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Modelling and optimization of nonylphenol biosorption by novel lowcost magnetic Chlorella vulgaris

Emerging Contaminants 2024年第3期10卷 170-180页

作者： Fatemeh Rahmani Nooshin Sajjadi Mohammad Hadi Dehghani Mozhgan Zaeimdar environmental Science and Technology Department Marine Science and Technology FacultyNorth Tehran BranchIslamic Azad UniversityTehranIran Department of environmental Health Engineering School of Public HealthTehran University of Medical SciencesTehranIran center for Solid Waste research Institute for Environmental ResearchTehran University of Medical SciencesTehranIran

Discharging untreated wastewater causes environmental *** research examined the efficiency of removal and the adsorption process of Emerging Contaminant nonylphenol(NP)using magnetic Chlorella vulgaris(M-Chlorella vulgaris).The characterization of M-Chlorella vulgaris involved XRD,FESEM,EDS-Mapping,BET,FTIR,and VSM *** impact of four different parametersdpH,MChlorella vulgaris dose,initial concentration of NP,and contact time on the biosorption process was *** model and optimize the study while minimizing costs and the number of experiments,Response Surface Methodology(RSM)with Central Composite Design(CCD)was *** to the findings,the quadratic model with adjusted R^(2)=0.96 was the best fitted among the other *** pH=3.5,dosage=2.5 g/l,NP concentration=4 mg/l,and reaction time=70 min,which are the optimal parameters,the maximum removal effectiveness was about 91%.The Langmuir model(R^(2)=0.998)and pseudo-second-order model(R^(2)=0.997)exhibited the best fits for the adsorption isotherm and kinetic studies,*** characteristics of M-Chlorella vulgaris were determined to facilitate a spontaneous nature,and thermodynamic experiments indicated that the process of adsorption of nonylphenol is *** inexpensiveness and availability of adsorbent,suitable efficiency in the biosorption of pollutant and magnetic collection of pollutant from the aquatic environment can be mentioned as the advantages of this process.

关键词： RSM-CCD Nonylphenol Biosorption Algea Emerging contaminants M-Chlorella vulgaris

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VOC emitted by biopharmaceutical industries:Source profiles,health risks,and secondary pollution

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Journal of environmental Sciences 2024年第1期135卷 570-584页

作者： Jiawei Ma Lin Li State Key Laboratory of environmental Aquatic Chemistry Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China National Engineering Laboratory for VOCs Pollution Control Material&Technology University of Chinese Academy of SciencesBeijing 101408China

The biopharmaceutical industry contributes substantially to volatile organic compounds(VOCs)emissions,causing growing concerns and social developmental *** study conducted an on-site investigation of the process-based emission of VOCs from three biopharmaceutical *** the workshops of the three enterprises,26 VOCs were detected,which could be sorted into 4 classes:hydrocarbons,aromatic hydrocarbons,oxygen-containing compounds,and nitrogen-containing *** were the main components of waste gases,accounting for 44.13%-77.85%of the overall ***-based source profiles were compiled for each process unit,with the fermentation and extraction units of tiamulin fumarate being the main source of VOC *** heptanone,vinyl acetate,diethylamine,propylene glycol methyl ether(PGME),and benzene were screened as priority pollutants through a fuzzy comprehensive evaluation *** level concentration simulation results of the Gauss plume diffusion model demonstrated that the diffusivity of VOCs in the atmosphere was relatively high,indicating potential non-carcinogenic and carcinogenic risks 1.5-2 km ***,the process-based formation potentials of ozone and secondary organic aerosols(SOAs)were determined and indicated that N-methyl-2-pyrrolidone,dimethyl heptanone,and PGME should be preferentially controlled to reduce the ozone formation potential,whereas the control of benzene and chlorobenzene should be prioritized to reduce the generation of *** results provide a basis for understanding the characteristics of VOC emission by biopharmaceutical industries and their diffusion,potentially allowing the development of measures to reduce health risks and secondary pollution.

关键词： Biopharmaceutical Volatile organic compound Priority pollutant Exposure risk Secondary pollution

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The configuration of Au^(δ+)-ZrO_(2)^(δ−)species induced activation enhances electrocatalytic CO_(2)to formate conversion

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Nano research 2024年第7期17卷 6006-6015页

作者： Yongjian Jia Yadi Zhang Mengque Lin Yangyang Cheng Yanjie Xu National Engineering research center for Technology and Equipment of environmental Deposition Lanzhou Jiaotong UniversityLanzhou 730070China Key Lab of Opt-Electronic Technology and Intelligent Control of Ministry of Education Lanzhou Jiaotong UniversityLanzhou 730070China School of environmental Engineering and Chemistry Luoyang Institute of Science and TechnologyLuoyang 471023China

Electrochemical CO_(2)conversion into value-added chemicals is a promising technology to solve the greenhouse effect and recycle chemical ***,the electrochemical CO_(2)reduction reaction(e-CO_(2)RR)is seriously compromised by weak CO_(2)adsorption and a rough CO_(2)activation process based on the chemical inertness of the CO_(2)molecule and the formed fragile metal–C/O *** this paper,we designed and fabricated Au particles embedded in ZrO_(2).The configuration of Au particles being of positive charge and ZrO_(2)with negative charge is induced and generated by metal–support interactions(MSIs).As a result,Au/ZrO_(2)@C presents a big difference in the CO_(2)conversion compared with the known work,affording a formate yield of 112.5μmol·cm^(−2)·h^(−1)at−1.1 V *** hydrogen electrode(RHE),and a max formate Faradaic efficiency of up to 94.1%at−0.9 V *** superior performance was attributed to the activated Au–ZrO_(2)interface to form the Au^(δ+)*** insitu Fourier transform infrared(FTIR)spectroscopy and theoretical calculations show that the MSIs configuration can be inclined to the*OCO intermediate generation on Au^(δ+)species activating CO_(2)molecules and then accelerate the formation of the*OCHO intermediate in e-CO_(2)RR,thereby favoring the CO_(2)conversion to formate.

关键词： electrochemical CO_(2)reduction reaction(e-CO_(2)RR) Au_(δ+)species formic acid *OCHO intermediate metal-support interactions

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Preface to the Special Topic on Ocean, Sea Ice and Northern Hemisphere Climate:In Remembrance of Professor Yongqi GAO's Key Contributions

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Advances in Atmospheric Sciences 2024年第8期41卷 1463-1464页

作者： Noel KEENLYSIDE Shengping HE Fei LI Geophysical Institute University of Bergen and Bjerkenes Centre for Climate ResearchBergen 5007Norway Nansen environmental and Remote Sensing center Bergen 5007Norway Nansen-Zhu International research center Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China

This special issue commemorates the life work of Prof. Yongqi GAO who passed away in July 2021, his time cut short by illness. He had many great achievements, but still much more to contribute. The seven articles in this special issue are from research areas where he contributed, and they illustrate how his close colleagues are continuing his work.

关键词： Ice Hemisphere Climate

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Rapid Energy Exchange between In Situ Formed Bromine Vacancies and CO_(2)Molecules Enhances CO_(2)Photoreduction

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research 2024年第2期2023卷 763-771页

作者： Qin Ren Ye He Hong Wang Yanjuan Sun Fan Dong research center for environmental and Energy Catalysis Institute of Fundamental and Frontier SciencesUniversity of Electronic Science and Technology of ChinaChengdu 611731China School of Resources and Environment University of Electronic Science and Technology of ChinaChengdu 611731China

Photocatalytic reduction of CO_(2)into fuels provides a prospective tactic for regulating the global carbon balance utilizing renewable solar ***,CO_(2)molecules are difficult to activate and reduce due to the thermodynamic stability and chemical *** this work,we develop a novel strategy to promote the adsorption and activation of CO_(2)molecules via the rapid energy exchange between the photoinduced Br vacancies and CO_(2)*** in situ continuous wave-electron paramagnetic resonance(cw-EPR)and pulsed EPR technologies,we observe that the spin-spin relaxation time(T_(2))of BiOBr is decreased by 198 ns during the CO_(2)photoreduction reaction,which is further confirmed by the broadened EPR *** result reveals that there is an energy exchange interaction between in situ formed Br vacancies and CO_(2)molecules,which promotes the formation of high-energy CO_(2)molecules to facilitate the subsequent reduction *** addition,theoretical calculations indicate that the bended CO_(2)adsorption configuration on the surface of BiOBr with Br vacancies caused the decrease of the lowest unoccupied molecular orbital of the CO_(2)molecule,which makes it easier for CO_(2)molecules to acquire electrons and get *** situ diffuse reflectance infrared Fourier transform spectroscopy further shows that the activated CO_(2)molecules are favorably converted to key intermediates of COOH*,resulting in a CO generation rate of 9.1μmol g^(-1)h^(-1)and a selectivity of 100%.This study elucidates the underlying mechanism of CO_(2)activation at active sites and deepens the understanding of CO_(2)photoreduction reaction.

关键词： reaction. adsorption activation

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Plasmonic quantum dots modulated nano-mineral toward photothermal reduction of CO_(2)coupled with biomass conversion

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Nano research 2024年第6期17卷 5061-5072页

作者： Guangbiao Cao Haoran Xing Haoguan Gui Chao Yao Yinjuan Chen Yongsheng Chen Xiazhang Li National-local Joint Engineering research center of Biomass Refining and High-quality Utilization Changzhou UniversityChangzhou 213164China School of Civil and environmental Engineering Georgia Institute of TechnologyAtlantaGA 30332-0373USA

Simultaneous conversion of CO_(2)and biomass into value-added chemicals through solar-driven catalysis holds tremendous importance for fostering a sustainable circular ***,plasmonic Bi quantum dots were immobilized on phosphoric acid modified attapulgite(P-ATP)nanorod using an in-situ reduction-deposition method,and were employed for photocatalytic reduction of CO_(2)coupled with oxidation of biomass-derived benzyl *** revealed that Bi atoms successfully integrated into the basal structure of P-ATP,forming chemically coordinated Bi-O-Si bonds that served as efficient transportation channels for *** incorporation of high-density monodispersed Bi quantum dots induced a surface plasmon resonance(SPR)effect,expanding the light absorption range into the near-infrared *** a consequence,the photo-thermal transformation was significantly accelerated,leading to enhanced reaction ***,50%Bi/P-ATP nanocomposite exhibited the highest plasmon-mediated photocatalytic CH4 generation(115.7μmol·g^(−1)·h^(−1))and CO generation(44.9μmol·g^(−1)·h^(−1)),along with remarkable benzaldehyde generation rate of 79.5μmol·g^(−1)·h^(−1)in the photo-redox coupling system under solar light *** hydrogen protons released from the oxidation of benzyl alcohol facilitated the incorporation of more hydrogen protons into CO_(2)to form key CH_(3)O−*** work demonstrates the synergistic solar-driven valorization of CO_(2)and biomass using natural mineral based catalyst.

关键词： photothermal catalysis clay mineral plasmon CO_(2)reduction biomass conversion

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Synthesis of chitosan-based grafting magnetic flocculants for flocculation of kaolin suspensions

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Journal of environmental Sciences 2024年第5期139卷 193-205页

作者： Chuang Liu Xiaoyu Wang Sicong Du Wenyan Liang Beijing Key Lab for Source Control Technology of Water Pollution/Engineering research center for Water Pollution Source Control&Eco-remediation/College of environmental Science and Engineering Beijing Forestry UniversityBeijing 100083China

A series of novel chitosan-based magnetic flocculants FS@CTS-P(AM-DMC)was prepared by molecular structure *** characterization results showed that FS@CTS-P(AM-DMC)had a uniform size of about 21.46 nm,featuring a typical core-shell structure,and the average coating layer thickness of CTS-P(AM-DMC)was about 5.03 ***@CTS-P(AM-DMC)exhibited excellent flocculation performance for kaolin suspension,achieved 92.54% turbidity removal efficiency under dosage of 150 mg/L,pH 7.0,even at high turbidity(2000 NTU)with a removal efficiency of 96.96%.The flocculation mechanism was revealed to be dominated by charge neutralization under acidic and neutral conditions,while adsorption and bridging effects play an important role in alkaline *** properties of magnetic aggregates during flocculation,breakage,and regeneration were studied at different pH levels and *** the process of magnetophoretic,magnetic particles collide and adsorb with kaolin particles continuously due to magnetic and electrostatic attraction,transform into magnetic chain clusters,and then further form three-dimensional network magnetic aggregates that can capture free kaolin particles and other chain *** image velocimetry confirmed the formation of eddy current of magnetic flocs and experienced three stages:acceleration,stabilization,and deceleration.

关键词： Magnetic flocculation Chitosan Fe_(3)O_(4) Graft copolymerization PIV

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Application of the finite analytic numerical method to a flowdependent variational data assimilation

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Acta Oceanologica Sinica 2024年第3期43卷 30-39页

作者： Yan Hu Wei Li Xuefeng Zhang Guimei Liu Liang Zhang Tianjin Key Laboratory for Marine environmental research and Service School of Marine Science and TechnologyTianjin UniversityTianjin 300072China School of Marine Science and Technology Tianjin UniversityTianjin 300072China National Marine environmental Forecasting center Ministry of Natural ResourcesBeijing 100081China

An anisotropic diffusion filter can be used to model a flow-dependent background error covariance matrix,which can be achieved by solving the advection-diffusion *** of the directionality of the advection term,the discrete method needs to be chosen very *** finite analytic method is an alternative scheme to solve the advection-diffusion *** a combination of analytical and numerical methods,it not only has high calculation accuracy but also holds the characteristic of the auto *** demonstrate its ability,the one-dimensional steady and unsteady advection-diffusion equation numerical examples are respectively solved by the finite analytic *** more widely used upwind difference method is used as a control *** result indicates that the finite analytic method has higher accuracy than the upwind difference *** the two-dimensional case,the finite analytic method still has a better *** the three-dimensional variational assimilation experiment,the finite analytic method can effectively improve analysis field accuracy,and its effect is significantly better than the upwind difference and the central difference ***,it is still a more effective solution method in the strong flow region where the advective-diffusion filter performs most prominently.

关键词： finite analytic method advection-diffusion equation data assimilation flow-dependent

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Efficient removal of U(VI) from wastewater by a sponge-like 3D porous architecture with hybrid electrospun nanofibers

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Water Science and Engineering 2024年第2期17卷 150-156页

作者： Lin Hu Lin Chen Xian-kun Wu Rui Luo Rong-guan Lv Zheng-hao Fei Feng Yang School of Chemistry and environmental Engineering Yancheng Teachers UniversityYancheng 224051China Jiangsu Province Engineering research center of Agriculural Breeding Pollution Control and Resource Yancheng 224051China Jiangsu Nanda Huaxing Science and Technology of environmental Protection Co.Ltd. Yancheng 224001China

Removal of uranium(VI)from nuclear wastewater is urgent due to the global nuclear energy *** study synthesized novel sponge-like 3D porous materials for enhanced uranium adsorption by combining electrospinning and fibrous freeze-shaping *** materials possessed an organic-inorganic hybrid architecture based on the electrospun fibers of polyacrylonitrile(PAN)and SiO_(2).As a sup-porting material,the surface of fibrous SiO_(2) could be further functionalized by cyano groups via(3-cyanopropyl)*** the cyano groups were turned into amidoxime(AO)groups to obtain a amidoxime-functionalized sponge(PAO/SiO_(2)-AO)through the subsequent ami-doximation *** proposed sponge exhibited enhanced uranium adsorption performance with a high removal capacity of 367.12 mg/g,a large adsorption coefficient of 4.0×10^(4)mL/g,and a high removal efficiency of 97.59%.The UO_(2)^(2+)adsorption kinetics perfectly conformed to the pseudo-second-order *** sorbent also exhibited an excellent selectivity for UO_(2)^(2+) with other interfering metal ions.2023 Hohai *** and hosting by Elsevier B.V.

关键词： Uranium removal Sponge Amidoximation Organic-inorganic hybrid structure Electrospinning

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Solute transport and geochemical modeling of the coastal quaternary aquifer, Delta Dahab Basin, South Sinai, Egypt

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Acta Geochimica 2024年第1期43卷 16-39页

作者： Amira Samy Mustafa Eissa Seham Shahen Moustafa M.Said Rabab M.Abou-shahaba Division of Water Resources and Arid Land Department of HydrogeochemistryDesert Research CenterCairoEgypt Egypt Desalination research center of Excellence Desert Research CenterCairoEgypt center for Water Supply Studies S&E-Physical&Environmental SciencesTexas A&M University Corpus ChristiCorpus ChristiUSA Department of Chemistry Faculty of Science(Girls)Al-Azhar UniversityYousef Abbas StrNasr CityP.O.Box:11754CairoEgypt

The wadi dahab delta is in a dry, arid coastal zone within Egypt’s south Sinai Peninsula’s eastern portion. The primary water source is the Quaternary coastal alluvial aquifer. The groundwater salinity varies from 890to 8213 mg/L, with a mean value of 3417 mg/L. The dissolved major ions have been used to calculate the seawater mixing index(SWMI) using a linear equation that discriminates the groundwater mostly affected by water–rock interaction(SWMI 1>) and other samples mixed with Seawater(SWMI < 1). The isotopic composition of groundwater for specifically chosen groundwater samples ranges from-0.645‰ to +5.212‰ for δ^(18)O and from-9.582‰ to + 22.778‰ for δ^(2)H, where the seawater represented by a Red Sea water sample(δ^(18)O + 1.64‰-δ^(2)H + 9.80‰) and reject brine water are considerably enriched the isotopic groundwater values. The geochemical NETPATH model constrained by the dissolved significant ions, isotopes, and the rock aquifer forming minerals as phases indicate the mixing percent with the seawater ranges from 9% to 97% of seawater from 91% to 3% of original recharge water. According to the SEAWAT 3-D flow models, seawater has penetrated the Northeastern Dahab delta aquifer, with the intrusion zone extending1500 m inland. The salt dissolution, upwelling of saline water, recharge from the upstream mountain block, and seawater encroachment are the primary aspects contributing to the deterioration of groundwater quality. These findings may have significance for effective groundwater withdrawal management in arid locations worldwide with similar hydrogeological systems.

关键词： Groundwater geochemistry Seawater intrusion Solute transport SEAWAT

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