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Lattice Boltzmann simulation study of anode degradation in solid oxide fuel cells during the initial aging process

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International Journal of Minerals,Metallurgy and Materials 2024年第2期31卷 405-411页

作者： Shixue Liu Zhijing Liu Shuxing Zhang Hao Wu Hydrogen Energy Industrial technology Innovation center China Nuclear Power Technology Research InstituteShenzhen 518031China Shenzhen Engineering research center for Hydrogen Safety Shenzhen 518031China

For present solid oxide fuel cells(SOFCs),rapid performance degradation is observed in the initial aging process,and the dis-cussion of the degradation mechanism necessitates quantitative ***,focused ion beam-scanning electron microscopy was em-ployed to characterize and reconstruct the ceramic microstructures of SOFC *** lattice Boltzmann method(LBM)simulation of multiphysical and electrochemical processes in the reconstructed models was *** samples collected from industrial-size cells were characterized,including a reduced reference cell and a cell with an initial aging *** parameters of the reconstructed microstructures revealed a significant decrease in the active triple-phase boundary and Ni connectivity in the aged cell compared with the reference *** LBM simulation revealed that activity degradation is dominant compared with microstructural degradation during the initial aging process,and the electrochemical reactions spread to the support layer in the aged *** microstructural and activity de-gradations are attributed to Ni migration and coarsening.

关键词： solid oxide fuel cell anode degradation focused ion beam-scanning electron microscopy lattice Boltzmann method

Influence of syngas components and ash particles on the radiative heat transfer in a radiant syngas cooler

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Chinese Journal of Chemical Engineering 2024年第4期68卷 203-215页

作者： Chen Han Youmin Situ Huaxing Zhu Jianliang Xu Zhenghua Dai Guangsuo Yu Haifeng Liu National Energy Coal Gasification technology research and Development center East China University of Science and TechnologyShanghai 200237China Shanghai Engineering research center of Coal Gasification East China University of Science and TechnologyShanghai 200237China

Radiant syngas cooler(RSC)is widely used as a waste heat recovery equipment in industrial *** this work,an RSC with radiation screens is established and the impact of gaseous radiative property models,gas components,and ash particles on heat transfer is investigated by the numerical simulation *** the syngas components and the pressure environment of the RSC,a modified weighted-sum-of-gray-gases model was *** modified model shows high accuracy in *** computational fluid dynamics simulation,the calculated steam production is only 0.63%in error with the industrial *** with Smith's model,the temperature decay along the axial direction calculated by the modified model is *** components are of great significance to heat recovery capacity,especially when the absorbing gas fraction is less than 10%.After considering the influence of particles,the outlet temperature and the proportion of radiative heat transfer are less affected,but the difference in steam output reaches 2.7 t·h^(-1).The particle deposition on the wall greatly reduces the heat recovery performance of an RSC.

关键词： Radiant syngas cooler Weighted-sum-of-gray-gases model Numerical simulation Particle radiation

An impact sensitivity assessment method of spacecraft based on virtual exterior wall

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Defence technology（防务技术） 2024年第1期31卷 142-157页

作者： Runqiang Chi Yuyan Liu Diqi Hu Baojun Pang Hypervelocity Impact research center Harbin Institute Of TechnologyHarbin150080China

The impact sensitivity assessment of spacecraft is to obtain the probability of spacecraft encountering the OD/M(orbital debris or meteoroid),which is a prerequisite for survivability assessment of on-orbit *** impact sensitivity assessment method of spacecraft based on virtual exterior wall was proposed to improve the computational *** method eliminates determination of the outermost surface elements of the spacecraft before generating the debris rays,which are assumed to originate from a non-concave virtual wall that completely wraps the *** Dist Mesh method was adopted for the generating of the virtual wall to ensure its mesh *** influences of the sizes,mesh densities,shapes of the virtual wall on the efficiency and accuracy were considered to obtain the best combination of the size and mesh density of the wall and *** results of this method were compared with those of S3DE(Survivability of Spacecraft in Space Debris Environment),BUMPER,MDPANTO,ESABASE2/Debris to verify the feasibility of the *** PCHIP(Piecewise Cubic Hermite Interpolating Polynomial)was used to fit the size *** relationship of the space debris to acquire the impact probability of OD/M with arbitrary size on the spacecraft.

关键词： Sensitivity OD/M Spacecraft Virtual exterior wall

B-COPNA resin formation from ethylene tar light fractions:Process development and mechanical exploration by molecular simulation

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Chinese Journal of Chemical Engineering 2024年第6期70卷 118-129页

作者： Hongyan Shen Lingrui Cui Xingguo Wei Yuanqin Zhang Lian Cen Jun Xu Fahai Cao Engineering research center of Large Scale Reactor East China University of Science and TechnologyShanghai 200237China

An efficient utilization strategy of ethylene tar(ET),the main by-product of the ethylene cracking unit,is urgently required to meet demands for modern petrochemical *** the other hand,condensed polynuclear aromatic resin of moderate condensation degree(B-COPNA)is a widely used carbon material due to its superb processability,the production of which is,however,seriously limited by the high cost of raw *** such context,an interesting strategy was proposed in this study for producing B-COPNA resin using crosslinked light fractions of ethylene tar(ETLF,boiling point<260℃)facilitated by molecular simulation.1,4-Benzenedimethanol(PXG)was first selected as the crosslinking agent according to the findings of molecular *** effects of operating conditions,including reactions temperature,crosslinking agent,and catalyst content on the softening point and yield of B-COPNA resin products were then investigated to optimize the *** reaction mechanism of resin production was studied by analyzing the molecular structure and transition state of ETLF and crosslinking *** was shown that PXG exhibited a superior capacity of withdrawing electrons and a higher electrophilic reactivity than other crosslinking *** addition to the highest yield and greatest heat properties,PXG-prepared resin contained the most condensed *** corresponding optimized conditions of resin preparation were 180℃,1:1.9(PXG:ETLF),and 3%(mass)of catalyst content with a resin yield of 78.57%.It was the electrophilic substitution reaction that occurred between the ETLF and crosslinking agent molecules that were responsible for the resin formation,according to the experimental characterization and molecular ***,it was confirmed that the proposed strategy and demonstrated process can achieve a clean and high value-added utilization of ETLF via B-COPNA resin preparation,bringing huge economic value to the current petrochemical industry.

关键词： Ethylene tar Crosslinking COPNA resin Molecular simulation Transient state

Non-blind super-resolution reconstruction for laser-induced damage dark-field imaging of optical elements

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Chinese Optics Letters 2024年第4期22卷 36-41页

作者：王倩陈凤东韩越越曾发路程刘国栋 Instrument Science and technology Harbin Institute of TechnologyHarbin 150001China research center of Laser Fusion China Academy of Engineering PhysicsMianyang 621900China

The laser-induced damage detection images used in high-power laser facilities have a dark background,few textures with sparse and small-sized damage sites,and slight degradation caused by slight defocus and optical diffraction,which make the image superresolution(SR)reconstruction *** propose a non-blind SR reconstruction method by using an exquisite mixing of high-,intermediate-,and low-frequency information at each stage of pixel reconstruction based on *** simplify the channel attention mechanism and activation function to focus on the useful channels and keep the global information in the *** pay more attention on the damage area in the loss function of our end-toend deep neural *** constructing a high-low resolution image pairs data set,we precisely measure the point spread function(PSF)of a low-resolution imaging system by using a Bernoulli calibration pattern;the influence of different distance and lateral position on PSFs is also considered.A high-resolution camera is used to acquire the ground-truth images,which is used to create a low-resolution image pairs data set by convolving with the measured *** on the data set,our network has achieved better results,which proves the effectiveness of our method.

关键词： laser-induced damage image superresolution image segmentation

Multi-Scale Design and Optimization of Composite Material Structure for Heavy-Duty Truck Protection Device

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Computer Modeling in Engineering & Sciences 2024年第5期139卷 1961-1980页

作者： Yanhui Zhang Lianhua Ma Hailiang Su Jirong Qin Zhining Chen Kaibiao Deng School of Mechanical and Automotive Engineering Guangxi University of Science and TechnologyLiuzhou545006China Commercial Vehicle technology center Dongfeng Liuzhou Automobile Co.Ltd.Liuzhou545005China School of Mechanical and Automotive Engineering South China University of TechnologyGuangzhou510641China

In this paper,to present a lightweight-developed front underrun protection device(FUPD)for heavy-duty trucks,plain weave carbon fiber reinforced plastic(CFRP)is used instead of the original high-strength ***,the mechanical and structural properties of plain carbon fiber composite anti-collision beams are comparatively analyzed from a multi-scale *** studying the design capability of carbon fiber composite materials,we investigate the effects of TC-33 carbon fiber diameter(D),fiber yarn width(W)and height(H),and fiber yarn density(N)on the front underrun protective beam of carbon fiber *** on the investigation,a material-structure matching strategy suitable for the front underrun protective beam of heavy-duty trucks is ***,the composite material structure is optimized by applying size optimization and stack sequence optimization methods to obtain the higher performance carbon fiber composite front underrun protection beam of commercial *** results show that the fiber yarn height(H)has the greatest influence on the protective beam,and theH1matching scheme for the front underrun protective beamwith a carbon fiber composite structure exhibits superior *** proposed method achieves a weight reduction of 55.21% while still meeting regulatory requirements,which demonstrates its remarkable weight reduction effect.

关键词： Structural optimization front underrun protection device carbon fiber reinforced plastic multi-scale model lightweight design

Single-atomic activation on ZnIn_(2)S_(4)basal planes boosts photocatalytic hydrogen evolution

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Nano research 2024年第7期17卷 5949-5955页

作者： Jianpeng Cui Ying Wang Luxue Lin Xiaotian Yang Xuyu Luo Shiying Guo Xiaoyong Xu College of Physics Science and technology and Center for Interdisciplinary ResearchYangzhou UniversityYangzhou 225002China

The use of single-atom cocatalysts plays a crucial role in enhancing artificial photocatalysis,where the precise construction of stable and efficient single-atom configuration is essential but remains ***,we report a simple one-step hydrothermal method for preparing single-atomic Mo modified ZnIn_(2)S_(4)(Mo-ZIS)nanosheets as a highly active photocatalytic hydrogen evolution(PHE)*** Mo substituting for portion of In atoms in ZIS nanosheets induces the spatial charge redistribution,which not only promotes the separation of photogenerated charge carriers but also optimizes the Gibbs free energy of adsorbing H*on S atoms at basal *** a result,Mo-ZIS exhibits an impressive PHE rate as high as 6.71 mmol·g^(−1)·h^(−1),over 10 times that of the pristine ZIS,with an apparent quantum efficiency(AQE)up to 38.8%at 420 *** study gains insights into the coordination configuration and electronic modulation resulting from single-atomic decoration,providing mechanistic cognitions for the development of advanced photocatalysts via non-precious metal atomic modification.

关键词： photocatalytic hydrogen evolution ZnIn_(2)S_(4) single-atom activation Gibbs free energy

Active disturbance rejection distributed secondary control for DC microgrids

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High Voltage 2024年第1期9卷 241-251页

作者： Jianlin Li Honghao You Shuo Liu Xingchen Li Ziyang Ding Fei Zou National User-Side Energy Storage Innovation research and Development center North China University of TechnologyBeijingChina

A novel control scheme is presented to eliminate the negative effects of communication disturbances,which introduces active disturbance rejection control(ADRC)in the control strategy design to achieve the objectives of the restoration of the bus voltage and the sharing of the power even in the presence of disturbances and delays in ***,its dynamic disturbance decoupling feature is used to realise the decoupling between power and voltage,so that the proposed controller only exchanges power information with its neighbours,reducing the communication burden and simplifying control *** control performance of the strategy is verified by employing steady-state *** impact of controller parameters is studied by establishing a small signal ***,both simulation cases and experimental tests prove the feasibility of this scheme.

关键词： Active disturbance establishing

Experimental and numerical study of hypervelocity impact damage on composite overwrapped pressure vessels

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Defence technology（防务技术） 2024年第1期31卷 58-72页

作者： Yong-Pan Duan Run-Qiang Chi Bao-Jun Pang Yuan Cai Hypervelocity Impact research center Harbin Institute of TechnologyHarbin150080China College of Science Heilongjiang University of Science and TechnologyHarbin 150022China

Ground-based tests are important for studying hypervelocity impact(HVI)damage to spacecraft pressure vessels in the orbital debris *** analyzed the damage to composite overwrapped pressure vessels(COPVs)in the HVI tests and classified the damage into non-catastrophic damage and catastrophic *** proposed a numerical simulation method to further study non-catastrophic damage and revealed the characteristics and mechanisms of non-catastrophic damage affected by impact conditions and internal *** fragments of the catastrophically damaged COPVs were collected after the *** crack distribution and propagation process of the catastrophic ruptures of the COPVs were *** findings contribute to understanding the damage characteristics and mechanisms of COPVs by HVIs.

关键词： Orbital debris Hypervelocity impact Composite overwrapped pressure vessels Damage mechanisms