检索结果-南通市图书馆

Journal of environmental sciences 2024年第7期141卷 235-248页

作者： Yu Liu Weibao Liu Xinrui Gan Jiangwei Shang Xiuwen Cheng college of Chemistry and environmental science Xinjiang Laboratory of Phase Transitions and Microstructures of Condensed Matter PhysicsYili Normal UniversityYining 835000China Key Laboratory for environmental Pollution Prediction and Control Gansu ProvinceCollege of Earth and Environmental SciencesLanzhou UniversityLanzhou 730000China

In this study,the cobalt-nickel layered double hydroxides(CoNi LDH)were synthesized with a variety of Co/Ni mass ratio,as CoxNiyLDHs.In comparison,Co1Ni3LDH presented the best peroxymonosulfate(PMS)activation efficiency for 2,4-dichlorophenol removal.Meanwhile,CoNi LDH@Nickel foam(CoNi LDH@NF)composite membrane was constructed for enhancing the stability of catalytic performance.Herein,CoNi LDH@NF-PMS system exerted high degradation efficiency of 99.22%within 90 min for 2,4-DCP when[PMS]_(0)=0.4 g/L,Co^(1)Ni^(3)LDH@NF=2 cm×2 cm(0.2 g/L),reaction temperature=298 K.For the surface morphology and structure of the catalyst,it was demonstrated that the CoNi LDH@NF composite membrane possessed abundant cavity structure,good specific surface area and sufficient active sites.Importantly,·OH,SO_(4)·^(-)and^(1)O_(2)played the primary role in the CoNi LDH@NF-PMS system for 2,4-DCP decomposition,which revealed the PMS activation mechanism in CoNi LDH@NF-PMS system.Hence,this study eliminated the stability and adaptability of CoNi LDH@NF composite membrane,proposing a new theoretical basis of PMS heterogeneous catalysts selection.

关键词： CoNi LDH@NF composite membrane Peroxymonosulfate 2,4-dichlorophenol Reactive radicals

Degradation of Rhodamine B by MnFe-LDH/PMS/O_(3) three-phase catalytic system: performance, mechanism and ecotoxicity studies

在线全文

学校读者我要写书评

暂无评论

Frontiers of environmental science & Engineering 2024年第1期18卷 111-127页

作者： Ying Han Ying Yang Weibao Liu Yilong Hou Ce Wang Jiangwei Shang Xiuwen Cheng Key Laboratory of Pollutant Chemistry and environmental Treatment College of Chemistry and Environmental ScienceYili Normal UniversityYining 835000China Key Laboratory for environmental Pollution Prediction and Control of Gansu Province College of Earth and Environmental SciencesLanzhou UniversityLanzhou 730000China

This study developed a novel MnFe-LDH/PMS/O3 three-phase catalytic system to degrade the organic dye RhB, which was used to address the drawbacks of persulfate oxidation and ozonation techniques. The structure, ionic and elemental composition, specific surface area, and magnetic properties of the LDHs were investigated using a variety of physicochemical characterization tools. The results showed that MnFe-LDH had a large specific surface area, a rich crystalline phase composition, and a functional group structure. The RhB degradation rate of MnFe-LDH/PMS/O3 was 0.34 min−1, which was much higher than that of other comparative systems. RhB could be completely degraded in 10 min after optimization and had a significant effect on TOC removal. The system was found to be effective over a wide pH range. Common anions were largely unaffected and humic acid acted as an inhibitor. At the same time, the system had generally effective degradation performance for different dyes. Combined with quenching experiments and EPR, it was found that SO4•−, •OH, O_(2)•−, and 1O_(2) all participated in the reaction, and •OH contributed more. The degradation pathway of RhB was derived by LC-MS, and the T.E.S.T. evaluation found that the toxicity of the intermediate product was significantly reduced. Finally, the stability and availability of LDHs were verified using cycling experiments and metal ion leaching. This work provides a theoretical basis and data support for the synergistic catalysis of PMS/O3 and the deep treatment of dye wastewater.

关键词： Rhodamine B Layered double hydroxides Peroxymonosulfate Ozonation

Characterizing the behavior of surge-type glaciers in the Puruogangri Ice Field, Tibetan Plateau

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Geographical sciences 2024年第6期34卷 1174-1194页

作者： ZHOU Sugang WANG Ninglian LI Zhijie YAO Xiaojun ZHANG Yuje QIN Gexia Shaanxi Key Laboratory of earth Surface System and environmental Carrying Capacity College of Urban and Environmental SciencesNorthwest UniversityXi'an 710127China Institute of earth Surface System and Hazards College of Urban and Environmental SciencesNorthwest UniversityXi'an 710127China college of Geography and environmental science Northwest Normal UniversityLanzhou 730070China

The Puruogangri Ice Field(PIF), classified as an ultra-continental glacier, is considered extremely stable. However, several glaciers in this area have recently experienced surge events with significant instability and information on surge-type glaciers(STGs) in this region remains scarce. In this study, we identified six STGs and reported the observed characteristics of their surging behavior in the region by mapping glacier boundaries, surface flow velocity information, and glacier surface elevation changes using recent Landsat satellite imagery and shuttle radar topography mission(SRTM), TanDEM, and ASTER digital elevation model(AST14DEM) data. These data provide valuable insights into recent glacial processes, flow instability, and rapid glacial movement. During the active phase of the glaciers,all exhibited frontal advances and changes in surface elevation. Owing to limitations in the satellite imagery, flow velocity profiles were only available for glaciers N1(G089071E33998N),NE1(G089128E33943N), and SE3(G089278E33913N) during the active phase. However,these results effectively reflect the velocity variations in both glaciers before, during, and after the surge. Based on the characteristics of the STG, scientific expeditions, and meteorological data, we believe that the surge in PIF was largely influenced by glacier meltwater and changes in subglacial drainage systems.

关键词： glacier surge glacier surface elevation changes glacier surface velocity Puruogangri Ice Field

Life forms affect beta-diversity patterns of larch forests in China

在线全文

学校读者我要写书评

暂无评论

Plant Diversity 2024年第1期46卷 49-58页

作者： Wenjing Fang Qiong Cai Chengjun Ji Jiangling Zhu Zhiyao Tang Jingyun Fang School of Ecology and environmental science Yunnan UniversityKunming 650091China Department of Ecology College of Urban and Environmental Sciencesand Key Laboratory for Earth Surface Processes of the Ministry of EducationPeking UniversityBeijing 100871China

Beta-diversity reflects the spatial changes in community species composition which helps to understand how communities are assembled and biodiversity is formed and maintained. Larch(Larix) forests, which are coniferous forests widely distributed in the mountainous and plateau areas in North and Southwest China, are critical for maintaining the environmental conditions and species diversity. Few studies of larch forests have examined the beta-diversity and its constituent components(species turnover and nestedness-resultant components). Here, we used 483 larch forest plots to determine the total betadiversity and its components in different life forms(i.e., tree, shrub, and herb) of larch forests in China and to evaluate the main drivers that underlie this beta-diversity. We found that total betadiversity of larch forests was mainly dependent on the species turnover component. In all life forms,total beta-diversity and the species turnover component increased with increasing geographic, elevational, current climatic, and paleoclimatic distances. In contrast, the nestedness-resultant component decreased across these same distances. Geographic and environmental factors explained 20%-25% of total beta-diversity, 18%-27% of species turnover component, and 4%-16% of nestedness-resultant component. Larch forest types significantly affected total beta-diversity and species turnover component. Taken together, our results indicate that life forms affect beta-diversity patterns of larch forests in China, and that beta-diversity is driven by both niche differentiation and dispersal limitation. Our findings help to greatly understand the mechanisms of community assemblies of larch forests in China.

关键词： Beta-diversity Species turnover Nestedness-resultant Geographic distance Climatic distance Larch forest

Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第4期35卷 199-203页

作者： Yinyin Xu Yuanyuan Li Jingbo Feng Chen Wang Yan Zhang Yukun Wang Xiuwen Cheng Key Laboratory for environmental Pollution Prediction and Control College of Earth and Environmental SciencesLanzhou UniversityLanzhou 730000China Key Laboratory of Pollutant Chemistry and environmental Treatment College of Chemistry and Environmental ScienceYili Normal UniversityYining 835000China

A novel N, O modified Mn_(3)O_(4)@porous carbon catalyst(NOC-Mn_(3)O_(4)) was prepared by direct carbonization using the manganese-metal organic framework(Mn-MOF) and covalent organic framework(COF) as precursors to activate peroxymonosulfate(PMS) for the degradation of bisphenol A(BPA) and rhodamine B(Rh B). Benefiting from the N and O co-doping of COF, larger specific surface area, faster electron transfer and Mn cycling, the optimum 1NOC-Mn_(3)O_(4)could significantly improve the degradation performance of BPA and Rh B(92.1% and 96.9% within 30 min) as compared to C-Mn_(3)O_(4)without COF doping. In addition, 1NOC-Mn_(3)O_(4) showed good reusability and strong anti-interference ability. Radical quenching experiments, X-ray photoelectron spectroscopy(XPS), Electron paramagnetic resonance spectrometer(EPR) and electrochemical tests showed that the 1NOC-Mn_(3)O_(4)/PMS system degraded BPA and Rh B by both radical and non-radical pathways. Moreover, the possible degradation pathways of BPA and Rh B were proposed by liquid chromatography-mass spectrometry(LC-MS). Except for that, the toxicity of BPA, Rh B and their intermediates were evaluated. This study opens up a new prospect for the design of COF-doped PMS catalysts.

关键词： Peroxymonosulfate Covalent organic framework Mn-metal organic framework Organic pollutant Degradation

Four decades of full-scale nitrous oxide emission inventory in China

在线全文

学校读者我要写书评

暂无评论

National science Review 2024年第3期11卷 137-149页

作者： Minqi Liang Zheyan Zhou Peiyang Ren Han Xiao Xu-Ri Zhongmin Hu Shilong Piao Hanqin Tian Qing Tong Feng Zhou Jing Wei Wenping Yuan School of Atmospheric sciences Guangdong Province Data Center of Terrestrial and Marine Ecosystems Carbon Cycle Sun Yat-sen University State Key Laboratory of Tibetan Plateau earth System Resources and Environment Institute of Tibetan Plateau Research Chinese Academy of Sciences Key Laboratory of Agro-Forestry environmental Processes and Ecological Regulation of Hainan Province Hainan University Sino-French Institute for earth System science College of Urban and Environmental SciencesPeking University Schiller Institute for Integrated science and Society Department of Earth and Environmental Sciences Boston College Institute of Energy Environment and Economy Tsinghua University Southern Marine science and Engineering Guangdong Laboratory(Zhuhai)

China is among the top nitrous oxide（N2O）-emitting countries, but existing national inventories do not provide full-scale emissions including both natural and anthropogenic sources. We conducted a four-decade（1980–2020） of comprehensive quantification of Chinese N2O inventory using empirical emission factor method for anthropogenic sources and two up-to-date process-based models for natural sources. Total N2O emissions peaked at 2287.4（1774.8–2799.9） Gg N2O yr-1in 2018, and agriculture-developed regions, like the East, Northeast, and Central, were the top N2O-emitting regions. Agricultural N2O emissions have started to decrease after 2016 due to the decline of nitrogen fertilization applications, while, industrial and energetic sources have been dramatically increasing after 2005. N2O emissions from agriculture, industry,energy, and waste represented 49.3%, 26.4%, 17.5%, and 6.7% of the anthropogenic emissions in 2020,respectively, which revealed that it is imperative to prioritize N2O emission mitigation in agriculture,industry, and energy. Natural N2O sources, dominated by forests, have been steadily growing from 317.3（290.3–344.1） Gg N2O yr-1in 1980 to 376.2（335.5–407.2） Gg N2O yr-1in 2020. Our study produces a Full-scale Annual N2O dataset in China（FAN2020）, providing emergent counting to refine the current national N2O inventories.

关键词： nitrous oxide four decades anthropogenic sources natural sources

Machine learning assisted adsorption performance evaluation of biochar on heavy metal

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Frontiers of environmental science & Engineering 2024年第5期18卷 29-42页

作者： Qiannan Duan Pengwei Yan Yichen Feng Qianru Wan Xiaoli Zhu Shaanxi Key Laboratory of earth Surface System and environmental Carrying Capacity College of Urban and Environmental SciencesNorthwest UniversityXi’an710127China Department of Environment science Shaanxi Normal UniversityXi’an710062China

Heavy metals(HMs)represent pervasive and highly toxic environmental pollutants,known for their long latency periods and high toxicity levels,which pose significant challenges for their removal and degradation.Therefore,the removal of heavy metals from the environment is crucial to ensure the water safety.Biochar materials,known for their intricate pore structures and abundant oxygen-containing functional groups,are frequently harnessed for their effectiveness in mitigating heavy metal contamination.However,conventional tests for optimizing biochar synthesis and assessing their heavy metal adsorption capabilities can be both costly and tedious.To address this challenge,this paper proposes a data-driven machine learning(ML)approach to identify the optimal biochar preparation and adsorption reaction conditions,with the ultimate goal of maximizing their adsorption capacity.By utilizing a data set comprising 476 instances of heavy metal absorption by biochar,seven classical integrated models and one stacking model were trained to rapidly predict the efficiency of heavy metal adsorption by biochar.These predictions were based on diverse physicochemical properties of biochar and the specific adsorption reaction conditions.The results demonstrate that the stacking model,which integrates multiple algorithms,allows for training with fewer samples to achieve higher prediction accuracy and improved generalization ability.

关键词： Machine learning Biochar Heavy metal Adsorption efficiency

COF-based membranes for liquid phase separation:Preparation,mechanism and perspective

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of environmental sciences 2024年第7期141卷 63-89页

作者： Yujie Zhao He Gu Yilun Zhou CaimeiWen Xiaolu Liu Suhua Wang Zhongshan Chen Hui Yang Xiangke Wang college of environmental science and Engineering North China Electric Power UniversityBeijing 102206China School of environmental science and Engineering Guangdong University of Petrochemical TechnologyMaoming 525000China

Covalent organic frameworks(COFs)are a new kind of crystalline porous materials composed of organic molecules connected by covalent bonds,processes the characteristics of low density,large specific surface area,adjustable pore size and structure,and easy to functionalize,which have been widely used in the field of membrane separation technology.Recently,there are more and more researches focusing on the preparation methods,separation application,and mechanism of COF membranes,which need to be further summarized and compared.In this review,we primarily summarized several conventional preparation methods,such as two-phase interfacial polymerization,in-situ growth on substrate,unidirectional diffusion method,layer-by-layer assembly method,mixed matrix membranes,and so on.The advantages and disadvantages of each method are briefly summarized.The application potential of COF membrane in liquid separation are introduced from four aspects:dyeing wastewater treatment,heavy metal removal,seawater desalination and oil-water separation.Then,the mechanisms including pore structure,hydrophilic/hydrophobic,electrostatic repulsion/attraction and Donnan effect are introduced.For the efficient removal of different kind of pollutions,researchers can select different ligands to construct membranes with specific pore size,hydrophily,salt or organic rejection ability and functional group.The ideas for the design and preparation of COF membranes are introduced.Finally,the future direction and challenges of the next generation of COF membranes in the field of separation are prospected.

关键词： Covalent organic frameworks Membrane materials Liquid phase separation Separation mechanism

Cardiac energy metabolism disorder mediated by energy substrate imbalance and mitochondrial damage upon tebuconazole exposure

在线全文

学校读者我要写书评

暂无评论

Journal of environmental sciences 2024年第2期136卷 270-278页

作者： Tingting Ku Jindong Hu Mengmeng Zhou Yuanyuan Xie Yutong Liu Xin Tan Lin Guo Guangke Li Nan Sang college of environmental science and Resources Research Center of Environment and HealthShanxi UniversityTaiyuan 030006China

Tebuconazole exposure has been described as an increasing hazard to human health.An increasing number of recent studies have shown a positive association between tebuconazole exposure and cardiovascular disease risk,which is characterized by the reduction of adenosine triphosphate(ATP)synthesis.However,researches on the damage of tebuconazole exposure to energy metabolism and the related molecular mechanisms are limited.In the present study,male C57BL/6 mice were treated with tebuconazole at different low concentrations for 4 weeks.The results indicated that tebuconazole could accumulate in the heart and further induce the decrease of ATP content in the mouse heart.Importantly,tebuconazole induced an obvious shift in substrate utilization of fatty acid and glucose by disrupting their corresponding transporters(GLUT1,GLUT4,CD36,FABP3 and FATP1)expression,and significantly repressed the expression of mitochondrial biogenesis(Gabpa and Tfam)and oxidative phosphorylation(CS,Ndufa4,Sdhb,Cox5a and Atp5b)related genes in a dosedependent manner.Further investigation revealed that these alterations were related to the IRS1/AKT and PPARγ/RXRαpathways.These findings contribute to a better understanding of triazole fungicide-induced cardiovascular disease by revealing the key indicators associated with this phenomenon.

关键词： Tebuconazole Cardiotoxicity Energy metabolic disorders Energy substrate Mitochondrial damage

Degradation of iopamidol in the permanganate/sulfite process:Evolution of iodine species and effect on the subsequent formation of disinfection by-products

在线全文

学校读者我要写书评

暂无评论

Journal of environmental sciences 2024年第1期135卷 345-352页

作者： Yimin Lin Hongyu Dong Yating Zhu Gongming Zhou Junlian Qiao Xiaohong Guan State Key Laboratory of Pollution Control and Resources Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Department of environmental science School of Ecological and Environmental SciencesEast China Normal UniversityShanghai 200241China

Permanganate/sulfite(Mn(VII)/S(IV))process is a promising pre-oxidation technology for sequestering the emerging organic contaminants in drinking water treatment plant.Iopamidol(IPM),a representative of iodinated X-ray contrast media,has been widely detected in water sources and has the risk of forming iodinated disinfection byproducts(I-DBPs)in water treatment system.In this study,we investigated the evolution of iodine species during the IPM degradation by the Mn(VII)/S(IV)process and its effect on the subsequent formation of I-DBPs during chlorination at pH 7.0 and 8.0.IPM could be effectively degraded in the Mn(VII)/S(IV)process at environmentally relevant pH(pH 7.0 and 8.0).The results of quenching and competitive oxidation kinetic experiments revealed that SO^(·-)_(4)was the major reactive oxidizing species contributing to the degradation of IPM whereas the contributions of HO·and reactive manganese species were negligible in the Mn(VII)/S(IV)process.I–and IO–3were generated while no HOI was detected during the degradation of IPM in the Mn(VII)/S(IV)process.The effects of IPM oxidation by Mn(VII)/S(IV)on the subsequent formation of chlorinated disinfection by-products(Cl-DBPs)during chlorination were related to the category of Cl-DBPs.The pre-oxidation of IPM by Mn(VII)/S(IV)resulted in the generation of I-DBPs during the disinfection process although no I-DBPs were detected if no pre-oxidation was applied.The finding of this study suggested that attention should be paid to the toxicity of DBPs when water containing iodinated organic contaminants is treated by Mn(VII)/S(IV)process or other pre-oxidation technologies.

关键词： Permanganate/sulfite Iopamidol Sulfate radical Iodinated disinfection byproducts Pre-oxidation