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Polydopamine-modified metal-organic frameworks nanoparticles enhance the corrosion resistance and bioactivity of polycaprolactone coating on high-purity magnesium

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Journal of Magnesium and Alloys 2024年第5期12卷 2070-2089页

作者： Qingyun Fu Shaojie He Junjie Yang Ziyu Su Ping Li Xincheng Yu Weihong Jin Shulan Xu Zhentao Yu Dingsheng Zha center of Oral Implantology Stomatological HospitalSouthern Medical UniversityGuangzhouChina Panyu Hospital of Chinese Medicine Guangzhou 511400China Institute of Advanced wear&corrosion resistant and Functional materials Jinan UniversityGuangzhou 510632China First Affiliated Hospital of Jinan University Guangzhou 510630China

Biodegradable magnesium(Mg)and its alloys exhibit excellent biocompatibility and mechanical compatibility,demonstrating tremendous potential for applications in ***,the rapid degradation rate has limited their clinical ***(PCL)is commonly employed as a polymer coating to impede the rapid degradation of ***,its long-term anti-corrosion capability and bioactivity are *** address these issues,polydopamine(PDA)-modified zeolitic imidazolate framework-8(PZIF-8)bioactive nanoparticles are fabricated and incorporated into the PCL *** PZIF-8 particles,featuring catechol motifs,can enhance the compactness of the PCL coating,reduce its defects,and possess biomineralization ability,thereby effectively improving its anti-corrosive and bioactive ***,the active substances released from the degradation of the PZIF-8 particles such as Zn^(2+)and PDA are beneficial for *** corrosion tests indicate that the corrosion current density of PCL-treated sample decreases by more than one order of magnitude and the amount of H_(2)released decreases from 0.23±0.12 to 0.08±0.08 ml cm^(-2)after doping with the ***,the improved corrosion resistance and released PDA and Zn^(2+)from the coating can promote osteogenic differentiation by up-regulating the expression of alkaline phosphatase activity,related osteogenic genes,and *** addition,in vivo implantation experiments in rabbit femur defects further offer strong evidence that the doping of PZIF-8 nanoparticles accelerates bone reconstruction of the PCL *** summary,this work implies a new strategy to fabricate a PCL-based coating on Mg-based implants by introducing the PZIF-8 particles for orthopedic applications.

关键词： Polydopamine ZIF-8 High-purity magnesium Polycaprolactone coating Anticorrosion Bone regeneration

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Catalytic transformation of 4-nitrophenol into 4-aminophenol over ZnO nanowire array-decorated Cu nanoparticles

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Green Chemical Engineering 2024年第2期5卷 205-212页

作者： Anlin Feng Chaoyu Lin Huiqin Zhou Weihong Jin Yidong Hu Dongyang Li Qingyang Li Institute of Advanced wear&corrosion resistant and Functional materials Jinan UniversityGuangzhou510632China School of Chemical Engineering and Technology Hebei University of TechnologyTianjin300401China Department of Chemical and materials Engineering University of AlbertaEdmontonT6G 2H5Canada

To realize economical and effective removal of hazardous 4-nitrophenol from the environment,we developed an easily recyclable ZnO nanowire array decorated with Cu *** salix argyracea-shaped structure not only provides a platform to achieve stable and good dispersion of Cu nanoparticles,but also offers a great deal of catalytically active *** density functional theory calculations reveal that ZnO and Cu have a very beneficial synergistic effect on their catalytic *** synergy is ascribed to the electronic localization occurring at ZnO/Cu interface,which helps improve Cu nanoparticle’s ability to adsorb electro-negatively 4-nitrophenolate ions and to capture hydrogen radicals,thereby accelerating the hydrogen transfer from metal hydride complex to *** from these characteristics,it exhibits high efficiency and reusability towards the catalytic reduction of waste 4-nitrophenol to valuable 4-aminophenol with a rate constant of 43.02×10^(-3)s^(-1)and an average conversion of 96.5%in 90 s during 10 *** activity is superior to that of most reported noble-or non-noble-metal powder,bulk,coating,and array catalysts,indicating its competitive advantages in cost and efficiency,as well as enticing application prospects.

关键词： ZnO nanowire Cu nanoparticle Nano-heterojunction 4-Nitrophenol catalytic reduction Density functional theory

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Selective leaching of lithium from spent lithium-ion batteries using sulfuric acid and oxalic acid

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International Journal of Minerals,Metallurgy and materials 2024年第4期31卷 688-696页

作者： Haijun Yu Dongxing Wang Shuai Rao Lijuan Duan Cairu Shao Xiaohui Tu Zhiyuan Ma Hongyang Cao Zhiqiang Liu Institute of Advanced wear&corrosion resistant and Functional materials Jinan UniversityGuangzhou 510632China Institute of Resources Utilization and Rare Earth Development Guangdong Academy of SciencesGuangzhou 510650China State Key Laboratory of Separation and Comprehensive Utilization of Rare Metals Guangzhou 510650China Guangdong Province Key Laboratory of Rare Earth Development and Application Guangzhou 510650China

Traditional hydrometallurgical methods for recovering spent lithium-ion batteries(LIBs)involve acid leaching to simultaneously extract all valuable metals into the *** methods usually are followed by a series of separation steps such as precipitation,extraction,and stripping to separate the individual valuable *** this study,we present a process for selectively leaching lithium through the synergistic effect of sulfuric and oxalic *** optimal leaching conditions(leaching time of 1.5 h,leaching temperature of 70°C,liquid-solid ratio of 4 mL/g,oxalic acid ratio of 1.3,and sulfuric acid ratio of 1.3),the lithium leaching efficiency reached89.6%,and the leaching efficiencies of Ni,Co,and Mn were 12.8%,6.5%,and 21.7%.X-ray diffraction(XRD)and inductively coupled plasma optical emission spectrometer(ICP-OES)analyses showed that most of the Ni,Co,and Mn in the raw material remained as solid residue oxides and *** study offers a new approach to enriching the relevant theory for selectively recovering lithium from spent LIBs.

关键词： selective leaching oxalic acid sulfuric acid spent lithium-ion batteries

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Microstructure,wear and friction behavior of CoCrAITaY-xCNTs composite coatings deposited by laser-induction hybrid cladding

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Rare Metals 2024年第4期43卷 1815-1827页

作者： Sheng-Feng Zhou Yu Long Yan-Liang Yi Cheng Deng Lian-Xi Hu Institute of Advanced wear&corrosion resistant and Functional materials Jinan UniversityGuangzhou510632China Wuhan National Laboratory for Optoelectronics(WNLO) Huazhong University of Science and TechnologyWuhan430074China MOE Key Laboratory of New Processing Technology for Non-Ferrous Metals and materials Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured MaterialsGuangxi UniversityNanning530004China School of Mechatronics Engineering Guangdong Polytechnic Normal UniversityGuangzhou510635China School of materials Science and Engineering Harbin Institute of TechnologyHarbin150001China

To improve the wear performance of CoCrAlYTa coating,part of the carbon nanotubes(CNTs)chemically reacted with Ta to form reinforcement phase(TaC),while the other CNTs were retained as lubrication ***,the CoCrAlYTa-xCNTs(x=0,1,2,and 4;wt%)composite coatings were prepared by laserinduction hybrid cladding(LIHC),and the microstructure and wear resistance of coatings were systematically *** show that the coatings are mainly composed of TaC,y-(Co,Cr)andβ-(Co,Cr)*** the CNTs content increases from 0 wt%to 4 wt%,the volume fraction of TaC increases from 13.11 vol%to 16.12 vol%.Meanwhile,the nano-hardness ofγ-(Co,Cr)andβ-(Co,Cr)Al are improved from 7.49 and 9.72 to 9.36 and 11.19 GPa,*** a result,the microhardness of coating increases from HV536.25 to HV 738.16,the wear rate decreases from32.4×10^(-3)to 6.1×10^(-3)mg·m^(-1),and the average friction coefficient decreases from 0.55 to *** good wear performance of the coating is attributed to the formation of TaC and the existence of remained CNTs lubricant film.

关键词： Carbon nanotube MCrAlY coating Friction and wear performance Laser-induction hybrid cladding

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Stress-corrosion coupled damage localization induced by secondary phases in bio-degradable Mg alloys:phase-field modeling

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Journal of Magnesium and Alloys 2024年第1期12卷 361-383页

作者： Chao Xie Shijie Bai Xiao Liu Minghua Zhang Jianke Du The Faculty of Mechanical Engineering and Mechanics Ningbo UniversityNingbo 315211P.R.China Key Laboratory of High Temperature wear resistant materials Preparation Technology of Hunan Province Hunan University of Science and TechnologyXiangtan 411201P.R.China

In this study,a phase-field scheme that rigorously obeys conservation laws and irreversible thermodynamics is developed for modeling stress-corrosion coupled damage(SCCD).The coupling constitutive relationships of the deformation,phase-field damage,mass transfer,and electrostatic field are derived from the entropy *** SCCD localization induced by secondary phases in Mg is numerically simulated using the implicit iterative algorithm of the self-defined finite *** quantitative evaluation of the SCCD of a C-ring is in good agreement with the experimental *** capture the damage localization,a micro-galvanic corrosion domain is defined,and the buffering effect on charge migration is *** cases are investigated to reveal the effect of localization on corrosion acceleration and provide guidance for the design for resistance to SCCD at the crystal scale.

关键词： Phase field Mg alloys Stress-corrosion coupled damage Damage localization Finite element method

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Investigation of Material Properties Based on 3D Graphite Morphology for Compacted Graphite Iron

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Acta Metallurgica Sinica(English Letters) 2024年第6期37卷 1077-1086页

作者： Chenglu Zou Yan Zhao Gang Zhu Jianchao Pang Shaogang Wang Yangzhen Liu Feng Liu Shouxin Li Zhefeng Zhang Institute of Metal Research Chinese Academy of SciencesShenyang110016China School of Mechanical Engineering Liaoning Petrochemical UniversityFushun113001China Institute of Advance wear and corrosion resistant and Functional materials Jinan UniversityGuangzhou510632China Jihua Laboratory Foshan528200China Key Laboratory of Pressure Systems and Safety Ministry of EducationSchool of Mechanical and Power EngineeringEast China University of Science and TechnologyShanghai200237China

The strength and thermal conductivity of compacted graphite iron(CGI)are crucial performance indicators in its engineering *** presence of graphite in CGI significantly influences the two *** the previous studies,graphite in CGI was often described using two-dimensional(2D)*** this study,the three-dimensional(3D)size,shape,and distribution of graphite in CGI were analyzed using X-ray *** on this,a new method is introduced to calculate the 3D vermicularity and compare it with the 2D vermicularity in terms of tensile properties and thermal *** results demonstrate that vermicular graphite exhibits greater connectivity in 3D observation compared to 2D ***,the calculation method of 3D vermicularity is determined by considering the surface area and volume of the connected *** a linear relationship between 3 and 2D vermicularity has been *** comparing the correlation coefficient,it has been found that the 3D vermicularity offers a more accurate method to establish the relationship among graphite morphology,thermal conductivity and tensile property of CGI.

关键词： Compacted graphite iron 3D graphite morphology X-ray tomography Thermal conductivity Tensile property

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Heterophase junction engineering-induced Co spin-state modulation of CoSe_(2) for large-current hydrogen evolution reaction

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Rare Metals 2024年第6期43卷 2660-2670页

作者： Bao-Chai Xu Ya-Ping Miao Min-Qin Mao Dong-Lian Li Song Xie Wei-Hong Jin Shu Xiao Jing Wen Zaenab Abd-Allah Zhi-Tian Liu Xiang Peng Paul K.Chu Hubei Key Laboratory of Plasma Chemistry and Advanced materials School of Materials Science and EngineeringWuhan Institute of TechnologyWuhan 430205China School of Textile Science and Engineering Xi'an Polytechnic UniversityXi'an 710048China Institute of Advanced wear and corrosion resistant and Functional materials Jinan UniversityGuangzhou 510632China Institute of Safety Science and Engineering South China University of TechnologyGuangzhou 510641China Department of Engineering Manchester Metropolitan UniversityManchester M156BHUK Department of Physics Department of Materials Science and Engineeringand Department of Biomedical EngineeringCity University of Hong KongHong Kong 999077China

Efficient electrocatalysts are vital to large-current hydrogen production in commercial water splitting for green energy ***,a novel heterophase engineering strategy is described to produce polymorphic CoSe_(2)*** composition of the electrocatalysts consisting of both cubic CoSe_(2)(c-CoSe_(2))and orthorhombic CoSe_(2)(o-CoSe_(2))phases can be controlled *** results demonstrate that junction-induced spin-state modulation of Co atoms enhances the adsorption of intermediates and accelerates charge transfer resulting in superior large-current hydrogen evolution reaction(HER)***,the CoSe_(2)based heterophase catalyst with the optimal c-CoSe_(2)content requires an overpotential of merely 240 mV to achieve 1,000 mA·cm^(-2)as well as a Tafel slope of 50.4 mV·dec^(-1).Furthermore,the electrocatalyst can maintain a large current density of 1,500 mA·cm^(-2)for over 320 h without *** results reveal the advantages and potential of heterophase junction engineering pertaining to design and fabrication of low-cost transition metal catalysts for large-current water splitting.

关键词： Heterophase junction Spin-state Hydrogen evolution reaction Large current electrochemical hydrogen production Water splitting

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Interface characteristics and wear resistance of Ni-B_(4)C plated ZTA reinforced high chromium cast iron composite

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China Foundry 2023年第3期20卷 253-262页

作者： Ke-liang Li Wei Li Yan-liang Yi Institute of Advanced wear&corrosion resistant and Functional materials Jinan UniversityGuangzhou 510632China National Joint Engineering Research center of High Performance Metal wear resistant materials Technology Jinan UniversityGuangzhou 510632China

A chemical composite plating of Ni-B_(4)C was used to prepare the surface-modified zirconia toughened alumina(ZTA)ceramic *** ceramic preforms were prepared by the plated ZTA and sodium silicate solution binder,followed by casting infiltration to prepare the ZTA particles reinforced high chromium cast iron(HCCI)*** result reveals that a distinct interface layer forms at the ZTA/HCCI interface,which consists of phases of ZrB_(2),FeB,Fe_(2)B,and NaSiO_(4).The interfacial wettability between ZTA and HCCI is improved by the diffusion and reaction of Ni and B_(4)*** wear test reveals that the Ni-B_(4)C plated ZTA particles can effectively improve the wear resistance of the ZTA/HCCI composite,and the wear rate of the composite is decreased to 11.6%of HCCI.

关键词： ZTA composite high chromium cast iron interface layer three-body abrasive wear

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corrosion of Duplex Stainless Steel Manufactured by Laser Powder Bed Fusion: A Critical Review

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Acta Metallurgica Sinica(English Letters) 2024年第4期37卷 587-606页

作者： Yiqi Zhou Decheng Kong Ruixue Li Xing He Chaofang Dong Beijing Advanced Innovation center for materials Genome Engineering Institute for Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing100083China Shanghai Key Laboratory of Advanced High-Temperature materials and Precision Forming School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai200240China

Laser powder bed fusion (LPBF) is a commonly used additive manufacturing (AM) method for efficiently producing intricate geometric components. This investigation examines factors such as pores, cellular structure, grain size, and inclusions from the manufacturing process that contribute to the corrosion resistance of LPBF DSS. Furthermore, the as-built LPBF duplex stainless steel (DSS) is primarily ferrite due to the rapid cooling process. Therefore, the transformation of ferrite to austenite after various heat treatments in LPBF DSS and its corresponding corrosion resistance are presented. Additionally, a new mixed powder method is proposed to increase the austenite content in the as-built LPBF DSS. This review also focuses on the passivation capability and pitting corrosion performance in LPBF and conventional DSS. This article summarizes the variations in microstructure between as-built and heat-treated LPBF DSS, with their impacts on corrosion resistance, offering insights for manufacturing highly corrosion-resistant LPBF DSS.

关键词： Laser powder bed fusion Duplex stainless steel Microstructure Heat treatment Passivation Pitting corrosion

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Effect of Mo on microstructure,mechanical and corrosion properties of FeCrNiMnMox high-entropy alloys

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China Foundry 2022年第6期19卷 464-472页

作者： Xue-wei Xing Jin-kang Hu Ying Liu Wei Li Institute of Advanced wear&corrosion resistant and Functional materials Jinan UniversityGuangzhou 510632China

Four FeCrNiMnMo_(x)(x=0,0.1,0.3,0.5,in molar ratio)high-entropy alloys(HEAs)were synthesized by vacuum arc melting to explore the potential impact of Mo on the microstructure,mechanical properties,and passivation and electrochemical behaviors in 0.5 M H_(2)SO_(4)*** results display that the FeCrNiMn alloy exhibits a single face-centered cubic(FCC)structure while the microstructures of the FeCrNiMnMo_(0.1),FeCrNiMnMo_(0.3),and FeCrNiMnMo_(0.5)alloys consist of the FCC andσ*** appear of theσphase ascribed to the addition of Mo enhances the hardness and yield strength with the sacrifice of *** FeCrNiMnMox HEAs achieve the maximum hardness of 414 HV_(0.2)and the highest compressive yield strength of 830 MPa when x=0.5,but compressive fracture strain is lowered to 10.8%.X-ray photoelectron spectroscopy(XPS)and electrochemical analysis show that the passivation film in FeCrNiMnMox alloy mainly consists of chromium oxides and molybdenum *** has a beneficial effect on the corrosion resistance of the FeCrNiMnMox HEAs in a 0.5 M H_(2)SO_(4)solution by increasing the corrosion potential(E_(corr))and decreasing the corrosion current density(I_(corr))and passivation current density(I_(pass)).The FeCrNiMnMo_(0.1)alloy shows the best corrosion resistance,mainly due to its passivation film consisting of a large proportion of chromium oxide(Cr_(2)O_(3)).More Mo additions promote the formation of the precipitate ofσphase and the matrix regions depleted Cr and Mo elements adverse to the resistance to preferential localized corrosion.

关键词： high-entropy alloy microstructure mechanical properties corrosion behavior X-ray photoelectron spectroscopy(XPS)

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