向I型光敏剂有效转化的新方法,成功展示了其在光催化有机转化中的实际应用.

关键词： photocatalysis reactive oxygen species singlet oxygen supramolecular organic frameworks superoxide radical

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Photo-enhanced uranium recovery from spent fuel reprocessing wastewater via S-scheme 2D/0D C_(3)N_(5)/Fe_(2)O_(3) heterojunctions

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SusMat 2024年第2期4卷 41-50页

作者： Qi Meng Linzhen Wu Xiaoyong Yang Ying Xiong Fanpeng Kong Tao Duan State Key Laboratory of Environment-friendly energy Materials NuclearWaste and Environmental Safety Key Laboratory of DefenseSouthwest University of Science and TechnologyMianyangSichuanChina MIIT Key Laboratory of Critical Materials Technology for New energy conversion and Storage Harbin Institute of TechnologyHarbinHeilongjiangChina Department of Materials Science and Engineering KTH Royal Institute of TechnologyStockholmSweden

Re-extracting environmentally transportable hexavalent uranium from wastew-ater produced by spent fuel reprocessing using the photocatalytic technology is a crucial strategy to avoid uranium pollution and recover nuclear fuel strategic ***,we have designed S-scheme 2D/0D C_(3)N_(5)/Fe_(2)O_(3)heterojunction photocatalysts based on the built-in electric field and the energy band bend-ing theory,and have further revealed the immobilization process of hexavalent uranium conversion into relatively insoluble tetravalent uranium in terms of thermodynamics and *** to the results,the hexavalent uranium removal and recovery ratios in wastewater are as high as 93.38%and 83.58%,***,C_(3)N_(5)/Fe_(2)O_(3)heterojunctions also exhibit satisfactory cat-alytic activity and selectivity even in the presence of excessive impurity cations(including Na^(+),K^(+),Ca^(^(2+)),Mg^(2+),Sr^(2+),and Eu^(3+))or various organics(such as xylene,tributylphosphate,pyridine,tannic acid,citric acid,and oxalic acid).It is believed that this work can provide a potential opportunity for S-scheme heterojunction photocatalysts to re-enrich uranium from spent fuel wastewater.

关键词： nuclear wastewater S-scheme heterostructure uranium recovery

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Controlled Synthesis of Graphdiyne-Based Multiscale Catalysts for energy conversion

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Precision Chemistry 2024年第7期2卷 355-375页

作者： Siao Chen Xuchen Zheng Yang Gao Xinyu Ping Yurui Xue Yuliang Li CAS Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of SciencesBeijing 100190China Shandong Provincial Key Laboratory for Science of Material Creation and energy conversion Science Center for Material Creation and Energy ConversionSchool of Chemistry and Chemical EngineeringShandong UniversityJinan 250100China School of Chemical Sciences University of Chinese Academy of SciencesBeijing 100049China

Graphdiyne(GDY)science is a new and rapidly developing interdisciplinary field that touches on various areas of chemistry,physics,information science,material science,life science,environmental science,and so *** rapid development of GDY science is part of the trend in development of carbon ***,with its unique structure and fascinating properties,has greatly promoted fundamental research toward practical applications of carbon *** important applications,such as catalysis and energy conversion,have been *** particular,GDY has shown great potential for application in the field of *** have precisely synthesized a series of GDY-based multiscale catalysts and applied them in various energy conversion and catalysis research,including ammonia synthesis,hydrogen production,CO_(2) conversion,and chemical-to-electrical energy *** this paper,we systematically review the advances in the precisely controlled synthesis of GDY and aggregated structures,and the latest progress with GDY in catalysis and energy conversion.

关键词： graphdiyne controlled growth atom catalyst heterostructure energy conversion

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Fe-doped Co_(3)O_(4) nanowire strutted 3D pinewood-derived carbon: A highly selective electrocatalyst for ammonia production via nitrate reduction

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Nano Research 2024年第4期17卷 2276-2282页

作者： Xuwei Liu Chaozhen Liu Xun He Zhengwei Cai Kai Dong Jun Li Xiaoya Fan Ting Xie Xiya Yang Yonglan Luo Dongdong Zheng Shengjun Sun Sulaiman Alfaifi Feng Gong Xuping Sun institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054China Key Laboratory of energy Thermal conversion and Control of Ministry of Education School of Energy and EnvironmentSoutheast UniversityNanjing 211189China College of Chemistry Chemical Engineering and Materials ScienceShandong Normal UniversityJinan 250014China Chemistry Department Frontier of ScienceKing Abdulaziz UniversityJeddah 21589Saudi Arabia

Nitrate(NO_(3)^(-)),a nitrogen-containing pollutant,is prevalent in aqueous solutions,contributing to a range of environmental and health-related *** electrocatalytic reduction of NO_(3)^(-)holds promise as a sustainable approach to both eliminating NO_(3)^(-)and generating valuable ammonia(NH_(3)).Nevertheless,the reduction reaction of NO_(3)^(-)(NO_(3)^(-)RR),involving 8-electron transfer process,is intricate,necessitating highly efficient electrocatalysts to facilitate the conversion of NO_(3)^(-)to NH_(3).In this study,Fe-doped Co_(3)O_(4) nanowire strutted three-dimensional(3D)pinewood-derived carbon(Fe-Co_(3)O_(4)/PC)is proposed as a high-efficiency NO_(3)^(-)RR electrocatalyst for NH_(3) *** within 0.1 M NaOH containing NO_(3)^(-),Fe-Co_(3)O_(4)/PC demonstrates exceptional performance,obtain an impressively large NH_(3) yield of 0.55 mmol·h^(-1)·cm^(-2) and an exceptionally high Faradaic efficiency of 96.5%at-0.5 V,superior to its Co_(3)O_(4)/PC counterpart(0.2 mmol·h^(-1)·cm^(-2),73.3%).Furthermore,the study delves into the reaction mechanism of Fe-Co_(3)O_(4) for NO_(3)^(-)RR through theoretical calculations.

关键词： Fe-doped Co_(3)O_(4) nanowire pinewood-derived carbon electrocatalytic NO_(3)-reduction NH_(3) synthesis density functional theory

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Enhanced nitrate reduction in hypotrophic waters with integrated photocatalysis and biodegradation

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Environmental Science and Ecotechnology 2024年第5期21卷 133-140页

作者： Bingjie Xue Li Tian Yaqi Liu Lingxiu Peng Waheed Iqbal Liangzhong Li Yanping Mao College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen518071PR China School of Chemistry and Chemical Engineering Northwestern Polytechnical UniversityXi'an710072PR China Guangzhou institute of energy conversion Chinese Academy of SciencesGuangzhou510640PR China

Addressing nitrate contamination in water bodies is a critical environmental challenge,and Intimately Coupling Photocatalysis and Biodegradation(ICPB)presents a promising ***,there is still debate about the effectiveness of ICPB in reducing nitrate under hypotrophic *** research is needed to understand its microbial metabolic mechanism and the functional changes in bacterial *** we explored microbial metabolic mechanisms and changes in bacterial structure in ICPB reactors integrating a meticulously screened TiO_(2)/g-C3N4 photocatalyst with *** achieved a 26.3%increase in nitrate reduction using 12.2%less organic carbon compared to traditional biodegradation *** analysis of the microbial communities in ICPB reactors revealed evolving metabolic pathways conducive to nitrate *** research not only elucidates the photocatalytic mechanism behind nitrate reduction in hypotrophic conditions but also provides genomic insights that pave the way for alternative approaches in water remediation technologies.

关键词： Nitrate reduction Photocatalysis Activated sludge Biodegradation Metabolic pathway

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Heterointerface engineering of assembled CoP_(2) on N-modified carbon as efficient trifunctional electrocatalysts for Zn-Air batteries and overall water splitting

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Nano Research 2024年第5期17卷 3801-3809页

作者： Yan Chen Zhenrui Yang Juan Wang Yun Yang Xuedong He Yang Wang Jiadong Chen Yaqing Guo Xin Wang Shun Wang Huile Jin Wenzhou Key Lab of Advanced energy Storage and conversion Zhejiang Province Key Lab of Leather EngineeringCollege of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325035China Zhejiang Engineering Research Center for Electrochemical energy Materials and Devices Institute of New Materials and Industrial TechnologiesWenzhou UniversityWenzhou 325035China School of Chemical and Biomedical Engineering Nanyang Technological UniversitySingapore 637459Singapore

Enhancing catalytic activity through modulating the interaction between N-doped carbon and metal phosphides clusters is an effective ***,the electronic structure modulation of CoP_(2) supported N-modified carbon(CoP_(2)/NC)has been designed and prepared as efficient electrocatalysts for oxygen reduction reaction(ORR),oxygen evolution reaction(OER),and hydrogen evolution reaction(HER).Notably,CoP_(2)/NC-1 catalyst exhibits impressive performance in alkaline media,with an ORR half-wave potential of 0.84 V,as well as OER and HER overpotentials of 290 and 129 mV(at 10 mA·cm^(−2)),*** addition,CoP_(2)/NC-1 produces a power density as high as 172.9 mW·cm^(−2),and excellent reversibility of 100 h at 20 mA·cm^(−2) in home-made Zn-air *** experimental results demonstrate that the synergistic interactions between N modified carbon substrate and CoP_(2) material significantly enhance the kinetics of ORR,OER,and *** functional theory(DFT)calculations reveal the strong electrons redistribution of CoP_(2) induced by high-density N atoms at the interface,thus optimizing the key intermediates and significantly lower the energy barrier of *** electronic adjustments of CoP_(2) greatly enhance its kinetics of ORR/OER/HER,leading to faster *** study provides profound insights into the specific modification of CoP_(2) by N-doped carbon,enabling the construction of efficient catalysts.

关键词： two-dimensional(2D)carbon metal-organic framework cobalt phosphide zinc air battery water splitting

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Diatomic Pd catalyst with conjugated backbone for synergistic electrochemical CO_(2)reduction

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Nano Research 2024年第6期17卷 4850-4855页

作者： Wenxuan Zhang Mengran Zhang Hongjuan Wang Wen Zhang Min Zhang MOE International Joint Laboratory of Materials Microstructure Institute for New Energy Materials and Low Carbon TechnologiesSchool of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China Tianjin Key Laboratory of Organic Solar Cells and Photochemical conversion School of Chemistry and Chemical EngineeringTianjin University of TechnologyTianjin 300384China

Double-site catalysts have attracted widespread attention in the field of electrocatalysis due to their high metal loading,adjustable active centres,and electronic valence ***,the development of bimetallic sites catalysts that coordinate with definite atoms is still in the exploratory ***,we designed and synthesized a bimetallic palladium complex(BPB-Pd_(2))with conjugated *** supported BPB-Pd_(2)was applied to electrochemical CO_(2)reduction reaction(CO_(2)RR)for the first *** as-obtained BPB-Pd_(2)gives an exceptional Faradaic efficiency of CO(FECO)of 94.4%at−0.80 V *** hydrogen electrode(RHE),which is significantly superior to monoatomic palladium catalyst(BPB-Pd1).The density functional theory(DFT)calculations revealed that the essential reason for the outstanding activity of BPB-Pd_(2)toward CO_(2)RR was that the electronic effect between diatomic palladium reduces the free energy change for CO_(2)RR ***,BPB-Pd_(2)exhibits moderate free energy change to form COOH*intermediate,which was beneficial for the generation of CO in CO_(2)RR.

关键词： synthesis electrocatalysis CO_(2)reduction bimetallic palladium complex synergistic catalysis

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The swirl and pyrolysis reaction synergistically enhance solid-solid heat transfer and product separation in cyclone pyrolyzer Author links open overlay panel

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Particuology 2024年第8期91卷 118-127页

作者： Haorui Niu Jingxuan Yang Wenhao Lian Nan Zhang Yongguo Li Hongzheng Ren Xiaogang Hao Guoqing Guan College of Chemical Engineering and Technology Taiyuan University of TechnologyTaiyuan030024 China School of Chemical Engineering and Technology North University of ChinaTaiyuan030051 China CNNC Key Laboratory on Radioactive Gas Purification Technology China Institute for Radiation ProtectionTaiyuan030006 China energy conversion Engineering Laboratory Institute of Regional InnovationHirosaki University3-BunkyochoHirosaki036-8561Japan

Cyclone pyrolyzer is a novel type of downer that combines centrifugal force field and double-layer cyclone *** on transfer behavior is helpful to optimize the pyrolyzer to meet the needs of *** this study,the Computational Particle Fluid Dynamics(CPFD)model is used to analyze the transfer behavior of binary particles,and finds that the swirl and reaction have a synergistic *** effect can increase the heating rate of the particles to the range of flash pyrolysis,and its mechanism lies in the flow field structure of the *** to the centrifugal force field,the particles gather to the near *** rapid swirl,which facilitates intense gas-solid heat transfer,leads to the rapid heating and pyrolysis of biomass *** the pyrolysis proceeds,the mass of the biomass particles becomes smaller and they are more easily affected by the gas flow in *** the action of gas flow,char particles serve as new heat carrier to form the inner cycle of particles,which strengthens the heating *** pyrolysis products are discharged from the exhaust port in time with the flow field of the pyrolyzer to achieve separation from the heat carrier and inhibit the occurrence of secondary reactions.

关键词： Biomass pyrolysis Cyclone pyrolyzer Intra-particle circulation Synergistic effect

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