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Enhanced dynamics of Al3+/H+ ions in aqueous aluminum ion batteries:Construction of metastable structures in vanadium pentoxide upon oxygen vacancies

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Journal of Energy Chemistry 2025年第2期101卷 562-569页

作者： Zhibao Wang Hanqing Gu Tianci Wu Wenming Zhang Zhanyu Li Hebei Key Laboratory of Optic-Electronic Information and materials National & Local Joint Engineering Laboratory of New Energy Photoelectric Devices College of Physics Science and Technology Hebei University

In recent years,aqueous aluminum ion batteries have been widely studied owing to their abundant energy storage and high theo retical *** in-depth study of vanadium oxide materials is necessary to address the precipitation of insoluble products covered cathode surface and the slow reaction ***,a method using a simple one-step hydrothermal preparation and oxalic acid to regulate oxygen vacancies has been reported.A high starting capacity(400 mAh g-1) can be achieved by Ov-V2O5,and it is capable of undergoing 200 cycles at 0.4 A g-1,with a termination discharge capacity of103 mAh *** analysis demonstrated that metastable structures（AlxV2O5and HxV2O5） were constructed through the insertion of Al3+/H+during discharging,which existed in the lattice intercalation with *** incorporation of oxygen vacancies lowers the reaction energy barrier while improving the ion transport *** addition,the metastable structure allows the electrostatic interaction between Al3+and the main backbone to establish protection and optimize the transport *** parallel,this work exploits ex-situ characterization and DFT to obtain a profound insight into the instrumental effect of oxygen vacancies in the construction of metastable structures during in-situ electrochemical activation,with a view to better understanding the mechanism of the synergistic participation of Al3+and H+in the *** work not only reports a method for cathode materials to modulate oxygen vacancies,but also lays the foundation for a deeper understanding of the metastable structure of vanadium oxides.

关键词： Electrochemical activation Metastable structure Oxygen vacancies Vanadium pentoxide

Strong absorption in ultra-wide band by surface nano engineering of metallic glass

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Fundamental Research 2025年第1期5卷 307-314页

作者： Jianan Fu Xin Li Zhen Li Fei Sun Wenxin Wen Jinlai Zhao Wenqing Ruan Shuai Ren Zhenxuan Zhang Xiong Liang Jiang Ma Shenzhen Key Laboratory of High Performance Nontraditional Manufacturing College of Mechatronics and Control EngineeringShenzhen UniversityShenzhen 518060China college of materials science and engineering Shenzhen Key Laboratory of Polymer Science and TechnologyGuangdong Research Center for Interfacial Engineering of Functional MaterialsShenzhen 518060China

Broadband light absorption is important for applications such as infrared detectors,solar energy collectors,and photothermal *** propose a facile and common strategy to fabricate light absorbers with strong ultra-wideband *** to their excellent thermoplastic forming ability,metallic glasses could be patterned into finely arranged nanowire arrays,which show extremely low reflectivity(∼0.6%)in the visible and near-infrared regimes,and a low reflectivity(∼15%)in the mid-infrared regime as caused by multiscale nano spacing,multiple reflections,and plasmonic *** strong absorption at surfaces with nanowires provides excellent photothermal conversion *** photothermal properties show that a surface with nanowires can be rapidly heated up to∼160°C at a rate of 28.75°C/s,which is 30 times higher than smooth ***,a surface with nanowires shows a high photothermal conversion efficiency(η_(PT)=56.36%).The fabricated metallic glass absorbers exhibit adaptability as they can be easily formed into various complex shapes and meet the requirements under harsh *** outcomes of our research open the door to manufacturing high-performance absorbers for applications in photothermal electric power generation,desalination,and photodetectors.

关键词： Metallic glass Nanoforming Ultra-wideband absorption Photothermal properties Thermoplastic forming

Dual-phase medium-entropy diboride–carbide ceramics with metal element exchange during sintering

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Journal of Advanced Ceramics 2025年第1期14卷 91-100页

作者： Pai Peng Ji-Xuan Liu Xiao-Ting Xin Weichao Bao Yongcheng Liang Fangfang Xu Guo-Jun Zhang State Key Laboratory of Advanced Fiber materials Institute of Functional MaterialsCollege of Materials Science and EngineeringCollege of PhysicsDonghua UniversityShanghai 201620China State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of CeramicsChinese Academy of SciencesShanghai 200050China

Multiphase composition design is a strategy for optimizing the microstructures and properties of ceramic materials through mutual inhibition of grain growth, complementary property improvement, or even mutually reinforcing effects. More interesting phenomena can be expected if chemical interactions between the constituent phases exist. In this study, spark plasma sintering was used to prepare fully dense dual-phase (Zr,Hf,Ta)B2–(Zr,Hf,Ta)C ceramics from self-synthesized equimolar medium-entropy diboride and carbide powders. The obtained ceramics were composed of two distinct solid solution phases, the Zr-rich diboride phase and the Ta-rich carbide phase, indicating that metal element exchange occurred between the starting equimolar medium-entropy diboride and carbide phases during sintering. Owing to the mutual grain-boundary pinning effect, fine-grained dual-phase ceramics were obtained. The chemical driving force originating from metal element exchange during the sintering process is considered to promote the densification process of the ceramics. The metal element exchange between the medium-entropy diboride and carbide phases significantly increased the Young’s modulus of the dual-phase ceramics. The dual-phase medium-entropy 50 vol% (Zr,Hf,Ta)B2–50 vol% (Zr,Hf,Ta)C ceramics with the smallest grain size exhibited the highest hardness of 22.4±0.2 GPa. It is inferred that optimized comprehensive properties or performance of dual-phase high-entropy or medium-entropy ceramics of diborides and carbides can be achieved by adjusting both the volume content and the metal element composition of the corresponding starting powders of diborides and carbides.

关键词： medium-entropy diboride medium-entropy carbide dual-phase medium-entropy ceramics metal element exchange densification mechanical properties

Construction of a 12-metal Zn(Ⅱ)-Nd(Ⅲ) nanocluster for ratiometric fluorescence detection of inflammatory marker neopterin

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Journal of Rare Earths 2025年第2期43卷 270-275,I0002页

作者： Huanyin Yu Xiaoping Yang Xiaoli Lv Xianfeng Huang college of Chemistry and materials engineering Wenzhou UniversityZhejiang Key Laboratory of Carbon MaterialsKey Lab of Biohealth Materials and Chemistry of WenzhouWenzhou325035China

A 12-metal Zn(Ⅱ)-Nd(Ⅲ) cluster 1(sizes:1.8 nm×2.0 nm×2.0 nm) was synthesized from a long-chain type Schiff base *** displays ratiometric fluorescence response to neopterin(Neo) with high selectivity and sensitivity,which can be expressed by the equation I_(545)_(nm)/I_(1060)_(nm)=A·[Neo]^(2)+B·[Neo]+C.1 is used to quantitatively test Neo concentrations in fetal calf serum(FCS) and urine,and the recovery ranges are 98.57%-103.82% and 99.25%-103.50%,respectively,while the relative standard deviations(RSDs) are 7.89%-9.46% and 1.85%-4.16%,*** limits of detection of 1 to Neo in FCS and urine are 0.034 and 0.021 μmol/L,respectively.

关键词： Rare earths Zn(Ⅱ)-Nd(Ⅲ)nanocluster NIR luminescence Ratiometric fluorescence detection Neopterin

Isothermal reduction kinetics and reduction prediction for iron ore pellets

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Journal of Iron and Steel Research International 2025年第1期32卷 64-72页

作者： Fei Meng Hao Liu Yue-lin Qin Huang-jie Hua Yin Deng Ze-zheng Sun Long-hai Liu School of Metallurgy and materials engineering Chongqing University of Science and TechnologyChongqing401331China CISDI Group Co. Ltd.Chongqing401122China college of materials science and engineering Chongqing UniversityChongqing400044China Sichuan Desheng Group Vanadium&Titanium Co. Ltd.Leshan614000SichuanChina

Iron ore pellets,as one of the main charges of blast furnaces,have a greater impact on the CO_(2)emission reduction and stable operation of blast *** isothermal reduction behavior of the pellets obtained from a Chinese steel plant was studied in the gas mixtures of CO and N_(2).The results showed the reduction process is divided into two *** reduction in the initial stage(time t≤40 min)is cooperatively controlled by internal diffusion and interface chemical reactions with the activation energy of 30.19 and 16.67 kJ/mol,*** controlling step of the reduction in the final stage(t>40 min)is internal diffusion with the activation energy of 34.60 kJ/*** reduction process can be described by two equations obtained from kinetic *** reduction degree can be predicted under different temperatures and time,and the predicted results showed an excellent correlation with the experimental *** reduction mechanisms were confirmed by the analysis of the scanning electron microscope equipped with an energy dispersive spectrometer and optical microscope.

关键词： Pellet Reduction behavior Kinetics Mechanism Reduction prediction

Understanding the iodine electrochemical behaviors in aqueous zinc batteries

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Journal of Energy Chemistry 2025年第2期101卷 402-415页

作者： Xuefang Xie Xiaoxin Xu Shuquan Liang Guozhao Fang college of Physical science and Technology Xinjiang University Xinjiang Key Laboratory of Solid State Physics and Devices Xinjiang University School of materials science & engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan Province Central South University National Energy Metal Resources and New materials Key Laboratory Central South University

Iodine is widely used in aqueous zinc batteries（ZBs） due to its abundant resources,low cost,and active redox *** addition to the active material in zinc-iodine batteries,iodine also plays an important role in other ZBs,such as regulating the electrochemical behavior of zinc ions,promoting the reaction kinetic and reversibility of other redox pairs,catalytic behaviors related to iodine reactions,coupling with other halogen ions,shuttle behaviors of polyiodides,***,there is currently a lack of comprehensive discussion on these ***,this review provides a comprehensive overview of the electrochemical behaviors of iodide in the aqueous *** effect of iodine ions on the Zn2+desolvation behaviors and the interfacial behaviors of Zn anode was *** redox pairs boosting other redox pairs,such as MnO2/Mn2+redox pair and vanadium redox pair to obtain high reversibility and capacity was also ***,the catalytic behaviors related to iodine reactions in aqueous ZBs,synergistic reaction with other halogen ions and suppression of shuttle behaviors for high performance zinc-iodine batteries were systematically ***,future prospects for designing effective iodine electrochemical behaviors with practicability are proposed,which will provide scientific guidance for the practical application of iodine-related aqueous ZBs.

关键词： Catalytic behavior Iodide ion Redox pairs Shuttle effect Zinc batteries

Phase changes and electromagnetic wave absorption performance of XZnC(X=Fe/Co/Cu)loaded on melamine sponge hollow carbon composites

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International Journal of Minerals,Metallurgy and materials 2025年第3期32卷 566-577页

作者： Xiubo Xie Ruilin Liu Chen Chen Di Lan Zhelin Chen Wei Du Guanglei Wu School of Environmental and Material engineering Yantai UniversityYantai 264005China School of materials science and engineering Hubei University of Automotive TechnologyShiyan 442002China Shandong Key Laboratory of Eco-Environmental science for the Yellow River Delta Shandong University of AeronauticsBinzhou 256603China Institute of materials for Energy and Environment State Key Laboratory of Bio-fibers and Eco-textilesCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071China

Non-stoichiometric carbides have been proven to be effective electromagnetic wave(EMW)absorbing *** this study,phase and morphology of XZnC(X=Fe/Co/Cu)loaded on a three dimensional(3D)network structure melamine sponge(MS)carbon composites were investigated through vacuum filtration followed by *** FeZnC/CoZnC/CuZnC with carbon nanotubes(CNTs)were uniformly dispersed on the surface of melamine sponge carbon skeleton and Co-containing sample exhibits the highest CNTs *** minimum reflection loss(RL_(min))of the CoZnC/MS composite(m_(composite):m_(paraffin)=1:1,m represents mass)reached-33.60 dB,and the effective absorption bandwidth(EAB)reached 9.60 *** outstanding electromagnetic wave absorption(EMWA)properties of the CoZnC/MS composite can be attributed to its unique hollow structure,which leads to multiple reflections and *** formed conductive network improves dielectric and conductive *** incorporation of Co enhances the magnetic loss capability and optimizes interfacial polarization and dipole *** simultaneously improving dielectric and magnetic losses,ex-cellent impedance matching performance is *** clarification of element replacement in XZnC/MS composites provides an effi-cient design perspective for high-performance non-stoichiometric carbide EMW absorbers.

关键词： electromagnetic wave absorption three dimensional network structure melamine sponge derived carbon non-stoichiometric carbide

Biomass materials for zinc-based sustainable and green energy storage devices:Strategy and mechanism

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Nano Research 2025年第1期18卷 294-314页

作者： Xiaotong Yang Xiaoxin Nie Chenke Tang Yiyang Xiao Qiongguang Li Du Yuan Meng Yao college of materials science and engineering Changsha University of Science and TechnologyChangsha 410004China college of materials science and engineering Sichuan UniversityChengdu 610065China Anhui Province International Research Center on Advanced Building materials School of Materials and Chemical EngineeringAnhui Jianzhu UniversityHefei 230601China

As next-generation rechargeable alternatives,zincbased energy storage devices(ZESs)are being intensely explored due to their merits of abundant resource,low cost,safety and environmental ***,ZESs face a succession of critical challenges on pursuing advancing performance,including the stability and kinetics of cathode,stability and transport of zinc electrolyte,reversibility and deep utilization of metallic Zn ***,possessing unique molecular structures with abundant functionals groups,motivates the interdisciplinary field emerging from biomass and aqueous rechargeable *** its high compatibility with ZES design,we here summarize the application of biomass materials in ZESs from the aspects of cathode,electrolyte,membrane/separator and Zn anode,with their corresponding operational mechanisms and attractive functionalities from polymeric ***,the outlooks and perspectives are provided,regarding current challenges and future *** anticipate our minireview paves way on exploring the roles of biomass in aqueous rechargeable batteries.

关键词： zinc biomass materials skeleton/host coating solid-electrolyte interphase(SEI)

Near-perfect replication on amorphous alloys through active force modulation based on machine learning/neural network parameter prediction

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science China(Physics,Mechanics & Astronomy) 2025年第1期68卷 177-187页

作者： Senkuan Meng Zheng Wang Ruisong Zhu Ruijie Liu Jiang Ma Lina Hu Weihua Wang Key Laboratory for Liquid-Solid Structural Evolution and Processing of materials(Ministry of Education) School of Materials Science and EngineeringShandong UniversityJinan 250061China college of Mechatronics and Control engineering Shenzhen UniversityShenzhen 518060China Songshan Lake materials Laboratory Dongguan 523808China Institute of Physics Chinese Academy of SciencesBeijing 100190China

As a microforming technique,micro/nano-structural replication possesses advantages of high precision and *** the remarkable superplasticity in the supercooled liquid region,amorphous alloys or metallic glasses(MGs)are regarded as ideal materials for miniature ***,due to the intrinsic metastable nature of supercooled liquids,the design of imprinting processes for MGs poses a *** the past,process parameters have largely relied on trial-and-error *** this work,a low-frequency active force modulation system is employed to apply a stable,precise,and real-time feedback stress field for imprinting of MG ***-frequency vibrations can facilitate the filling of microstructures on the template surface by reducing the effective viscosity of the supercooled *** the dataset composed of orthogonal experiments,a machine learning strategy based on back-propagation(BP)neural networks was utilized to construct a 3D parameter space for temperature,stress,and time,and to predict the corresponding filling ***,the optimal combination of imprinting process parameters was identified,and its filling ratio was experimentally validated to reach as high as *** near-perfect replication of microstructures confirms the superiority of the active force modulation system and the data-driven strategy of machine learning-assisted parameter *** the same time,this one-step microforming process provides a new approach to addressing the accuracy-cost trade-off dilemma in precision manufacturing.

关键词： metallic glass amorphous alloy microforming imprinting machine learning