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Recent progress in constructing fluorinated solid-electrolyte interphases for stable lithium metal anodes

International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 270-291页

作者： Di Zhang Pengfei Lv Wei Qin Xin He Yuanhua He civil Aircraft Fire Science and Safety Engineering Key Laboratory of Sichuan Province College of Civil Aviation Safety EngineeringCivil Aviation Flight University of ChinaGuanghan 618307China School of Chemical Engineering Sichuan UniversityChengdu 610065China

Lithium metal batteries(LMBs)are emerging as a promising energy storage solution owing to their high energy density and specific ***,the non-uniform plating of lithium and the potential rupture of the solid-electrolyte interphase(SEI)during extended cycling use may result in dendrite growth,which can penetrate the separator and pose significant short-circuit *** a stable SEI is essential for the long-term operation of the ***-rich SEI has garnered significant attention for its ability to effectively passivate electrodes,regulate lithium deposition,and inhibit electrolyte *** the structural components and preparation methods of existing fluorinated SEI is crucial for optimizing lithium metal anode *** paper reviews the research on optimizing LiF passivation interfaces to protect lithium metal *** focuses on four types of compositions in fluorinated SEI that work synergistically to enhance SEI *** instance,combining compounds with LiF can further enhance the mechanical strength and ionic conductivity of the *** metals with LiF significantly improves electrochemical performance at the SEI/anode interface,with a necessary focus on reducing electron tunneling ***,incorporating polymers with LiF offers balanced improvements in interfacial toughness and ionic conductivity,though maintaining structural stability over long cycles remains a critical area for future *** alloys combined with LiF increase surface energy and lithium affinity,challenges such as dendrite growth and volume expansion *** summary,this paper emphasizes the crucial role of interfacial structures in LMBs and offers comprehensive guidance for future design and development efforts in battery technology.

关键词： LiF lithium metal anodes solid-electrolyte interphase interface cycling stability

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On Behaviors of Functionally Graded SMAs under Thermo-Mechanical Coupling

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Acta Mechanica Solida Sinica 2016年第1期29卷 46-58页

作者： Bingfei Liu Pengcheng Ni Wei Zhang Airport college Civil Aviation University of China Sino-European Institute of aviation Engineering Civil Aviation University of China

An analytical solution is obtained for the Functionally Graded Shape Memory Alloy （FG-SMA） composites subjected to thermo-mechanical coupling. Young＇s modulus and thermal expansion coefficient of the material are assumed to vary in different forms of power function through the thickness, with the Poisson＇s ratio being constant. An SMA constitutive model is combined with the averaging techniques of composite to determine the mechanical properties of the FG-SMA composites. Different phase transformation steps and the corresponding stress distributions through the thickness direction are given. The results show that the average stresses decrease as the transformations proceed.

关键词： functionally graded SMAs phase transformation constitutive model

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An Improved Enthalpy-Based Lattice Boltzmann 3D Model with Added Probability Function for the Growth Characteristics of Frost Layer

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Journal of Thermal Science 2019年第2期28卷 378-392页

作者： CUI Jing YANG Tinghao YANG Fan YANG Guangfeng Airport college Civil Aviation University of China

In this paper, the effects of different surface properties on the growth of frost layer were numerically studied from the mesoscopic scale using the lattice Boltzmann method. The improved enthalpy method and nucleation probability model were combined to establish a three-dimensional lattice Boltzmann model based on nucleation probability theory. The model was used to carry out numerical research on frost layer formation and growth process on cold wall surface. The model could not only simulate the gradual densification and thickening process of frost layer growth from the macro scale, but also describe the change process of the frost layer structure caused by ice branch growth on the micro scale. The average thickness, average density and the amount of the frost layer could be obtained. Through this model, the temporal and spatial evolution characteristics of the topography of the frost layer were obtained. The model was used to analyze the effects of cold wall surface temperature, relative humidity and cold surface wettability on the frosting characteristics. The average thickness, frost average density, frost quality and average solid volume fraction of frost at different times were obtained by calculation.

关键词： lattice Boltzmann model improved enthalpy model nucleation probability model three-dimensional frost surface wettability

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Brownian Dynamics Simulations of Rigid Polyelectrolyte Chains Grafting to Spherical Colloid

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Chinese Journal of Polymer Science 2018年第6期36卷 791-798页

作者： Qing-Hai Hao Zhen Zheng Gang Xia Hong-Ge Tan college of Science Civil Aviation University of China

Brownian dynamics simulations are employed to explore the effects of chain stiffness and trivalent salt concentration on the conformational behavior of spherical polyelectrolyte brush. The rigid brush adopts bundle-like morphology at a wide range of trivalent salt concentration. The number variation of bundles pinned on the colloid surface shows a non-monotonic profile as a function of the chain stiffness. The radial distributions of monomers and ions and the charge ratio between condensed ions and monomers are calculated. The charge inversion is observed for the high salt concentration regardless of chain rigidity. Furthermore, the pair correlation functions of monomer-monomer and monomer-salt cation are used to elucidate the aggregated mechanism of the bundle-like structure.

关键词： Brownian dynamics simulation Spherical polyelectrolyte brush Chain stiffness Trivalent salt concentration Pinned bundle morphology

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STRUCTURE EVOLUTION OF THE CYLINDRICAL PHASE OF DIBLOCK COPOLYMERS IN FILMS

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Chinese Journal of Polymer Science 2008年第6期26卷 759-766页

作者：谭红革 college of Science Civil Aviation University of China

In the weak segregation limit,the structure evolution of the hexagonal cylindrical phase of diblock copolymers in films was *** the Landau-Brazovskii mean field theory,we obtained three amplitude parameters as functions of temperature,surface field strength and film *** controlling confinement size and surface field strength, lamellae and undulated lamellae appear in the cylindrical bulk phase of diblock copolymers.'Phase diagrams'of confinement-induced structures are constructed...

关键词： Theory Block copolymers Film Surfaces Mean field.

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Time Sequence Change-Point Model of Electrostatic State Parameters of Aircraft Engine

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Transactions of Nanjing University of Aeronautics and Astronautics 2018年第1期35卷 126-134页

作者： Fu Yu Wei Dongdong Zuo Hongfu Feng Zhengxing college of Aeronautical Engineering Civil Aviation University of China college of civil aviation Nanjing University of Aeronautics and Astronautics

Electrostatic monitoring technology of particle charging information can facilitate online monitoring of aero-engine,which effectively enhances engine fault diagnosis and health *** traditional engine state monitoring technologies,aircraft engine monitoring by gas path electrostatic monitoring not only covers the predicted information source itself,but also detects the information that can provide an early warnings for initial fault states through gas path charging *** paper establishes a non-stationary time sequence change-point model for anomaly recognition of electrostatic signals based on change-point theory combined with difference method of non-stationary time ***,electrostatic induction data were utilized by the engine life test for a particular aircraft to validate the proposed *** results indicate that the activity level and the event rate were0.5—0.8(nc)and 50%,respectively,which were far greater than 4—12(pc)and 0—4% under normal working conditions of the engine.

关键词： aero-engine state identification electrostatic monitoring technology time series change-point statistics

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Solvo-thermal synthesis and characterization of nest-like zinc oxide

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中国有色金属学会会刊：英文版 2010年第1期20卷 119-122页

作者：李酽凤慧云张楠刘传生 college of Science Civil Aviation University of China

With Zn(NO3)2·6H2O and NaOH as starting materials, a novel nest-like ZnO nanostructure was successfully synthesized by a solvo-thermal method. The products were characterized by X-ray diffraction, photoluminescence and scanning electron microscopy. The growth mechanism of the nest-like ZnO was discussed. The results show that the as-synthesized samples have a wurtzite structure, with a weak UV emission at about 395 nm, a green emission at around 557 nm and a blue-green emission at 453 nm. SEM investigation reveals that the growth route of the nest-like ZnO can be considered involving three stages: nano-sized ZnO sheet can be firstly achieved, then outspreads quickly and increasingly becomes a long fishbone-like strip with many branch sheets, and finally these sheets curl into a nest-like structure.

关键词：氧化锌热合成表征扫描电子显微镜巢纳米结构绿光发射 X射线衍射

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Preparation and characterization of CeO_2 doped ZnO nano-tubes fluorescent composite

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Journal of Rare Earths 2010年第4期28卷 571-575页

作者：李酽刘秀琳栗建钢 college of Science Civil Aviation University of China

ZnO nanotubes were hydrothermally synthesized and the ZNTs/CeO2 fluorescent composite were prepared by introducing nano CeO2 particles into ZnO nano-tubes via a chemical solution adsorption and annealing process. The samples were characterized by X-ray diffraction, scanning electron microscopy, Fourier transformation infrared spectroscopy and room temperature photoluminescence measurement. Due to the interaction between Ce4+ and the surface atoms of ZnO2 nano-tubes, a photoluminescence enhancement was obser...

关键词： chemical synthesis inorganic compounds Fourier transform infrared spectroscopy photoluminescence spectroscopy rare earths

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Generalized mixed finite element method for 3D elasticity problems

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Acta Mechanica Sinica 2018年第2期34卷 371-380页

作者： Guanghui Qing Junhui Mao Yanhong Liu college of Aeronautical Engineering Civil Aviation University of China

Without applying any stable element techniques in the mixed methods, two simple generalized mixed element(GME) formulations were derived by combining the minimum potential energy principle and Hellinger–Reissner(H–R) variational principle. The main features of the GME formulations are that the common C0-continuous polynomial shape functions for displacement methods are used to express both displacement and stress variables, and the coefficient matrix of these formulations is not only automatically symmetric but also invertible. Hence, the numerical results of the generalized mixed methods based on the GME formulations are stable. Displacement as well as stress results can be obtained directly from the algebraic system for finite element analysis after introducing stress and displacement boundary conditions simultaneously. Numerical examples show that displacement and stress results retain the same accuracy. The results of the noncompatible generalized mixed method proposed herein are more accurate than those of the standard noncompatible displacement method. The noncompatible generalized mixed element is less sensitive to element geometric distortions.

关键词： Minimum potential energy principle Hellinger–Reissner (H–R) variational principle Generalized variational principle Generalized mixed element (GME) Elasticity problem Noncompatible mode

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Accuracy analysis of a single-fault Markov model for FADEC system

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Journal of Systems Engineering and Electronics 2019年第5期30卷 1044-1052页

作者： CAI Jing HU Wei CAI Kunye college of civil aviation Nanjing University of Aeronautics and Astronautics

Time-limited dispatching(TLD)analysis of the full authority digital engine control(FADEC)systems is an important part of the aircraft system safety analysis and a necessary task for the certification of commercial aircraft and *** the time limited dispatch guidance document ARP5107B,a single-fault Markov model(MM)approach is proposed for TLD ***,ARP5107B also requires that the loss of thrust control(LOTC)rate error calculated by applying the single-fault MM must be less than 5%when performing airworthiness ***,the sources of accuracy errors in three kinds of MM are analyzed and specified through a case study of the general FADEC system,and secondly a two-fault MM considering maintenance policy is established through analyzing and calculating the expected repair time when two related faults ***,a specific FADEC system is given to study on the influence factors of accuracy error in the single-fault MM,and the results show that the accuracy error of the single-fault MM decreases with the increase of short or long prescribed dispatch time,and the range values of short time(ST)and long time(LT)are determined to satisfy the requirement of accuracy error within 5%.

关键词： full authority digital engine control(FADEC)system Markov model(MM) accuracy analysis loss of thrust control(LOTC)

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