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Omnidirectional simulation analysis of thermomechanical coupling mechanism in inertia friction welding of Ni-based superalloy

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Chinese Journal of Aeronautics 2025年第1期38卷 202-216页

作者： Chang-an LI Guoliang QIN Hao WANG school of materials science and engineering Shandong UniversityJinan 250061China

The coupling between heat and pressure is the kernel of inertia friction welding(IFW)and is still not fully understood.A novel 3D fully coupled finite element model based on a plastic friction pair was developed to simulate the IFW process of a Ni-based superalloy and reveal the omnidirectional thermo-mechanical coupling mechanism of the friction *** numerical model successfully simulated the deceleration,deformation processes,and peak torsional moments in IFW and captured the evolution of temperature,contact pressure,and *** simulated results were validated through measured thermal history,optical macrography,and axial *** results indicated that interfacial friction heat was the primary heat source,and plastic deformation energy only accounted for 4%of the *** increase in initial rotational speed and friction pressure elevated the peak temperature,reaching a maximum of 1525.5K at an initial rotational speed of 2000 r/min and friction pressure of 400 *** interface heat generation could form an axial temperature gradient exceeding 320K/*** radial inhomogeneities of heat generation and temperature were manifested in a concentric ring distribution with maximum heat flux and temperature ranging from 2/5 to 2/3 *** radial inhomogeneities were caused by increasing linear velocity along the radius and an opposite distribution of contact pressure,which could reach 1.7 times the set pressure at the *** circumferential inhomogeneity of thermomechanical distribution during rotary friction welding was revealed for the first time,benefiting from the 3D *** deflection and transformation of distribution in contact pressure and Mises stress were indicators of plastic deformation and transition of quasi-steady state *** critical Mises stress was 0.5 times the friction pressure in this *** presented modeling provides a reliable insight into the thermo-mechanical coupling mechanism of IFW and lays a solid found

关键词： Inertia friction welding Thermo-mechanical coupling Inhomogeneity Numerical simulation Ni-based superalloy

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Layered metal carbo–selenide Nb2CSe2 with van der Waals interlayer coupling

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Journal of Advanced Ceramics 2025年第1期14卷 101-110页

作者： Junchao Wang Renfei Cheng Tao Hu Xinyue Tang Yan Liang Min Tian Ting Xiong Qiuhong Lu Qi Zhu Zhiqing Yang Xiaohui Wang Yanchun Zhou Shenyang National Laboratory for materials science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China school of materials science and engineering University of Science and Technology of ChinaShenyang 110016China Institute of materials science and Devices School of Materials Science and EngineeringSuzhou University of Science and TechnologySuzhou 215009China school of materials science and engineering Shenyang Ligong UniversityShenyang 110159China Ji Hua Laboratory Foshan 528000China Key Laboratory for Anisotropy and Texture of materials(Ministry of Education) School of Materials Science and EngineeringNortheastern UniversityShenyang 110819China school of materials science and engineering Zhengzhou UniversityZhengzhou 450001China

The stacking structure of Nb,CSe2,a newly synthesized layered metal carbo-selenide,was elucidated by scanning transmission electron ***,CSe2 features Se-Nb-C-Nb-Se quintuple atomic *** layers are stacked in Bernal *** this mode,Nb,CSe2 crystallizes in a trigonal symmetry(space group P3m1,No.164),with lattice parameters of a=3.33 A and c=18.20 *** structure calculations indicate that the metal carbo-selenide has Fermi energy crossing the bands where it touches to give a zero gap,indicating that it is an electronic *** evidenced experimentally,the electrical conductivity is as high as 6.6x105 S.m-,outperforming the counterparts in the MXene *** to the layered structure,the bonding in Nb,CSe2 with an ionic formula of(Nb1.48+),(C1.74-)(Se0.61-)2 is highly anisotropic,with metallic-covalent-ionic bonding in intralayers and weak bonding between *** layered nature is further evidenced by elastic properties,interlayer energy,and friction coefficient *** characteristics indicate that Nb,CSe2 is an analog of molybdenum disulfide(MoS2),which is a typical binary van der Waals(vdw)***,vibrational properties are reported,which may offer an optical identification standardfor new ternaryvdW solids in spectroscopic studies,including Raman scatteringand infraredabsorption.

关键词： MXene Nb2CSe2 crystal structure electronic structure elastic properties interlayer coupling Raman spectroscopy friction coefficient

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Bilinear magnetoelectric resistance induced by spin Hall effect

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science china materials 2025年第2期68卷 687-688页

作者： Ruiyue Chu Cheng Song school of materials science and engineering Tsinghua UniversityBeijing 100084China

Magnetoresistance(MR)is a fundamental transport phenomenon crucial for reading magnetic *** also plays a key role in understanding how time-reversal symmetry breaking affects electrical *** discoveries of anisotropic MR[1],giant MR[2],tunneling MR[3],and spin Hall magnetoresistance[4]have driven the development of diverse spintronic devices used in data storage,computing,and sensing ***,these MR effects do not scale linearly with the electric field(and thus,electric current).Recently,nonlinear MR,which scales specifically with the electric current(Ic),has been *** magnetic/non-magnetic bilayers,unidirectional spin Hall magnetoresistance(USMR)[5]shows a linear dependence on Ic,with voltage scaling quadratically with the applied electric field,due to interfacial spin-dependent and electron-magnon scattering mechanisms.

关键词： breaking symmetry linearly

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Co/Co_(7)Fe_(3)heterostructures with controllable alloying degree on carbon spheres as bifunctional electrocatalyst forrechargeable zinc-air batteries

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International Journal of Minerals,Metallurgy and materials 2025年第2期32卷 476-487页

作者： Junkang Chen Yongyue Zhuang Yanxin Qiao Yu Zhang Aihua Yuan Hu Zhou school of materials science and engineering Jiangsu University of Science and TechnologyZhenjiang 212003China school of Environmental and Chemical engineering Jiangsu University of Science and TechnologyZhenjiang 212003China

Exploring efficient and nonprecious metal electrocatalysts of oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)is crucial for developing rechargeable zinc-air batteries(ZABs).Herein,an alloying-degree control strategy was employed to fabricate nitrogen-doped carbon sphere(NCS)decorated with dual-phase Co/Co_(7)Fe_(3)heterojunctions(CoFe@NCS).The phase composition of materials has been adjusted by controlling the alloying *** optimal CoFe_(0.08)@NCS electrocatalyst displays a half-wave potential of 0.80 V for ORR and an overpotential of 283 mV at 10 mA·cm^(-2)for OER in an alkaline *** intriguing bifunctional electrocatalytic activity and durability is attributed to the hierarchically porous structure and interfacial electron coupling of highly-active Co_(7)Fe_(3)alloy and metallic Co *** the CoFe_(0.08)@NCS material is used as air-cathode catalyst of rechargeable liquid-state zinc-air battery(ZAB),the device shows a high peak power-density(157 mW·cm^(-2))and maintains a stable voltage gap over 150 h,outperforming those of the benchmark(Pt/C+RuO_(2))-based *** particular,the as-fabricated solid-state flexible ZAB delivers a reliable compatibility under different bending *** work provides a promising strategy to develop metal/alloy-based electrocatalysts for the application in renewable energy conversion technologies.

关键词： bifunctional electrocatalysts oxygen reduction reaction oxygen evolution reaction zinc-air battery metal/alloy carbon sphere

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In situ construction of Cu(Ⅰ)-Cu(Ⅱ) pairs for efficient electrocatalytic nitrate reduction reaction to ammonia

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Journal of Energy Chemistry 2025年第1期100卷 106-113页

作者： Muyun Zheng Yuchi Wan Leping Yang Shen Ao Wangyang Fu Zhengjun Zhang Zheng-Hong Huang Tao Ling Feiyu Kang Ruitao Lv State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Institute of New Energy materials and engineering School of Materials Science and EngineeringFuzhou UniversityFuzhou 350108FujianChina Key Laboratory of Advanced materials(MOE) School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education Tianjin Key Laboratory of Composite and Functional MaterialsSchool of Materials Science and EngineeringTianjin UniversityTianjin 300072China

Electrocatalytic nitrate reduction reaction (NO_(3)-RR) to ammonia under ambient conditions is expected to be a green process for ammonia synthesis and alleviate water pollution *** report a CuO nanoparticles incorporated on nitrogen-doped porous carbon (CuO@NC) catalyst for NO_(3)-*** of Cu(Ⅱ) is reduced to Cu(Ⅰ) during the NO_(3)-RR process to construct Cu(Ⅰ)-Cu(Ⅱ) pairs,confirmed by in situ X-ray photoelectron spectroscopy (XPS) and Raman *** functional theory (DFT) calculations indicated that the formation of Cu(Ⅰ) could provide a reaction path with smaller energy barrier for NO_(3)-RR,while Cu(Ⅱ) effectively suppressed the competition of hydrogen evolution reaction (HER).As a result,CuO@NC catalyst achieved a Faradaic efficiency of 84.2% at -0.49 V versus reversible hydrogen electrode (RHE),and a NH_(3)yield rate of 17.2 mg h^(-1)mg^(-1)*** -0.79 V ***,higher than the HaberBosch process (<3.4 g h^(-1)g^(-1)cat.).This work may open a new avenue for effective NO_(3)-RR by modulating oxidation states.

关键词： Ammonia synthesis Cu oxidation state Electrochemistry Nitrate reduction In situ XPS

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Electrocatalytic nitrite reduction to ammonia on isolated bismuth alloyed ruthenium

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Journal of Energy Chemistry 2025年第1期100卷 369-376页

作者： Shiyao Shang Fuzhou Wang Zeyi Sun Chaofan Qiang Ke Chu school of materials science and engineering Lanzhou Jiaotong UniversityLanzhou 730070GansuChina

Electrochemical reduction of NO_(2)-to NH_(3)(NO_(2)-RR) is recognized as an appealing approach for achieving renewable NH_(3)synthesis and waste NO_(2)-***,we report isolated Bi alloyed Ru (Bi1Ru) as an efficient NO_(2)-RR *** calculations and in situ electrochemical measurements reveal the creation of Bi1-Ru dual sites which can remarkably promote NO_(2)-activation and suppress proton adsorption,while accelerating the NO_(2)-RR protonation energetics to render a high NO_(2)--to-NH_(3)conversion ***,Bi1Ru assembled in a flow cell delivers an NH_(3)yield rate of 1901.4μmol h^(-1)cm^(-2)and an NH_(3)-Faradaic efficiency of 94.3%at an industrial-level current density of 324.3 mA cm^(-2).This study offers new perspectives for designing and constructing p-block single-atom alloys as robust and high-current-density NO_(2)-RR catalysts toward the ammonia electrosynthesis.

关键词： Electrocatalytic reduction of NO_(2)-to NH_(3) Theoretical computations In situel ectrochemical measurements p-Block single-atom alloys

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Preparation of silver nanoparticles through the reduction of straw-extracted lignin and its antibacterial hydrogel

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International Journal of Minerals,Metallurgy and materials 2025年第2期32卷 504-514页

作者： Lou Zhang Shuo Li Fu Tang Jingkai Zhang Yuetong Kang Hean Zhang Lidong Li State Key Laboratory for Advanced Metals and materials School of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijing 100083China

Silver nanoparticles(Ag NPs)have attracted attention in the field of biomaterials due to their excellent antibacterial ***,the reducing and stabilizing agents used for the chemical reduction of Ag NPs are usually toxic and may cause water *** this work,Ag NPs(31.2 nm in diameter)were prepared using the extract of straw,an agricultural waste,as the reducing and stabilizing *** analysis revealed that the straw extract contained lignin,the structure of which possesses phenolic hydroxyl and methoxy groups that facilitate the reduction of silver salts into Ag *** surfaces of Ag NPs were negatively charged due to the encapsulation of a thin layer of lignin molecules that prevented their *** the prepared Ag NPs were added to the precursor solution of acrylamide,free radical polymerization was triggered without the need for extra heating or light irradiation,resulting in the rapid formation of an Ag NP-polyacrylamide composite *** inhibition zone test proved that the composite hydrogel possessed excellent antibacterial ability due to the presence of Ag *** prepared hydrogel may have potential applications in the fabrication of biomedical materials,such as antibacterial dressings.

关键词： silver nanoparticles hydrogel straw extraction antibacterial

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Influence of laser shock peening on microstructure and high-temperature oxidation resistance of Ti45Al8Nb alloy fabricated via laser melting deposition

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Transactions of Nonferrous Metals Society of china 2025年第1期35卷 157-168页

作者： Lu-lu JIANG Liang LAN Cheng-yan BAI Ru-yi XIN Shuang GAO Hao-yu WANG Bo HE Chao-yue CHEN Guo-xin LU Research Center of High-Temperature Alloy Precision Forming School of Materials Science and EngineeringShanghai University of Engineering ScienceShanghai 201620China State Key Laboratory of Advanced Special Steels School of Materials Science and EngineeringShanghai UniversityShanghai 200444China school of materials science and engineering Shandong UniversityJinan 250061China

Laser shock peening(LSP)was used to enhance the high-temperature oxidation resistance of laser melting deposited Ti45Al8Nb *** microstructure and high-temperature oxidation behavior of the as-deposited Ti45Al8Nb alloy before and after LSP were investigated by scanning electron microscopy,X-ray diffraction,and electron backscatter *** results indicated that the rate of mass gain in the as-deposited sample after LSP exhibited a decrease when exposed to an oxidation temperature of 900℃,implying that LSP-treated samples exhibited superior oxidation resistance at high temperatures.A gradient structure with a fine-grain layer,a deformed-grain layer,and a coarse-grain layer was formed in the LSP-treated sample,which facilitated the diffusion of the Al atom during oxidation,leading to the formation of a dense Al_(2)O_(3)layer on the *** mechanism of improvement in the oxidation resistance of the as-deposited Ti45Al8Nb alloy via LSP was discussed.

关键词： TiAl alloy laser melting deposition laser shock peening additive manufacturing oxidation resistance

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Temperature-sensitive Micelles as Artificial Chaperones for Insulin Protection

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Chinese Journal of Polymer science 2025年第2期43卷 350-359页

作者： Jia-Wen Chen Yan Xiao Mei-Dong Lang Shanghai Key Laboratory of Advanced Polymeric materials Key Laboratory for Ultrafine Materials of Ministry of EducationSchool of Materials Science and EngineeringEast China University of Science and TechnologyShanghai200237China

Insulin is an essential and versatile protein taking part in the control of blood glucose levels and protein ***,under prolonged storage or high temperature stress,insulin tends to unfold and aggregate into toxic amyloid fibrils,leading to loss of physiological *** by natural chaperones,a series of temperature-sensitive polycaprolactone-based micelles were designed to prevent insulin from *** micelles were fabricated through the self-assembly of amphiphilic copolymers of methoxy poly(ethylene glycol)-poly(4-diethylformamide caprolactone-co-caprolactone)(mPEG_(17)-P(DECL-co-CL)),which had a regular spherical morphology with particle sizes of about 100 *** addition,the lower critical solution temperature(LCST)of the micelles could be tuned to 9 and 29℃by changing the ratio of DECL to *** from the temperature-sensitivity of DECL segment,the binding ability of micelles to insulin could be modulated by changing the *** LCST,micelles effectively inhibited insulin aggregation and protected it from thermal inactivation due to the strong binding ability between the hydrophobic segment DECL and *** LCST,DECL segment returned to hydrophilic and bound weakly with insulin,leading to the release of insulin and assisting in its recovery of secondary ***,these temperature-sensitive micelles provided an effective strategy for insulin protection.

关键词： Temperature-sensitive Insulin Micelles Chaperones

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Oxygen vacancies-rich molybdenum tungsten oxide nanowires as a highly active nitrogen fixation electrocatalyst

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Chinese Chemical Letters 2025年第1期36卷 545-548页

作者： Jincheng Zhang Mengjie Sun Jiali Ren Rui Zhang Min Ma Qingzhong Xue Jian Tian school of materials science and engineering Shandong University of Science and TechnologyQingdao 266590China

Herein,vacancy engineering is utilized reasonably to explore molybdenum tungsten oxide nanowires(W_(4)MoO_(3)NWs)rich in O-vacancies as an advanced electrochemical nitrogen reduction reaction(eNRR)electrocatalyst,realizing further enhancement of NRR *** 0.1 mol/L Na_(2)SO_(4),W_(4)MoO_(3)NWs rich in O vacancies(CTAB-D-W_(4)MoO_(3))achieve a large NH3yield of 60.77μg h^(-1)mg^(-1)***-0.70 V *** and a high faradaic efficiency of 56.42%at-0.60 V,much superior to the W_(4)MoO_(3)NWs deficient in oxygen vacancies(20.26μg h^(-1)mg^(-1)*** 17.1%at-0.70 V ***).Meanwhile,W_(4)MoO_(3)NWs rich in O-vacancies also show high electrochemical *** functional theory(DFT)calculations present that O vacancies in CTAB-D-W_(4)MoO_(3)reduce the energy barrier formed by the intermediate of^(*)N-NH,facilitate the activation and further hydrogenation of^(*)N-N,promote the NRR process,and improve NRR activity.

关键词： Electrocatalytic N_(2) reduction reaction Molybdenum-tungsten oxide Nanowires Oxygen vacancies Non-noble metal

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