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Hydrothermal carbonization pretreatment makes a remarkable difference in activation of rice and lettuce in food waste

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Green Chemical engineering 2024年第3期5卷 348-363页

作者： Lijun Zhang Yifan Sun Chao Li Shu Zhang Mortaza Gholizadeh Xun Hu School of material Science and engineering University of Jinan Joint International Research Laboratory of Biomass Energy and materials College of Materials Science and Engineering Nanjing Forestry University Faculty of Chemical and Petroleum engineering University of Tabriz

Cooked rice and the vegetables like lettuce are common kitchen waste, which are carbonaceous materials and have the potential as feedstock for the production of activated carbon. Cooking is similar to hydrothermal treatment（HTC）, which might impact the subsequent activation of kitchen waste. In this study, the HTC of lettuce, rice, or their mixture and the activation of the resulting hydrochars were conducted. The results indicated that cross-polymerization between the N-containing organics from lettuce and the sugar derivatives from rice took place in their co-HTC, which significantly increased the hydrochar yield. Activation of the hydrochar from the coHTC generated the AC with a yield of 2 times that from direct activation of mixed lettuce/rice. However, the coHTC facilitated aromatization, reducing reactivity with K2C2O4in activation and producing the AC with main micropores and low specific surface area. Activation of the hydrochar from HTC of rice followed the above trend,while that from lettuce was the opposite. The organics in lettuce were thermally unstable and could not undergo sufficient aromatization. The activation of hydrochar from HTC of lettuce thus generated the AC with the lowest yield, but the highest specific surface area（1684.9 m2/g）, abundant mesopores, and superior capability for adsorption of tetracycline. However, the environmental impacts and energy consumption for the production of AC from the hydrochar of lettuce were higher than that from hydrochar of co-HTC.

关键词： Food waste Hydrothermal pretreatment Hydrochar Chemical activation Products properties

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Robust Cross-Linked Na3V2（PO4）2F3 Full Sodium-Ion Batteries

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Energy & Environmental materials 2024年第1期7卷 13-24页

作者： Jinqiang Gao Ye Tian Lianshan Ni Baowei Wang Kangyu Zou Yingchang Yang Ying Wang Craig E.Banks Dou Zhang Kechao Zhou Huan Liu Wentao Deng Guoqiang Zou Hongshuai Hou Xiaobo Ji college of Chemistry and Chemical engineering Central South University college of material and Chemical engineering Tongren University Department of Chemistry The Chinese University of Hong Kong Faculty of Science and engineering Manchester Metropolitan University State Key Laboratory of Powder Metallurgy Central South University School of materials Science and engineering Hunan Provincial Key Lab of Advanced Materials for New Energy Storage and Conversion Hunan University of Science and Technology School of materials and engineering Zhengzhou University

Sodium-ion batteries（SIBs） have rapidly risen to the forefront of energy storage systems as a promising supplementary for Lithium-ion batteries（LIBs）.Na3V2（PO4）2F3（NVPF） as a common cathode of SIBs,features the merits of high operating voltage,small volume change and favorable specific energy ***,it suffers from poor cycling stability and rate performance induced by its low intrinsic conductivity.

关键词： dual-nanocarbon networks full sodium-ion battery ion transfer kinetics Na3V2(PO4)2F3 NASICON structure

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Utilizing a metal-forging inspired chain combing strategy to enhance properties and expand applications of Nylon 66 plastic via heat inducing

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Nano Research 2024年第3期17卷 2164-2171页

作者： Junyu Yang Jiangwei Zhang Nan Wang Guangyuan Zhou Division of Energy materials Daglian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China Innovation Center of Energy material and Chemistry College of Chemistry and Chemical EngineeringInner Mongolia UniversityHohhot 010021China

The mechanical properties of engineering plastics can be enhanced through effective surface mechanical treatment(SMT),which can be applied to various types of engineering plastics,eliminating the limitations of conventional polymer processing and could potentially extend their applications and improve their performance and reliability as structural-functional *** by metal forging,this work proposes a simple and effective SMT strategy to enhance the mechanical properties of polyamide 66(PA66).Tensile tests have shown that SMTed PA66 samples exhibit significant improvements in both Young’s modulus and ultimate tensile strength(UTS),with a 2104 MPa Young’s modulus,almost double that of the pristine samples,and a 35.56%increase in UTS,reaching 183 ***,the modulus within the localized SMTed surface layer could reach up to 14 GPa,which is approximately 14 times higher than that of the pristine *** Vickers hardness within the localized SMTed surface layer can be doubled,reaching 10.72 Hv,and the crystallinity can increase by approximately 20%compared to the untreated ***,force field molecular dynamics(FFMD)simulations were conducted to investigate the ternary relationship between the SMT method,PA66’s molecular structure,and its *** combination of MD simulations and versatile structural characterizations provides evidence that the SMT method’s mechanism,under heat induction,results in a chain-combing procedure that changes the polymer’s molecular morphology microscopically and enhances its mechanical properties macroscopically.

关键词： Nylon 66 mechanical properties hardness crystallinity structural characterizations molecular dynamics simulation

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An active high-static-low-dynamic-stiffness vibration isolator with adjustable buckling beams:theory and experiment

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Applied Mathematics and Mechanics(English Edition) 2024年第3期45卷 425-440页

作者： Kefan XU Muqing NIU Yewei ZHANG Liqun CHEN School of Science Harbin Institute of TechnologyShenzhen 518055Guangdong ProvinceChina college of aerospace engineering Shenyang Aerospace UniversityShenyang 110136China Shanghai Key Laboratory of Mechanics in Energy engineering Shanghai Frontier Science Center of MechanoinformaticsShanghai Institute of Applied Mathematics and MechanicsSchool of Mechanics and Engineering ScienceShanghai UniversityShanghai 200444China Shanghai Institute of Aircraft Mechanics and Control Shanghai 200092China

High-static-low-dynamic-stiffness(HSLDS)vibration isolators with buckling beams have been widely used to isolate external *** active adjustable device composed of proportion integration(PI)active controllers and piezoelectric actuators is proposed for improving the negative stiffness stroke of buckling beams.A nonlinear output frequency response function is used to analyze the effect of the vibration *** prototype of the active HSLDS device is built,and the verification experiment is *** results show that compared with the traditional HSLDS vibration isolator,the active HSLDS device can broaden the isolation frequency bandwidth,and effectively reduce the resonant amplitude by adjusting the active control *** maximum vibration reduction rate of the active HSLDS vibration isolator can attain 89.9%,and the resonant frequency can be reduced from 31.08 Hz to 13.28 ***,this paper devotes to providing a new design scheme for enhanced HSLDS vibration isolators.

关键词： active control high-static-low-dynamic-stiffness(HSLDS) vibration isola-tor dynamic analysis

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Phase reconfiguration of heterogeneous CoFeS/CoNiS nanoparticles for superior battery-type supercapacitors

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Journal of Energy Chemistry 2024年第9期96卷 217-225页

作者： Lina Ma Fan Li Min Zhou Jidong Dong Hao Luo Wei Zhang Wenchao Zhao Xinliang Li Zaixing Jiang Yudong Huang college of Chemistrynd Chemical engineering Qingdao UniversityQingdao 266071ShandongChina School of materials Sciencend engineering Xiamen University of TechnologyXiamen 361024FujianChina Co-Innovation Center of Efficient Processingnd Utilization of Forest Resources College of Materials Sciencend EngineeringNanjing Forestry UniversityNanjing 210037JiangusChina Key Laboratory of material Physics Ministry of EducationSchool of Physicsnd MicroelectronicsZhengzhou UniversityZhengzhou 450052HenanChina MIIT Key Laboratory of Critical materials Technology for New Energy Conversionnd Storage State Key Laboratory of Urban Water Resourcend EnvironmentSchool of Chemistrynd Chemical EngineeringHarbin Institute of TechnologyHarbin 150001HeilongjiangChina material Sciencend engineering college Northeast Forestry UniversityHarbin 150040HeilongjiangChina

Developing advanced battery-type materials with abundant active sites,high conductivity,versatile morphologies,and hierarchically porous structures is crucial for realizing high-quality hybrid ***,heterogeneous FeS@NiS is synthesized by cationic Co doping via surface-structure *** density functional theory(DFT)theoretical calculations are firstly performed to predict the advantages of Co dopant by improving the OH^(−)adsorption properties and adjusting electronic structure,benefiting ions/electron *** dynamic surface evolution is further explored which demonstrates that CoFeS@CoNiS could be quickly reconstructed to Ni(Co)Fe_(2)O_(4)during the charging process,while the unstable structure of the amorphous Ni(Co)Fe_(2)O_(4)results in partial conversion to Ni/Co/FeOOH at high potentials,which contributes to the more reactive active site and good structural ***,the free-standing electrode reveals excellent electrochemical performance with a superior capacity(335.6 mA h g^(−1),2684 F g^(−1))at 3 A g^(−1).Furthermore,the as-fabricated device shows a quality energy density of 78.1 W h kg^(−1)at a power density of 750 W kg^(−1)and excellent cycle life of 92.1%capacitance retention after 5000 *** work offers a facile strategy to construct versatile morphological structures using electrochemical activation and holds promising applications in energy-related fields.

关键词： In-situ reconfiguration Heterogeneous design Battery-type supercapacitors Superior performance Sulphide

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A multiple flame-retardant,early fire-warning,and highly sensitive thread-shaped all-fabric-based piezoresistive sensor

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Science China(Technological Sciences) 2024年第4期67卷 1151-1159页

作者： LI WeiBiao ZHANG Shuai MA ShuQi WANG JiaCheng WANG Huan YANG QiRong SONG YongTao ZHU Jie North China Institute of aerospace engineering Langfang 065000China Langfang Fire and Rescue Division of Hebei Province Langfang 065000China School of Information Science and engineering Xinjiang College of Science and TechnologyKorla 841000China

In the artificial intelligence age,multifunctional and intelligent fireproof fabric-based electronics are urgently ***,a novel thread-shaped all-fabric-based piezoresistive sensor(denoted as TAFPS)with properties such as flame retardancy,firewarning,and piezoresistivity is proposed,which is composed of an inner nickel-plated fabric electrode,a multifunctional double helix fabric,and an external flame-retardant encapsulation *** to the multiple flame-retardant properties of glass fiber tubular fabric,aminated carbon nanotubes(ACNTs),and ammonium polyphosphate,the char residue of the TAFPS reaches40.3 wt%at 800℃.In addition,the heat-sensitive effect of ACNTs during combustion causes a rapid decrease in the TAFPS resistance,triggering the fire alarm system within 2 ***,benefiting from the force-sensitive behavior of the double helix layer and tightly wrapped pattern of the external heat-shrinkable tubular fabric,TAFPS demonstrated a high sensitivity of4.40 kPa^(-1)(0–5.81 k Pa)and good stability for 10000 *** its excellent flame resistance,high sensitivity,and agreeable stability,the developed TAFPS can be integrated into fire suits to monitor the exercise training process and the external fire *** work offers a novel approach for fabricating all-fabric-based piezoresistive sensors in the future for fire prevention and fire alarms,with promising applications in fire protection,the Internet of Things,and smart apparel.

关键词： all-fabric piezoresistive sensor multiple flame retardancy agile fire-warning high sensitivity

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Raman signal enhancement for gas detection using a dual near-concentric cavities group

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Chinese Optics Letters 2024年第5期22卷 47-52页

作者：任一凡杨德旺孙颖欣许家旋刘硕芳陈月娥 Key Laboratory for Microstructural material Physics of Hebei Province School of ScienceYanshan UniversityQinhuangdao 066004China college of Ocean Science and engineering Shandong University of Science and TechnologyQingdao 266590China

Effective methods are urgently required to optimize Raman spectroscopy technology to ameliorate its low detection ***,we superposed two near-concentric cavities to develop a dual near-concentric cavities group(DNCCG)to assess its effect on gas Raman signal intensity,signal-to-noise ratio(SNR),and limit of detection(LOD).The results showed that DNCCG generally had higher CO_(2) Raman signal intensity than the sum of two near-concentric ***,the noise intensity of DNCCG was not enhanced by the superposition of near-concentric ***,DNCCG increased the *** LOD for CO_(2) was 24.6 parts per *** could be an effective method to improve the detection capability of trace gases and broaden the dynamic detection range,which might aid the future development of innovative technology for multicomponent gas detection.

关键词： Raman spectroscopy gas detection sensitivity dual near-concentric cavities group

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NHC-derived carbon-centered luminescent radicals with shortwavelength emission via suppression of Kasha's rule

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Science China Chemistry 2024年第8期67卷 2679-2685页

作者： Can Chen Xin Li Xinhua Ouyang Ying-Feng Han Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Xi’an Key Laboratory of Functional Supramolecular Structure and MaterialsCollege of Chemistry and Materials ScienceNorthwest UniversityXi’an 710127China college of material engineering Fujian Agriculture and Forestry University Fuzhou 350108China

Luminescent organic radicals have garnered increasing attention owing to their versatile applications in sensing, imaging, and organic light-emitting diodes(OLEDs), attributed to their unique emission properties originating from the doublet spin ***, the natural narrow bandgap of organic free radicals typically limits their emission to the long-wavelength *** luminescent organic radicals with short-wavelength emission remains a significant challenge. Herein, a series of carbon-centered radicals with short-wavelength emission(383–476 nm) by combining N-heterocyclic carbenes with various polycyclic aromatic hydrocarbons(PAHs)(2-naphthyl, 2a~Ⅰ and 2b~Ⅰ;2-phenanthryl, 2a~Ⅱand 2b~Ⅱ;2-anthryl, 2a~Ⅲand 2b~Ⅲ;3-phenanthryl, 2a~Ⅳand 2b~Ⅳ). Theoretical calculations reveal that the introduction of PAHs significantly increases the ΔE_(D2-D1) in 2a^(Ⅰ–Ⅲ)and 2b^(Ⅰ–Ⅲ)compared to that in phenyl-derived radical congeners. Consequently, the internal transition from D2 to D1 is impeded, leading to a high yield of D2 emission and a suppressed Kasha's rule, thereby overcoming the limitations imposed by their narrow bandgap. For 2a~Ⅳ and 2b~Ⅳ, despite a moderately large ΔED2-D1value, the ΔED3-D1value exceeds 1 e V, indicating that their emission likely originates from the D3 state. Furthermore, we utilized 2a~Ⅲand 2b~Ⅲ as emissive materials in OLEDs,resulting in blue emissions with external quantum efficiencies of 7.5% and 6.5%, respectively.

关键词： N-heterocyclic carbenes luminescent organic molecules carbon-centered radicals short-wavelength emission

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Fabrication of UV-Curing Linalool-Polysiloxane Hybrid Films with High Refractive Index and Transparency

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Journal of Renewable materials 2024年第3期12卷 569-583页

作者： Wenqing Xiao Lewen Tan Xunjun Chen Qiaoguang Li Yunqing Ruan college of Chemistry and Chemical engineering Zhongkai University of Agriculture and EngineeringGuangzhou510225China R&D Department Guangzhou Silicon Core Material Technology Co.Ltd.Guangzhou510220China

In this article,a series of high refractive indices(1.50-1.53)thiol phenyl polysiloxane(TPS)were synthesized via hydrolytic sol-gel *** Fourier transform infrared spectra(FT-IR)and nuclear magnetic resonance spectra(NMR)results showed that TPS conformed to the predicted *** terpene linalool was exploited as photocrosslinker to fabricate UV-curing linalool-polysiloxane hybrid films(LPH)with TPS via photoinitiated thiol-ene *** rapidly cured under UV irradiation at the intensity of 80 mW/cm^(2) in 30 s,exhibiting good UV-curing *** optical transmittance of LPH in the wavelength of 300-800 nm was over 90%,exhibiting good optical *** water contact angle and water vapor permeability results showed that the introduction of phenyl groups enhance the hydrophobicity and water vapor barrier properties of *** results indicated the potential of LPHs in the applications of optical functional coatings.

关键词： UV-curing polysiloxane hybrid films high refractive index transparency

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Application of epoxy resin in cultural relics protection

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Chinese Chemical Letters 2024年第4期35卷 31-42页

作者： Zhaoru Chen Xiaoxu Liu Haonan Chen Jialong Li Xiaofeng Wang Jianfeng Zhu Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic materials School of Material Science and EngineeringShaanxi University of Science and TechnologyXi'an 710021China college of Mechanical&Electrical engineering Shaanxi University of Science and TechnologyXi'an 710021China

Cultural relics have their unique artistic, cultural and historical value, and the protection of important cultural relics is conducive to the inheritance of historical culture. As a kind of cementing agent and binder commonly seen in cultural relics protection, epoxy resin is widely used in the bonding and consolidation of various materials in cultural relics, which has important practical application value. In this review, a systematic classification of commonly used epoxy resins, including their molecular structures, synthesis reactions and properties are provided, the problems and solutions of epoxy resin in cultural relics protection are summarized. The solutions are classified into three aspects: functional epoxy resin, blending modification, and other modification. Representative application examples of epoxy resin are listed in the field of cultural relics protection, and the development direction of epoxy resin in cultural relics protection in the future is proposed, which provides useful guidance for the modification of epoxy resin and its application in cultural relics protection in the future.

关键词： Epoxy resin Cultural relics Modified UV resistance

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