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Zircon Hf Isotope Mapping for Understanding Crustal Architecture and Its Controls on mineralization during Early Cretaceous in the Southern Great Xing'an Range,NE China

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Journal of Earth Science 2024年第1期35卷 41-50页

作者： Feng Yuan Huanan Liu Shengjin Zhao Mingjing Fan State Key Laboratory of Geological Processes and mineral resources Collaborative Innovation Center for Exploration of Strategic Mineral ResourcesSchool of Earth ResourcesChina University of GeosciencesWuhan 430074China State Key Laboratory of Geological Processes and mineral resources School of Earth Sciences and ResourcesChina University of GeosciencesBeijing100083China No.10 Institute of Geological Exploration Inner Mongolia Bureau of Geology and Mineral ResourcesChifeng 024000China Key Laboratory of Metallogeny and mineral Assessment Institute of Mineral ResourcesChinese Academy of Geological SciencesBeijing 100037China

Voluminous Early Cretaceous granitoids and associated large-scale ore deposits are distributed within the southern Great Xing'an Range(SGXR),NE *** on previously published geochronology and zircon Hf-isotope data,Hf isotope mapping is undertaken to improve our understanding of crustal architecture and its controls on ore *** ore-related Early Cretaceous granitoids were sourced predominantly from juvenile crust,with the involvement of variable proportions of ancient crustal *** crustal architecture,as inferred from Hf isotopic contour maps,indicates two distinct Hf isotopic domains in SGXR,including(1)a higher-ε_(Hf)(+7 to+11)juvenile crust containing minor ancient crustal material,and(2)a lower-ε_(Hf)(+2 to+6)juvenile crust containing a greater proportion of ancient crustal *** Hf isotopic maps identify links between crustal architecture and regional *** deposits and other deposits with significant Cu production are restricted mainly to the higher-ε_(Hf)juvenile crustal regions in the northern and eastern *** dominated by other metals(e.g.,Mo,Sn,W,Pb,Zn,and Ag)occur mainly in the lower-ε_(Hf)juvenile crustal regions in the southern and western *** between juvenile crust-derived melts and ancient crustal components played an important role on the distribution of various ore metals.

关键词： Hf isotope mapping crustal architecture large-scale Early Cretaceous granitoids distribution of ore deposits southern Great Xing'an Range zircon

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Provenance of the Southeastern South China Block in the Late Triassic and Initiation of Paleo-Pacific Subduction: Evidence from Detrital Zircon U-Pb Geochronology

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Journal of Earth Science 2024年第5期35卷 1426-1446页

作者： Jintao Kong Zhongjie Xu Rihui Cheng Duo Wan college of Earth Sciences Jilin University Key Laboratory of mineral resources Evaluation in Northeast Asia Ministry of Natural and Resources

During the Late Paleozoic–Early Mesozoic Era, the sediment transport system and tectonic regime in the southeastern margin of the South China Block(SESCB) all changed, significantly affected by the Paleo-Pacific subduction. However, controversy exists about the Paleo-Pacific subduction's initiation time. This study uses detrital zircon U-Pb ages to discuss the Late Triassic source-tosink system in the SESCB. It provides some references for the Paleo-Pacific subduction process based on crucial age information and zircons' trace elements. The paleogeography and similarity of detrital zircon age distribution indicate that three sinks were found in the SESCB during the Late Triassic: 1. the Yangchun-Kaiping-Gaoming area, comprising major age ranges of 260–220, 460–400, and 1 200–800 Ma, which might be sourced from the Yunkai terrane; 2. the Jiexi-Kanshi-Nanjing area, characterized by the significant age component of 2 000–1 800 Ma, which corresponded to the Wuyi terrane; 3. the Xinan area, consisting of significant age groups of 290 – 250 and 380 – 320 Ma, which might be sourced from the magmatic rocks formed by the Huinan Movement and Paleo-Pacific subduction. Note that 290–250 Ma zircons were widely distributed in the Upper Triassic strata, and their trace elements suggested the existence of a magmatic arc near the SESCB during the 290–250 Ma. Thus, we propose that the Paleo-Pacific subduction might have begun in the Early Permian.

关键词： detrital zircon geochronology South China Block Paleo-Pacific Block provenance analysis geochronology geochemistry

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A review on vanadium extraction techniques from major vanadium-containing resources

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Rare Metals 2024年第9期43卷 4115-4131页

作者： Yin-Hui Wang Yi-Fan Wang Yu-Ting Li Chang Wu Xiu-Li Han Ning-Ning Zhao Ze-Kun Zhang Lei Dai Ling Wang Zhang-Xing He college of Mining Engineering North China University of Science and Technology Collaborative Innovation Center of Green Development and Ecological Restoration of mineral resources college of Chemical Engineering North China University of Science and Technology

The critical role of vanadium in metallurgy and the increasing commercialization of vanadium redox flow batteries have contributed to a rise in market demand for vanadium, emphasizing the need to ensure the sustainability of vanadium production. Converter vanadium slag and stone coal, generated during the smelting process of vanadium–titanium magnetite, serve as primary raw materials for vanadium extraction. This paper reviews the process mineralogy of converter vanadium slag and stone coal, encompassing the chemical and physical phase compositions of the raw materials and the state of vanadium occurrence. The aim is to establish a theoretical foundation for the mechanistic study of the vanadium extraction techniques and to provide a reference for the optimization of the process afterward. This paper systematically summarizes the current vanadium extraction technology from converter vanadium slag, covering roasting,direct leaching, sub-molten salt method, and the technology and research status of vanadium extraction from stone coal. Most importantly, it identifies key issues in the current vanadium extraction techniques and challenges faced in actual production, based on the analysis of the current vanadium extraction process and mechanism research. The forward feasibility and prospects for the development of vanadium extraction technology are outlined.

关键词： Vanadium

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Structural Stability of Natural Magnesiochromite at High-Temperature-Pressure Conditions

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Journal of Earth Science 2024年第4期35卷 1196-1203页

作者： Shuyu Jin Xiang Wu Yungui Liu Yanfei Zhang Chao Wang State Key Laboratory of Geological Processes and mineral resources China University of GeosciencesWuhan430074China college of Gems and materials Hebei GEO UniversityShijiazhuang050031China

The podiform chromitites in the Luobusha ophiolite have been thought to experience a very deep formation,but the maximum depth is still an open ***,we have investigated the structural stability of natural magnesiochromite using the synchrotron-based powder X-ray diffraction and diamond anvil cells up to 48.6 GPa and 2450 *** results have shown that spinel-type magnesiochromite first decomposes into corundum-type‘Cr_(2)O_(3)’+B1-type‘MgO’at 11–14 GPa and 1250–1450 K,then modified ludwigite(mLd)-type‘Mg_(2)Cr_(2)O_(5)’+corundum-type‘Cr_(2)O_(3)’at 14.3–20.5 GPa and 1300–2000 K,and finally CaTi_(2)O_(4)-type phase at 24.5 *** the quenching procession from high-temperature-pressure conditions,the mLd-type phase appeared again and was kept at ambient *** also obtained the isothermal equation states of spinel-type and CaTi_(2)O_(4)-type phases,revealing the composition effect on their *** on the updated results,we propose chromitites could not experience pressure exceeding∼14.3 GPa(approximate maximum depth∼400 km)in the subduction-recycling genesis model.

关键词： chromite high-temperature and high-pressure phase transitions equation of state chromitites genesis

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Deep learning CNN-APSO-LSSVM hybrid fusion model for feature optimization and gas-bearing prediction

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Petroleum Science 2024年第4期21卷 2329-2344页

作者： Jiu-Qiang Yang Nian-Tian Lin Kai Zhang Yan Cui Chao Fu Dong Zhang college of Earth Sciences and Engineering Shandong University of Science and Technology Laboratory for Marine mineral resources Qingdao National Laboratory for Marine Science and Technology Transportation Institute of Inner Mongolia University Key Laboratory of Gas Hydrate Qingdao Institute of Marine Geology Ministry of Natural Resources

Conventional machine learning(CML) methods have been successfully applied for gas reservoir prediction. Their prediction accuracy largely depends on the quality of the sample data; therefore, feature optimization of the input samples is particularly important. Commonly used feature optimization methods increase the interpretability of gas reservoirs; however, their steps are cumbersome, and the selected features cannot sufficiently guide CML models to mine the intrinsic features of sample data efficiently. In contrast to CML methods, deep learning(DL) methods can directly extract the important features of targets from raw data. Therefore, this study proposes a feature optimization and gas-bearing prediction method based on a hybrid fusion model that combines a convolutional neural network(CNN)and an adaptive particle swarm optimization-least squares support vector machine(APSO-LSSVM). This model adopts an end-to-end algorithm structure to directly extract features from sensitive multicomponent seismic attributes, considerably simplifying the feature optimization. A CNN was used for feature optimization to highlight sensitive gas reservoir information. APSO-LSSVM was used to fully learn the relationship between the features extracted by the CNN to obtain the prediction results. The constructed hybrid fusion model improves gas-bearing prediction accuracy through two processes of feature optimization and intelligent prediction, giving full play to the advantages of DL and CML methods. The prediction results obtained are better than those of a single CNN model or APSO-LSSVM model. In the feature optimization process of multicomponent seismic attribute data, CNN has demonstrated better gas reservoir feature extraction capabilities than commonly used attribute optimization methods. In the prediction process, the APSO-LSSVM model can learn the gas reservoir characteristics better than the LSSVM model and has a higher prediction accuracy. The constructed CNN-APSO-LSSVM mode

关键词： Multicomponent seismic data Deep learning Adaptive particle swarm optimization Convolutional neural network Least squares support vector machine Feature optimization Gas-bearing distribution prediction

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The dynamic characteristics of saturated remolded loess under cyclic load

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Earthquake Research Advances 2024年第2期4卷 27-35页

作者： Yuting Fu Yanbo Cao Jiaxu Kong Jia Zheng Jiaqi Mu Jie Wang Jianqi Zhuang college of Geological Engineering and Geomatics Key Laboratory of Western China Mineral Resources and Geological EngineeringChang’an UniversityXi’an710054China

Due to the joint development characteristic and macropore structure of loess,it is easy to cause structure collapse under earthquake or artificial *** study on the loess disaster effect and its mechanism under earthquake action is insufficient due to its ***,to study the deformation and mechanical properties more accurately,the dynamic characteristics of saturated remolded loess under cyclic dynamic load were tested using a GDS dynamic triaxial instrument in this *** test results show that strain and pore water pressure increase gradually at different rates with the development of vibration,and there is an obvious inflection point in the time-history curve of *** the number of vibrations(N)exceeds this point,the strain increases rapidly,and pore water pressure tends to be *** the action of large amplitude and low-frequency dynamic load,the strain and pore water pressure increase rapidly with fewer vibrations and the deviator stress(q)decreases rapidly,while the sample achieves damage faster with the increase of *** the application of a dynamic load,the effective stress(p)gradually decreases and its rate of change slows ***,when the saturated remolded loess is subjected to a constant-amplitude dynamic load,the combination of large amplitude and low frequency leads to the failure of the sample in the shortest time.

关键词： Loess Pore water pressure Strain Frequency Amplitude Quake(vibration)

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Depositional Responses to the Mongol-Okhotsk Ocean Closure in the Central Area of the Great Xing’an Range: Insights into Thrust Faults and Foreland Basins

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Journal of Earth Science 2024年第3期35卷 797-811页

作者： Zheren Zhao Shichao Li Lingyu Zhang college of Earth Sciences Jilin UniversityChangchun 130061China Key Laboratory of mineral resources Evaluation in Northeast Asia Ministry of Natural ResourcesChangchun 130061China Department of Geosciences and Natural Resource Management University of CopenhagenCopenhagen 1350Denmark

The Mongol-Okhotsk Ocean,which has been closing gradually from the west to the east beginning since the Late Paleozoic,was an important part of the Central Asian Orogenic *** influenced the tectonic framework of Northeast Asia in the Mesozoic,especially the Late Mesozoic arc-basin system that is widely distributed in the Great Xing’an ***,the manner in which the Mongol-Okhotsk Ocean affected the sedimentary basin development remains poorly *** address this issue,we conducted U-Pb dating of detrital zircon deposited sedimentary basins of the central Great Xing’an *** examining the possible provenances of the detrital zircon and the structural controls of the basins,we found that a key sedimentary unit was deposited around Late Jurassic-Early *** provenance was a felsic source in a back-arc setting of an active continental *** findings also suggest the existence of a unified geodynamic setting that affected the coeval development of basins in the northern Great Xing’an Range and the Yanshan fold-thrust belt along the northern margin of North China *** research helps to better understand the complex tectonic processes which shaped the Northeast Asia during the Late Mesozoic.

关键词： Mongol-Okhotsk tectonic domain depositional responses Murui Formation zircon geochemistry tectonics.

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Hydrochemical Characterization,Controlling Factors and Water Quality of Surface Water in Shandong Province,North China

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Journal of Earth Science 2024年第1期35卷 155-166页

作者： Ran An Jiutan Liu Zongjun Gao Changsuo Li Yuming Peng School of Earth Sciences and resources China University of GeosciencesBeijing 100083China college of Earth Science and Engineering Shandong University of Science and TechnologyQingdao 266590China 801 Institute of Hydrogeology and Engineering Geology Shandong Provincial Bureau of Geology&Mineral ResourcesJinan 250014China Key Laboratory of Groundwater resources and Environment Shandong Provincial Bureau of Geology&Mineral ResourcesJinan 250014China Shandong Engineering Research Center for Groundwater Environmental Protection and Remediation Jinan 250014China

In this study,90 surface water samples were collected from Shandong Province(SDP)in the dry and wet seasons and analyzed using statistical analysis,hydrochemical methods and water quality index(WQI).The content of main ions showed seasonal variations,with a higher average value in the dry season than in the wet *** points exhibiting high contents of the main chemical components were mainly distributed in areas southwest of SDP,north of Weifang,and around *** saturation index of carbonate minerals was greater than zero,while that of evaporite minerals was less than *** hydrochemical characteristics of surface water are mainly dominated by rock weathering as well as cation *** addition,surface water in SDP has significantly been affected by anthropogenic *** of the surface water could be classified as weakly alkaline soft-fresh water,with the hydrochemical types of SO_(4)·Cl-Ca·Mg and SO_(4)·*** terms of WQI,47.88% and 37.88% of the water samples in SDP were classified as poor water in the dry and wet seasons,*** the whole,the water quality is higher in the wet season than in the dry season,and surface water in SDP is generally suitable for agricultural irrigation.

关键词： surface water hydrochemical characteristics controlling factors water quality Shandong Province

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The abundance,distribution,and enrichment mechanism of harmful trace elements in coals from Guizhou,Southwestern China

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Acta Geochimica 2024年第5期43卷 889-903页

作者： Hui Hou Wei Cheng Ruidong Yang Yan Zhang college of Mining Guizhou UniversityGuiyangChina National and Local Joint Laboratory of Engineering for Effective Utilization of Regionalmineral resources from Karst Areas GuiyangChina Guizhou Key Laboratory of Comprehensive Utilization of Non-Metallic mineral resources GuiyangChina college of Resource and Environment Engineering Guizhou UniversityGuiyangChina

Coal seams can enrich a variety of harmful trace elements under specific geological *** spatial distribution of harmful trace elements in coal is extremely uneven,and the distribution characteristics of each element content are *** harmful elements released in the process of coal mining and utilization will cause serious harm to the environment and the human *** is of great resource significance to study the geochemistry of coal that affects the enrichment and distribution characteristics of harmful trace *** on the domestic and foreign literature on coal geochemistry in Guizhou published by previous investigators,this study counted 1097 sample data from 23 major coal-producing counties in Guizhou Province,systematically summarized the relevant research results of harmful trace elements in the coal of Guizhou,and revealed the overall distribution and enrichment characteristics of harmful trace elements in the coal of *** results show that the average contents of Cd,Pb,Se,Cu,Mo,U,V,As,Hg,and Cr in coal of Guizhou are higher than those in Chinese coal and world coal.A variety of harmful trace elements in the coal of Guizhou have high background values,especially in Liupanshui,Xingyi and Qianbei *** enrichment of various harmful trace elements in the Late Permian coal in Guizhou is mainly related to the combined action of various geological and geochemical *** supply of terrigenous debris and sedimentary environment may be the basic background of the enrichment of harmful elements in western Guizhou,while low-temperature hydrothermal activity and volcanic ash deposition may be the main reasons for the enrichment of harmful elements in southwestern Guizhou.

关键词： Harmful trace elements Distribution characteristics Enrichment law Geological and geochemical features Guizhou

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Deformation Characteristics of Hydrate-Bearing Sediments

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Journal of Ocean University of China 2024年第1期23卷 149-156页

作者： DONG Lin LI Yanlong ZHANG Yajuan HU Gaowei LIAO Hualin CHEN Qiang WU Nengyou Key Laboratory of Gas Hydrate Ministry of Natural ResourcesQingdao Institute of Marine GeologyQingdao 266237China Laboratory for Marine mineral resources Laoshan LaboratoryQingdao 266237China college of Oceanography Hohai UniversityNanjing 210098China college of Petroleum Engineering China University of Petroleum(East China)Qingdao 266555China

The safe and efficient development of natural gas hydrate requires a deep understanding of the deformation behaviors of *** this study,a series of triaxial shearing tests are carried out to investigate the deformation properties of hydrate-bearing *** of volumetric and lateral strains versus hydrate saturation are analyzed *** indicate that the sediments with high hydrate saturation show dilative behaviors,which lead to strain-softening characteristics during *** volumetric strain curves have a tendency to transform gradually from dilatation to compression with the increase in effective confining *** easy prediction model is proposed to describe the relationship between volumetric and axial *** model coefficientβis the key dominating factor for the shape of volumetric strain curves and can be determined by the hydrate saturation and stress ***,a modified model is established for the calculation of lateral *** corresponding determination method is provided for the easy estimation of model coefficients for medium sand sediments containing *** study provides a theoretical and experimental reference for deformation estimation in natural gas hydrate development.

关键词： gas hydrate deformation characteristics volumetric strain lateral strain prediction model

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