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Synergistic effects of high-entropy engineering and particulate toughening on the properties of rare-earth aluminate-based ceramic composites

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Journal of Advanced Ceramics 2023年第4期12卷 861-872页

作者： Tian-Zhe Tu Ji-Xuan Liu Yue Wu Lin Zhou Yongcheng Liang Guo-Jun Zhang State Key Laboratory for Modification of Chemical Fibers and Polymer materials College of Materials Science and EngineeringCollege of ScienceInstitute of Functional MaterialsDonghua UniversityShanghai 201620China

Rare-earth aluminates(REAIOs)are potential thermal barrier coating(TBC)materials,but the relatively high thermal conductivity(ko,~13.6 W·m^(-1)·K^(-1))and low fracture toughness(K_(1c),-1.9 MPa·m^(1/2))limit their application.This work proposed a strategy to improve their properties through the synergistic effects of high-entropy engineering and particulate toughening.High-entropy(La_(0.2)Nd_(0.2)Sm_(0.2)Eu_(0.2)Gd_(0.2)AlO_(3))(HEAO)-based particulate composites with different contents of high-entropy(La_(0.2)Nd_(0.2)Sm_(0.2)Eu_(0.2)Gd_(0.2))_(2)Zr_(2)O_(7)(HEZO)were designed and successfully prepared by solid-state sintering.The high-entropy feature of both the matrix and secondary phases causes the strong phonon scattering and the incorporation of the HEZO secondary phase,remarkedly inhibiting the grain growth of the HEAO phase.As a result,HEAO-xHEZO(x=0,5%,10%,25%,and 50%in volume)ceramic composites show low thermal conductivity and high fracture toughness.Compared to the most commonly applied TBC material-yttria stabilized-zirconia(YSZ),the HEAO-25%HEZO particulate composite has a lower thermal conductivity of 0.96-1.17 W·m^(-1)·K^(-1)(298-1273 K),enhanced fracture toughness of 3.94±0.35 MPa-m,and comparable linear coefficient of thermal expansion(CTE)of 10.5×10^(-6)K^(-1).It is believed that the proposed strategy should be revelatory for the design of new coating materials including TBCs and environmental barrier coatings(EBCs).

关键词： high-entropy particulate composites thermal barrier coating(TBC) thermal properties mechanical properties fine grains

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MoO_(x) nanoclusters on Mo-doped TiO_(2) nanosheets with enhanced singlet oxygen generation and sulfide conversion abilities for photocatalytic aerobic oxidative desulfurization

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Science China Chemistry 2024年第1期67卷 408-414页

作者： Suting Xie Xinyu Zhao Dongxiao Wang Huawei Yang Lixia Yang Liangjiu Bai Donglei Wei Wenxiang Wang Ying Liang Hou Chen Shaojun Guo college of Chemistry and materials Science Ludong UniversityYantai 264025China College of Materials Science and Engineering Peking UniversityBeijing 100871China

Photocatalytic aerobic oxidation desulfurization(PAODS)is a promising and sustainable alternative to conventional,energyintensive desulfurization techniques for petroleum products.However,its development is greatly plagued by the low capability in generating highly reactive oxygen species and sluggish kinetics of sulfide oxidation of reported photocatalysts.Here we report a class of MoO_(x)nanocluster decorated on ultrathin Mo-doped TiO_(2)nanosheet(MoO_(x)/MoTiO)catalyst for efficiently facilitating the photocatalytic aerobic oxidation of sulfides.We demonstrate that MoO_(x)/MoTiO can not only promote the generation of highly reactive singlet oxygen(^(1)O_(2))but also enhance the aerobic conversion of sulfides,which leads to a record dibenzothiophene oxidation activity of 3.90 mmol g^(-1)h^(-1).The multiple experimental characterizations and density functional theory calculations collectively reveal that the doped-Mo sites can interact with the photogenerated excitons,enabling directly energy transfer generation of^(1)O_(2)through a new exciton modulation mechanism,and the coordination unsaturated MoO_(x)clusters play the role of co-catalyst to enhance the separation of charge carriers,and effectively catalyze the reaction between sulfides and1O_(2)to form sulfones.

关键词： titanium dioxide photocatalytic aerobic oxidation desulfurization dibenzothiophene singlet oxygen

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Single-source-precursor derived Sioc ceramics with in-situ formed CNTs and core-shell structured CoSi@C nanoparticles towards excellent electromagnetic wave absorption properties

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Journal of Advanced Ceramics 2023年第6期12卷 1119-1135页

作者： Zhaoju Yu Ting Chen Hanzi Du Fen Li Qikun Zhu College of Materials Key Laboratory of High Performance Ceramic Fibers(Xiamen University)Ministry of EducationXiamen 361005China College of Materials Xiamen Key Laboratory of Electronic Ceramic Materials and DevicesXiamen UniversityXiamen 361005China College of Materials Fujian Key Laboratory of Advanced MaterialsXiamen UniversityXiamen 361005China

In this work,novel carbon nanotube(CNT)/CoSi/SiOC nanocomposite ceramics with in-situ formed multi-walled CNTs and core-shell structured CoSi@C nanoparticles were successfully prepared via a single-source-precursor derived ceramic approach.Ppolymericprecursor characterization as well as phase evolution,microstructure,and electromagnetic wave(EMW)absorption properties of the ceramics were investigated in detail.The results show that the in-situ formed CNTs and magnetic CoSi@C nanoparticles provide a synergistic effect on both dielectric loss(tand:)and magnetic loss,leading to outstanding EMW absorption properties of the ceramics annealed at only 1100 C.(i)For the Co feeding of 6.25 wt%,the minimum reflection loss(RLmin)is-53.1 dB,and the effective absorption bandwidth(EAB)is 4.96 GHz(7.12-12.08 GHz)with a ceramic-paraffin hybrid sample thickness of 3.10 mm,achieving full X-band coverage;(i)for the Co feeding of 9.09 wt%,the RLmin value of-66.4 dB and the EAB value of 3.04 GHz(8.40-11.44 GHz)were achieved with a thickness of only 2.27 mm.Therefore,the present CNT/CoSi/SiOC nanocomposite ceramics have potential applications for thin,lightweight,and efficient EMW absorption in harsh environments.

关键词： polymer-derived ceramics(PDCs) in-situ formed carbon nanotubes(CNTs) core-shell structure electromagnetic properties electromagnetic wave(EMW)absorption properties

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High-entropy-alloy nanoparticles with 21 ultra-mixed elements for efficient photothermal conversion

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National Science Review 2022年第6期9卷 124-134页

作者： Yijun Liao Yixing Li Rongzhi Zhao Jian Zhang Lizhong Zhao Lianze Ji Zhengyu Zhang Xiaolian Liu Gaowu Qin Xuefeng Zhang Key Laboratory for Anisotropy and Texture of materials (MOE) School of Materials Science and EngineeringNortheastern University Institute of Advanced Magnetic materials College of Materials and Environmental EngineeringHangzhou Dianzi University

Multi-metallic nanoparticles have been proven to be an efficient photothermal conversion material, for which the optical absorption can be broadened through the interband transitions(IBTs), but it remains a challenge due to the strong immiscibility among the repelling combinations. Here, assisted by an extremely high evaporation temperature, ultra-fast cooling and vapor-pressure strategy, the arc-discharged plasma method was employed to synthesize ultra-mixed multi-metallic nanoparticles composed of 21 elements(FeCoNiCrYTiVCuAlNbMoTaWZnCdPbBiAgInMnSn), in which the strongly repelling combinations were uniformly distributed. Due to the reinforced lattice distortion effect and excellent IBTs, the nanoparticles can realize an average absorption of >92% in the entire solar spectrum(250 to 2500 nm). In particular, the 21-element nanoparticles achieve a considerably high solar steam efficiency of nearly 99%under one solar irradiation, with a water evaporation rate of 2.42 kg m-2h-1, demonstrating a highly efficient photothermal conversion performance. The present approach creates a new strategy for uniformly mixing multi-metallic elements for exploring their unknown properties and various applications.

关键词： high-entropy alloy nanoparticle ultra-mixing arc-discharged method photothermal conversion

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基于非对称PVA/墨水/PE双层膜的光驱动柔性致动器和多功能传感器

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Science China materials 2023年第12期66卷 4782-4793页

作者：吴凤林晓莹许雨倩章迪何韵晴刘明贤 Department of materials Science and Engineering College of Chemistry and Materials ScienceJinan UniversityGuangzhou 511443China

聚乙烯醇/中国墨水混合物被均匀涂覆在聚乙烯薄膜上制备了结构稳定的双层软驱动器.由于两层材料的热膨胀系数的显著差异,在氙灯照射下,驱动器能以较快的响应速度实现较大的弯曲变形.通过改变光的强度以及结合尺蠖的仿生结构设计,机器人... 详细信息

聚乙烯醇/中国墨水混合物被均匀涂覆在聚乙烯薄膜上制备了结构稳定的双层软驱动器.由于两层材料的热膨胀系数的显著差异,在氙灯照射下,驱动器能以较快的响应速度实现较大的弯曲变形.通过改变光的强度以及结合尺蠖的仿生结构设计,机器人可以在不同的表面(如纸张和树叶)上实现各种形式的运动.同时在光的驱动下,它可以实现物体的捕获、表情的改变、象鼻的收缩与卷曲以及仿生花朵的开闭等.此外,基于双层驱动器良好的光热转换和灵敏的压力传感性能,它可以实现人体运动监测(如关节弯曲、呼吸、吞咽等),还能与光电转换装置集成.这种多功能、多驱动模式软机器人在可穿戴设备、交通运输、光电转换设备等应用领域具有巨大潜力.

关键词： Chinese ink soft actuator light-driven actuation integration of photoelectric conversion motion monitoring

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Lignin-based carbon fibers: Formation, modification and potential applications

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Green Energy & Environment 2022年第4期7卷 578-605页

作者： Shichao Wang Jixing Bai Mugaanire Tendo Innocent Qianqian Wang Hengxue Xiang Jianguo Tang Meifang Zhu Institute of Hybrid materials College of Materials Science and EngineeringQingdao UniversityQingdao266071China State Key Laboratory for Modification of Chemical Fibers and Polymer materials College of Materials Science and EngineeringDonghua UniversityShanghai201620China

As an aromatic polymer in nature, lignin has recently attracted gross attention because of its advantages of high carbon content, low cost and bio-renewability. However, most lignin is directly burnt for power generation to satisfy the energy demand of the pulp mills. As a result, only a handful of isolated lignin is used as a raw material. Thus, increasing value addition on lignin to expand its scope of applications is currently a challenge demanding immediate attention. Many efforts have been made in the valorization of lignin, including the preparation of precursors for carbon fibers. However, its complex structure and diversity significantly restrict the spinnability of lignin. In this review, we provide elaborate knowledge on the preparation of lignin-based carbon fibers ranging from the relationships among chemical structures, formation conditions and properties of fibers, to their potential applications. Specifically, control procedures for different spinning methods of lignin, including melt spinning, solution spinning and electrospinning, together with stabilization and carbonization are deeply discussed to provide an overall understanding towards the formation of lignin-based carbon fibers. We also offer perspectives on the challenges and new directions for future development of lignin-based carbon fibers.

关键词： Lignin-based carbon fiber Melt spinning Solution spinning Electrospinning

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Variant selection of nanocrystalline a phase in metastableβTB8 titanium alloy via electric pulse treatment

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稀有金属:英文版 2023年第8期42卷 2781-2794页

作者： Shan-Shan Wu Ya Yang Yuan-Biao Tan Song Xiang Ya-Li Zhou Min Ma Fei Zhao Wei Shi Guizhou Key Laboratory of materials Mechanical Behavior and Microstructure College of Materials and MetallurgyGuizhou UniversityGuiyang 550025China College of Materials Science and Engineering Hunan University of Science and TechnologyXiangtan 411201China

In this paper,the metastableβTB8 titanium alloy with nanocrystallineαphase is achieved by electric pulse treatment.The morphology evolution and variant selection of nanocrystallineαphase in metastableβTB8titanium alloy were investigated by using scanning electron microscope(SEM),electron backscattered diffraction(EBSD)and transmission electron microscope(TEM)analysis.The results indicated that the morphologies of the nanocrystallineαphase were mainly triangular clusters and needle-like at the pressure of 0 MPa.With increasing pressure from 20 to 50 MPa,the volume fraction of needlelikeαphase decreased,and a large amount of V-shapedαphase formed in the interior ofβgrains.Based on the EBSD data,the parentβphase was reconstructed by MTEX software.In the interior of theβgrains,12 variants can form for the samples electric pulse treated at 0 and20 MPa,while only 3 and 6 variants can form for the samples electric pulse treated at 30 and 50 MPa.In the grain boundary of theβgrains,one or more grain boundaryαvariants can be generated for the samples electric pulse treated at different pressures as long as one of the neighborβgrains follows the Burgers orientation relationship.

关键词： TB8 titanium alloy Parentβgrain reconstruction Morphology ofαphase Variant selection

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Recovery of vanadium from vanadium slag by composite additive roasting-acid leaching process

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Journal of Iron and Steel Research(International) 2023年第7期30卷 1426-1439页

作者： Jun-yi Xiang Ming-shuai Luo Xi Lu Lu-wei Bai Zhong-peng Zhu Qing-yun Huang Sheng-qin Zhang Kun-peng Guo Xue-wei Lv college of Metallurgy and materials Engineering Chongqing University of Science and TechnologyChongqing 401331China College of Materials Science and Engineering Chongqing UniversityChongqing 400044China

To minimize the vanadium content in the vanadium extraction tailings, composite additive roasting with (CaO + MgO) and subsequent acid leaching process was carried out dealing with vanadium-bearing converter slag. The effect of additive with different MgO/(CaO + MgO) molar ratios on the roasting and leaching behaviours of vanadium slag was investigated, and the optimum process conditions were obtained. The results show that in the roasting experiment, under the conditions of roasting temperature of 850 ℃ and roasting time of 2 h, the main kinds of vanadate transformed from Ca_(2)V_(2)O_(7) to Ca_(5)Mg_(4)V_(6)O_(2)4 and then to Mg_(2)V_(2)O_(7) with the increase in the MgO/(CaO + MgO) molar ratio. In the leaching experiment, under the conditions of particle size less than 75 μm, leaching temperature of 50 ℃, pH of 2.5, liquid–solid ratio of 20:1, and MgO/(CaO + MgO) molar ratio of 1:3, the leaching efficiency of vanadium is increased by about 5%, but the substitution of MgO for most or all of CaO will significantly reduce the leaching efficiency of vanadium. Furthermore, the leaching efficiency of impurities (P and Cr) can also be decreased by a composite addictive (CaO + MgO) roasting process. The X-ray diffraction, scanning electron microscopy, energy dispersive spectrometry, and X-ray photoelectron spectroscopy of the original vanadium slag and solid products of both roasting and leaching processes were also evaluated.

关键词： Vanadium slag Roasting Leaching Vanadate Recovery

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Volume of fluid simulation of single argon bubble dynamics in liquid steel under RH vacuum conditions

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Journal of Iron and Steel Research(International) 2024年第4期31卷 828-837页

作者： Gu-jun Chen Sheng-ping He College of Materials Science and Engineering Yangtze Normal UniversityChongqing 400044China College of Materials Science and Engineering Chongqing UniversityChongqing 400044China

Single argon bubble dynamics in liquid steel under Ruhrstahl-Heraeus(RH)vacuum conditions were simulated using the volume of fluid method,and the ideal gas law was used to consider bubble growth due to heat transfer and pressure drop.Additional simulation with a constant bubble density was also performed to validate the numerical method,and the predicted terminal bubble shape and velocity were found to agree with those presented in the Grace diagram and calculated by drag correlation,respectively.The simulation results under RH conditions indicate that the terminal bubble shape and velocity cannot be reached.The primary bubble growth occurs within a rising distance of 0.3 m owing to heating by the high-temperature liquid steel;subsequently,the bubble continues to grow under equilibrium with the hydrostatic pressure.When the initial diameter is 8-32 mm,the bubble diameter and rising velocity near the liquid surface are 80-200 mm and 0.5-0.8 m/s,respectively.The bubble rises rectilinearly with an axisymmetric shape,and the shape evolution history includes an initial sphere,(dimpled)ellipsoid,and spherical cap with satellite bubbles.

关键词： Bubble dynamics Liquid steel Volume of fluid Bubble growth Bubble shape Rising velocity

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Influence of pre-stretching on the tensile strength,fatigue properties and the in-plane anisotropy in Al-Cu-Li alloy AA2099

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Journal of materials Science & Technology 2023年第14期145卷 249-259页

作者： Xianghui Zhu Xusheng Yang Weijiu Huang Weiyi Qiu Xin Wang Fei Guo Li Hu Miao Gong College of Materials Science and Engineering Kunming University of Science and TechnologyKunming 650093China College of Materials Science and Engineering Chongqing University of Arts and SciencesChongqing 402160China College of Materials Science and Engineering Chongqing University of TechnologyChongqing 400044China

The influence of pre-stretching prior to artificial aging on microstructure,tensile properties,and fatigue behavior of AA2099-T8 sheets was investigated.The results showed that increased pre-strain level from 1%to 6%resulted in a more uniform distribution and increasing density of the T_(1)phase.The localized plastic deformation during pre-stretching led to the formation of dense precipitation bands(DPBs)and precipitation free bands(T_(1)-PFBs)in the sheets with the 1%pre-strain.The non-uniform distribution of the T_(1)phase with T_(1)-PFBs and DPBs resulted in a decrement in elongation and a strong in-plane anisotropy of tensile properties.An appropriate level of pre-strain should be executed aiming to improve elongation and reduce the tensile anisotropy by promoting a uniform distribution of the T_(1)phase.In-plane anisotropy of yield strength due to the presence of DPBs and T_(1)-PFBs was quantitatively analyzed by the modified Hall-Petch formula.The results of the calculation for the modified model showed good agreement with the experiment.In addition,resistances of fatigue crack propagation(FCP)in the same orientation were gradually decreased with the increment of pre-strain due to the increment in yield strength and more uniform distribution of the T_(1)phase.For the in-plane anisotropy of FCP resistance,the main reasons were the development of rough fracture surfaces and the transgranular fracture modes in L-T orientation.

关键词： Aluminum-lithium alloys Precipitation Mechanical properties Fatigue crack propagation

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