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Constructing Al@C-Sn pellet anode without passivation layer for lithium-ion battery

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International Journal of Minerals,Metallurgy and Materials 2024年第3期31卷 552-561页

作者： Kangzhe Cao Sitian Wang Yanan He Jiahui Ma Ziwei Yue Huiqiao Liu college of Chemistry and Chemical engineering Xinyang Normal UniversityXinyang 464000China Xinyang Key Laboratory of Low-Carbon energy Materials Xinyang 464000China Henan Province Key Laboratory of Utilization of Non-Metallic Mineral in the South of Henan Xinyang 464000China

Al is considered as a promising lithium-ion battery(LIBs)anode materials owing to its high theoretical capacity and appropri-ate lithation/de-lithation ***,its inevitable volume expansion causes the electrode structure instability,leading to poor cyclic ***’s worse,the natural Al2O3 layer on commercial Al pellets is always existed as a robust insulating barrier for elec-trons,which brings the voltage dip and results in low reversible ***,this work synthesized core-shell Al@C-Sn pellets for LIBs by a plus-minus *** this proposal,the natural Al2O3 passivation layer is eliminated when annealing the pre-introduced SnCl2,meanwhile,polydopamine-derived carbon is introduced as dual functional shell to liberate the fresh Al core from re-oxidization and alle-viate the volume *** from the addition of C-Sn shell and the elimination of the Al2O3 passivation layer,the as-prepared Al@C-Sn pellet electrode exhibits little voltage dip and delivers a reversible capacity of 1018.7 mAh·g^(-1) at 0.1 A·g^(-1) and 295.0 mAh·g^(-1) at 2.0 A·g^(-1)(after 1000 cycles),***,its diffusion-controlled capacity is muchly improved compared to those of its counterparts,confirming the well-designed nanostructure contributes to the rapid Li-ion diffusion and further enhances the lithium storage activity.

关键词： lithium-ion battery high-performance anode aluminum passivation layer plus-minus strategy

Virtual Conductance Based Cascade Voltage Controller for VSCs in Islanded Operation Mode

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Journal of Modern Power Systems and Clean energy 2022年第6期10卷 1704-1713页

作者： Francisco Jesús Matas-Díaz Manuel Barragán-Villarejo Juan Carlos Olives-Camps Juan Manuel Mauricio JoséMaría Maza-Ortega Department of elec‐trical engineering Universidad de SevillaSeville 41092Spain

Voltage source converters have become the main enabler for the integration of distributed energy resources in *** the case of islanded operation,these devices normally set the amplitude and frequency of the network voltage by means of a cascade controller composed of an outer voltage control loop and an inner current control *** strategies to compute the gains of both control loops have been proposed in the literature in order to obtain a fast and decoupled response of the voltages at the point of common *** paper proposes an alternative and simple methodology based on the introduction of a virtual conductance in the classic cascade *** strategy allows to design each control loop independently,obtaining a closed-loop response of a first-order *** this way,the gains of each control loop are easily derived from the parameters of the LC coupling filter and the desired closed-loop time ***,a state observer is included in the controller to estimate the inductor current of the LC filter in order to reduce the number of required measurements.A laboratory testbed is used to validate and compare the proposed *** experimental results demonstrate the effectiveness of the proposal both in steady-state and transient regimes.

关键词： Voltage source converter microgrid cascade controller virtual conductance

调节铜催化剂表面分子亲电性以调控电催化二氧化碳还原选择性

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Science China Materials 2024年第6期67卷 1858-1865页

作者：周贤龙单洁琼郑敏李欢夏宝玉郑尧 School of Chemical engineering and Advanced Materials The University of AdelaideAdelaideSA 5005Australia Key Laboratory of Material Chemistry for energy Conversion and Storage(Ministry of Education) Hubei Key Laboratory of Material Chemistry and Service FailureNational Laboratory for OptoelectronicsSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074China Jiangsu Co-Innovation Centre of Efficient Processing and Utilization of Forest Resources College of Chemical EngineeringNanjing Forestry UniversityNanjing 210037China

Cu是唯一能选择性将二氧化碳电还原(CRR)为多碳产物的过渡金属.然而,调控Cu的CRR选择性获得多种产物仍非常具有挑战性.本文选择了一系列具有不同亲电性的分子来修饰Cu催化剂以调控其CRR选择性,从而产生CH_(4)或C_(2)H_(4).理论计算表明... 详细信息

Cu是唯一能选择性将二氧化碳电还原(CRR)为多碳产物的过渡金属.然而,调控Cu的CRR选择性获得多种产物仍非常具有挑战性.本文选择了一系列具有不同亲电性的分子来修饰Cu催化剂以调控其CRR选择性,从而产生CH_(4)或C_(2)H_(4).理论计算表明,分子的亲电性决定催化反应中的质子活度,进而能促进或抑制CRR中的质子耦合电子转移(PCET)过程.实验发现,低亲电性分子(如1,2-双(4-吡啶基)乙烷)可以促进质子转移,加快^(*)CO中间体氢化过程而生成CH_(4),实现58.2%的法拉第效率;而高亲电性分子(如顺-1,2-双(4-吡啶基)乙烯)能构建强的氢键以稳定^(*)CO中间体,促进其偶联生成C_(2)H_(4),实现65.9%的法拉第效率.理论计算结合原位光谱表征揭示,分子亲电性可调节催化剂质子活度,影响CRR反应中^(*)CO氢化或偶联,进而调控CRR选择性.不同于常规的催化剂结构工程,本策略通过调节CRR中的PCET过程来调控选择性,为CRR的发展提供了新的认识.

关键词： molecular electrophilicity Cu catalysts proton transfer CO_(2)electroreduction C1/C2 selectivity

Recent advances in g-C_(3)N_(4)-based direct Z-scheme photocatalysts for environmental and energy applications

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Absorption Enhancement of Ultrathin Crystalline Silicon Solar Cells with Dielectric Si3N4 Nanostructures

Chinese Journal of Structural Chemistry 2024年第2期43卷 66-84页

作者： Xiaoming Fu Haibo Huang Guogang Tang Jingmin Zhang Junyue Sheng Hua Tang School of Intelligent engineering and Technology Jiangsu Vocational College of Finance&EconomicsHuai'anJiangsu223003PR China School of Modem Equipment Manufacturing Changzhou Institute of Light Industry Technology ChangzhouJiangsu213164PR China School of Environmental Science and engineering Qingdao UniversityQingdao266071PR China School of Materials Science and engineering Hainan UniversityHaikou570228PR China

In the midst of the rapid advancement of photocatalysis,direct Z-scheme heterojunction photocatalysts have emerged as a powerful solution to address environmental challenges and the looming energy *** precise engineering of direct Z-scheme heterojunction photocatalysts proves highly beneficial in optimizing their elec-tronic structure,ultimately enhancing their photocatalytic ***,graphitic carbon nitride(g-C_(3)N_(4))has recently gained recognition as a leading candidate for the creation of direct Z-scheme heterojunctions,owing to its favorable attributes such as a moderate band-gap(2.7 eV),high reduction potential and abundant active *** this review,we offer a concise overview of the fundamental principles and recent advancements in g-C_(3)N_(4)-based direct Z-scheme photocatalytic ***,we delve into the various practical applica-tions of g-C_(3)N_(4)-based direct Z-scheme photocatalysts,specifically in the realms of energy conversion and envi-ronmental *** applications include the removal of contaminant pollutants through photocatalytic degradation,water splitting(comprising H_(2)-generation,O_(2)-evolution,and overall water splitting),and CO_(2)***,we present comprehensive characterization methods and strategies aimed at further enhancing the photocatalytic activity of g-C_(3)N_(4)-based direct Z-scheme photocatalytic *** conclude,this review offers summarizing insights and a brief discussion on future challenges and prospects pertaining to g-C_(3)N_(4)-based direct Z-scheme *** believe that this review will inspire continued exploration and foster a deeper understanding of the groundbreaking possibilities within photocatalytic *** also provides valuable guidance for the design and construction of innovative direct Z-scheme photocatalysts.

关键词： Carbon nitride Photocatalyst Z-scheme systems Environmental remediation energy conversion

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Communications in Theoretical Physics 2019年第11期71卷 1346-1352页

作者：谭新玉孙磊张国容邓灿涂伊腾关丽 China Three Gorges University College of Materials and Chemical EngineeringKey Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion MaterialsYichang 443002China Lei Sun Department of Physics Science and Technology Hebei UniversityBaoding 071000China college of elec trical engineering&new energy Hubei Provincial Collaborative Innovation Center for New Energy MicrogridYichang 443002China

A design of ultrathin crystalline silicon solar cell with Si3 N4 circular truncated cone holes(CTCs)arrays on the top is *** this article,we perform an optical simulation of the *** finite-difference time-domain method is used to calculate the optical absorption of different periods,radius of top and bottom circles and depth of Si3 N4 *** short-circuit current density generated by the optimized cells(30.17 mA/cm^2)is 32.44%more than the value gained by control group(with flat Si3 N4).Then adding a layer of back silver to allow us to better analyze optical ***,we simulate the optimization of the same configuration of different silicon thicknesses andfind that our structure does enhance the light *** work uses a combined path towards achieving higher photocurrent ultrathin crystalline silicon solar cells by constructing the texture of anti-reflection coating.

关键词： photovoltaic silicon diffraction gratings antireflection coatings

一体化可拉伸的多功能电化学传感纤维构建微量汗液健康监测织物

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Science China Materials 2024年第1期67卷 251-260页

作者：张安宁周靓靓梁琦敏王欣胡晓康贾康康储宏伟罗勇锋丘龙斌彭慧胜何思斯 Shenzhen Key Laboratory of Flexible Printed electronics Technology School of ScienceHarbin Institute of Technology(Shenzhen)Shenzhen 518055China Department of Mechanical and energy engineering Southern University of Science and TechnologyShenzhen 518055China Hunan Province Key Laboratory of Materials Surface&Interface Science and Technology College of ScienceMaterial Science and Engineering SchoolCentral South University of Forestry and TechnologyChangsha 410004China State Key Laboratory of Molecular engineering of Polymers Department of Macromolecular Science and Laboratory of Advanced MaterialsFudan UniversityShanghai 200438China

透气舒适的传感纺织品可以检测人体汗液中的多种生物标记物,是在日常生活中实现全面健康监测的有效途径.然而,目前的可穿戴柔性电化学纺织品缺乏伸展性,这可能会导致信号不稳定或在移动过程中损坏设备.此外,这些纺织品对多种指示器的集... 详细信息

透气舒适的传感纺织品可以检测人体汗液中的多种生物标记物,是在日常生活中实现全面健康监测的有效途径.然而,目前的可穿戴柔性电化学纺织品缺乏伸展性,这可能会导致信号不稳定或在移动过程中损坏设备.此外,这些纺织品对多种指示器的集成度有限,需要较大的表面积和大量的汗液来激活传感器.在此,我们报告了一种一体化多功能电化学生物传感器纤维,该纤维具有可拉伸性,通过微量汗液即可检测汗液中的多种生物标志物.这种生物传感器是通过将多功能碳纳米管条带以螺旋状排列的方式负载在预先拉伸的聚合物纤维芯上从而充当微电极,并且两者之间具有稳定界面.此外,通过引入超亲水鞘层,提高了生物传感器的汗液捕获效率.该生物传感器能够同时监测pH、K^(+)、Na^(+)、葡萄糖、乳酸和尿酸六种生物标记物,300%的应变下表现出稳定的传感性能.仅需1μL的汗液即可启动对六种生物标记物进行高效检测.由此编织的织物传感系统可以连续、实时地监测多种生物标记信息,从而完成人体健康状况的评估.

关键词：生物传感器生物标记物人体健康状况健康监测聚合物纤维损坏设备伸展性微电极

Joint Optimal Scheduling for electric Vehicle Battery Swapping-charging Systems Based on Wind Farms

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CSEE Journal of Power and energy Systems 2021年第3期7卷 555-566页

作者： Mingfei Ban Jilai Yu Yiyun Yao college of Mechanical and elec-trical engineering Northeast Forestry UniversityHarbin 150040China Department of electrical engineering Harbin Institute of TechnologyHarbin 150001China National Renewable energy Laboratory Golden 80401USA

Insufficiencies in charging facilities limit the broad application of electric vehicles(EVs).In addition,EV can hardly represent a green option if its electricity primarily depends on fossil *** these two problems,this paper studies a battery swapping-charging system based on wind farms(hereinafter referred to as W-BSCS).In a W-BSCS,the wind farms not only supply electricity to the power grid but also cooperate with a centralized charge station(CCS),which can centrally charge EV batteries and then distribute them to multiple battery swapping stations(BSSs).The operational framework of the W-BSCS is analyzed,and some preprocessing technologies are developed to reduce complexity in ***,a joint optimal scheduling model involving a wind power generation plan,battery swapping demand,battery charging and discharging,and a vehicle routing problem(VRP)is *** a heuristic method based on the exhaustive search and the Genetic Algorithm is employed to solve the formulated NP-hard *** results verify the effectiveness of the joint optimal scheduling model,and they also show that the W-BSCS has great potential to promote EVs and wind power.

关键词： Battery swapping station electric vehicle vehicle routing problem wind power

利用过渡金属氧化物调控金属铋纳米片的p轨道从而实现CO_(2)的高效电还原

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Science China Materials 2024年第6期67卷 1965-1974页

作者：尹伟勃刘博文王晓蕾王文倩宋子辰任志宇付宏刚 Key Laboratory of Functional Inorganic Material Chemistry Ministry of Education of ChinaSchool of Chemistry and Materials ScienceHeilongjiang UniversityHarbin 150080China Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education College of Materials Science and Chemical EngineeringHarbin Engineering UniversityHarbin 150001China

p-d轨道之间的相互作用是一种提升电催化性能的有效方法.然而,其对主族金属的电催化CO_(2)还原(eCO_(2)RR)的增强机制尚不清晰.因此,我们向金属Bi纳米片中引入了一系列过渡金属氧化物(TMO:Fe_(2)O_(3)、Co_(3)O_(4)、NiO),并以此研究引... 详细信息

p-d轨道之间的相互作用是一种提升电催化性能的有效方法.然而,其对主族金属的电催化CO_(2)还原(eCO_(2)RR)的增强机制尚不清晰.因此,我们向金属Bi纳米片中引入了一系列过渡金属氧化物(TMO:Fe_(2)O_(3)、Co_(3)O_(4)、NiO),并以此研究引入TMO对Bi物种eCO_(2)RR性能的影响.根据原位傅里叶变换红外光谱(FTIR)和CO_(2)-程序升温脱附(TPD)的结果,Bi/TMO中的TMO可以增强CO_(2)的吸附和活化能力.密度泛函理论(DFT)计算结果表明,Bi活性位点^(*)OCHO吸附能及p轨道的优化可以降低CO_(2)到^(*)OCHO过程和^(*)OCHO到HCOOH过程的理论过电位.同时,由于Bi与TMO之间因复合而发生的电子重排也促进了催化剂与反应物之间的电子传输.因此,在热力学和动力学的双重作用下,Bi/TMO中的Bi活性位点表现出最佳的催化能力,在更宽的电位区间内实现了更高的催化活性和甲酸选择性.其中,Bi/Fe_(2)O_(3)的增强效果最为显著.在500 mV的宽电位区间内达到较高的甲酸的法拉第效率(>90%),在-0.8 VRHE时,甲酸的法拉第效率达到最大值99.7%(Bi的1.11倍),甲酸局部电流密度达到12.65 mA cm^(-2)(Bi的1.86倍).这一研究不仅建立了eCO_(2)RR性能增强与引入TMO之间的关系,也为理性设计高性能电催化剂提供了一条实用的、可扩展的途径.

关键词： transition metal oxides Bi/Fe_(2)O_(3)nanosheets elec-trocatalytic CO_(2)reduction HCOOH p-orbital regulation

Dynamic reconfiguration for TEG systems under heterogeneous temperature distribution via adaptive coordinated seeker

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Protection and Control of Modern Power Systems 2022年第1期7卷 567-585页

作者： Yijun Chen Bo Yang Zhengxun Guo Jingbo Wang Mengmeng Zhu Zilin Li Tao Yu Faculty of electric Power engineering Kunming University of Science and TechnologyKunming 650500China electric Power Research Institute of Yunnan Power Grid Co. LtdKunming 650217China Department of elec-trical engineering Hong Kong Polytechnic UniversityKowloon 999077Hong Kong SARChina college of electric Power South China University of Tech-nologyGuangzhou 510640China.

A thermoelectric generation(TEG)system has the weakness of relatively low thermoelectric conversion efficiency caused by heterogeneous temperature distribution(HgTD).Dynamic reconfiguration is an effective technique to improve its overall energy efficiency under ***,numerous combinations of electrical switches make dynamic reconfiguration a complex combinatorial optimization *** paper aims to design a novel adaptive coordinated seeker(ACS)based on an optimal configuration strategy for large-scale TEG systems with series-paral-lel connected modules under *** properly balance global exploration and local exploitation,ACS is based on'divide-and-conquer'parallel computing,which synthetically coordinates the local searching capability of tabu search(TS)and the global searching capability of a pelican optimization algorithm(POA)during *** addition,an equivalent re-optimization strategy for a reconfiguration solution obtained by meta-heuristic algorithms(MhAs)is proposed to reduce redundant switching actions caused by the randomness of *** case studies are carried out to assess the feasibility and superiority of AcS in comparison with the artificial bee colony algorithm,ant colony optimization,genetic algorithm,particle swarm optimization,simulated annealing algorithm,TS,and *** results indicate that ACS can realize fast and stable dynamic reconfiguration of a TEG system under *** addition,RTLAB platform-based hardware-in-the-loop experiments are carried out to further validate the hardware implemen-tation feasibility.

关键词： Thermoelectric generation systems Dynamic reconfiguration Heterogeneous temperature distribution Adaptive coordinated seeker