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Electrochemical conversion of methane to bridge the gap in the artificial carbon cycle

Journal of Energy Chemistry 2025年第1期100卷 286-308页

作者： Yuhao Peng Yuefeng Song Ihar Razanau Juanxiu Xiao Wei Xiao Di Hu Guoxiong Wang college of Chemistry and Molecular sciences Hubei Key Laboratory of Electrochemical Power Sources Wuhan University State Key Laboratory of Catalysis Dalian National Laboratory for Clean Energy iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Dalian Institute of Chemical Physics Chinese Academy of Sciences Laboratory of Physical-Chemical Technologies SSPA Scientific and Practical Materials Research Centre of NAS of Belarus State Key Laboratory of marine resources Utilization in South China Sea Collaborative Innovation Center of Marine Science and Technology School of Marine Science and Engineering Hainan University Department of Chemical and Environmental Engineering University of Nottingham Ningbo China

Methane, an abundant one-carbon（C1） resource, is extensively used in the industrial production of vital fuels and value-added chemicals. However, current industrial methane conversion technologies are energy-and carbon-intensive, mainly due to the high activation energy required to break the inert C–H bond, low selectivity, and problematic side reactions, including CO2emissions and coke deposition. Electrochemical conversion of methane（ECM） using intermittent renewable energy offers an attractive solution, due to its modular reactor design and operational flexibility across a broad spectrum of temperatures and pressures. This review emphasizes conversion pathways of methane in various reaction systems, highlighting the significance and advantages of ECM in facilitating a sustainable artificial carbon cycle. This work provides a comprehensive overview of conventional methane activation mechanisms and delineates the complete pathways of methane conversion in electrolysis contexts. Based on surface/interface chemistry, this work systematically analyzes proposed reaction pathways and corresponding strategies to enhance ECM efficiency towards various target products, including syngas, hydrocarbons, oxygenates, and advanced carbon materials. The discussion also encompasses opportunities and challenges for the ECM process, including insights into ECM pathways, rational electrocatalyst design, establishment of benchmarking protocols, electrolyte engineering, enhancement of CH4conversion rates, and minimization of CO2emission.

关键词： Methane Electrochemical conversion Reaction mechanism Catalyst design Electrode Electrocatalysis

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Overview of in-situ oxygen production technologies for lunar resources

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 233-255页

作者： Youpeng Xu Sheng Pang Liangwei Cong Guoyu Qian Dong Wang Laishi Li Yusheng Wu Zhi Wang college of Materials Science and Engineering Shenyang University of TechnologyShenyang 110870China CAS Key Laboratory of Green Process and Engineering National Engineering Research Center for Green Recycling of Strategic Metal ResourcesInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China Innovation Academy for Green Manufacture Chinese Academy of SciencesBeijing 100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China

The rich resources and unique environment of the Moon make it an ideal location for human expansion and the utilization of extraterrestrial ***,crucial for supporting human life on the Moon,can be extracted from lunar regolith,which is highly rich in oxygen and contains polymetallic *** oxygen and metal extraction can be achieved using existing metallurgical ***,the ample reserves of water ice on the Moon offer another means for oxygen *** paper offers a detailed overview of the leading technologies for achieving oxygen production on the Moon,drawing from an analysis of lunar resources and environmental *** delves into the principles,processes,advantages,and drawbacks of water-ice electrolysis,two-step oxygen production from lunar regolith,and one-step oxygen production from lunar *** two-step methods involve hydrogen reduction,carbothermal reduction,and hydrometallurgy,while the one-step methods encompass fluorination/chlorination,high-temperature decomposition,molten salt electrolysis,and molten regolith electrolysis(MOE).Following a thorough comparison of raw materials,equipment,technology,and economic viability,MOE is identified as the most promising approach for future in-situ oxygen production on the *** the corrosion characteristics of molten lunar regolith at high temperatures,along with the Moon's low-gravity environment,the development of inexpensive and stable inert anodes and electrolysis devices that can easily collect oxygen is critical for promoting MOE technology on the *** review significantly contributes to our understanding of in-situ oxygen production technologies on the Moon and supports upcoming lunar exploration initiatives.

关键词： lunar resources in-situ oxygen production space metallurgy molten lunar regolith electrolysis

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Optimizing the key parameter to accelerate the recovery of AMOC under a rapid increase of greenhouse gas forcing

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Atmospheric and Oceanic Science Letters 2025年第1期18卷 39-45页

作者： Haolan Ren Fei Zheng Tingwei Cao Qiang Wang International Center for Climate and Environment Science(ICCES) Institute of Atmospheric PhysicsChinese Academy of SciencesBeijingChina University of Chinese Academy of sciences BeijingChina college of Oceanography Hohai UniversityNanjingChina CAS Key Laboratory of Ocean Circulation and Waves Institute of OceanologyChinese Academy of Sciences and Pilot National Laboratory for Marine Science and Technology(Qingdao)QingdaoChina

Atlantic Meridional Overturning Circulation(AMOC)plays a central role in long-term climate variations through its heat and freshwater transports,which can collapse under a rapid increase of greenhouse gas forcing in climate *** studies have suggested that the deviation of model parameters is one of the major factors in inducing inaccurate AMOC *** this work,with a low-resolution earth system model,the authors try to explore whether a reasonable adjustment of the key model parameter can help to re-establish the AMOC after its *** a new optimization strategy,the extra freshwater flux(FWF)parameter is determined to be the dominant one affecting the AMOC’s *** traditional ensemble optimal interpolation(EnOI)data assimilation and new machine learning methods are adopted to optimize the FWF parameter in an abrupt 4×CO_(2) forcing experiment to improve the adaptability of model parameters and accelerate the recovery of *** results show that,under an abrupt 4×CO_(2) forcing in millennial simulations,the AMOC will first collapse and then re-establish by the default FWF parameter ***,during the parameter adjustment process,the saltier and colder sea water over the North Atlantic region are the dominant factors in usefully improving the adaptability of the FWF parameter and accelerating the recovery of AMOC,according to their physical relationship with FWF on the interdecadal timescale.

关键词： Recovery of AMOC 4×CO_(2)forcing Key parameter Parameter estimation Data assimilation Machine learning

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Impacts of the annual cycle of background SST in the tropical Pacific on the phase and amplitude of ENSO

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Atmospheric and Oceanic Science Letters 2025年第1期18卷 12-17页

作者： Song Jiang Congwen Zhu Ning Jiang State Key Laboratory of Severe Weather(LASW) Chinese Academy of Meteorological SciencesBeijingChina college of Earth and Planetary sciences University of Chinese Academy of SciencesBeijingChina

The dominant annual cycle of sea surface temperature(SST)in the tropical Pacific exhibits an antisymmetric mode,which explains 83.4%total variance,and serves as a background of El Niño-Southern Oscillation(ENSO).However,there is no consensus yet on its anomalous impacts on the phase and amplitude of *** on data during 1982-2022,results show that anomalies of the antisymmetric mode can affect the evolution of ENSO on the interannual scale via Bjerknes feedback,in which the positive(negative)phase of the antisymmetric mode can strengthen El Niño(La Niña)in boreal winter via an earlier(delayed)seasonal cycle transition and larger(smaller)annual *** magnitude of the SST anomalies in the equatorial eastern Pacific can reach more than±0.3◦C,regulated by the changes in the antisymmetric mode based on random sensitivity *** reveal the spatial pattern of the annual cycle associated with the seasonal phase-locking of ENSO evolution and provide new insight into the impact of the annual cycle of background SST on ENSO,which possibly carries important implications for forecasting ENSO.

关键词： Annual cycle SST anomaly Antisymmetric mode ENSO

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Long-term impact of municipal sewage irrigation on treated soil and black locust trees in a semi-arid suburban area of Iran

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Journal of Environmental sciences 2009年第10期21卷 1438-1445页

作者： Masoud Tabari Azadeh Salehi Department of Forestry Faculty of Natural Resources and Marine Sciences Tarbiat Modares University

The effects of municipal sewage irrigation on the soil and black locust （Robinia pseudoacacia L.） tree were studied. For this purpose, two artificial black locust stands under irrigation of municipal sewage and well water were selected in south of Tehran, Iran. Data were collected using technique of systematic random sampling with 4 replicates in each stand. It was found that the growth of black locust tree, as indicated by diameter at breast height, total height, crown length, average crown diameter, basal area and volume, in sewage irrigation stand was much higher than that of well water irrigation stand （P 〈 0.01）. Plant analysis indicated that concentrations of leaf nutrients （N, E K, Ca, Mg, Na, Fe, Mn, Cu and Zn） were greater in sewage-irrigated trees, without toxicity to the minerals of tree leaf, than those of well waterirrigated trees, and positively correlated with their respective value in soil. Ni, Cr and Pb were not detected in leaf samples. Application of sewage resulted in a 1.5-fold increase in the concentrations of soil nutrients, Ni, Cr and Pb. Among these minerals only Pb and Ni in some soil samples exceeded the toxicity limit. The increase in pH, electrical conductivity （EC） and organic carbon of soil was also observed in sewage irrigation. Results confirm that besides the use as irrigation water, municipal sewages are also a potential source of plant nutrients. However, significant accumulation of heavy metals such as Pb and Ni in soil needs to be monitored.

关键词： afforestation irrigation municipal sewage black locust nutrient heavy metal

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Effects of Pits and Mounds Following Windthrow Events on Soil Features and Greenhouse Gas Fluxes in a Temperate Forest

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Pedosphere 2015年第6期25卷 853-867页

作者： Yahya KOOCH Sakineh Mollaei DARABI Seyed Mohsen HOSSEINI Department of Forestry Faculty of Natural Resources & Marine SciencesTarbiat Modares University

Pit and mound micro-relief(resultant microsites from trees uprooted by windthrow) could have regimes of microclimate and soil features that differ from areas of undisturbed soil. In an attempt to provide a comprehensive evaluation of the significance of pits and mounds on soil features and also the dynamics of greenhouse gas(GHG) fluxes at local scale, this study was carried out in a reserved area of Darabkola forest in Mazandaran Province, northern Iran. The age of a pit and mound was considered equal to the degree of decay of the blown down tree. Three microsites were distinguished, consisting of pit bottom(PB), mound top(MT) and undisturbed area(UA). Soil samples were taken at 0–15 and 15–30 cm depths from all microsites and analysed for soil physical, chemical and biological features. Our findings suggested that in context of forest ecology, pits and mounds following windthrow events should be considered as an effective factor influencing soil features(i.e., density, texture, water content, p H, organic C, total N, available nutrients and earthworm density/biomass) and especially GHG fluxes. Results showed that MT acted as a sink for N2O(-0.010 mg N2 O m-2d-1) and CH4(-0.257 mg CH4m-2d-1) fluxes and also produced lower CO2 concentrations(0.095 mg CO2 m-2d-1) than PB(0.207 mg CO2 m-2d-1) and UA(0.098 mg CO2 m-2d-1). As a consequence, a separation into pits/mounds would be important for a precise budgeting of greenhouse gases.

关键词： carbon dioxide, methane microsite, nitrous oxide oriental beech, uprooted tree

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Distribution and enrichment patterns of selenium in the Ediacaran and early Cambrian strata in the Yangtze Gorges area, South China

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Science China Earth sciences 2017年第7期60卷 1268-1282页

作者： TIAN XingLei LUO KunLi Institute of Geographic sciences and natural resources Research Chinese Academy of Sciences college of resources and Environment University of the Chinese Academy of Sciences

The distribution and enrichment patterns of selenium(Se) in the E-?1 strata in the Yangtze Gorges area of South China were obtained. The geochemical characteristics of the significantly and non-significantly enriched strata of Se were *** observed enrichment factor(EF, relative to the upper continental crust) and concentration coefficient(CC, relative to the similar lithology in Eastern China) both suggest that Se is the most enriched/concentrated(SeEF=26.97, SeCC=48.04) among the analyzed23 trace elements the E-?1 strata. The normalized enrichment factor(EF′, EF after Al or Th normalized) shows Se is secondly enriched(SeEF′=218.73), which is slightly lower than cadmium(CdEF′=288.46) but significantly higher than the third enriched trace element arsenic(AsEF′=97.49). Se concentrations in the E-?1 strata vary from Yanjiahe(54.45)>Doushantuo(24.72)>Dengying(2.48)>Shipai(1.95)>lower Tianheban(1.24)Formations. Se concentrations in the E-?1 strata are best displayed on natural logarithm normal quantile-quantile(Q-Q) plots and shown as a positive-skewed distribution pattern. The Se significantly enriched(EF>10) strata sequences mainly include the lower and upper Doushantuo member II(DST-II), top DST-III, DST-IV, the basal and upper Yanjiahe Formation, and lower and upper Shuijingtuo Formation. Geochemical characteristics indicate that Se concentrations in the significantly enriched strata were generally influenced by terrigenous detrital as well as the combined action of single or multiple factors, such as hydrotherm,volcanic debris and deep source. Moreover, pyrite and organic matter promoted the enrichment of Se in the upper DST-II, DST-IV,upper Shuijingtuo Formation and lower DST-II, upper Shuijingtuo Formation, respectively. The Se concentrations in the n

关键词： Ediacaran-early Cambrian Selenium Distribution and enrichment patterns Elemental geochemistry

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Spatio-temporal patterns and climatic drivers of spring phenology in eight forest communities across the north-south transitional zone of China

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Journal of Geographical sciences 2025年第1期 17-38页

作者： ZHU Wenbin LU Yu Institute of Geographic sciences and natural resources Research CAS School of Geographical Science Nanjing University of Information Science & Technology

The Qinba Mountains are climatically and ecologically recognized as the northsouth transitional zone of *** of its phenology is critical for comprehending the response of vegetation to climatic *** retrieved the start of spring phenology （SOS）of eight forest communities from the MODIS products and adopted it as an indicator for spring *** analysis,partial correlation analysis,and Geo Detector were employed to reveal the spatio-temporal patterns and climatic drivers of *** results indicated that the SOS presented an advance trend from 2001 to 2020,with a mean rate of–0.473 d yr–*** SOS of most forests correlated negatively with air temperature （TEMP） and positively with precipitation （PRE）,suggesting that rising TEMP and increasing PRE in spring would forward and delay SOS,*** dominant factors influencing the sensitivity of SOS to climatic variables were altitude,forest type,and latitude,while the effects of slope and aspect were relatively *** response of SOS to climatic factors varied significantly in space and among forest communities,partly due to the influence of altitude,slope,and aspect.

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Constraints on holographic QCD phase transitions from PTA observations

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Science China(Physics,Mechanics & Astronomy) 2025年第1期Mechanics & Astronomy) .卷 71-78页

作者： Song He Li Li Sai Wang Shao-Jiang Wang Center for Theoretical Physics and college of Physics Jilin University School of Physical Science and Technology Ningbo University Max Planck Institute for Gravitational Physics (Albert Einstein Institute) CAS Key Laboratory of Theoretical Physics Institute of Theoretical Physics Chinese Academy of Sciences School of Fundamental Physics and Mathematical sciences Hangzhou Institute for Advanced StudyUniversity of Chinese Academy of Sciences (UCAS) School of Physical sciences University of Chinese Academy of Sciences (UCAS) Theoretical Physics Division Institute of High Energy Physics Chinese Academy of Sciences

The underlying physics of QCD phase transition in the early Universe remains largely unknown due to its strong-coupling nature during the quark-gluon plasma/hadron gas transition, yet a holographic model has been proposed to quantitatively fit the lattice QCD data while with its duration of the first-order phase transition(FoPT) left undetermined. At specific baryon chemical potential, the first-order QCD phase transition agrees with the observational constraint of baryon asymmetry. It, therefore, provides a scenario for phase transition gravitational waves(GWs) within the standard model of particle physics. If these background GWs could contribute dominantly to the recently claimed common-spectrum red noise from pulsar timing array(PTA) observations, the duration of this FoPT can be well constrained, and the associated primordial black holes are still allowed by current observations.

关键词： pulsar timing array QCD phase transition gravitational waves primordial black holes

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Combined effects of two sulfonylurea herbicides on soil microbial biomass and N-mineralization

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Journal of Environmental sciences 2001年第3期13卷 311-317页

作者： A.M.EL-Ghamry HUANG Chang-yong XU Jian-ming college of natural resources and Environmental sciences Zhejiang UniversityHangzhou 310029China

The interaction effect of two sulfonylurea herbicides, bensulfuron methyl (B) and metsulfuron methyl(M), were tested on microbial biomass C, N, N mineralization and C/N ratio in a loamy sand soil. The herbicides were applied at various levels of: control (B0M0), 0.01 and 0.01 (B1M1), 0.01 and 0.1 (B1M2), and 0.01 and 1.0 (B1M3) μg/g soil. Determinations of soil microbial biomass C, N and N mineralization contents were carried out at 1, 3, 5, 7, 10, 15, 25 and 45 days after herbicides application. The results showed that the soil microbial biomass C (C mic ) and microbial biomass N (N mic ) decreased consistently with the increasing rates of herbicides. The results further indicated that B1M1 and B1M2 caused a significant reduction in C mic and N mic within first 10 and 7 days of incubation, respectively, as compared with the control. These reductions in C mic and N mic were also significant ( P =0.05) with B1M3 application especially within first 15 days of incubation. A significant reduction in N mineralization (N min) was observed with high doses (B1M2, B1M3) of herbicides within first 5 days of incubation, while low rate (B1M1) failed to produce any significant effect. An increase in the soil microbial biomass C:N ratio was also noted.

关键词： bensulfuron methyl metsulfuron methyl C mic N mic N mineralization loamy sand soil

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