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Geochemical and Isotopic Techniques Constraints on the Origin,Evolution,and Residence Time of Low-enthalpy Geothermal Water in Western Wugongshan,SE china

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Acta Geologica Sinica(English Edition) 2024年第3期98卷 801-818页

作者： WANG Luyao LIU Kai MA Yan ZHANG Yaoyao TONG Jue JIA Wuhui ZHANG Shouchuan SUN Junliang Chinese Academy of geological Sciences Beijing 100037China School of Water Resources and Environment China University of Geoscience(Beijing)Beijing 100083China The Fourth geological Brigade of Jiangxi geological bureau PingxiangJiangxi 337000China

Geothermal resources are increasingly gaining attention as a competitive,clean energy source to address the energy crisis and mitigate climate *** Wugongshan area,situated in the southeast coast geothermal belt of china,is a typical geothermal anomaly and contains abundant medium-and low-temperature geothermal *** study employed hydrogeochemical and isotopic techniques to explore the cyclic evolution of geothermal water in the western Wugongshan region,encompassing the recharge origin,water-rock interaction mechanisms,and residence *** results show that the geothermal water in the western region of Wugongshan is weakly alkaline,with low enthalpy and mineralization *** hydrochemistry of geothermal waters is dominated by Na-HCO_(3)and Na-SO_(4),while the hydrochemistry types of cold springs are all Na-HCO_(3).The hydrochemistry types of surface waters and rain waters are NaHCO_(3)or Ca-HCO_(3).The δD and δ^(18)O values reveal that the geothermal waters are recharged by atmospheric precipitation at an altitude between 550.0 and 1218.6 *** ratios of maj or solutes and isotopic compositions of^(87)Sr/^(86)Sr underscore the significant role of silicate weathering,dissolution,and cation exchange in controlling geothermal water ***,geothermal waters experienced varying degrees of mixing with cold water during their ***δ^(13)C values suggest that the primary sources of carbon in the geothermal waters were biogenic and ***δ^(34)S value suggests that the sulfates in geothermal water originate from sulfide minerals in the surrounding *** dating using 3H and^(14)C isotopes suggests that geothermal waters have a residence time exceeding 1 kaBP and undergo a long-distance cycling process.

关键词： geothermal water hydrochemistry isotope residence time Wugongshan area

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Genesis of the Nuri Cu-W-Mo Deposit,Tibet,china:Constraints from in situ Trace Elements and Sr Isotopic Analysis of Scheelite

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Acta Geologica Sinica(English Edition) 2024年第1期98卷 117-131页

作者： WANG Yiyun WU Zhishan CHEN Wenqing DU Qing’an TANG Liwei SHI Hongzhao MA Guotao ZHANG Zhi LIANG Wei WU Bo MIAO Hengyi Chengdu Center China Geological Survey(Geoscience Innovation Center of Southwest China)Chengdu 610081China The Second geological Institute of china’s Metallurgical Geology bureau Fuzhou 351111China

The Nuri deposit is the only Cu-W-Mo polymetallic deposit with large-scale WO3 resources in the eastern section of the Gangdese metallogenic belt,Tibet,***,the genetic type of this deposit has been controversial since its *** on a study of the geological characteristics of the deposit,this study presents mineralization stages,focusing on the oxide stage and the quartz-sulfide stage where scheelite is mainly formed,referred to as Sch-A and Sch-B,*** LA-ICP-MS trace element and Sr isotope analyses,the origin,evolutionary process of the oreforming fluid and genesis of the ore deposit are *** Electron Microscope-Cathodoluminescence(SEMCL)observations reveal that Sch-A consists of three generations,with dark gray homogenous Sch-A1 being replaced by relatively lighter and homogeneous Sch-A2 and Sch-A3,with Sch-A2 displaying a gray CL image color with vague and uneven growth bands and Sch-A3 has a light gray CL image color with hardly any growth *** contrast,Sch-B exhibits a‘core-rim’structure,with the core part(Sch-B1)being dark gray and displaying a uniform growth band,while the rim part(Sch-B2)is light gray and *** normalized distribution pattern of rare earth elements in scheelite and Sr isotope data suggest that the early ore-forming fluid in the Nuri deposit originated from granodiorite porphyry and,later on,some country rock material was mixed in,due to strong water-rock *** the O-H isotope data further indicates that the ore-forming fluid in the Nuri deposit originated from magmatic-hydrothermal sources,with contributions from metamorphic water caused by water-rock interaction during the mineralization process,as well as later meteoric *** intense water-rock interaction likely played a crucial role in the precipitation of scheelite,leading to varying Eu anomalies in different generations of scheelite from the oxide stage to the quartz-sulfide stage,while also causing a

关键词： trace elements in situ Sr isotopes tungsten mineralization Gangdese metallogenic belt Tibet

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Petrogenesis and tectonic implications of the Silurian adakitic granitoids in the eastern segment of the Qilian Orogenic Belt,Northwest china

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Acta Geochimica 2024年第1期43卷 72-86页

作者： Jiao-Long Zhao Xiao-Jun Huang Pei-Qing Hu Zhen-Xi Yang Ying Fan Er-Teng Wang Fu-Bo Yang Jing-Yu Zhang School of Earth Sciences Key Laboratory of Mineral Resources in Western China(Gansu Province)Lanzhou UniversityLanzhou 730000China Nuclear Industry 247 Brigade Tianjin North China Geological Survey BureauTianjin 301800China Fourth Institute of geological and Mineral Exploration of Gansu Provincial bureau of Geology and Mineral Resources Jiuquan 735000China

Geodynamic mechanism responsible for the generation of Silurian granitoids and the tectonic evolution of the Qilian orogenic belt remains controversial. In this study, we report the results of zircon U–Pb age, and systematic whole-rock geochemical data for the Haoquangou and Liujiaxia granitoids within the North Qilian orogenic belt and the Qilian Block, respectively, to constrain their petrogenesis, and the Silurian tectonic evolution of the Qilian orogenic belt. Zircon U–Pb ages indicate that the Haoquangou and Liujiaxia intrusions were emplaced at423 ± 3 Ma and 432 ± 4 Ma, respectively. The Haoquangou granodiorites are calc-alkaline, while the Liujiaxia granites belong to the high-K calc-alkaline *** are peraluminous in composition and have relatively depleted Nd isotopic [ε_(Nd)(t) =(-3.9 – + 0.6)] characteristics compared with regional basement rocks, implying their derivation from a juvenile lower crust. They show adakitic geochemical characteristics and were generated by partial melting of thickened lower continental crust. Postcollisional extensional regime related to lithospheric delamination was the most likely geodynamic mechanism for the generation of the Haoquangou granodiorite, while the Liujiaxia granites were generated in a compressive setting during continental collision between the Qaidam and Qilian blocks.

关键词： Silurian adakitic granitoids Petrogenesis Tectonic setting Qilian Orogenic Belt

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Three-dimensional Modeling of Ore-forming Elements and Mineralization Prognosis for the Yechangping Mo Deposit,Henan Province,china

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Acta Geologica Sinica(English Edition) 2024年第3期98卷 736-752页

作者： DING Gaoming JI Genyuan YAN Guolong XU Yongzhong WANG Kunming XIAO Chun WANG Quanle GUO Dongbao china National Administration of coal Geology Beijing 100038China MNR Key Laboratory of Metallogeny and Mineral Assessment Institute of Mineral ResourcesCAGSBeijing 100037China china Gold Group geological Co. Ltd.Beijing 100011China china Gold Group ZhongYuan Mining Co. Ltd.SanmenxiaHenan 472000China Lanzhou Mineral Exploration Institute of Gansu Nonferrous Metal geological Exploration bureau Lanzhou 730046China

Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep *** approach provides key information for the quantitative prediction of deep mineral localization,three-dimensional fine interpolation,analysis of spatial distribution patterns,and extraction of quantitative mineral-seeking *** Yechangping molybdenum(Mo)deposit is a significant and extensive porphyry-skarn deposit in the East Qinling-Dabie Mo polymetallic metallogenic belt at the southern margin of the North china *** borehole data on oreforming elements underpin deep geochemical *** methodology includes the following steps:(1)Threedimensional geological modeling of the deposit was established.(2)Correlation,cluster,and factor analyses post delineation of mineralization stages and determination of mineral generation sequence to identify(Cu,Pb,Zn,Ag)and(Mo,W,mfe)assemblages.(3)A three-dimensional geochemical block model was constructed for Mo,W,mfe,Cu,Zn,Pb,and Ag using the ordinary kriging method,and the variational function was developed.(4)Spatial distribution and enrichment characteristics analysis of ore-forming elements are performed to extract geological information,employing the variogram and w(Cu+Pb+Zn+Ag)/w(Mo+W)as predictive indicators.(5)Identifying the western,northwestern,and southwestern areas of the mine with limited mineralization potential,contrasted by the northeastern and southeastern areas favorable for mineral exploration.

关键词： 3D geochemical model ore-forming elements geostatistics deep mineralization prediction Yechangping Mo deposit

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Stratigraphic framework and sedimentary evolution during the Cryogenian-Ediacaran transition in northeastern Sichuan Basin,South china

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Petroleum Science 2024年第2期21卷 823-835页

作者： Yi Zhang Hong-Wei Kuang Yong-Qing Liu Qiang Shi Dong-Ge Wang Ke-Ning Qi Yu-Chong Wang Da-Wei Qiao Xiao-Shuai Chen Li-Zhi Wu Meng Tian Long Chen Yi Wei Liao-Yuan Song Jian Li Zi-Gang Wu Yun-Qian Liu Xuan-Chun Liu An-Qing Chen Zhi-Wei Liao Institute of Geology Chinese Academy of Geological SciencesBeijing100037China State Key Laboratory of coal Mine Disaster Dynamics and Control School of Resources and Safety EngineeringChongqing UniversityChongqing400044China No.205 geological Team Chongqing Bureau of Geology and Minerals ExplorationChongqing401121China Chongqing Institute of geological Survey Chongqing401122China Key Laboratory of Deep-time Geography and Environment Reconstruction and Applications of Ministry of Natural Resources Chengdu University of TechnologyChengdu610059SichuanChina

The northeastern Sichuan area in the northern Yangtze margin has unique Ediacaran geological records,especially the Doushantuo Formation(DST),and become a hot research area in recent ***,the Cryogenian-Ediacaran(C-E)boundary has not been precisely identified,which restricts the in-depth study of geological information during this crucial transitional period and is unfavorable for a systematic and complete understanding of the Yangtze Block and even the global paleogeographic *** study conducted stratigraphy,sedimentology,and chronostratigraphy to establish the stratigraphic framework and sedimentary evolution of the C-E transition strata in northeastern *** results showed that the Ediacaran sediments,without the cap dolomite,unconformably overlaid the Cryogenian sediments in the studied *** Member II of the DST,characterized by 50-160 m of red-green sandstone(approximately equivalent to the original Chengkou“Guanyinya Formation”),directly overlaid the Cryogenian sediments and displayed a 623±2.3 Ma maximum depositional age from the detrital zircon U-Pb *** stratigraphic correlations indicate that the C-E transition strata in northeastern Sichuan had a consistent lithological association and sedimentary sequence characteristics but differed from the Three ***,the upper Nantuo massive glacial diamictites transition to the icebergs rafted lonestone-bearing mudstones at the top,then change upward to DST barrier coast *** proposed DST of the northeastern Sichuan Basin was divided into three lithostratigraphic members without the regional Member I cap dolomite:(i)Member II purple-red,gray-green sandstone strata,(ii)MemberⅢblack mudstone strata,and(iii)Member IV P-Mn bearing *** the C-E transition,the study area experienced(i)the global deglaciation stage in the terminal Marinoan glaciation and(ii)the filling-leveling up stage with clastic rocks in the early ***,the early Ediacaran

关键词： Marinoan glaciation Doushantuo formation Cap dolomite Deglacial and coastal deposits Detrital zircon U-Pb dating

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Organic Matter Accumulation in the Upper Permian Dalong Formation from the Lower Yangtze Region,South china

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Acta Geologica Sinica(English Edition) 2024年第1期98卷 150-167页

作者： FANG Chaogang ZHANG Chengcheng MENG Guixi XU Jinlong XU Naicen LI Hualing LIU Mu LIU Bo Institute of International Rivers and Eco-Security Yunnan UniversityKunming 650500China Nanjing Center China Geological SurveyNanjing 210016China Exploration Research Institute Anhui Provincial Bureau of Coal GeologyHefei 230088China china United coalbed Methane Corporation Ltd. Beijing 100015China geological Survey of Anhui Province Hefei 230001China Key Laboratory of Cenozoic Geology and Environment Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China

The Late Permian was marked by a series of important geological events and widespread organic-rich black shale depositions,acting as important unconventional hydrocarbon source ***,the mechanism of organic matter(OM)enrichment throughout this period is still *** on geochemical data,the marine redox conditions,paleogeographic and hydrographic environment,primary productivity,volcanism,and terrigenous input during the Late Permian in the Lower Yangtze region have been studied from the Putaoling section,Chaohu,to provide new insights into OM *** Phases are distinguished based on the TOC and environmental *** Phase I,anoxic conditions driven by water restriction enhanced OM *** Phase II,euxinic and cycling hydrological environments were the two most substantial controlling factors for the massive OM *** Phase III,intensified terrestrial input potentially diluted the OM in sediment and the presence of oxygen in bottom water weakened the preservation *** IV was characterized by a relatively higher abundance of mercury(Hg)and TOC(peak at 16.98 wt%),indicating that enhanced volcanism potentially stimulated higher productivity and a euxinic *** Phase V,extremely lean OM was preserved as a result of terrestrial dilutions and decreasing primary *** I,II and IV are characterized as the most prominent OM-rich zones due to the effective interactions of the controlling factors,namely paleogeographic,hydrographic environment,volcanism,and redox conditions.

关键词： geochemistry redox condition primary productivity OM accumulation Lopingian/Changhsingian Lower Yangtze region

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Metamorphic P-T conditions and ages of garnet-biotite schists in the Dahongshan Group from the southwestern Yangtze Block

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Acta Geochimica 2024年第4期43卷 707-718页

作者： Jun-xiao Ma Guang-shu Yang Yong-feng Yan Xiao-Fei Xu Yun-hua Ren Hui Zhao Xiao-jun Zheng Yuan Qin Faculty of Land Resources Engineering Kunming University of Science and TechnologyKunming 650093China geological Team 306 of Yunnan Non-Ferrous Metals geological bureau Kunming 650217China Yunnan Provincial bureau of Non-Ferrous Geology Kunming 650051China

The Dahongshan Group,situated at the southwestern margin of the Yangtze Block,represents a geological unit characterized by relatively high-grade metamorphism in the *** paper investigates the garnet-biotite schist from the Laochanghe Formation of the Dahongshan Group,employing an integrated approach that includes petrological analysis,phase equilibrium modeling,and zircon U-Pb *** schist is mainly composed of garnet,biotite,plagioclase,quartz,rutile,and *** equilibrium modeling revealed the peak metamorphic conditions of 8-9 kbar and 635-675°*** further integrating the prograde metamorphic profile of garnet and geothermobarometric results,a clockwise P-T metamorphic evolution path is constructed,which includes an increase in temperature and pressure during the prograde ***-ICP-MS zircon U-Pb dating and zircon Ti thermometry constrains the post-peak metamorphic age of 831.2±7.2 *** with previously reported results,it is revealed that the southwestern margin of the Yangtze Block experienced a large-scale regional metamorphism during the Neoproterozoic(890-750 Ma),which is related to the collisional orogenic *** may be associated with the late-stage assembly of the Rodinia supercontinent or with local compression and subduction processes during the breakup of the Rodinia supercontinent.

关键词： Southwestern Yangtze Block Dahongshan Group Phase equilibrium modeling Zircon U-Pb dating Neoproterozoic metamorphism

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Structural Control of the Getang Carlin-Type Gold Deposit in Southwest china

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Journal of Earth Science 2024年第2期35卷 536-552页

作者： Guoping Zeng Xinlu Hu Diwei Luo Jianzhong Liu Shuzhen Yao Yongjie Jin Wuhan Center China Geological SurveyWuhan430205China Central South china Innovation Center for Geosciences Wuhan430205China Faculty of Earth Resources China University of GeosciencesWuhan430074China geological Party 105 Guizhou Bureau of Geology and Mineral Exploration&DevelopmentGuiyang550018China

The Getang is a representative Carlin-type gold deposit in Southwest *** has a proven reserve of about 30 tonnes at an average grade of 5.1 g/t *** orebodies occur as strat-abound lenses,and are structurally controlled by shallow NWW-and NE-trending fold-fault systems and the unconformity between the Upper and Middle *** this study,the regional-and deposit-scale structural investigations,joints and finite strain measurements,and stress and dynamic analysis were conducted with an aim to reveal the structural process of the Getang gold deposit and clarify the relationship between the gold mineralization and *** phases of deformation were identified in the deposit:(1)paleokarst was generated by a crustal uplift when the Youjiang Basin experienced extension at the end of the Middle Permian,laying the foundation for the unconformity;(2)the NW-trending structures were formed under a NNE-SSW compression during the Indochina-South china collision(Indosinian orogeny)in Triassic;(3)the NE-trending structures were generated or reactivated under a NW-SE-oriented compression during the Yanshanian intracontinental *** unconformity recorded two episodes of tectonic evolution in the NNE-SSW and NW-SE *** analyses and geochronology data suggest that the Getang gold deposit was formed as a result of tectonic transition from compression to extension during the Yanshanian intracontinental orogeny.

关键词： Carlin-type gold deposit structural features finite strain Getang Southwest china economy geology geochemistry

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Study on hydrodynamic diffusion law of the swelling particle slurry in karst pipeline

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Particuology 2024年第4期87卷 218-231页

作者： Bingchuan Cheng Haibo Li Guangming Pan Runhuai Deng Yu'an Gong Shujun Xu Kun Zhou Zhuo Zheng School of Civil Engineering Geotechnical and Structural Engineering Research CenterShandong UniversityJinan250061China The Fourth Prospecting of Shandong coal Geology bureau Weifang261000China china Railway 14th bureau Group Corporation Limited Jinan250101China School of Trafic Engineering Shandong Jianzhu University.Fengming RoadLingang Development ZoneJinan250101China

The swelling particle grouting material has demonstrated remarkable plugging effectiveness in high-pressure and large-flow burst water within karst ***,current research on the rheolog-ical model,flow computation theory,and plugging mechanism of this material is *** conven-tional grouting slurry diffusion process,using the liquid-liquid two-phase flow method,fails to accurately simulate high solubility slurry and particle *** address these limitations,this study established a precise constitutive model to describe the swelling particle slurry diffusion process in dynamic ***,a coupling calculation method was proposed to analyze the spatiotemporal heterogeneity of viscosity during slurry diffusion by considering the migration of slurry and the changes in *** investigate the interaction between particle swelling and flow field changes,a Compu-tational Fluid Dynamics-Discrete Element Method(CFD-DEM)coupling model was developed for the diffusion of swelling particle *** is demonstrated that slurry viscosity increases exponentially within the diffusion front as the particle swelling rate rises,and the drag force exhibits an intriguing behavior of initially increasing and then decreasing as the slurry flows through the ***-more,the CFD-DEM coupling model proved to be more accurate in describing viscosity distribution and diffusion distance compared to the finite element *** primary objective of this paper is to reveal the plugging mechanism and provide theoretical support for the engineering application of the swelling particle grouting material.

关键词： Karst pipeline Swelling particle grouting material Dynamic water diffusion Spatiotemporal variation of viscosity CFD-DEM coupling model

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Texture and Geochemistry of Multi-stage Hydrothermal Scheelite in the Mamupu Cu-Au-Mo(-W)Deposit,Eastern Tibet:Implications for Tungsten Mineralization in the Yulong Belt

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Acta Geologica Sinica(English Edition) 2024年第3期98卷 701-716页

作者： ZHANG Xiaoxu TANG Juxing LIN Bin WANG Qin HE Liang YAN Gang SHAO Rui WU Qiang DU Qiu ZHAXI Pingcuo Chengdu Center China Geological Survey(Geosciences Innovation Center of Southwest China)Chengdu 610081China MNR Key Laboratory of Metallogeny and Mineral Assessment Institute of Mineral ResourcesChinese Academy of Geological SciencesBeijing 100037China SinoProbe Laboratory Chinese Academy of Geological SciencesBeijing 100094China Earth Sciences College Chengdu University of TechnologyChengdu 610059China No.6 geological Party Tibetan Bureau of Geology and Mineral Exploration and DevelopmentLhasa 851400China Tibet Shengyuan Mining Group Co. Ltd.Lhasa 851400China

Multistage tungsten mineralization was recently discovered in the Mamupu copper-polymetallic deposit in the southern Yulong porphyry copper belt(YPCB),*** study reports the results of cathodoluminescence,trace element and Sr isotope analyses of Mamupu scheelite samples,undertaken in order to better constrain the mechanism of W mineralization and the sources of the ore-forming *** different types of scheelite are identified in the Mamupu deposit:scheelite A(Sch A)mainly occurs in breccias during the prograde stage,scheelite B(Sch B)forms in the chlorite-epidote alteration zone in the retrograde stage,while scheelite C(Sch C)occurs in distal quartz sulfide *** extremely high Mo content and negative Eu anomaly in Sch A represent high oxygen fugacity in the prograde *** with ore-related porphyries,Sch A has a similar REE pattern,but with higher ΣREE,more depleted HREE and slightly lower(^(87)Sr/^(86)Sr)i *** features suggest that Sch A is genetically related to ore-related porphyries,but extensive interaction with carbonate surrounding rocks affects the final REE and Sr isotopic *** B shows dark(Sch B-I)and light(Sch B-II)domains under CL *** Sch B-I to Sch B-II,LREEs are gradually depleted,with MREEs being gradually *** C has the highest LREE/HREE ratio,which indicates that it inherited the geochemical characteristics of fluids after the precipitation of HREE-rich minerals,such as diopside and garnet,in the early prograde *** Mo content in Sch B and Sch C gradually decreased,indicating that the oxygen fugacity of the fluids changed from oxidative in the early stages to reductive in the later,the turbulent Eu anomaly in Sch B and Sch C indicating that the Eu anomaly in the Mamupu scheelite is not solely controlled by oxygen *** extensive interaction of magmatic-hydrothermal fluids and carbonate provides the necessary Ca^(2+)for the precipitation of scheelite in the Mamupu deposit.

关键词： scheelite geochemistry Mamupu Cu deposit Yulong porphyry copper belt eastern Tibet

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