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Depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 335-345页

作者： Feng Zhang Chenyang Zhang Linlin Wu Wei Sun Hongliang Zhang Jianhua Chen Yong Pei Songjiang Li Engineering research Center of Ministry of Education for Carbon Emission Reduction in Metal Resource Exploitation and Utilization Hunan International Joint Research Center for Efficient and Clean Utilization of Critical Metal Mineral ResourcesSchool of Minerals Processing and BioengineeringCentral South UniversityChangsha 410083China State Key Laboratory of Mineral Processing Beijing General Research Institute of Mining&MetallurgyBeijing 100160China Hunan Provincial Key Laboratory of Micro&Nano Materials Interfaces Science College of Chemistry and Chemical EngineeringCentral South UniversityChangsha 410083China School of Resources Environment and MaterialsGuangxi UniversityNanning 530004China Department of Chemistry Xiangtan UniversityXiangtan 411105China China Railway Resource Group Co.Ltd Beijing 102300China

The depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite still lacked in-depth ***,the depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite was further systematically investigated with experiments and density functional theory(DFT)*** X-ray photoelectric spectroscopy(XPS)results,DFT calculation results,and frontier molecular orbital analysis indicated that sulfite ions were difficult to be adsorbed on sphalerite surface,suggesting that sulfite ions achieved depression effects on sphalerite through other non-adsorption ***,the oxygen content in the surface of sphalerite treated with sulfite ions in creased,which enhanced the hydrophilicity of the sphalerite and further increased the difference in hydrophilicity between sphalerite and ***,sulfite ions were chelated with lead ions to form PbSO_(3)in *** hydrophilic PbSO_(3)was more easily adsorbed on sphalerite than *** interaction between sulfite ions and lead ions could effectively inhibit the activation of *** addition the UV spectrum showed that after adding sulfite ions,the peak of perxanthate in the sphalerite treated xanthate solution was significantly stronger than that in the galena with xanthate solution,indicating that xanthate interacted more readily with sulfite ions and oxygen mo lecules within the sphalerite system,leading to the formation of ***,sulfite ions hardly depressed the flotation of ga lena and could promote the flotation of galena to some *** study deepened the understanding of the depression mechanism o sulfite ions on sphalerite and Pb^(2+)activated sphalerite.

关键词： sphalerite galena sulfite ion density functional theory depression mechanism

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Extraction of locked-up coal by strengthening of rib pillars with FRP--A comparative study through numerical modelling

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International Journal of mining Science and Technology 2017年第2期27卷 261-267页

作者： Das Arka Jyoti Mandal Prabhat Kumar Ghosh Chandra Nath Sinha Amalendu CSIR-central institute of mining and fuel research Dhanbad 826001India

In some of the coalfields in India, coal seams are only developed but no extraction of pillars is possible due to the presence of surface or sub-surface structures and also non-availability of stowing materials which leads to huge amounts of coal being locked-up underground. Spontaneous heating and fire, accumulation of poisonous gases, severe stability issues leading to unsafe workings and environmental hazards are the major problems associated with the developed coal pillars. So, there is a pressing need for a technology for the mining industry to extract the huge amount of coal locked-up under different constraints. In this study, the locked-up coal is proposed to be extracted by artificially strengthening the rib pillars. The detailed comparative study is carried out to know the increase of extraction percentage of locked-up coal by strengthening the rib pillars with FRP. Extraction methodology is designed and studied through numerical modelling for its stability analysis to evaluate its suitability of application in underground.

关键词： Locked-up coal Confined core Yield criterion Strengthened rib pillar Strain softening

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CFD modeling to study the effect of particle size on dispersion in 20l explosion chamber: An overview

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International Journal of mining Science and Technology 2020年第3期30卷 321-327页

作者： Santosh Kumar Ray Niroj Kumar Mohalik Asfar Mobin Khan Debashish Mishra Nikhil Kumar Varma Jai Krishna Pandey Pradeep Kumar Singh CSIR-central institute of mining and fuel research Dhanbad 826001India

Mine disasters occur predominantly due to methane or coal dust explosion or a combination of *** the top ten worst coal mine disasters in India, nine are due to coal dust explosion. The current paper describes a general overview of the parameters causing dispersion leading to coal dust explosion,and computational fluid dynamics(CFD) simulation study to observe the effects of particle size on dispersion in Indian coal mines. Turbulent kinetic energy(TKE) and velocity vector path of dust-air mixture and dust-free air were simulated to understand their effects on coal dust dispersion. The TKE contours and velocity vector paths for dust-free air were uniform and symmetrical due to resistance-free path available. The TKE contours and velocity vector paths for dust-air mixture shows the asymmetrical distribution of contours, due to entrainment of air with dust particles. Vortices were observed in velocity vector paths which gradually diminish on increment of time sequence. These vortices are dead centres where velocity and coal dust particles concentration are both zero.

关键词： Coal dust explosibility CFD 20l explosion chamber Dispersion Turbulent kinetic energy

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Effects of aggregate size distribution and carbon nanotubes on the mechanical properties of cemented gangue backfill samples under true triaxial compression

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 311-324页

作者： Qian Yin Fan Wen Zhigang Tao Hai Pu Tianci Deng Yaoyao Meng Qingbin Meng Hongwen Jing Bo Meng Jiangyu Wu State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering China University of Mining and TechnologyXuzhou 221116China State Key Laboratory of mining Response and Disaster Prevention and Control in Deep Coal Mines Anhui University of Science and TechnologyHuainan 232001China State Key Laboratory for Geomechanics&Deep Underground Engineering China University of Mining and Technology(Beijing)Beijing 100083China Key Laboratory of Xinjiang Coal Resources Green mining Ministry of EducationXinjiang Institute of EngineeringUrumqi 830023China

The mechanical behavior of cemented gangue backfill materials(CGBMs)is closely related to particle size distribution(PSD)of aggregates and properties of cementitious ***,the true triaxial compression tests,CT scanning,SEM,and EDS tests were conducted on cemented gangue backfill samples(CGBSs)with various carbon nanotube concentrations(P_(CNT))that satisfied fractal theory for the PSD of *** mechanical properties,energy dissipations,and failure mechanisms of the CGBSs under true triaxial compression were systematically *** results indicate that appropriate carbon nanotubes(CNTs)effectively enhance the mechanical properties and energy dissipations of CGBSs through micropore filling and microcrack bridging,and the optimal effect appears at P_(CNT)of 0.08wt%.Taking PSD fractal dimension(D)of 2.500 as an example,compared to that of CGBS without CNT,the peak strength(σ_(p)),axial peak strain(ε_(1,p)),elastic strain energy(Ue),and dissipated energy(U_(d))increased by 12.76%,29.60%,19.05%,and90.39%,***,excessive CNTs can reduce the mechanical properties of CGBSs due to CNT agglomeration,manifesting a decrease inρ_(p),ε_(1,p),and the volumetric strain increment(Δε_(v))when P_(CNT)increases from 0.08wt%to 0.12wt%.Moreover,the addition of CNTs improved the integrity of CGBS after macroscopic failure,and crack extension in CGBSs appeared in two modes:detour and pass through the ***σ_(p)and U_(d)firstly increase and then decrease with increasing D,and porosity shows the opposite ***ε_(1,p)andΔε_(v)are negatively correlated with D,and CGBS with D=2.150 has the maximum deformation parameters(ε_(1,p)=0.05079,Δε_(v)=0.01990)due to the frictional slip effect caused by coarse *** increasing D,the failure modes of CGBSs are sequentially manifested as oblique shear failure,"Y-shaped"shear failure,and conjugate shear failure.

关键词： cemented gangue backfill materials particle size distribution true triaxial compression test carbon nanotubes mechanical properties failure modes

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Record-breaking bifunctional oxygen electrocatalyst accomplished by a data-driven approach for zinc-air batteries

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Journal of Energy Chemistry 2025年第1期100卷 144-145页

作者： Deviprasath Chinnadurai Zhi Wei Seh institute of Materials research and Engineering (IMRE) Agency for Science Technology and Research (A*STAR)

Rechargeable zinc-air batteries(ZABs) have recently drawn great attention in energy research due to their high theoretical capacity,low costs, and inherently safe nature [1–3]. However, the sluggish cathode reactions necessitate the development of bifunctional oxygen electrocatalysts with lower ΔE indicator values. The ΔE indicator is commonly employed to quantitatively evaluate the electrocatalytic activity of a bifunctional oxygen electrocatalyst,representing the overall overpotential from oxygen reduction reaction(ORR) to oxygen evolution reaction(OER).

关键词： Data-driven approach Bifunctional oxygen electrocatalyst Record breaking performance Zinc-air batteries

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Sorption of methane and CO_2 for enhanced coalbed methane recovery and carbon dioxide sequestration

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Journal of Natural Gas Chemistry 2008年第1期17卷 29-38页

作者： Basanta Kumar Prusty central institute of mining and fuel research Barwa RoadDhanbad-826 001India

Sequestration of CO2 in deep and unmineable coal seams is one of the attractive alternatives to reduce its atmospheric concentration. Injection of CO2 in coal seams may help in enhancing the recovery of coalbed methane. An experimental study has been carried out using coal samples from three different coal seams, to evaluate the enhanced gas recovery and sequestration potential of these coals. The coals were first saturated with methane and then by depressurization some of the adsorbed methane was desorbed. After partial desorption, CO2 was injected into the coals and subsequently they were depressurized again. Desorption of methane after the injections was studied, to investigate the ability of CO2 to displace and enhance the recovery of methane from the coals. The coals exhibited varying behavior of adsorption of CO2 and release of methane. For one coal, the release of methane was enhanced by injection of CO2, suggesting preferential adsorption of CO2 and desorption of methane. For the other two coals, CO2 injection did not produce incremental methane initially, as there was initial resistance to methane release. However with continued CO2 injection, most of the remaining methane was produced. The study suggested that preferential sorption behavior of coal and enhanced gas recovery pattern could not be generalized for all coals.

关键词： coal coalbed methane CO2 injection enhanced coalbed methane CO2 sequestration

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Multi boron-doping effects in hard carbon toward enhanced sodium ion storage

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Journal of Energy Chemistry 2025年第1期100卷 730-738页

作者： Peng Zheng Wang Zhou Ying Mo Biao Zheng Miaomiao Han Qin Zhong Wenwen Yang Peng Gao Lezhi Yang Jilei Liu College of Materials Science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology Hunan University Greater Bay Area institute for Innovation Hunan University Changsha research institute of mining & Metallurgy Co. LTD.

Hard carbon （HC） has been considered as promising anode material for sodium-ion batteries （SIBs）.The optimization of hard carbon’s microstructure and solid electrolyte interface （SEI） property are demonstrated effective in enhancing the Na+storage capability,however,a one-step regulation strategy to achieve simultaneous multi-scale structures optimization is highly ***,we have systematically investigated the effects of boron doping on hard carbon’s microstructure and interface chemistry.A variety of structure characterizations show that appropriate amount of boron doping can increase the size of closed pores via rearrangement of carbon layers with improved graphitization degree,which provides more Na+storage ***-situ Fourier transform infrared spectroscopy/electrochemical impedance spectroscopy （FTIR/EIS） and X-ray photoelectron spectroscopy （XPS） analysis demonstrate the presence of more BC3and less B–C–O structures that result in enhanced ion diffusion kinetics and the formation of inorganic rich and robust SEI,which leads to facilitated charge transfer and excellent rate *** a result,the hard carbon anode with optimized boron doping content exhibits enhanced rate and cycling *** general,this work unravels the critical role of boron doping in optimizing the pore structure,interface chemistry and diffusion kinetics of hard carbon,which enables rational design of sodium-ion battery anode with enhanced Na+storage performance.

关键词： X ray photoelectron spectroscopy

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Co-gasification of coal and biomass an emerging clean energy technology: Status and prospects of development in Indian context

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International Journal of mining Science and Technology 2019年第2期29卷 171-186页

作者： Alka D.Kamble Vinod Kumar Saxena Prakash Dhondiram Chavan Vinod Atmaram Mendhe Department of Chemical Engineering Indian Institute of Technology (ISM) CSIR-central institute of mining and fuel research

Co-gasification of coal and biomass is emerging as potential clean fuel technology to achieve high thermodynamic efficiency with relatively low CO2 emission. The coal and biomass have been exclusively gasified more than a century to obtain gas–liquid fuels and the production of chemicals. Co-gasification has higher efficiency than the solitary coal gasification because the cellulose, hemicellulose and lignin content of biomass help to ignite and enhance the rate of gasification. It is suggested that the extensive research on carbon reactivity pattern, heat release, reaction kinetics, etc. may support to reduce the uncertainties in the co-gasification performance of coal and biomass blends, particularly in India. The prospects of co-gasification technology in Indian context have been discussed considering the abundance of varieties of coal and biomass. The suitability of existing gasifier procedures and their limitations with operating parameters like temperature, residence time, density optimisation, feed rate, agglomeration intensity, the tar formation and techno-economics involved are described. Also, this paper reviews the research highlights of the history of co-gasification and the advancement in upcoming challenges like a design of gasifier, access and preparation of biomass, disposal of residue, environmental concerns and reassurance to the operators for execution of large and small-scale projects.

关键词： Co-gasification Coal Biomass Clean fuel Advancement Challenges

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Rock fragmentation control in opencast blasting

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Journal of Rock Mechanics and Geotechnical Engineering 2016年第2期8卷 225-237页

作者： P.K.Singh M.P.Roy R.K.Paswan Md.Sarim Suraj Kumar Rakesh Ranjan Jha CSIR-central institute of mining and fuel research

The blasting operation plays a pivotal role in the overall economics of opencast *** blasting subsystem affects all the other associated sub-systems,***,transport,crushing and milling *** control through effective blast design and its effect on productivity are the challenging tasks for practicing blasting engineer due to inadequate knowledge of actual explosive energy released in the borehole,varying initiation practice in blast design and its effect on explosive energy release *** paper describes the result of a systematic study on the impact of blast design parameters on rock fragmentation at three mines in *** mines use draglines and shoveledumper combination for removal of *** its pivotal role in controlling the overall economics of a mining operation,the expected blasting performance is often judged almost exclusively on the basis of poorly defined parameters such as powder factor and is often qualitative which results in very subjective assessment of blasting *** an approach is very poor substitutes for accurate assessment of explosive and blasting *** one blasts were conducted with varying blast designs and charging patterns,and their impacts on the rock fragmentation were documented.A high-speed camera was deployed to record the detonation sequences of the *** efficiency of the loading machines was also correlated with the mean fragment size obtained from the fragmentation analyses.

关键词： Opencast blast Rock fragmentation Explosives performance Dragline efficiency Fragment size

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Rib stability: A way forward for safe coal extraction in India

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International Journal of mining Science and Technology 2017年第6期27卷 1087-1091页

作者： Singh Satyendra K. Agrawal Harshit Singh Awanindra P. mining Methods and Design Simulation research Group CSIR-Central Institute of Mining and Fuel Research (CSIR-CIMFR) Dhanbad 826015 India

Ensuring rib stability during pillar extraction is of prime importance in bord and pillar(B&P) method of underground coal mining with caving. Rib stability has been assessed here by way of assessing factor of safety(FOS), a ratio of the strength of rib to stress on it. Earlier formulations for rib stability when applied to case studies gave very low FOS value suggesting significant ground control problems, which were contrary to the field observations. This has necessitated the need to revisit the concept of rib stability. The stress coming on the rib is estimated with the use of numerical modeling technique using the FLAC^(3D) software. The methodology of assessing rib-stability with the help of suggested rib-strength formulation has been validated at eight Indian coal mines. The outcome of this study finds relevance and importance in ensuring underground coal liquidation with improved safety and conservation.

关键词： Rib stress estimation Rib-strength Rib-stability Numerical modeling Bord & pillar method Underground coal extraction

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