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Electrocatalytic cleavage of a lignin β-O-4 model compound and coupling with nitrogen-containing aromatics using Prussian blue analogue-derived nickel–cobalt spinel

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Journal of Energy Chemistry 2025年第1期100卷 628-636页

作者： Yi Qi Xueying Chen Bowen Liu Xuliang Lin Xueqing Qiu Yanlin Qin Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology Guangdong Provincial Laboratory of Chemistry and Fine Chemical engineering Jieyang center Guangdong Basic Research center of excellence for Ecological Security and Green Development Guangdong University of Technology

Electrochemical conversion of lignin for the production of high-value heterocyclic aromatic compounds has great *** demonstrate the targeted synthesis and cation modulation of NiCo2O4spinel nanoboxes,synthesized via cation exchange and calcination *** catalysts exhibit excellent efficacy in the electrocatalytic conversion of lignin model compounds,specifically 2-phenoxy-1-phenylethanol,into nitrogen-containing aromatics,achieving high conversion rates and *** catalysts were synthesized via a cation exchange and calcination oxidation process,using Prussian blue nanocubes as *** porous architecture and polymetallic composition of the NiCo2O4spinel demonstrated superior performance in electrocatalytic oxidative coupling,achieving a 99.2 wt%conversion rate of the 2-phenoxy-1-phenylethanol with selectivities of 37.5 wt%for quinoline derivatives and 31.5 wt%for *** innovations include the development of a sustainable one-pot synthesis method for quinoline derivatives,the elucidation of a multistage reaction pathway involving CAO bond cleavage,hydroxyaldol condensation,and CAN bond formation,and a deeper mechanistic understanding derived from DFT *** work establishes a new strategy for lignin valorization,offering a sustainable route to produce high-value nitrogen-containing aromatics from renewable biomass under mild conditions,without the need for additional reagents.

关键词： Spinel Biomass valorization Electrocatalysis Lignin oxidation Coupling

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All-optical neuromorphic devices: materials, working mechanism,and applications

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Science China Chemistry 2025年

作者： Song Wang Hao Chen Hui Huang College of Materials Science and Opto-Electronic Technology Center of Materials Science and Optoelectronics Engineering CAS Center for Excellence in Topological Quantum Computation CAS Key Laboratory of Vacuum Physics University of Chinese Academy of Sciences College of Chemistry and Molecular engineering Peking University

Traditional von Neumann computing, with physical separation of memory and processing units, cannot satisfy the development of artificial intelligence and cloud computing. Neuromorphic computing, inspired by the human brain, has drawn much ***-optical neuromorphic (AON) devices employ optical signals as information carriers and leverage the neuromorphic functions to implement fast operation speed, low energy consumption, and high bandwidth of neuromorphic computing. Here, we discuss the recent progress in AON devices, including materials, device performance, working mechanisms, and applications. Moreover,the advantages and limitations of AON are presented and discussed. Finally, the perspective of AON devices points out the future research direction of neuromorphic computing.

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Estimation of the axial capacity of high-strength concrete-filled steel tube columns using artificial neural network,random forest,and extreme gradient boosting approaches

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Frontiers of Structural and Civil engineering 2024年第11期18卷 1794-1814页

作者： Payam SARIR Anat RUANGRASSAMEE Mitsuyasu IWANAMI center of excellence in earthquake engineering and vibration Department of Civil EngineeringFaculty of EngineeringChulalongkorn UniversityBangkok 10330Thailand Infrastructure Management Laboratory Department of Civil EngineeringTokyo Institute of TechnologyTokyo 152-8550Japan

The study aims to develop machine learning-based mechanisms that can accurately predict the axial capacity of high-strength concrete-filled steel tube(CFST)*** predicting the axial capacity of a CFST column is always challenging for *** artificial neural networks(ANNs),random forest(RF),and extreme gradient boosting(XG-Boost),a total of 165 experimental data sets were *** selected input parameters included the steel tensile strength,concrete compressive strength,tube diameter,tube thickness,and column *** results indicated that the ANN and RF demonstrated a coefficient of determination(R2)value of 0.965 and 0.952 during the training and 0.923 and 0.793 during the testing *** most effective technique was the XG-Boost due to its high efficiency,optimizing the gradient boosting,capturing complex patterns,and incorporating regularization to prevent *** outstanding R2 values of 0.991 and 0.946 during the training and testing were *** to flexibility in model hyperparameter tuning and customization options,the XG-Boost model demonstrated the lowest values of root mean square error and mean absolute error compared to the other *** to the findings,the diameter of CFST columns has the greatest impact on the output,while the column length has the least influence on the ultimate bearing capacity.

关键词： artificial neural network extreme gradient boosting random forest concrete-filled steel tube machine learning

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Development of seismic force requirements for buildings in Taiwan

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earthquake engineering and engineering vibration 2009年第3期8卷 349-358页

作者： Juin-Fu Chai Tsung-Jen Teng Keh-Chyuan Tsai center for Research on earthquake engineering

This paper describes static and dynamic procedures to calculate seismic demand specified by the current seismic design code for buildings in Taiwan, which was issued in 2005. For design levels with a return period of 475 years, the design spectral response acceleration can be developed for general sites, near-fault sites and Taipei Basin. In addition, in order to prevent building collapse during extremely large earthquakes and yielding of structural components and elements during frequent small earthquakes, the required seismic demands at the maximum considered earthquake level （MCE, 2%/50 years） and operational level are also included in the new seismic design *** dynamic analysis procedures, both the response spectrum method and time history method are specified in the new seismic design code. Finally, procedures to generate spectrum compatible ground motions for time history analysis are illustrated in this paper.

关键词： building code seismic force requirement design spectrum spectrum compatible design ground motion site effect near-fault basin effect

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Development of dynamic slip model for a shear crack

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earthquake engineering and engineering vibration 2010年第1期9卷 1-7页

作者： Juin-Fu Chai Tsung-Jen Teng center for Research on earthquake engineering

The objective of this paper is to develop a dynamic slip model for a shear crack under constant stress drop. This crack problem is formulated by a traction boundary integral equation （BIE） in the frequency domain and then solved by the hyper-singular boundary element method as well as the regularization technique proposed in this paper. Based on the spectral integral form of the kernel function, the unbounded term can be isolated and extracted from the hyper-singular kernel function by using the method of subtracted and added back in wave number domain. Finally, based on the inverse transformation from the frequency domain to the time domain, the time histories of crack opening displacement under constant stress drop can be determined. Three rupture models （simultaneous rupture model, symmetric bilaterally-propagating model and unilaterally propagating model） with specified time histories of stress drop are considered in this paper. Even though these three models will cause the same final slip shapes because of the same constant stress drop, the associated slip time functions differ significantly from each other during the rupture process.

关键词： dynamic rupture model traction boundary element method (BIE) hyper-singular boundary element method (HBEM) regularization technique

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Lipid droplets in the nervous system:involvement in cell metabolic homeostasis

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Neural Regeneration Research 2025年第3期20卷 740-750页

作者： Yuchen Zhang Yiqing Chen Cheng Zhuang Jingxuan Qi Robert Chunhua Zhao Jiao Wang School of Life Sciences Shanghai UniversityShanghaiChina School of Medicine Shanghai UniversityShanghaiChina Institute of Basic Medical Sciences Chinese Academy of Medical Sciences School of Basic MedicinePeking Union Medical CollegeBeijingChina center of excellence in Tissue engineering Chinese Academy of Medical SciencesBeijingChina Beijing Key Laboratory of New Drug Development and Clinical Trial of Stem Cell Therapy BeijingChina

Lipid droplets serve as primary storage organelles for neutral lipids in neurons,glial cells,and other cells in the nervous *** droplet formation begins with the synthesis of neutral lipids in the endoplasmic ***,lipid droplets were recognized for their role in maintaining lipid metabolism and energy homeostasis;however,recent research has shown that lipid droplets are highly adaptive organelles with diverse functions in the nervous *** addition to their role in regulating cell metabolism,lipid droplets play a protective role in various cellular stress ***,lipid droplets exhibit specific functions in neurons and glial *** of lipid droplet formation leads to cellular dysfunction,metabolic abnormalities,and nervous system *** review aims to provide an overview of the role of lipid droplets in the nervous system,covering topics such as biogenesis,cellular specificity,and ***,it will explore the association between lipid droplets and neurodegenerative *** the involvement of lipid droplets in cell metabolic homeostasis related to the nervous system is crucial to determine the underlying causes and in exploring potential therapeutic approaches for these diseases.

关键词： Alzheimer's disease lipid droplet biogenesis lipid droplets lipid metabolism nervous system neurodegenerative disorders oxidative stress Parkinson's disease

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Design equation for stability of a circular tunnel in anisotropic and heterogeneous clay

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Underground Space 2022年第1期7卷 76-93页

作者： Suraparb Keawsawasvong Boonchai Ukritchon Department of Civil engineering Thammasat Engineering SchoolThammasat UniversityPathumthani 12120Thailand Centre of excellence in Geotechnical and Geoenvironmental engineering Department of Civil EngineeringFaculty of EngineeringChulalongkorn UniversityBangkok 10330Thailand center of excellence on earthquake engineering and vibration Department of Civil EngineeringFaculty of EngineeringChulalongkorn UniversityBangkok 10330Thailand

The safety assessment of tunnel stability is critical to tunnel construction and requires accurate analysis to obtain a reliable *** anisotropy is an important aspect of clay behavior,but it is mostly neglected in practical stability *** this study,the effects of undrained strength anisotropy and strength nonhomogeneity on the stability of unlined circular tunnels in clays are *** static approach of lower-bound(LB)analysis using finite-element and second-order cone programming is employed to exam-ine the aforementioned *** anisotropic shear strength of clay is modeled by employing an elliptical yield function under plane strain conditions.A complete set of dimensionless parameters covering the cover depth ratios of tunnels,normalized overburden pressure ratios,normalized strength gradient ratios of clays,and anisotropic strength ratios,are systematically *** new LB solutions indicate that the stability load factor of the problem has a nonlinear relationship with the cover depth ratio and the anisotropic strength ratio,and there exists a linear relationship with the normalized overburden pressure and the normalized strength *** influ-ence on the predicted failure mechanism is parametrically evaluated.A statistically approximate stability equation of unlined circular tunnels in anisotropic and non-homogeneous clay is proposed for the first time,which contains four new stability factors,namely,con-stant undrained strength,linearly increasing strength gradient,undrained strength anisotropy,and soil unit weight,and it can serve as a fast and accurate tool for predicting the undrained stability of this problem in practice.

关键词： Circular tunnel Anisotropy Nonhomogeneity Lower bound Second-order cone programming

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Numerical Simulation of the Seismic Response of a Horizontal Storage Tank Based on a SPH-FEM Coupling Method

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Computer Modeling in engineering & Sciences 2024年第5期139卷 1655-1678页

作者： Peilei Yan Endong Guo HouliWu Liangchao Zhang Key Laboratory of earthquake engineering and engineering vibration Institute of Engineering MechanicsChina Earthquake AdministrationHarbin150080China Key Laboratory of earthquake Disaster Mitigation Ministry of Emergency ManagementHarbin150080China

A coupled numerical calculation method combining smooth particle hydrodynamics(SPH)and the finite element method(FEM)was implemented to investigate the seismic response of horizontal storage *** of a horizontal storage tank featuring a free liquid surface under seismic action was constructed using the SPH–FEM coupling *** stored liquid was discretized using SPH particles,while the tank and supports were discretized using the *** interaction between the stored liquid and the tank was simulated by using the meshless particle contact ***,the numerical simulation results were compared and analyzed against seismic simulation shaking table test data to validate the ***,a series of numerical models,considering different liquid storage volumes and seismic effects,were constructed to obtain time history data of base shear and top center displacement,which revealed the seismic performance of horizontal storage *** simulation results and experimental data showed good agreement,with an error rate of less than 18.85%.And this conformity signifies the rationality of the SPH-FEM coupling *** base shear and top center displacement values obtained by the coupled SPH-FEM method were only 53.3% to 69.1% of those calculated by the equivalent mass method employed in the current *** the stored liquid volume increased,the seismic response of the horizontal storage tank exhibited a gradual upward trend,with the seismic response increasing from 73% to 388% for every 35% increase in stored liquid *** maximum von Mises stress of the tank and the supports remained below the steel yield strength during the *** coupled SPH-FEM method holds certain advantages in studying the seismic problems of tanks with complex structural forms,particularly due to the representation of the flow field distribution during earthquakes by involving reservoir fluid participation.

关键词： SPH-FEM coupling method horizontal storage tank seismic response sloshing

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Free vibration and transient response of double curved beams connected by intermediate straight beams

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Applied Mathematics and Mechanics(English Edition) 2025年第1期46卷 37-62页

作者： R.A.JAFARI-TALOOKOLAEI H.GHANDVAR E.JUMAEV S.KHATIR T.CUONG-LE School of Mechanical engineering Babol Noshirvani University of Technology Department of Mechanical engineering Faculty of Engineering New Uzbekistan University University of Business and Science center for engineering Application and Technology Solutions Ho Chi Minh City Open University

This paper investigates the free vibration and transient response of interconnected structures including double curved beams and intermediate straight beams,which are all constructed from functionally graded porous(FGP) materials. The strain potential and kinetic energies of each beam along with the work done by the external force are calculated. Additionally, a higher-order beam element is introduced to derive stiffness and mass matrices, along with the force vector. The curved and straight beams are discretized, and their assembled stiffness, mass matrices, and force vectors, are *** conditions at the joints are used to derive the total matrices of the entire structure. Subsequently, the natural frequencies and transient response of the system are determined. The accuracy of the mathematical model and the self-developed computer program is validated through the comparison of the obtained results with those of the existing literature and commercial software ANSYS, demonstrating excellent ***, a comprehensive study is conducted to investigate the effects of various parameters on the free vibration and transient response of the considered structure.

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Design high-performance narrowband emitters for blue light-emitting diodes through manipulating resonance structure of aromatic heterocycles

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Science China Chemistry 2025年

作者： Yue Yu Lei Xu Wenle Tan Yuyu Pan Jiyin Xiao Bohan Wang Guangjun Tian Yuguang Ma Lei Ying Institute of Polymer Optoelectronic Materials and Devices Guangdong Basic Research Center of Excellence for Energy and Information Polymer Materials State Key Laboratory of Luminescent Materials and Devices South China University of Technology School of Petrochemical engineering Shenyang University of Technology Key Laboratory for Microstructural Material Physics of Hebei Province School of Science Yanshan University

Narrowband light-emitting materials play critical roles in improving the color gamut and energy consumption of electroluminescence. Herein we demonstrated that by regulating the ground state resonance structure form of emitters with polycyclic aromatic heterocycles, the high-energy vibration of the C–C bond can be effectively suppressed, resulting in narrow emission like classical cyanine dyes. The designed compounds consist of twist and planar conformation, while having differences in the orientation of the positioning electron-donating(nitrogen) and electron-accepting(carbonyl) groups in the polycyclic aromatic hydrocarbon skeleton. The resulting compound Ac-Ph-Ac with a dominated zwitterionic resonance structure exhibits a relatively wide electroluminescent profile with the full width at half maximum(FWHM) of 42 nm and moderate device performance. In contrast, the “soliton transition” of 2AcPh based on the cyanine limit character effectively suppresses C–C stretching vibration in the polycyclic aromatic heterocycle skeleton, leading to a narrow electroluminescent profile with FWHM of 30 nm(0.16 eV)associated with an impressively high external quantum efficiency of 28.52%, which is among the highest efficiencies of so far reported non-sensitized organic light-emitting diodes.

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