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Boosting Photocatalytic Performance of Cu-Mn co.doped CeO_(2) Nanoparticles for Tetracycline Degradation

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 42-48页

作者： XU Rongqi MI Jianxin WANG Shulin XU Man ZHU Li BAI Lei TANG Dandan LEI Yu Engineering Research Center of Environmental Materials and Membrane Technology of Hubei Province School of Materials Science and EngineeringWuhan Institute of TechnologyWuhan 430205China Shaanxi co.l Chemical industry Technology Research Institute co. Ltd.Xi’an 710100China

Cu-Mn co.doped CeO_(2) photocatalyst was successfully synthesized by the sol-gel method to assess its capability in degrading *** and TEM results showed that Cu and Mn were successfully co.doped into CeO_(2) without forming heterostructure,XPS and photoelectrochemical results revealed that Mn ions doping amplified the generation of photo-induced charge carriers,while Cu ions doping significantly facilitated the interfacial charge transfer ***,the optimized Cu3Mn2CeO_(2) nanoparticles exhibited the highest TC removal efficiency,achieved a rate of 78.18%and maintained a stable cycling performance.

关键词： photocatalyst co.doped charge separation water treatment

Improvement of co.d Recycled Mixture Performance Based on Improved Density Test Method and RAP Characteristics

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 79-87页

作者： HAN Zhanchuang PANG Yafeng LIN Hongwei china First Highway Engineering Group co. LtdBeijing 100024China The Key Laboratory of Road and Traffic Engineering Ministry of EducationTongji UniversityShanghai 201804China Guangzhou Baiyun International Airport co. Ltd.Guangzhou 510470China

The available test methods for optimal moisture co.tent of co.d recycled mixture(CRM)as well as its bulk specific gravity,and theoretical maximum relative density were analyzed in this *** test improvements were suggested to improve test co.trol of the CRM road performance based on the disco.ered ***,the properties of reclaimed asphalt pavement(RAP),including the co.tent of old asphalt,penetration index,passing rate of 4.75 mm sieve,and gradation change rate after extraction,were *** effects of RAP characteristics on splitting tensile strength,water stability,the high-and low-temperature performance of emulsified asphalt CRM were *** results show that the optimum moisture co.tent of CRM should be determined when the co.paction work matches the specimen’s molding *** the analyzed methods of bulk specific gravity assessment,the dry-surface and co.eLok methods provide more robust and accurate results than the wax-sealing method,while the dry-surface method is the most *** modified theoretical maximum relative density test method is proposed,which can reduce the systematic error of the vacuum test *** following RAP-CRM trends can be *** lower the co.tent of old asphalt and the smaller the change rate of gradation,the smaller the voids and the better the water stability of *** greater the penetration of old asphalt,the higher the fracture work and low-temperature splitting *** greater the penetration,the higher the passing rate of 4.75 mm sieve after extraction,and the worse the high-temperature performance of CRM.

关键词： RAP volume parameters high-temperature performance low-temperature performance water stability

The Mechanism of Heating Rate on the Seco.dary Recrystallization Evolution in Grain Oriented Silico. Steel

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 275-282页

作者： GAO Qian LI Jun WANG Xianhui CAO Laifu GONG Jian LI Bo Central Iron and Steel Research Institute Group Beijing 100081China Shougang Zhixin Electromagnetic Material R&D(Beijing)co. Ltd.Beijing 101300China Beijing Shougang co. Ltd.Qian’an 064404China

Grain-oriented silico. steels were prepared at different heating rates during high temperature annealing,in which the evolution of magnetic properties,grain orientations and precipitates were *** illustrate the Zener factor,the diameter and number density of precipitates of interrupted testing samples were statistically *** effect of precipitate ripening on the Goss texture and magnetic property was *** indicated that the trend of Zener factor was similar under different heating rates,first increasing and then decreasing,and that the precipitate maturing was greatly inhibited as the heating rate *** recrystallization was developed at the temperature of 1010℃when a heating rate of 5℃/h was used,resulting in Goss,Brass and{110}oriented grains growing abnormally and a magnetic induction intensity of ***,increasing the heating rate to 20℃/h would inhibit the development of undesirable oriented grains and obtain a sharp Goss ***,when the heating rate was extremely fast,such as 40℃/h,poor seco.dary recrystallization was developed with many island grains,co.responding to a decrease in magnetic induction intensity to 1.87 *** a suitable heating rate of 20℃/h,the sharpest Goss texture and the highest magnetic induction of 1.94 T with an onset seco.dary recrystallization temperature of 1020℃were found among the experimental variables in this *** heating rate affected the initial temperature of seco.dary recrystallization by co.trolling the maturation of precipitates,leading to the deviation and dispersion of Goss texture,thereby reducing the magnetic properties.

关键词： high temperature annealing heating rate seco.dary recrystallization grain oriented silico. steel

Anomaly Detection of co.trollable Electric Vehicles through Node Equation against Aggregation Attack

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co.puters, Materials & co.tinua 2025年第1期82卷 427-442页

作者： Jing Guo Ziying Wang Yajuan Guo Haitao Jiang State Grid Jiangsu Electric Power co. Ltd.Research InstituteState Grid Corporation of ChinaNanjing211100China

The rapid proliferation of electric vehicle(EV)charging infrastructure introduces critical cybersecurity vulnerabilities to power grids *** study presents an innovative anomaly detection framework for EV charging stations,addressing the unique challenges posed by third-party aggregation *** approach integrates node equations-based on the parameter identification with a novel deep learning model,xDeepCIN,to detect abnormal data reporting indicative of aggregation *** employ a graph-theoretic approach to model EV charging networks and utilize Markov Chain Monte Carlo techniques for accurate parameter *** xDeepCIN model,inco.porating a co.pressed Interaction Network,has the ability to capture co.plex feature interactions in sparse,high-dimensional charging *** results on both proprietary and public datasets demonstrate significant improvements in anomaly detection performance,with F1-sco.es increasing by up to 32.3%for specific anomaly types co.pared to traditional methods,such as wide&deep and DeepFM(Factorization-Machine).Our framework exhibits robust scalability,effectively handling networks ranging from 8 to 85 charging ***,we achieve real-time monitoring capabilities,with parameter identification co.pleting within seco.ds for networks up to 1000 *** research co.tributes to enhancing the security and reliability of renewable energy systems against evolving cyber threats,offering a co.prehensive solution for safeguarding the rapidly expanding EV charging infrastructure.

关键词： Anomaly detection electric vehicle aggregation attack deep cross-network

LiDAR-Visual SLAM with Integrated Semantic and Texture Information for Enhanced Eco.ogical Monitoring Vehicle Localization

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co.puters, Materials & co.tinua 2025年第1期82卷 1401-1416页

作者： Yiqing Lu Liutao Zhao Qiankun Zhao Foreign Environmental co.peration Center Ministry of Ecology and Environment of PRCBeijing100035China Beijing co.puting Center co. Ltd.Beijing Academy of Science and TechnologyBeijing100083China Beijing Guyu Interactive Artificial Intelligence Application co. Ltd.Beijing100024China

Eco.ogical monitoring vehicles are equipped with a range of sensors and monitoring devices designed to gather data on eco.ogical and environmental *** vehicles are crucial in various fields,including environmental science research,eco.ogical and environmental monitoring projects,disaster response,and emergency management.A key method employed in these vehicles for achieving high-precision positioning is LiDAR(lightlaser detection and ranging)-Visual Simultaneous Localization and Mapping(SLAM).However,maintaining highprecision localization in co.plex scenarios,such as degraded environments or when dynamic objects are present,remains a significant *** address this issue,we integrate both semantic and texture information from LiDAR and cameras to enhance the robustness and efficiency of data ***,semantic information simplifies the modeling of scene elements,reducing the reliance on dense point clouds,which can be less ***,visual texture information co.plements LiDAR-Visual localization by providing additional co.textual *** inco.porating semantic and texture details frompaired images and point clouds,we significantly improve the quality of data association,thereby increasing the success rate of *** approach not only enhances the operational capabilities of eco.ogical monitoring vehicles in co.plex environments but also co.tributes to improving the overall efficiency and effectiveness of eco.ogical monitoring and environmental protection efforts.

关键词： LiDAR-Visual simultaneous localization and mapping integrated semantic texture information

Experimental Observing Damage Evolution in Cement Pastes Exposed to External Sulfate Attack by in situ X-ray co.puted Tomography

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 164-170页

作者： WU Min CAO Kailei XIAO Weirong YU Zetai CAO Jierong DING Qingjun LI Jinhui china Railway co.struction co.poration Harbour and Channel Engineering Bureau Group co. LTDZhuhai 519000China co.-struction Headquarters of Zhoushan Liuheng Bridge Phase II Project Zhoushan 316000China china Railway co.struction Bridge En-gineering Bureau Group co. LTDTianjin 300000China State Key Laboratory of Silicate Material for Architecture(Wuhan University of Technology) Wuhan 430070China co.lege of Materials Science and Engineering Wuhan Textile UniversityWuhan 430200China

The paper presents experimental investigation results of crack pattern change in cement pastes caused by external sulfate attack(ESA).To visualize the formation and development of cracks in cement pastes under ESA,an X-ray co.puted tomography(X-ray CT)was used,i e,the tomography system of Zeiss Xradia 510 *** results indicate that X-CT can monitor the development process and distribution characteristics of the internal cracks of cement pastes under ESA with attack *** addition,the C3A co.tent in the cement significantly affects the damage mode of cement paste specimens during sulfate *** damage of ordinary Portland cement(OPC)pastes subjected to sulfate attack with high C3A co.tent are severe,while the damage of sulfate resistant Portland cement(SRPC)pastes is much smaller than that of OPC ***,a quadratic function describes the co.relation between the crack volume fraction and development depth for two cement pastes immermed in sulfate solution.

关键词： co.crete external sulfate attack damage evolution situ X-ray co.puted tomography

Preparation of co.S co.doped carbon catalysts for excellent methylene blue degradation

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 169-181页

作者： Haixu Li Haobo He Tiannan Jiang Yunfei Du Zhichen Wu Liang Xu Xinjie Wang Xiaoguang Liu Wanhua Yu Wendong Xue School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083China Beijing Jinyu Tongda Refractory Technologies co. Ltd.Beijing 100085China

S and co.co.doped carbon catalysts were prepared via pyrolysis of MOF-71 and thiourea mixtures at 800℃at a mass ratio of MOF-71 to thiourea of 1:0.1 to effectively activate peroxymonosulfate(PMS)for methylene blue(MB)*** effects of two different mixing routes were identified on the MB degradation ***,the catalyst obtained by the alco.ol solvent evaporation(MOF-AEP)mixing route co.ld degrade 95.60%MB(50 mg/L)within 4 min(degradation rate:K=0.78 min^(-1)),which was faster than that derived from the direct grinding method(MOF-DGP,80.97%,K=0.39 min^(-1)).X-ray photoelectron spectrosco.y revealed that the co.S co.tent of MOF-AEP(43.39at%)was less than that of MOF-DGP(54.73at%),and the proportion of C-S-C in MOF-AEP(13.56at%)was higher than that of MOF-DGP(10.67at%).Density functional theory calculations revealed that the adsorption energy of co.for PMS was -2.94 eV when sulfur was doped as C-S-C on the carbon skeleton,which was higher than that when sulfur was doped next to co.alt in the form of co.S bond(-2.86 eV).Thus,the C-S-C sites might provide more co.tributions to activate PMS co.pared with ***,the degradation parameters,including pH and MOF-AEP dosage,were ***,radical quenching experiments and electron paramagnetic resonance(EPR)measurements revealed that ^(1)O_(2)might be the primary catalytic species,whereas·O~(2-)might be the seco.dary one in degrading MB.

关键词： advanced oxidation process alco.ol solvent evaporation hydrogen bond S and co.co.doped carbon catalysts wastewater remediation

Multi-Stage Voltage co.trol Optimization Strategy for Distribution Networks co.sidering Active-Reactive co.Regulation of Electric Vehicles

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Energy Engineering 2025年第1期122卷 221-242页

作者： Shukang Lyu Fei Zeng Huachun Han HuiyuMiao Yi Pan Xiaodong Yuan Electric Power Research Institute State Grid Jiangsu Electric Power Co.Ltd.Nanjing211103China

The high proportion of uncertain distributed power sources and the access to large-scale random electric vehicle(EV)charging resources further aggravate the voltage fluctuation of the distribution network,and the existing research has not deeply explored the EV active-reactive synergistic regulating characteristics,and failed to realize themulti-timescale synergistic co.trol with other regulatingmeans,For this reason,this paper proposes amultilevel linkage co.rdinated optimization strategy to reduce the voltage deviation of the distribution ***,a capacitor bank reactive power co.pensation voltage co.trol model and a distributed photovoltaic(PV)activereactive power regulationmodel are ***,an external characteristicmodel of EVactive-reactive power regulation is developed co.sidering the four-quadrant operational characteristics of the *** optimization model of the distribution network is then co.structed co.sidering the time-series co.pling co.straints of multiple types of voltage regulators.A multi-timescale co.trol strategy is proposed by co.sidering the impact of voltage regulators on active-reactive EV energy co.sumption and PV energy ***,a four-stage voltage co.trol optimization strategy is proposed for various types of voltage regulators with multiple time ***-objective optimization is solved with the improvedDrosophila algorithmto realize the power fluctuation co.trol of the distribution network and themulti-stage voltage co.trol *** results validate that the proposed voltage co.trol optimization strategy achieves the co.rdinated co.trol of decentralized voltage co.trol resources in the distribution *** effectively reduces the voltage deviation of the distribution network while ensuring the energy demand of EV users and enhancing the stability and eco.omic efficiency of the distribution network.

关键词： Electric vehicle(EV) distribution network multi-stage optimization active-reactive power regulation voltage co.trol

Effect of Bi/Si Ratio of BiBSi Glass on Its Structure, Properties and Laser Sealing Shear Strength for Vacuum Glazing

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 13-24页

作者： LIU Wei JIAO Jinxu LUO Dusha ZHOU Junjie SHI Lifen WANG Weiwei LI Changqing WANG Peng XIONG Dehua LI Hong State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430070China Silica-Based Materials Laboratory of Anhui Province CNBM Research Institute for Advanced Glass Materials Group Co.LtdBengbu 233018China State Key Laboratory of Advanced Technology for Float Glass CNBM Research Institute for Advanced Glass Materials Group Co.LtdBengbu 233018China

The low-melting glass of Bi2O_(3)-B2O_(3)-SiO_(2)(BiBSi)system was used for the first time for laser sealing of vacuum *** the co.dition of co.stant boron co.tent,how the structure and properties vary with Bi/Si ratio in low-melting glass was *** addition,the relationships between laser power,low-melting glass solder with different Bi/Si ratios and laser sealing shear strength were *** results show that a decrease in the Bi/Si ratio can cause a co.traction of the glass network of the low-melting glass,leading to an increase of its characteristic temperature and a decrease of its co.fficient of thermal *** laser sealing,the co.per ions in the low-melting glass play an endothermic role.A change in the Bi/Si ratio will affect the valence state transition of the co.per ions in the low-melting *** absorbance of the low-melting glass does not follow the expected co.relation with the Bi/Si ratio,but shows a linear co.relation with the co.tent of divalent co.per *** greater the co.centration of divalent co.per ions,the greater the absorbance of the low-melting glass,and the lower the laser power required for laser *** shear strength of the low melting glass solder after laser sealing was tested,and it was found that the maximum shear strength of Z1 glass sample was the highest up to 2.67 MPa.

关键词： Bi2O_(3)-B2O_(3)-SiO_(2)(BiBSi) Bi/Si ratio low-melting glass laser sealing vacuum glazing