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Study and application of the influence of inclination angle on the cross-fusion mechanism of high gas thick coal seam

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International Journal of Mining Science and Technology 2025年第1期35卷 69-85页

作者： Pengxiang Zhao Zechen Chang Shugang Li Risheng Zhuo Yongyong Jia Qiudong Shao Wen Lei College of Safety Science and Engineering Xi'an University of Science and TechnologyXi’an 710054China Western Mining Gas Intelligent Extraction Engineering research Centre Xi’an 710054China Xinjiang Coal and coalbed methane Engineering Technology research Centre Urumqi 830091China Xinjiang Key Laboratory of Coal Mine Disaster Intelligent Prevention and Emergency Response Xinjiang Institute of EngineeringUrumqi 830023China Xinjiang Uygur Autonomous Region Coal Science research Institute Urumqi 830091China Xinjiang Changji Heze Tengda Mining Co. Ltd.Changji 831100China

In this study,to better decide the effect of coal seam dip angle upon the dynamic change of the crossfusion in gas transport and storage areas during the progress of working face in the high gas thick coal seam,a two-dimensional physical simulation experiment regarded as the theoretical research was conducted to properly explore the variation law of overburden *** results demonstrated that the boundary of the gas transport zone was located in the region of fracture *** boundary of the gas storage area was located in the abrupt penetration ***,according to the information theory,the state of the gas transport and storage areas was determined by the changing trend of the fracture rate and fracture *** mathematical representation model of the dip effect in gas transport and storage areas was *** criteria upon which the regional location of the gas transport area and gas storage area can be based were put *** cross-fusion evolution process of the dip effect in gas transport and storage areas was revealed as *** research results could provide guidance for realising directional and accurate gas extraction.

关键词： Coal seam dip angle Cross fusion High gas thick coal seam Overburden fracture Gas transport and storage areas

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research on the hazards of gas leakage and explosion in a full-scale residential building

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Defence Technology(防务技术) 2025年第1期43卷 168-181页

作者： Chengjun Yue Li Chen Zhan Li Bin Feng Ruizhi Xu Engineering research center of Safety and Protection of Explosion&Impact of Ministry of Education Southeast UniversityNanjing 211189China

The gas explosion in residential building has always been a highly concerned *** in homogeneous mixtures have been extensively ***,mixtures are often inhomogeneous in the practical scenarios due to the differences in the densities of methane and *** order to investigate the effects of gas explosions in inhomogeneous mixtures,experimental studies involving gas leakage and explosion are conducted in a full-scale residential building to reproduce the process of gas *** fitting the dimensionless buoyancy as a function of dimensionless height and dimensionless time,a distribution model of gas in large-scale spaces is established,and the mechanism of inhomogeneous distribution of methane is also be ***,the stratified reconstruction method(SRM)is introduced for efficiently setting up inhomogeneous concentration fields in *** simulation results highlight that for the internal overpressure,the distribution of methane has no effect on the first overpressure peak(ΔP1),while it significantly influences the subsequent overpressure peak(ΔP2),and the maximum difference between the overpressure of homogeneous and inhomogeneous distribution is174.3%.Moreover,the initial concentration distribution also has a certain impact on the external overpressure.

关键词： methane distribution Inhomogeneous mixture Gradient layer Gas explosion Explosive simulation

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The generalized method for estimating reserves of shale gas and coalbed methane reservoirs based on material balance equation

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Petroleum Science 2022年第6期19卷 2867-2878页

作者： Jun-Tai Shi Yan-Ran Jia Long-Long Zhang Chang-Jiang Ji Guo-Fu Li Xian-Yue Xiong Hong-Xing Huang Xiang-Fang Li Sui-An Zhang State Key Laboratory of Petroleum Resources and Prospecting in China University of Petroleum(Beijing) Beijing102249China coalbed methane research center China University of Petroleum(Beijing)Beijing102249China State Key Laboratory of Coal and CBM Co-Mining in Nancun Town Jincheng048012ShanxiChina Petro China coalbed methane Company Limited Beijing100028China China United coalbed methane National Engineering research center Co.Ltd Beijing100095China

As the main unconventional natural gas reservoirs,shale gas reservoirs and coalbed methane(CBM)reservoirs belong to adsorptive gas reservoirs,i.e.,gas reservoirs containing adsorbed *** gas and CBM reservoirs usually have the characteristics of rich adsorbed gas and obvious dynamic changes of porosity and permeability.A generalized material balance equation and the corresponding reserve evaluation method considering all the mechanisms for both shale gas reservoirs and CBM reservoirs are *** this work,a generalized material balance equation(GMBE)considering the effects of critical desorption pressure,stress sensitivity,matrix shrinkage,water production,water influx,and solubility of natural gas in water is ***,by converting the GMBE to a linear relationship between two parameter groups related with known formation/fluid properties and dynamic performance data,the straight-line reserve evaluation method is *** using the slope and the y-intercept of this straight line,the original adsorbed gas in place(OAGIP),original free gas in place(OFGIP),original dissolved gas in place(ODGIP),and the original gas in place(OGIP)can be quickly ***,two validation cases for shale gas reservoir and CBM reservoir are conducted using commercial reservoir simulator and the coalbed methane dynamic performance analysis software,***,two field studies in the Fuling shale gas field and the Baode CBM field are *** show that the GMBE and the corresponding straight-line reserve evaluation method are rational,accurate,and effective for both shale gas reservoirs and CBM *** detailed information about reserves of shale gas and CBM reservoirs can be clarified,and only the straight-line fitting approach is used to determine all kinds of reserves without iteration,proving that the proposed method has great advantages compared with other current methods.

关键词： Shale gas coalbed methane Material balance equation Reserve evaluation Dissolved gas Generalized method

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Engineering nanoparticle structure at synergistic Ru-Na interface for integrated CO_(2)capture and hydrogenation

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Journal of Energy Chemistry 2025年第1期100卷 779-791页

作者： Hanzi Liu Ling Cen Xinlin Xie Lei Liu Zhao Sun Zhiqiang Sun Hunan Engineering research center of Clean and Low-Carbon Energy Technology School of Energy Science and EngineeringCentral South UniversityChangsha 410083HunanChina

The development of dual functional material for cyclic CO_(2)capture and hydrogenation is of great significance for converting diluted CO_(2)into valuable fuels,but suffers from kinetic limitation and deactivation of adsorbent and ***,we engineered a series of RuNa/γ-Al_(2)O_(3)materials,varying the size of ruthenium from single atoms to clusters/*** coordination environment and structure sensitivity of ruthenium were quantitatively investigated at atomic *** findings reveal that the reduced Ru nanoparticles,approximately 7.1 nm in diameter with a Ru-Ru coordination number of 5.9,exhibit high methane formation activity and selectivity at 340°*** Ru-Na interfacial sites facilitate CO_(2)migration through a deoxygenation pathway,involving carbonate dissociation,carbonyl formation,and ***-situ experiments and theoretical calculations show that stable carbonyl intermediates on metallic Ru nanoparticles facilitate heterolytic C–O scission and C–H bonding,significantly lowering the energy barrier for activating stored CO_(2).

关键词： CO_(2)capture Hydrogenation Ru-Na interface Dual functional material Reaction mechanism

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Characteristics and control mechanisms of coalbed permeability change in various gas production stages

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Petroleum Science 2015年第4期12卷 684-691页

作者： Da-Zhen Tang Chun-Miao Deng Yan-Jun Meng Zhi-Ping Li Hao Xu Shu Tao Song Li School of Energy Resources China University of Geosciences Coal Reservoir Laboratory of National Engineering research center of coalbed methane Development & Utilization

According to dimensionless analysis of the coalbed methane （CBM） production data of Fanzhuang block in southern Qinshui basin, the dimensionless gas production rate is calculated to quantitatively divide the CBM well production process into four stages, i.e., drai- nage stage, unstable gas production stage, stable gas pro- duction stage, and gas production decline stage. By the material balance method, the coal reservoir permeability change in different stages is quantitatively characterized. The characteristics and control mechanisms of change in coalbed permeability （CICP） during different production stages are concluded on five aspects, i.e., permeability trend variation, controlling mechanism, system energy, phase state compositions, and production performance. The study reveals that CICP is characterized by first decline, then recovery, and finally by increase and is controlled directly by effective stress and matrix shrinkage effects. Further, the duration and intensity of the matrix shrinkage effect are inherently controlled by adsorption and desorp- tion features.

关键词： Production stage - coalbed methane Permeability Dynamic change - Control mechanism

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Excess pore pressure behavior and evolution in deep coalbed methane reservoirs

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International Journal of Mining Science and Technology 2024年第6期34卷 763-781页

作者： Changqing Liu Zhaobiao Yang Yong Qin Xia Yan Yunhai Wang Zhe Wang Key Laboratory of coalbed methane Resources and Reservoir Formation Process Ministry of EducationChina University of Mining and TechnologyXuzhou 221008China School of Resources and Geosciences China University of Mining and TechnologyXuzhou 221116China National Engineering research center of coalbed methane Development&Utilization Beijing 100095China PetroChina coalbed methane Company Limited Beijing 102200China SINOPEC East China Oil and Gas Company Nanjing 210000China

Deep coalbed methane(DCBM),an unconventional gas reservoir,has undergone significant advancements in recent years,sparking a growing interest in assessing pore pressure dynamics within these *** some production data analysis techniques have been adapted from conventional oil and gas wells,there remains a gap in the understanding of pore pressure generation and evolution,particularly in wells subjected to large-scale hydraulic *** address this gap,a novel technique called excess pore pressure analysis(EPPA)has been introduced to the coal seam gas industry for the first time to our knowledge,which employs dual-phase flow principles based on consolidation *** technique focuses on the generation and dissipation for excess pore-water pressure(EPWP)and excess pore-gas pressure(EPGP)in stimulated deep coal *** have been developed respectively and numerical solutions have been provided using the finite element method(FEM).Application of this model to a representative field example reveals that excess pore pressure arises from rapid loading,with overburden weight transferred under undrained condition due to intense hydraulic fracturing,which significantly redistributes the weight-bearing role from the solid coal structure to the injected fluid and liberated gas within artificial pores over a brief ***,field application indicates that the dissipation of EPWP and EPGP can be actually considered as the process of well production,where methane and water are extracted from deep coalbed methane wells,leading to consolidation for the artificial ***,history matching results demonstrate that the excess-pressure model established in this study provides a better explanation for the declining trends observed in both gas and water production curves,compared to conventional practices in coalbed methane reservoir engineering and petroleum *** research not only enhances the understanding of DCBM re

关键词： Deep coalbed methane Consolidation Excess pore-water pressure Excess pore-gas pressure Production data analysis

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Study on in-situ microbial methanogenesis of CO2 and in-situ inhibition of H2S and increase of coalbed methane production in low-quality coalbed methane of the Southern Junggar Basin

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Meitan Xuebao/Journal of the China Coal Society 2025年第1期50卷 532-545页

作者： Su, Xianbo Ding, Rui Zhao, Weizhong Yan, Detian Li, Ruiming Wang, Yibing Wang, Haichao Huang, Shenghai Zhou, Yixuan Wang, Xiaoming Fu, Haijiao School of Resources and Environment Henan Polytechnic University Jiaozuo454000 China Unconventional gas research institute Henan Polytechnic University Jiaozuo454000 China School of Energy Resources China University of Geosciences Wuhan430074 China Collaborative Innovation center of coalbed methane and Shale Gas for Central Plains Economic Region Jiaozuo454000 China Xinjiang Coal Field Geology Bureau Urumqi830091 China Co. Ltd. Urumqi830011 China School of Geological and Mining Engineering Xinjiang University Urumqi830047 China Co. Ltd. Urumqi830011 China

The development and utilization of coalbed methane (CBM) not only ensures national energy security, but also provides a boost to carbon neutrality. The southern edge of the Junggar Basin is a major CBM resource area and a key development hotspot in China. However, the region has few high-yield wells, and maintaining stable production is challenging. There is an urgent need for a technology that can increase the production of CBM resources within the control range of a single well. Additionally, high volume fractions of CO2 and H2S have become common in the CBM of this region, creating an urgent need for in-situ disposal technology for these gases. coalbed gas bioengineering offers a promising technology for enhancing both the quality and production of CBM in this region. On-site monitoring and laboratory simulation experiments indicate that the CO2 volume fraction is closely linked to reservoir temperature. Acid-producing fermentative bacteria and Hydrogen-producing acetic acid bacteria remain active and continue to produce CO2 across a broad range of reservoir temperatures. At lower reservoir temperatures, the metabolism of hydrogenotrophic methanogens is weak and CO2 is difficult to be reduced, which is the main reason for the high CO2 volume fraction in this area. It was also found that the microbial community in the groundwater interacts with organic matter and SO24− during migration. H2S is generated when the groundwater recharge and drainage rates are consistent with the metabolic cycle of methanogens, which is called epigenetic H2S. The presence of these two acidic gases not only compromises production safety but also significantly reduces the quality of CBM. This study introduces a key technology for in-situ microbial-mediated enhancement of CBM quality and production, addressing the issue of low-quality CBM in southern Junggar Basin. The necessity and feasibility of this technology are discussed, highlighting its potential to enhance CBM production, facilit

关键词： Coal deposits

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Adsorption behavior of carbon dioxide and methane in bituminous coal:A molecular simulation study

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Chinese Journal of Chemical Engineering 2016年第9期24卷 1275-1282页

作者： Jing You Li Tian Chao Zhang Hongxing Yao Wu Dou Bin Fan Songqing Hu Production Engineering research Institute in Huabei Oilfield Company of CNPC Renqiu 062552China College of Science China University of Petroleum(East China)Qingdao 266580China Huabei Oilfield Shanxi coalbed methane Exploration and Development Branch of CNPC Changzhi 048000China Huabei Oilfield Changzhi coalbed methane Exploration and Development Branch of CNPC Changzhi 046000China

The adsorption behavior of CO_2, CH_4 and their mixtures in bituminous coal was investigated in this study. First, a bituminous coal model was built through molecular dynamic(MD) simulations, and it was confirmed to be reasonable by comparing the simulated results with the experimental data. Grand Canonical Monte Carlo(GCMC)simulations were then carried out to investigate the single and binary component adsorption of CO_2 and CH_4with the built bituminous coal model. For the single component adsorption, the isosteric heat of CO_2 adsorption is greater than that of CH_4 adsorption. CO_2 also exhibits stronger electrostatic interactions with the heteroatom groups in the bituminous coal model compared with CH_4, which can account for the larger adsorption capacity of CO_2 in the bituminous coal model. In the case of binary adsorption of CO_2 and CH_4mixtures, CO_2 exhibits the preferential adsorption compared with CH_4 under the studied conditions. The adsorption selectivity of CO_2 exhibited obvious change with increasing pressure. At lower pressure, the adsorption selectivity of CO_2 shows a rapid decrease with increasing the temperature, whereas it becomes insensitive to temperature at higher pressure. Additionally, the adsorption selectivity of CO_2 decreases gradually with the increase of the bulk CO_2 mole fraction and the depth of CO_2 injection site.

关键词： Bituminous coal model Adsorption selectivity Enhanced coal bed methane recovery Carbon dioxide sequestration Molecular simulation

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Development Strategy and Countermeasures of China's CBM Industry under the Goal of “Carbon Peak and Neutrality”

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Journal of Earth Science 2023年第4期34卷 975-984页

作者： Fengyin Xu Xia Yan Fenglin Wang Xinyuan Ma Jian Yun Hongna Wang Borui Xu Shuangyuan Zhang Delei Mao China United coalbed methane National Engineering research center Co. Ltd.Beijing 100095China research Institute of Petroleum Exploration&Development PetroChina Coalbed Methane Co.Ltd.Beijing 100028China research management department CNPC Research Institute of Safety and Environment Technology Co.Ltd.Beijing 102249China Exploration technical R&D center CNPC Exploration Software Co.Ltd.Beijing 100080China

China’s coalbed methane(CBM) industry is in an extremely important “climbing period” and “strategic opportunity period”,which can be generally characterized by “three low and one small”:low degree of exploration and development,low adaptability of main technology,low return on investment and small development *** the “carbon peak and neutrality” background,the development status of CBM industry is systematically *** resources,technology,management problems and reasons are *** and countermeasures to accelerate the industrial development are put forward according to the factors such as efficient development of resources,major technical breakthrough,talent team training,policy formulation and implementation,return on investment and so *** existing problems are as follows:(a) The overall occurrence conditions in China are complicated and the development is difficult compared with the other countries.(b) The research precision accuracy of CBM resource conditions is not enough.(c) The adaptability of technology is poor.(d) The management mode is not *** view of these problems,this paper puts forward the “two steps” development strategy and the technical and management countermeasures of “five in one”.The corresponding “five in one” technology and management countermeasures are the formulation and implementation of relevant safeguard measures in accordance with the principle of collaborative innovation in five aspects:resources,technology,talents,policies and *** the above measures,the dream and grand blueprint of CBM industry shall be realized.

关键词： coalbed methane CBM industry carbon peak carbon neutrality development strate-gy countermeasures.

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High-strength and self-degradable sodium alginate/polyacrylamide preformed particle gels for conformance control to enhance oil recovery

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Petroleum Science 2022年第6期19卷 3149-3158页

作者： Xiao Zhang Jia-Nan Deng Kai Yang Qian Li Sen-Yao Meng Xiu-Xia Sun Zhao-Zheng Song Yong-Dong Tian Sui-An Zhang Xin-Jia Liu Zhan-Yi Wang Xin-Yu Liu Gui-Wu Lu Zi-Long Liu coalbed methane research center Beijing Key Laboratory of Optical Detection Technology for Oil and GasCollege of ScienceChina University of Petroleum-BeijingBeijing102249China Shanxi Lanyan coalbed methane Group Co. LtdJinchengShanxi048012China State Key Laboratory of Coal and CBM Co-Mining in Nancun Town JinchengShanxi048012China Institute of Oil and Gas Technology research Changqing OilfieldCNPCXi’anShaanxi710021China

Excess water production has become an important issue in the oil and gas extraction *** particle gels(PPGs),show the capability to control the conformance and reduce excess water ***,conventional PPGs have poor mechanical properties and their swollen particles are easily damaged by shearing force when passing through the fractures in formations,meanwhile PPGs can be also degraded into various byproducts,leading to permanent damage to the reservoir permeability after temporary ***,a novel type of dual cross-linked PPGs(dPPGs)was designed and synthesized using sodium alginate(SA)and acrylamide(AAm),cross-linked with N,N’-methylenebisacrylamide(MBA)and Fe^(3+).Results show that dPPGs have excellent mechanical properties with a storage modulus up to 86,445 Pa,which is almost 20 times higher than other reported ***,dPPGs can be completely degraded into liquid without any solid residues or byproducts and the viscosity of dPPGs degraded liquid was found to be lower than 5 mPa·s.A laboratory coreflooding test showed that the plugging efficiency of dPPGs was up to 99.83%on open *** obtained results demonstrated that dPPGs could be used as economical and environment-friendly temporary plugging agent with high-strength,self-degradation,thermal stability,and salt stability,thus making it applicable to a wide range of conformance control to enhance oil recovery.

关键词： Conformance control Sodium alginate Dual cross-linked Temporary plugging agent High-strength Self-degradation

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