检索结果-南通市图书馆

Depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite

引用

International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 335-345页

作者： Feng Zhang Chenyang Zhang Linlin Wu Wei Sun Hongliang Zhang Jianhua Chen Yong Pei Songjiang Li Engineering Research center of Ministry of Education for Carbon Emission Reduction in Metal resource Exploitation and Utilization Hunan International Joint Research Center for Efficient and Clean Utilization of Critical Metal Mineral ResourcesSchool of Minerals Processing and BioengineeringCentral South UniversityChangsha 410083China State Key Laboratory of Mineral Processing Beijing General Research Institute of Mining&MetallurgyBeijing 100160China Hunan Provincial Key Laboratory of Micro&Nano Materials Interfaces Science College of Chemistry and Chemical EngineeringCentral South UniversityChangsha 410083China School of resources Environment and MaterialsGuangxi UniversityNanning 530004China Department of Chemistry Xiangtan UniversityXiangtan 411105China China Railway resource Group Co.Ltd Beijing 102300China

The depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite still lacked in-depth ***,the depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite was further systematically investigated with experiments and density functional theory(DFT)*** X-ray photoelectric spectroscopy(XPS)results,DFT calculation results,and frontier molecular orbital analysis indicated that sulfite ions were difficult to be adsorbed on sphalerite surface,suggesting that sulfite ions achieved depression effects on sphalerite through other non-adsorption ***,the oxygen content in the surface of sphalerite treated with sulfite ions in creased,which enhanced the hydrophilicity of the sphalerite and further increased the difference in hydrophilicity between sphalerite and ***,sulfite ions were chelated with lead ions to form PbSO_(3)in *** hydrophilic PbSO_(3)was more easily adsorbed on sphalerite than *** interaction between sulfite ions and lead ions could effectively inhibit the activation of *** addition the UV spectrum showed that after adding sulfite ions,the peak of perxanthate in the sphalerite treated xanthate solution was significantly stronger than that in the galena with xanthate solution,indicating that xanthate interacted more readily with sulfite ions and oxygen mo lecules within the sphalerite system,leading to the formation of ***,sulfite ions hardly depressed the flotation of ga lena and could promote the flotation of galena to some *** study deepened the understanding of the depression mechanism o sulfite ions on sphalerite and Pb^(2+)activated sphalerite.

关键词： sphalerite galena sulfite ion density functional theory depression mechanism

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Electrochemical conversion of methane to bridge the gap in the artificial carbon cycle

引用

Journal of Energy Chemistry 2025年第1期100卷 286-308页

作者： Yuhao Peng Yuefeng Song Ihar Razanau Juanxiu Xiao Wei Xiao Di Hu Guoxiong Wang College of Chemistry and Molecular Sciences Hubei Key Laboratory of Electrochemical Power Sources Wuhan University State Key Laboratory of Catalysis Dalian National Laboratory for Clean Energy iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Dalian Institute of Chemical Physics Chinese Academy of Sciences Laboratory of Physical-Chemical Technologies SSPA Scientific and Practical Materials Research Centre of NAS of Belarus State Key Laboratory of Marine resources Utilization in South China Sea Collaborative Innovation Center of Marine Science and Technology School of Marine Science and Engineering Hainan University Department of Chemical and Environmental Engineering University of Nottingham Ningbo China

Methane, an abundant one-carbon（C1） resource, is extensively used in the industrial production of vital fuels and value-added chemicals. However, current industrial methane conversion technologies are energy-and carbon-intensive, mainly due to the high activation energy required to break the inert C–H bond, low selectivity, and problematic side reactions, including CO2emissions and coke deposition. Electrochemical conversion of methane（ECM） using intermittent renewable energy offers an attractive solution, due to its modular reactor design and operational flexibility across a broad spectrum of temperatures and pressures. This review emphasizes conversion pathways of methane in various reaction systems, highlighting the significance and advantages of ECM in facilitating a sustainable artificial carbon cycle. This work provides a comprehensive overview of conventional methane activation mechanisms and delineates the complete pathways of methane conversion in electrolysis contexts. Based on surface/interface chemistry, this work systematically analyzes proposed reaction pathways and corresponding strategies to enhance ECM efficiency towards various target products, including syngas, hydrocarbons, oxygenates, and advanced carbon materials. The discussion also encompasses opportunities and challenges for the ECM process, including insights into ECM pathways, rational electrocatalyst design, establishment of benchmarking protocols, electrolyte engineering, enhancement of CH4conversion rates, and minimization of CO2emission.

关键词： Methane Electrochemical conversion Reaction mechanism Catalyst design Electrode Electrocatalysis

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Ethanol mediated As(Ⅲ) adsorption onto Zn-loaded pinecone biochar：Experimental investigation,modeling,and optimization using hybrid artificial neural network-genetic algorithm approach

引用

Journal of Environmental Sciences 2017年第4期29卷 114-125页

作者： Mohd.Zafar N.Van Vinh Shishir Kumar Behera Hung-Suck Park center for clean technology and resource recycling University of Ulsan Ulsan 680749 South Korea Department of Applied Biotechnology Sur College of Applied Sciences Sur 411 Al Shariya Sultanate of Oman Department of Civil and Environmental Engineering University of Ulsan Ulsan 680749 South Korea Chemical Engineering Department GMR Institute of Technology Rajam 532127 Srikakulam Dist. India

Organic matters（OMs） and their oxidization products often influence the fate and transport of heavy metals in the subsurface aqueous systems through interaction with the mineral surfaces. This study investigates the ethanol（EtO H）-mediated As（Ⅲ） adsorption onto Zn-loaded pinecone（PC） biochar through batch experiments conducted under Box–Behnken design. The effect of EtO H on As（Ⅲ） adsorption mechanism was quantitatively elucidated by fitting the experimental data using artificial neural network and quadratic modeling approaches. The quadratic model could describe the limiting nature of EtO H and pH on As（Ⅲ） adsorption,whereas neural network revealed the stronger influence of Et OH（64.5%） followed by pH（20.75%）and As（Ⅲ） concentration（14.75%） on the adsorption phenomena. Besides, the interaction among process variables indicated that Et OH enhances As（Ⅲ） adsorption over a pH range of2 to 7, possibly due to facilitation of ligand–metal（Zn） binding complexation ***, hybrid response surface model–genetic algorithm（RSM–GA） approach predicted a better optimal solution than RSM, i.e., the adsorptive removal of As（Ⅲ）（10.47 μg/g） is facilitated at 30.22 mg C/L of Et OH with initial As（Ⅲ） concentration of 196.77 μg/L at pH 5.8. The implication of this investigation might help in understanding the application of biochar for removal of various As（Ⅲ） species in the presence of OM.

关键词： As(Ⅲ) removal Competitive adsorption Ethanol Box–Behnken design Artificial neural network Hybrid RSM–GA optimization

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Mineral phase reconstruction behavior of direct reduction and smelting titanium slag at high temperature and slow cooling

引用

Rare Metals 2015年第6期34卷 440-444页

作者： Yi-Jie Wang Shu-Ming Wen Qi-Cheng Feng Zhi-Wen Ye Min Wang State Key Laboratory of Complex Nonferrous Metal resources clean Utilization Kunming University of Science and Technology Faculty of Land resource Engineering Kunming University of Science and Technology Advanced Analysis and Measurement center Yunnan University

Titanium slag in this study was produced by subjecting titanomagnetite concentrate to direct reductionelectric furnace smelting. Processing mineralogy and mineral phase reconstruction behavior at high temperature and slow cooling treatment were examined by chemical analysis, X-ray diffraction （XRD）, optical microscopy （OM）, scanning electron microscopy （SEM）, and energydispersive spectroscopy （EDS）. Anosovite solid solution is the main titanium product by the direct reduction and smelting process. Results of slow-cooling experiments show that crystal volume and size increase as cooling rate decreases. Anosovite and gangue mineral crystals develop fully with large crystal volume and size at a cooling rate of 2 ***-1. Moreover, the growth of anosovite crystal was characterized by crystal nucleation and growth theory. These results provide further insights into the separation of anosovite from gangue by mineral processing.

关键词： Direct reduction Smelting titanium slag Anosovite Slow cooling Crystal

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Synthesis of nitrogen-doped carbon nanotubes-FePO_4 composite from phosphate residue and its application as effective Fenton-like catalyst for dye degradation

引用

Journal of Environmental Sciences 2019年第2期31卷 188-198页

作者： Lianmei Wei Yi Zhang Shengwen Chen Luping Zhu Xiaoyu Liu Lingxue Kong Lijun Wang School of Environmental and Materials Engineering Shanghai Polytechnic University Research center of resource recycling Science and Engineering Shanghai Polytechnic University Institute for Frontier Materials Deakin University

Phosphate residue is regarded as a hazardous waste, which could potentially create significant environmental and health problems if it is not properly treated and disposed of. In this study, nitrogen-doped carbon nanotubes-FePO_4(NCNTs-FePO_4) composite was successfully synthesized from phosphate residue, and its application as an effective catalyst was explored. Firstly, an effective method was developed to recover FePO_4 from phosphate residue, achieving an impressive FePO_4 mass recovery rate of 98.14%. Then, the NCNTsFePO_4 catalyst was synthesized from the recovered FePO_4 by two main reactions, including surface modification and chemical vapor deposition. Finally, the synthesized NCNTs-FePO_4 was applied to photo-degrade 15 mg/L Rhodamine B(RhB) in a Fenton-like system. The results showed that 98.9% of RhB could be degraded in 60 min, closely following the pseudofirst-order kinetics model. It was found that even after six consecutive cycles, NCNTs-FePO_4 still retained a high catalytic capacity(>50%). Moreover, ·OH radicals participating in the RhB degradation process were evidenced using quenching experiments and electron paramagnetic resonance analysis, and a rational mechanism was proposed. It was demonstrated that the materials synthesized from hazardous phosphate residue can be used as an effective catalyst for dye removal.

关键词： Phosphate residue Fenton-like Nitrogen-doped carbon nanotubes-FePO4 Hydroxyl radical

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Comprehensive recovery of W,V,and Ti from spent selective reduction catalysts

引用

Rare Metals 2023年第10期42卷 3518-3531页

作者： Li-Wen Ma Xiao-Li Xi Jia-Peng Chen Fan Guo Zi-Jie Yang Zuo-Ren Nie Key Laboratory of Advanced Functional Materials Ministry of EducationFaculty of Materials and ManufacturingBeijing University of TechnologyBeijing100124China Collaborative Innovation center of Capital resource-recycling Material technology Beijing University of TechnologyBeijing100124China National Engineering Laboratory for Industrial Big-Data Application technology Beijing University of TechnologyBeijing100124China

In this study,spent WO_(3)/V_(2)O_(5)-TiO_(2) catalysts used for selective catalytic reduction were treated by a hydrometallurgical process to comprehensively recover valuable metallic elements,such as W,V,and *** and Si impurities were preferentially removed by selective micro wave-assisted alkali leaching.W and V were leached by enhanced high-pressure leaching with efficiencies estimated at 95% and 81%.The leaching of W and V followed the nuclear shrinkage model controlled by the combination of product layer diffusion and interfacial chemical reaction.A synergistic extraction was applied to separate W and V using an extractant mixture of di-(2-ethylhexyl)phosphoric acid P204 and the primary amine *** extraction efficiencies of V and W reached 86.5% and 6.3%,respectively,with a separation coefficient(V/W) of *** product was precipitated after extraction to yield ammonium paratung state(APT) and NH_(4)VO_(3).The TiO_(2)catalyst carrier residue meets commercial specifications for *** comprehensive recovery process with the characteristics of high-pressure leaching and synergistic extraction realizes the resourceful utilization of the spent catalysts.

关键词： Spent selective catalytic reduction(SCR)catalysts Microwaveleaching Pressure leaching Synergistic extraction Comprehensive recovery

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Preparation and optical properties of three-dimensional navel-like Bi_2WO_6 hierarchical microspheres

引用

Chinese Chemical Letters 2019年第3期30卷 783-786页

作者： Qiang Chen Yuqin Mao Naici Bing Yongjin Zou Luping Zhu School of Environmental and Materials Engineering Research Center of Resource Recycling Science and Engineering Shanghai Polytechnic University (SSPU) Guangxi Key Laboratory of Information Materials Guilin University of Electronic Technology (GUET) Shanghai Innovation Institute for Materials

Three-dimensional(3D) navel-like Bi_2WO_6(BWO) hierarchical microspheres(HMSs) were successfully prepared using a simple hydrothermal method. The as-obtained BWO samples were characterized by a variety of techniques. XRD result indicated that the as-synthesized samples were well-crystallized orthorhombic phase Bi_2WO_6 structure. SEM observations revealed that the hierarchical microspheres with an average diameter of 2 μm were built from several dozen of nanosheets. UV-vis diffuse reflectance spectrum study revealed that the obtained BWO sample had band gap energy of about 3.3 ***(PL) result showed that the sample had weak emission intensity. The BET specific surface area of the BWO sample was about 35.40 m^2/g. The photocatalytic efficiency of the as-obtained BWO was evaluated by the degradation of norfloxacin(NOR) antibiotic. The result showed an about 67%NOR degradation in 8 h.

关键词： Semiconductors Bi2WO6 Crystal growth Microstructure Optical properties

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Influence of PTFE on Electrode Structure for Performance of PEMFC and 10-Cells Stack

引用

Chinese Journal of Mechanical Engineering 2012年第6期25卷 1171-1175页

作者： LIN Rui ZHAO Tiantian ZHANG Haiyan CAO Chunhui LI Bing MA Jianxin clean Automotive Engineering center Tongji University Shanghai 201804 China School of Automotive Studies Tongji University Shanghai 201804 China School of resource and Environmental Engineering East China University of Science of Technology Shanghai 200237 China

Water plays a critical role on the performance, stability and lifetime of proton exchange membrane fuel cells（PEMFCs）. The addition of poly tetrafluoroethylene（PTFE） to the gas diffusion layer, especially, the cathode side, would optimize the transportation of water, electron and gas and thus improve the performance of the fuel cell. But until now, the studies about directly applying the PTFE to the catalyst layer are rarely reported. In this paper, the membrane electrode is fabricated by using directly coating catalyst to the membrane method（CCM） and applying PTFE directly to the cathode electrode catalyst layer. The performance of the single cell is determined by polarization curves and durability tests. Electrochemical impedance spectroscopy（EIS） and scanning electron microscopy（SEM） techniques are used to characterize the electrochemical properties of PEMFC. Also the performance of a 10-cells stack is detected. Combining the performance and the physical-chemistry characterization of PEMFC shows that addition of appropriate content of PTFE to the electrode enhances the performance of the fuel cell, which may be due to the improved water management. Addition of appropriate content of PTFE enhances the interaction between the membrane and the catalyst layer, and bigger pores and highly textured structure form in the MEA, which favors the oxygen mass transfer and protons transfer in the fuel cell. While superfluous addition of PTFE covers the surface of catalysts and hindered the contact of catalyst with Nation, which leads to the reduction of electrochemical active area and the decay of the fuel cell performance. The proposed research would optimize the water management of the fuel cell and thus improve the performance of the fuel cell.

关键词： proton exchange membrane fuel cell poly-tetrafluoroethylene electrochemical impedance spectroscopy scanning electron microscopy fuel cell stack

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Facile synthesis of W-Mo bimetallic oxides with high adsorption properties from secondary resources

引用

Tungsten 2024年第4期6卷 806-820页

作者： Jia-Li Cheng Yang-Si Liu Xiao-Li Xi Zuo-Ren Nie Collaborative Innovation center of Capital resource-recycling Material technology College of Materials Science and EngineeringBeijing University of TechnologyBeijing100124China National Engineering Laboratory for Industrial Big-Data Application technology Beijing University of TechnologyBeijing100124China Key Laboratory of Advanced Functional Materials Ministry of EducationBeijing University of TechnologyBeijing100124China

A simple solvothermal method was used to obtain W-Mo bimetallic oxides from W-Mo alloy scrap,and pure metal powders were also used as the raw materials to simulate *** products had a sea urchin-like structure with abundant oxygen vacancies and the products prepared at low temperatures forms a sosoloid resembling orthorhombic W_(0.4)Mo_(0.6)O_(3).The WMo bimetallic oxide prepared at the reaction temperature of 120℃exhibited excellent selective adsorption performance for methylene blue(MB),which the adsorption rate of MB reached 99%in 12 min and the adsorption rate reached 90%after6 adsorption *** the W-Mo molar ratio is 1:3,the maximum adsorption capacity of sample for MB can reach1148 mg·g^(-1).The adsorption process followed the Langmuir and pseudo-second-order models,which is surface-controlled monolayer *** experimental results show the feasibility of preparing W-Mo bimetal oxide products from pure materials and *** process is simple and effective,which offered a potential approach for secondary resource recycling and reusing.

关键词： W-Mo bimetallic oxide Oxygen vacancy Selective adsorption W-Mo alloy scrap Solvothermal

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Improvement in oxidation resistance of Cantor alloy through microstructure tailoring

引用

China Foundry 2022年第6期19卷 503-510页

作者： Bao-lin Pang Man Wang Yue-gang Shen Xiao-li Xi Zuo-ren Nie Collaborative Innovation center of Capital resource-recycling Material technology Faculty of Materials and ManufacturingBeijing University of TechnologyBeijing 100124China Key Laboratory of Advanced Functional Materials Ministry of EducationBeijing University of TechnologyBeijing 100124China National Engineering Laboratory for Industrial Big-data Application technology Beijing University of TechnologyBeijing 100124China

A method of improving the oxidation resistance of Cantor alloy through microstructure tailoring was *** with distinctive microstructures were achieved by different annealing treatments on the cold-rolled Cantor *** test was then carried out on the various annealed samples at 800°C for 24 h in *** oxidation behavior was evaluated in terms of oxidation rate,surface and cross-section microstructure *** stratified oxide layers including outer Mn_(2)O_(3) and inner Cr_(2)O_(3) were observed in all the annealed samples,the thickness of Mn_(2)O_(3) and Cr_(2)O_(3) layers was ***,the samples exhibited different oxidation *** results indicate that the oxidation resistance of various annealed samples is closely related with grain size as well as twin density.

关键词： Cantor alloy annealing temperature grain size twins oxidation behavior

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：