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Rheological study of methane gas hydrates in the presence of micron-sized sand particles

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Chinese Journal of Chemical Engineering 2024年第6期70卷 149-161页

作者： Bohui Shi Shangfei Song Yuchuan Chen Shunkang Fu Lihao Liu Xinyao Yang Haihao Wu Guangjin Chen Jing Gong national Engineering Research Center of oil and gas Pipeline Transportation Safety MOE Key Laboratory of Petroleum EngineeringBeijing Key Laboratory of Urban Oil and Gas Distribution TechnologyChina University of Petroleum-BeijingBeijing 102249China china's oil and gas exploration and development Company(CNODC) Beijing 100034China china national Petroleum corporation Mozambique LDA MaputoMozambique Pipechina West East Pipeline Company Shanghai 200122China

Natural gas hydrates,intricate crystalline structures formed by water molecules and small gas molecules,have emerged as a significant and globally impactful clean energy ***,their commercial exploitation faces challenges,particularly operational disruptions caused by sand-related *** the rheological properties of hydrate slurry,especially in the presence of micron-sized sand particles,is imperative for ensuring the flow assurance of subsea hydrate *** study extensively investigates the rheological properties of sand-containing hydrate *** findings reveal that these slurries exhibit non-Newtonian fluid characteristics,including yield stress,thixotropy,and shear-thinning ***-like elastic features are observed in sand-containing hydrate slurries before yielding,transitioning to viscous behavior after *** with a minimal amount of sand,both static yield stress and yield strain experience substantial changes,correlating with the increase in sand *** research conclusively establishes the thixotropic nature of sand-hydrate slurries,where the viscosity decay rate is directly influenced by the shear *** insights aim to contribute comprehensively to the development of effective flow assurance strategies,ensuring the safe and stable operation of subsea hydrate exploitation.

关键词： Natural gas hydrate production Sand-containing hydrate slurries Yield stress Thixotropy Shear-thinning behavior

Study on the Impact of Massive Refracturing on the Fracture Network in Tight oil Reservoir Horizontal Wells

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Fluid Dynamics & Materials Processing 2024年第5期20卷 1147-1163页

作者： Jianchao Shi Yanan Zhang Wantao Liu Yuliang Su Jian Shi exploration and development Research Institute Changqing Oilfield CompanyXi’an710018China national Engineering Laboratory for exploration and development of Low Permeability oil and gas Fields Xi’an710018China Key Laboratory of Unconventional oil and gas development(china University of Petroleum(East china)) Ministry of EducationQingdao266580China

Class III tight oil reservoirs have low porosity and permeability,which are often responsible for low production rates and limited *** repeated fracturing is a well-known technique to fix some of these *** such methods,existing fractures are refractured,and/or new fractures are created to facilitate communication with natural *** study explored how different refracturing methods affect horizontal well fracture networks,with a special focus on morphology and related fluid flow *** particular,the study relied on the unconventional fracture model(UFM).The evolution of fracture morphology and flow field after the initial fracturing were analyzed *** simulation results indicated that increased formation energy and reduced reservoir stress differences can promote fracture *** was shown that the length of the fracture network,the width of the fracture network,and the complexity of the fracture can be improved,the oil drainage area can be increased,the distance of oil and gas seepage can be reduced,and the production of a single well can be significantly increased.

关键词： Type III tight oil reservoirs refracturing methods horizontal wells fracture network study fracture network evolution

Advancements and New Frontiers in Offshore Seismic exploration Technology

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Journal of Earth Science 2024年第5期35卷 1749-1757页

作者： Yuhong Xie Yunfei Ye Xiaogang Huang Wenbo Sun Yanwen Wei china national Offshore oil corporation CNOOC Nanhai oil and gas Energy Academician Workstation CNOOC Research Institute Ltd. national Engineering Research Center of Offshore oil and gas exploration

0 INTRODUCTION china's external dependence on oil and gas remains high, making the independent exploration and development of oil and gas resources crucial for ensuring national energy security and the sustainable development of the economy and society. In 2023, china continued to step up its efforts in offshore oil and gas exploration and development, with offshore crude oil production surpassing 62 million tons, accounting for about 70% of the national increase in crude oil production. Deepening offshore oil and gas exploration and development is of great significance for guaranteeing national energy security.

关键词： offshore guarantee continued

Reactive transport modeling constraints on the complex genesis of a lacustrine dolomite reservoir: A case from the Eocene Qaidam Basin,china

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Petroleum Science 2024年第4期21卷 2240-2256页

作者： Ying Xiong Bo Liu Xiu-Cheng Tan Zheng-Meng Hou Jia-Shun Luo Ya-Chen Xie Kai-Bo Shi Kun-Yu Wu School of Earth and Space Sciences Peking University Institute of oil and gas Peking University china national Petroleum corporation Key Laboratory of Carbonate Reservoirs Southwest Petroleum University Institute of Subsurface Energy Systems Clausthal University of Technology Research Institute of exploration and development PetroChina Qinghai Oil Field Company

Reactive transport modeling(RTM) is an emerging method used to address geological issues in diagenesis research. However, the extrapolation of RTM results to practical reservoir prediction is not sufficiently understood. This paper presents a case study of the Eocene Qaidam Basin that combines RTM results with petrological and mineralogical evidence. The results show that the Eocene Xiaganchaigou Formation is characterized by mixed siliciclastic-carbonate-evaporite sedimentation in a semiclosed saline lacustrine environment. Periodic evaporation and salinization processes during the syngeneticpenecontemporaneous stage gave rise to the replacive genesis of dolomites and the cyclic enrichment of dolomite in the middle-upper parts of the meter-scale depositional sequences. The successive change in mineral paragenesis from terrigenous clastics to carbonates to evaporites was reconstructed using RTM simulations. Parametric uncertainty analyses further suggest that the evaporation intensity(brine salinity) and particle size of sediments(reactive surface area) were important rate-determining factors in the dolomitization, as shown by the relatively higher reaction rates under conditions of higher brine salinity and fine-grained sediments. Combining the simulation results with measured mineralogical and reservoir physical property data indicates that the preservation of original intergranular pores and the generation of porosity via replacive dolomitization were the major formation mechanisms of the distinctive lacustrine dolomite reservoirs(widespread submicron intercrystalline micropores) in the Eocene Qaidam Basin. The results confirm that RTM can be effectively used in geological studies, can provide a better general understanding of the dolomitizing fluid-rock interactions, and can shed light on the spatiotemporal evolution of mineralogy and porosity during dolomitization and the formation of lacustrine dolomite reservoirs.

关键词： Reactive transport modeling Lacustrine dolomite Mineralogy and porosity evolution Reservoir genesis

Differences in and factors controlling organic matter enrichment in the Ziliujing Formation shale in the Sichuan Basin

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Petroleum Science 2024年第1期21卷 77-86页

作者： Peng Li Zhong-Bao Liu He Bi Tao Jiang Rui-Kang Bian Peng-Wei Wang Xiao-Yu Shang State Key Laboratory of Shale oil and gas Enrichment Mechanisms and Efficient development Beijing102206China Key Laboratory of Shale oil/gas exploration and Production Technology SINOPECBeijing102206China Petroleum exploration and Production Research Institute SINOPECBeijing102206China Research Institute of Petroleum exploration and development PetroChinaBeijing100083China Chinese Academy of Geological Sciences Beijing100037China No.4 oil Production Plant in Daqing oilfield Co Ltd. Daqing163511HeilongjiangChina

Lacustrine shale oil and gas are important fields for unconventional exploration and development in china,and organic-rich shale deposition lays down the critical foundation for hydrocarbon *** are two sets of shale,the Dongyuemiao and Da’anzhai Members,in the Ziliujing Formation in the Sichuan *** identify the differential enrichment characteristics of organic matter and clarify its controlling factors,geochemical analyses of organic and inorganic geochemical analyses were *** results showed that the total organic carbon content of the Dongyuemiao shale(1.36%)is slightly higher than that of the Da’anzhai shale(0.95%).The enrichment of organic matter in the two shales resulted from the comprehensive controls of paleoproductivity,paleoenvironment,and terrigenous input,but different factors have different *** addition,driven by climate,the change in the sulfate concentration in the bottom water further led to the different intensities of bacterial sulfate reduction in early *** made a great difference regarding organic matter accumulation in the two *** general,climate may have played a dominant role in organic matter enrichment in the two sets of shale.

关键词： Lacustrine shale Ziliujing Formation Sichuan Basin Enrichment mechanism of organic matter

Hydrodynamic resistance of pore–throat structures and its effect on shale oil apparent permeability

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International Journal of Coal Science & Technology 2024年第2期11卷 101-110页

作者： Wendong Wang Qian Zhang Jilong Xu Da Zheng Lifeng Liu Yuliang Su Key Laboratory of Unconventional oil and gas development Ministry of EducationQingdao 266580China School of Petroleum Engineering China University of Petroleum(East China)Qingdao 266580ShandongChina Petrochina oil Gas and New Energies CompanyBeijing 100083China Research Institute of Petroleum exploration and development PetroChinaBeijing 100083China

oil transport is greatly affected by heterogeneous pore–throat structures present in *** is therefore very important to accurately characterize pore–throat ***,it remains unclear how pore–throat structures affect oil transport *** this paper,using finite element(FE)simulation and mathematical modeling,we calculated the hydrodynamic resistance for four pore–throat *** addition,the influence of pore throat structure on shale oil permeability is *** to the results,the hydrodynamic resistance of different pore throat structures can vary by 300%.The contribution of additional resistance caused by streamline bending is also in excess of 40%,even without slip ***-thermore,Pore–throat structures can affect apparent permeability by more than 60%on the REV scale,and this influence increases with heterogeneity of pore size distribution,organic matter content,and organic matter ***,modeling shale oil flow requires consideration of porous–throat structure and additional resistance,otherwise oil recovery and flow capacity may be overestimated.

关键词： Pore–throat structure Hydrodynamic resistance Apparent permeability REV-scale Shale oil

The formation and evolutionary characteristics of organic matter and pyrites in the continental shales of the 3^(rd)submember of Chang 7 Member,Yanchang formation,Ordos Basin,china

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Energy Geoscience 2024年第2期5卷 31-39页

作者： Ruikang Bian State Key Laboratory of Shale oil and gas Enrichment Mechanisms and Effective development Beijing 102206China Key Laboratory of Shale oil and gas exploration&Production Technology SinopecBeijing 102206China SINOPEC exploration&Production Research Institute Beijing102206China

Through microscopic analyses(e.g.,organic macerals,thin section observation,scanning electron microscope(SEM)imaging of fresh bedding planes via argon ion milling,and energy spectrum tests)combined with Rock-Eval analyses,this study systematically investigated the organic matter and pyrites in the continental shales in the 3^(rd)submember of the Chang 7 Member(Chang 7^(3)submember)in the Yanchang Formation,Ordos Basin and determined their types and the formation and evolutionary *** results are as *** organic matter of the continental shales in the Chang 7^(3)submember is dominated by amorphous bituminites and migrabitumens,which have come into being since the early diagenetic stage and middle diagenetic stage A,*** formation and transformation of organic matter is a prerequisite for the formation of *** Ordos Basin was a continental freshwater lacustrine basin and lacked sulphates in waters during the deposition of the Chang 7 ***,the syndiagenetic stage did not witness the formation of large quantities of *** the basin entered early diagenetic stage A,large quantities of sulfur ions were released as the primary organic matter got converted into bituminites and,accordingly,pyrites started to ***,this stage featured poorer fluid and spatial conditions compared with the syndepositional stage due to withdraw of water,the partial formation of bituminites,and a certain degree of *** a result,large quantities of pyrrhotite failed to transition into typical spherical framboidal pyrites but grew into euhedral monocrystal *** addition,pyrites are still visible in the migrabitumens in both microfractures and inorganic pores of mudstones and shales,indicating that the pyrite formation period can extend until the middle diagenetic stage A.

关键词： Organic matter Pyrite Formation and evolution Continental shale Chang 7^(3)submember Ordos Basin

Fracturing timing of Jurassic reservoirs in the Dibei-Tuziluoke gas field,Kuqa foreland basin:Evidence from petrography,fluid inclusions,and clumped isotopes

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Energy Geoscience 2024年第2期5卷 129-140页

作者： Guoding Yu Wenfang Yuan Kelai Xi Yin Liu Shuai Wang Zhenping Xu Jing Yuan Lu Zhou Keyu Liu Key Laboratory of Deep oil and gas China University of PetroleumQingdaoShandong266580China Research Institute of Petroleum exploration and development Tarim Oil FieldCNPCKorla841000China

Determining the timing of fracturing is crucial for understanding reservoir evolution and hydrocarbon accumulation in foreland *** fracturing data from cores,borehole images,and outcrops,combined with the clumped isotope(D47)and fluid inclusion analyses of carbonate minerals filled in pores and fractures,this study ascertained the fracturing timing of the Jurassic reservoirs in the Dibei-Tuziluoke gas Field,Kuqa Foreland *** from outcrops and borehole images show two dominant fracture sets in the study area:W-E and NE-SW striking *** W-E striking fractures are carbonate-filled,while NE-SW striking fractures lack mineral *** veins,not easy to be identified in borehole images,are prevalent in *** petrographic analysis reveals that these bitumen veins formed before the calcite cementation in pores and display high viscosity and low *** temperatures(T_(h))from primary fluid inclusion assemblages in two representative calcite vein samples were notably lower than T_(△47) values from corresponding *** suggests the △_(47) signature underwent alteration due to partial reordering during ***,△_(47)-derived temperatures(apparent temperatures)may not faithfully represent the mineral precipitation *** plotting these apparent temperatures *** burial history,only the possible latest ages of fracturing *** ages were further refined by considering petroleum charging,tectonic evolution,and stress ***-filled fractures likely resulted from the Late Cretaceous uplift,marking the migration of low-maturity hydrocarbons in the study ***-filled E-W striking fractures emerged during the late Miocene(~13-6.5 Ma)alongside fold ***-striking fractures that crosscut W-E ones possibly formed recently due to stress reorientation.

关键词： Fracture Borehole imaging Bitumen vein Clumped isotope Fracturing timing

A novel algorithm for evaluating cement azimuthal density based on perturbation theory in horizontal well

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Petroleum Science 2024年第1期21卷 244-251页

作者： Ji-Lin Fan Feng Zhang Qian Chen Hao-Chen Song Lu-Yu Zhong Yue-Xiang Dai national Key Laboratory of Deep oil and gas School of GeosciencesChina University of Petroleum(East China)Qingdao 266580ShandongChina china national Logging corporation Xi'an 710076ShaanxiChina Sinopec Matrix corporation Qingdao 266001ShandongChina

Cement density monitoring plays a vital role in evaluating the quality of cementing projects,which is of great significance to the development of oil and ***,the presence of inhomogeneous cement distribution and casing eccentricity in horizontal wells often complicates the accurate evaluation of cement azimuthal *** this regard,this paper proposes an algorithm to calculate the cement azimuthal density in horizontal wells using a multi-detector gamma-ray detection *** spatial dynamic response functions are simulated to obtain the influence of cement density on gamma-ray counts by the perturbation theory,and the contribution of cement density in six sectors to the gamma-ray recorded by different detectors is obtained by integrating the spatial dynamic response *** with the relationship between gamma-ray counts and cement density,a multi-parameter calculation equation system is established,and the regularized Newton iteration method is employed to invert casing eccentricity and cement azimuthal *** approach ensures the stability of the inversion process while simultaneously achieving an accuracy of 0.05 g/cm^(3) for the cement azimuthal *** accuracy level is ten times higher compared to density accuracy calculated using calibration ***,this algorithm enhances the accuracy of cement azimuthal density evaluation,provides valuable technical support for the monitoring of cement azimuthal density in the oil and gas industry.

关键词： Cement azimuthal density Perturbation theory Casing eccentricity Spatial dynamic response function Regularized Newton iteration