检索结果-南通市图书馆

Geochemical signatures of potassium metasomatism in anthracite from the Himalayan fold‑thrust belts of Sikkim,India

International Journal of coal Science & Technology 2022年第2期9卷 48-69页

作者： Santanu Ghosh Anwita Ojha Atul Kumar Varma Coal Geology and Organic Petrology Laboratory Department of Applied GeologyIndian Institute of Technology(Indian School of Mines)DhanbadJharkhand 826004India Department of Earth Sciences Indian Institute of Technology BombayPowaiMumbaiMaharashtra 400076India

The present study focuses on the inorganic geochemical features of the bituminous coal samples from the Raniganj and the Jharia Basins,as well as the anthracite samples from the Himalayan fold-thrust belts of Sikkim,India.The SiO_(2)content(48.05 wt%to 65.09 wt%and 35.92 wt%to 50.11 wt%in the bituminous and anthracite samples,respectively)and the ratio of Al_(2)O_(3)/TiO_(2)(6.97 to 17.03 in the bituminous coal samples and 10.34 to 20.07 in the anthracite samples)reveal the intermediate igneous source rock composition of the minerals.The ratio of the K_(2)O/Al_(2)O_(3)in the ash yield of the bituminous coal samples(0.03 to 0.09)may suggest the presence of kaolinite mixed with montmorillonite,while its range in the ash yield of the anthracite samples(0.16 to 0.27)may imply the presence of illite mixed with kaolinite.The chemical index of alteration values may suggest the moderate to strong chemical weathering of the source rock under sub-humid to humid climatic conditions.The plot of the bituminous coal samples in the A–CN–K diagram depicts the traditional weathering trend of parent rocks,but the anthracite samples plot near the illite feld and are a bit ofset from the weathering trend.This may imply the plausible infuences of the potassium-metasomatism at post coalifcation stages,which is further supported by high K_(2)O/Na_(2)O ratio(29.88–80.13).The Fourier transform infrared spectra further reveal the hydroxyl stretching intensity of illite in the anthracite samples substantiating the efect of the epigenetic potassium-metasomatism.The decrease in total kaolinite intensity/compound intensity of quartz and feldspar may provide additional evidence towards this epigenetic event.

关键词： Himalayan fold-thrust belts Anthracite Potassium metasomatism Kaolinite to quartz-feldspar intensity ratio Montmorillonite stretching and bending intensities Illite-stretching frequency

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Spectral narratives of microstructural restyling and their controls on hydrocarbon generation potential from coal

引用

International Journal of coal Science & Technology 2023年第3期10卷 167-189页

作者： Tushar Adsul Santanu Ghosh Anwita Ojha Sudip Bhattacharyya Atul Kumar Varma Coal Geology and Organic Petrology Laboratory Department of Applied GeologyIndian Institute of Technology(Indian School of Mines)DhanbadJharkhand 826004India Department of geology Mizoram UniversityAizawlMizoram 796004India Specialized coal Petrography laboratory Natural Energy ResourcesMission II-BGeological Survey of IndiaDK-6Sector-IlSalt Lake CityKolkataWest Bengal 700091India

The low to medium-rank Tertiary coals from Meghalaya,India,are explored for the first time for their comprehensive micro-structural characterization using the FTIR and Raman spectroscopy.Further,results from these coals are compared with the Permian medium and high-rank coals to understand the microstructural restyling during coalification and its controls on hydrocarbon generation.The coal samples are grouped based on the mean random vitrinite reflectance values to record the transformations in spectral attributes with increasing coal rank.The aliphatic carbon and the apparent aromaticity respond sharply to the first coalification jump(R:0.50%)during low to medium-rank transition and anchizonal metamorphism of the high-rank coals.Moreover,the Raman band intensity ratio changes during the first coalification jump but remains invari-able in the medium-rank coals and turns subtle again during the onset of pregraphitization in high-rank coals,revealing a polynomial trend with the coal metamorphism.The Rock-Eval hydrogen index and genetic potential also decline sharply at the first coalification jump.Besides,an attempt to comprehend the coal microstructural controls on the hydrocarbon poten-tial reveals that the Tertiary coals comprise highly reactive aliphatic functionalities in the type I-S kerogen,along with the low paleotemperature(74.59-112.28℃)may signify their potential to generate early-mature hydrocarbons.However,the presence of type II-II admixed kerogen,a lesser abundance of reactive moieties,and overall moderate paleotemperature(91.93-142.52℃)of the Permian medium-rank coals may imply their mixed hydrocarbon potential.Meanwhile,anchizonal metamorphism,polycondensed aromatic microstructure,and high values of paleotemperature(~334.25 to~366.79℃)of the high-rank coals indicate a negligible potential of producing any hydrocarbons.

关键词： Early mature oil generation Meghalaya high-sulfur coal Type II-S kerogen Microstructural ordering coalification jump Hydrocarbon generation potential

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Eocene lignites from Cambay basin, Western India： An excellent source of hydrocarbon

引用

Geoscience Frontiers 2016年第5期7卷 811-819页

作者： P.K.Singh V.K.Singh P.K.Rajak M.P.Singh A.S.Naik S.V.Raju D.Mohanty coal & organic petrology Lab Centre of Advanced Study in Geology Banaras Hindu University Varanasi 221005 Uttar Pradesh India Research & Development Oil India Limited Duliajan Assam 786 602 India Central Institute of Mining and Fuel Research Barwa Road Dhanbad 826015 India

In the present paper lignites from the Cambay basin have been studied for their hydrocarbon potential.The samples were collected from three lignite fieldse Vastan, Rajpardi and Tadkeshwar, and were investigated by petrography, chemical analyses and Rock-Eval pyrolysis. The results are well comparable with the empirically derived values. The study reveals that these ‘low rank C＇ lignites are exceedingly rich in reactive macerals（huminite t liptinite） while inertinite occurs in low concentration. These high volatile lignites generally have low ash yield except in few sections. The Rock-Eval data indicates the dominance of kerogen type-III with a little bit of type-II. The study reveals that the lignites of Vastan（lower and upper seams） and Tadkeshwar upper seam are more gas-prone while Rajpardi and Tadkeshwar lower seams are oil-prone. Further, the fixed hydrocarbons are several times higher than the free hydrocarbons. The relation between TOC and fixed hydrocarbon indicates that these lignites are excellent source rock for hydrocarbon which could be obtained mainly through thermal cracking. The empirically derived values reveal a high conversion（94e96%） and high oil yield（64e66%） for these lignites.

关键词： Eocene lignites Cambay basin Rock-Eval Maceral Hydrocarbon

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Petrographic characteristics and paleoenvironmental history of Eocene lignites of Cambay basin, Western India

引用

International Journal of coal Science & Technology 2017年第3期4卷 214-233页

作者： Prakash K. Singh Vijay K. Singh M. P. Singh P. K. Rajak coal and organic petrology Lab Centre of Advanced Study in Geology Banaras Hindu University Varanasi Uttar Pradesh 221005 India

Lignite samples collected from Vastan, Rajpardi and Tadkeshwar lignite mines of Cambay basin (Gujarat) were subjected to organic petrographic investigations and geochemical analyses and the data, thus generated, is used to reconstruct the paleodepositional history of these lignite sequences. The lignites of Cambay basin dominantly comprise huminite maceral group (71.6%–86.3%) followed by liptinite (10.1%–19.3%) and inertinite (3.6%–11.0%) maceral groups. The mineral matter varies from 9.0% to 20.0%. The petrography based facies model indicates that these lignites have high values of gelification index (GI) and low tissue preservation index revealing a continuous wet condition in the basin and a relatively slower rate of subsidence during the decay of organic matter. On several occasions, during the formation of seams in Tadkeshwar, Rajpardi and Vastan mines, the value of GI exceeded 10 which indicates a forest permanently flooded and the cause of pronounced degree of degradation. However, few sections in Tadkeshwar seam had relatively drier spells of environmental conditions due to fluctuation in the water table as revealed by moderately high content of inertinite macerals. This is specially indicated by the occurrence of funginite which normally thrives in the upper oxygenated peatigenic layer and indicates prevalence of oxic conditions during plant deposition. Such conditions prevailed during a transgressive phase but there were intermittent fluvial activities also giving rise to supratidal flood plain as reflected in the form of associated carbonaceous shales in the basin.

关键词：有机岩石学演化历史古环境褐煤盆地特征和始新世煤显微组分

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Understanding the paleomires of Eocene lignites of Kachchh Basin, Gujarat （Western India）： petrological implications

引用

International Journal of coal Science & Technology 2017年第2期4卷 80-101页

作者： Prakash K. Singh Vijay K. Singh M. P. Singh P. K. Rajak coal and organic petrology Lab Centre of Advanced Studyin Geology Banaras Hindu University VaranasiUttar Pradesh 221005 India

The present paper entails the results of the investigations carried out on the lignite deposits of Kachchh Basin. The lignite samples were drawn from five lignite seams from Panandhro lignite field (Seam-I to -V) and eight lignite seams (Seam-I to -VIII) from the Matanomadh lignite field which are currently operational. The petrographic analysis of the lignites indicates a dominance of huminite group of macerals which is mainly contributed by ulminite-A, ulminite-B, attrinite, densinite, and phlobaphinite. Liptinite (chiefly sporinite, cutinite, resinite, and liptodetrinite) and inertinite (chiefly fusinite, funginite, and inertodetrinite) groups occur in subordinated amount. The mineral matter occurs in moderate concentration. Though sulfur content is high in these lignites, there is no fixed trend of variation of sulfur from bottom seam to top seam. The investigation reveals a flooded forest swamp having high rate of degradation. However, there were a few drier periods indicated by relatively more inertinite macerals. The petrography-based models indicate that the Kachchh lignites of Gujarat evolved in coastal marshy setting under transgressive phase. However, there were few intermittent fluvial activities giving rise to supratidal flood plain. This led to the formation of the associated carbonaceous shales in the basin.

关键词： Kachchh Basin Eocene lignite Petrography Paleomire

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Influence of coke structure on coke quality using image analysis method

引用

International Journal of coal Science & Technology 2018年第4期5卷 473-485页

作者： B.Ghosh B.K.Sahoo B.Chakrabortv K.K.Manjhi S.K.Das J.N.Sahu Atul K.Varma Research & Development Centre for Iron and Steel Steel Authority of India Limited (SAIL)RanchiJharkhand 834002India Institute of Chenlical Technology Faculty of ChemistryUniversity of Stuttgart70550 StuttgartGermany Coal Geology and Organic Petrology Laboratory Department of Applied GeologyIITIndian School of Mines (ISM)Dhanbad 826004India South Ural State University 76Lenin Aven.ChelyabinskRussia 454080

The quality of coke affects the performance of the blast furnace, factors affecting coke quality include coal properties, coal charge granulometry and carbonization conditions. The coke properties in elude the size analysis, cold strength (Micum Indices-M4(). MI0) and hot strength (Coke Reactivity Index-CRI, Coke Strength after Reaction-CSR) properties and structural properties such as coke structure and texture. Structural properties comprise the porosity, pore-cell wall thickness and pore sizes, while textures consist of the carbon forms in the coke. In present work, advanced method such as image analysis method was used to interpret coke microstructure. Conventional methods such as determination of coke porosity by measurement of real and apparent density and mercury porosimetry have a number of limitations. Coke size, magnification, number of image frames captured, process of pellet preparations and coke properties such as M4(), M|0, CRI and CSR (low, medium and high values) were taken as variables for experimental purposes. The coke structure parameters such as porosity, length, perimeter, breadth, roundness, pore-wall thickness and pore size distribution of the pores were determined by image analysis method. This method provided average porosity in addition to pore-wall thickness and pore-size distribution. The pore wall thickness measuremenl by image analysis method provided significant correlations with M40, CRI and CSR values. This explained the usability of image analysis for coke structure measurement.

关键词： Image analysis Coke structure Porosity Micro structure Roundness Pore wall thickness

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Inertinite in coal and its geoenvironmental significance:Insights from AI and big data analysis

引用

Science China Earth Sciences 2024年第6期67卷 1779-1801页

作者： Longyi SHAO Jiamin ZHOU Timothy PJONES Fanghui HUA Xiaotao XU Zhiming YAN Haihai HOU Dongdong WANG Jing LU State Key laboratory for Fine Exploration and Intelligent Development of coal Resources and College of Geoscience and Surveying Engineering China University of Miningand Technology(Beijing)Beijing 100083China School of Earth and Environmental Sciences Cardiff UniversityCardiff CF103YEWalesEngland General Prospecting Institute of China National Administration of coal geology Beijing 100039China Institute of Architectural Engineering Weifang UniversityWeifang 261061China College of Mining Liaoning Technical UniversityFuxin 123000China College of Earth Science and Engineering Shandong University of Science and TechnologyQingdao 266590China

Inertinite,as an important and abundant maceral group in coal,is critical for the study of palaeowildfires and their roles in the Earth’s ecosystems.Recently,there has been a significant amount of research on the relationship between palaeowildfire,palaeoclimate change and palaeovegetation evolution based on inertinite data.The reflectance of fusinite and semifusinite has been used to estimate the combustion temperature and type of palaeowildfires,and then to evaluate the combustion characteristics of different types of palaeowildfires.The relative abundance of inertinite can be used to estimate the atmospheric oxygen contents.The rapid development of artificial intelligence(AI)and online tools to search scientific databases has presented an opportunity for us to find,collect,arrange,and analyse data from the earliest to latest publications on inertinite.The data extraction tool Deep Shovel is used to collect and analyse global inertinite data from the Silurian to the Neogene.The software programs such as Gplates,ArcGIS pro and Tableau are then applied to model the relative abundance of inertinite over geological time,which can be correlated with other parameters such as atmospheric oxygen contents,plant evolution and palaeoclimate changes.The distribution of inertinite in coals varied over different geological periods,being typified by the“high inertinite content-high atmospheric oxygen level”period in the Permian and the“low inertinite content-low atmospheric oxygen level”period in the Cenozoic.This study has proposed a possible model of the positive and negative feedbacks between inertinite characteristics and palaeoenvironmental factors,and has revealed the exceptional role of inertinite in palaeoenvironmental studies.Future research on inertinite will be focused on the integrated study of organic petrology and organic geochemistry of inertinite,the big data-driven research on the temporal and spatial distribution of the global inertinite,the exploration of the functions of palaeowildfires in the Earth system

关键词： Inertinite Palaeowildfires Atmospheric oxygen Palaeoclimates Palaeoecosystems

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Quantitative Gas-in-place Comparison of Original and Bitumen-free Lacustrine Shale

引用

Acta Geologica Sinica(English Edition) 2022年第2期96卷 559-570页

作者： LI Jing ZHOU Shixin FU Deliang CHEN Kefei ZHANG Chen SUN Zexiang LI Pengpeng Northwest Institute of Eco-Environment and Resources Chinese Academy of SciencesLanzhou 730000China Key laboratory of Petroleum Resources Gansu ProvinceLanzhou 730000China Key laboratory of coal Exploration and Comprehensive Utilization Ministry of Nature and ResourcesShaanxi Coal Geology Group CoLtd.Xi’an 710021China University of Chinese Academy of Sciences Beijing 100101China

Residual bitumen in organic-rich shale of oil windows exists widely, and its effect on the gas storage capacity of shale could be two-fold. Bitumen could occupy and block the nanopores of shale, thereby reducing the gas storage capacity. On the other hand, gas could be dissolved in bitumen in shale gas reservoirs, leading to enhanced gas storage capacity. To quantify the effect of bitumen on the gas-in-place(GIP) estimation of lacustrine organic-rich shale, the micropore characteristics and methane sorption capacity of original and bitumen-free shale from the Triassic Yangchang Formation of the Ordos Basin, combined with the methane dissolution capacity for the isolated bitumen, were analyzed and compared. GIP for the original and bitumen-free shale in the depth range of 500–2500 m was evaluated. The results show that micropores in the shale samples were mainly related to organic matter. Clay mineral-hosted pores contributed slightly to microporosity. Bitumen significantly reduced the micropore surface area and volume of the original shale, with average percentages of 28.09% and 51.26%, respectively. The methane sorption capacity decreased after bitumen removal. When normalized to the original shale mass, the sum of the methane sorption capacity for bitumen-free shale and the methane dissolution capacity for isolated bitumen was similar to the methane sorption capacity of the original shale, indicating that the lack of methane absorbed on bitumen is the main reason for the decrease in methane sorption capacity after bitumen removal. The contribution of absorbed methane on bitumen to sorbed methane in shale could be higher than 36.23%. Dual effects of bitumen on shale GIP were observed. A high content of bitumen(1.12%) increased the GIP of the shale samples, with an average percentage of 23.5% in the depth range of 500–2500 m, while a low content of bitumen(0.06%) decreased the GIP, with an average percentage of 13.6%.

关键词： lacustrine shale gas-in-place bitumen methane sorption methane dissolution

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Accumulation model and geochemistry characteristics of oil occurring from Jurassic coal measures in the Huangling mining area of the Ordos Basin, China

引用

Frontiers of Earth Science 2023年第1期17卷 158-169页

作者： Yuan BAO Yiliang HU Wenbo WANG Chen GUO Guochang WANG College of geology and Environment Xi’an University of Science and TechnologyXi’an 710054China Key laboratory of coal Resources Exploration and Comprehensive Utilization Xi’an 710021China Engineering Department Saint Francis UniversityLorettoPA 15940USA

The Ordos Basin is an important intracontinental sedimentary basin in China,containing a significant amount of coal,oil,and natural gas.This study analyzed the sedimentary environment,sedimentary facies,parent material type,maturity,and carbon isotopic composition of the coal-bearing organic matter using gas chromatography–mass spectrometry(GC–MS)and stable isotope ratio mass spectrometry.The source of oil occurring in the No.2 coal seam of the Jurassic Yan’an Formation(An-1 oil)and its accumulation model were also investigated.The results show that the relative abundances of C_(27),C_(28),and C_(29) steranes in the An-1 oil are 43.8%,33.0%,and 23.2%,respectively.The tricyclic terpanes,C_(29)20S/(20S+20R),and C_(29)ββ/(ββ+αα)contents of the An-1 oil are 31.4%−34.8%,0.85 and 0.81,respectively.Pr/n-C17,Ph/n-C18,and Pr/Ph values are 0.34,0.42,and 0.87,respectively.Biomarker parameters indicate that the An-1 oil mainly comes from the plankton source rock deposited in the freshwater lake facies and a reducing environment,which has evolved to maturity.The correlation of oil-oil indicates that the An-1 oil is homologous to the Chang-7 oil(Chang-7 member of the Triassic Yanchang Formation).The correlation of oil-source rock presents that the An-1 oil is generated from the Yanchang Formation(Chang-6 and Chang-7 source rocks)and occurred in the coal seam during the stage of stratum uplift since the Early of Late Cretaceous.The distribution characteristics of δ13C group components in the An-1 oil and Chang-7 oil also reveal the fractionation phenomenon during the migration of crude oil.

关键词： coal measures oil source biomarker compounds carbon isotope Ordos Basin

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

A study on assessment of hydrocarbon potential of the lignite deposits of Saurashtra basin, Gujarat （Western India）

引用

International Journal of coal Science & Technology 2017年第4期4卷 310-321页

作者： Prakash K. Singh V. K. Singh P. K. Rajak Neeraj Mathur coal and organic petrology Lab Centre of Advanced Studyin Geology Banaras Hindu University VaranasiUttar Pradesh 221005 India Centre of Excellence for Energy Studies Oil India LimitedRukminigaon GS Road Guwahati Assam 781022 India

In the present investigation, Bhavnagar lignites of the Saurashtra basin (Gujarat) have been studied to assess their hydrocarbon generating potential. The samples of upper as well as lower lignite seams have been studied through microscopy and subjected to various chemical analyses viz. proximate analysis, ultimate analysis and Rock-Eval Pyrolysis. These lignites have high moisture and low to moderate ash yield but are characterized by high volatile matter. Petrographically they comprise predominantly of huminite group maceral while liptinite and inertinite groups occur in subordinated amount. Huminite is chiefly composed of detrohuminite and telohuminite. The T max (av. 416.23 °C) and huminite reflectivity (0.28%–0.30%) indicate a low degree of maturity for these lignites which is also substantiated by the T max versus hydrogen index plot. The organic matter is subjugated by kerogen Type-III with a potential to expel hydrocarbon on liquefaction. Study further reveals that the fixed hydrocarbon is several folds higher than the free hydrocarbons. Being high in reactive maceral content, a high ‘conversion’ and good ‘oil yield’ values for these lignites were observed. Thus, the empirically derived values match well with those obtained through the experimental values of Rock-Eval Pyrolysis and validate their hydrocarbon generating potential.

关键词： Saurashtra lignite Reactive maceral Rock-Eval Hydrocarbon generating potential

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：