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Tailoring sub-5 nm Fe-doped CeO2 nanocrystals within confined spaces to boost photocatalytic hydrogen evolution under visible light

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Journal of Energy Chemistry 2025年第2期101卷 263-277页

作者： Giuseppina Iervolino Olimpia Tammaro Marco Fontana Bruno Masenelli Anne D.Lamirand Vincenzo Vaiano Serena Esposito Department of Industrial Engineering University of Salerno Department of applied Science and Technology and INSTM Unit of Torino-Politecnico Politecnico di Torino center for Sustainable Future technologies POLITO Istituto Italiano di Tecnologia INSA Lyon Ecole Centrale de Lyon CNRS Universite Claude Bernard Lyon 1 CPE LyonINL

This work aimed to study the efficiency of the reverse micelle（RM） preparation route in the syntheses of sub-5 nm Fe-doped CeO2nanocrystals for boosting the visible-light-driven photocatalytic hydrogen production from methanol aqueous *** effectiveness of confining precipitation reactions within micellar cages was evaluated through extensive physicochemical cha *** particula r,the nominal composition（0-5 mol% Fe） was preserved as ascertained by ICP-MS analysis,and the absence of separate iron-containing crystalline phases was supported by X-ray *** effective aliovalent doping and modulation of the optical properties were investigated using UV-Vis,Raman,and photoluminescence spectroscopies.2.5 mol% iron was found to be an optimal content to achieve a significant decrease in the band gap,enhance the concentration of oxygen vacancy defects,and increase the charge carrier *** photocatalytic activity of Fe-doped CeO2prepared at different Fe contents with RM preparation was studied and compared with undoped *** optimal iron load was identified to be2.5 mol%,achieving the highest hydrogen production(7566 μmol L-1after 240 min under visible light).Moreover,for comparison,the conventional precipitation（P） method was adopted to prepare iron containing CeO2at the optimal content（2.5 mol% Fe）.The Fe-doped CeO2catalyst prepared by RM showed a significantly higher hydrogen production than that obtained with the sample prepared by the P *** optimal Fe-doped CeO2,prepared by the RM method,was stable for six reuse ***,the role of water in the mechanism of photocatalytic hydrogen evolution under visible light was studied through the test in the presence of *** obtained results evidenced that hydrogen was produced from the reduction of H+by the electrons promoted in the conduction band,while methanol was preferentially oxidized by the photogenerated positive holes.

关键词： Hydrogen evolution Mesoporous CeO2 Photocatalysis Reverse micelles Sub-5 nm Fe-doped CeO2 Visible light

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Damage analysis caused by ^(60)Co ions in functionally graded materials

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Defence Technology(防务技术) 2025年第2期44卷 248-256页

作者： Zübeyde Özkan Ugur Gökmen Sema Bilge Ocak Department of Advanced technologies Graduate School of Natural and Applied SciencesGazi UniversityAnkara06560Turkiye Department of Metallurgical and Materials Engineering Faculty of TechnologyGazi UniversityAnkara 06560Turkiye Basic and Engineering Sciences Central Laboratory Application and Research center Gazi UniversityAnkara 06560Turkiye

Functionally graded composite/hybrid materials(FGCM/FGHCM)were produced by adding B_(4)C,TiO_(2),and B_(4)C+TiO_(2)ceramic materials at various ratios(0-50%)into the AA6082 *** analysis of the damage caused by^(60) ions'(1.173-1.1332 MeV)on the material was examined using the SRIM/TRIM Monte Carlo simulation *** the simulation,the following data regarding the atoms of the target materials were obtained:ion distribution,target ionization,total displacements,surface binding energy,lattice binding energy,and displacement *** the studied four materials,the one with the highest ion range value was found to be AA6082 with ***_(2)was found to be the reinforcement material that reduced the ion range the most in the *** to its high binding energy,B_(4)C reinforced AA6082+(0-50%)B_(4)C FGCM was found to have the least vacancy with 4782/ion.

关键词： SRIM/TRIM Damage analysis AA6082 ^(60)Co ion

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Secure beamforming and deployment design for rate-splitting multiple access-based UAV communications

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Science China(Information Sciences) 2025年第1期68卷 342-356页

作者： Bing WANG Xiaofeng TAO Shujun HAN Huici WU Kai YANG Zhu HAN National Engineering Research center of Mobile Network technologies Beijing University of Posts and Telecommunications Peng Cheng Laboratory Department of Electrical and Computer Engineering University of Houston

Rate-splitting multiple access(RSMA) has recently gained attention as a potential robust multiple access(MA)scheme for upcoming wireless networks. Given its ability to efficiently utilize wireless resources and design interference management strategies, it can be applied to unmanned aerial vehicle(UAV) networks to provide convenient services for large-scale access ground users. However, due to the line-of-sight(LoS) broadcast nature of UAV transmission, information is susceptible to eavesdropping in RSMA-based UAV networks. Moreover, the superposition of signals at the receiver in such networks becomes complicated. To cope with the challenge, we propose a two-user multi-input single-output(MISO) RSMA-based UAV secure transmission framework in downlink communication networks. In a passive eavesdropping scenario, our goal is to maximize the sum secrecy rate by optimizing the transmit beamforming and deployment location of the UAV-base station(UAV-BS),while considering quality-of-service(QoS) constraints, maximum transmit power, and flight space limitations. To address the non-convexity of the proposed problem, the optimization problem is first decoupled into two subproblems. Then, the successive convex approximation(SCA) method is employed to solve each subproblem using different propositions. In addition, an alternating optimization(AO)-based location RSMA(L-RSMA) beamforming algorithm is developed to implement joint optimization to obtain the suboptimal solution. Numerical results demonstrate that(1) the proposed L-RSMA scheme yields a28.97% higher sum secrecy rate than the baseline L-space division multiple access(SDMA) scheme;(2) the proposed L-RSMA scheme improves the security performance by 42.61% compared to the L-non-orthogonal multiple access(NOMA) scheme.

关键词： rate-splitting multiple access UAV communication precoding optimization deployment location physical layer security

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Transformation of leather waste into microwave-activated and N-doped carbon for Li-S batteries

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新型炭材料(中英文) 2025年

作者： Carolina Pano-Azucena Roberto Rosas-Rangel Miguel Olvera-Sosa David Salvador González-González Rene Rangel-Mendez Luis Felipe Chazaro-Ruiz Miguel Avalos-Borja Javier Antonio Arcibar-Orozco CIATEC.center for applied Innovation in Competitive technologies Tecnologico de Monterrey School of Engineering and Sciences Instituto Potosino de Investigación Científica y Tecnológica Universidad Autónoma de Coahuila Facultad de SistemasCiudad Universitaria

The use of carbon from waste biomass has the potential to buffer the drawbacks of Li-S batteries and improve their overall performance. Chrome-Tanned-LeatherShavings(CTLS) are undesirable wastes, highly available for transformation into porous carbon. Microwave activation is an efficient state-of-the-art procedure to obtain unique porous structures and nitrogen incorporation can improve the performance of porous carbons. This study proposes the transformation of CTLS into a microwave activated porous carbon, and then was modified to introduce nitrogen. A microporous activated carbon with a specific surface area of 556 m2g-1 with honeycomb-like structure was obtained. Both urea thermal decomposition and ethanolamine impregnation improves the nitrogen and amine presence of surface groups. However,the results indicated that only urea treatment was effective in improving the initial capacity of the cell(1363 mAhg-1), which is probably linked with the sorption of long-chain polysulfides. This investigation confirms that it is possible to obtain carbon materials from CTLS, for use as sulfur-host cathodes in Li-S batteries, and improve their performance with urea thermal decomposition. Furthermore, a Radial basis function neural network was fitted to provide statistical support to the experimental results. The trained model corroborated the importance of nitrogen content of the carbons in the discharge capacity of the cells.

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Mesh-supported V2O5-WO3/TiO2 nanosheet array catalysts for efficient removal of NOx

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Tungsten 2025年第1期7卷 100-111页

作者： Zhi-Qi Zhang Liu Yang Wen Luo Vladimir An Jing Li Bao-Dan Liu School of Materials Science and Engineering Northeastern University Foshan Graduate School of Innovation Northeastern University Kizhner Research center School of Advanced Manufacturing Technologies Tomsk Polytechnic University

The design and synthesis of vanadium-based denitration catalysts with low-temperature activity pose significant challenges in the field of toxic gas *** this study,we have developed a novel approach to fabricate highly efficient V2O5-WO3/TiO2monolithic mesh catalysts for NOxreduction at low ***,TiO2nanosheets with strong adhesion and large surface area were grown on Ti mesh using plasma electrolytic oxidation technology and hydrothermal ***,super-small traces of WO3and V2O5active nano-species were subsequently deposited on TiO2nanosheets using the deposition-precipitation *** to traditional ceramic-based V2O5-WO3/TiO2catalysts,our V2O5-WO3/TiO2monolithic mesh catalyst exhibits superior mechanical performance,excellent thermal conductivity,lower pressure drop,higher utilization of active components,and stronger synergistic ***,the V2O5-WO3/TiO2monolithic mesh catalysts exhibited excellent low-temperature catalytic activity with 98% of NOxconversion at 220℃,and remarkable long-term SO2tolerance and water resistance in the selective catalytic reduction（SCR） of NOxwith *** SCR reaction of tiny V2O5and WO3active species supported on TiO2nanosheets directly demonstrated to follow the Eley-Rideal mechanism by in situ infrared spectra.

关键词： Low temperature activity Monolithic mesh catalysts NH3-SCR SO2 tolerance V2O5-WO3/TiO2

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Applications of variable thermal features for the bioconvective flow of Jeffrey nanofluids due to stretching surface with mass suction effects: Cattaneo-Christov model

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applied Mathematics and Mechanics(English Edition) 2025年第2期46卷 391-402页

作者： S.U.KHAN M.GARAYEV ADNAN K.RAMESH M.EL MELIGY D.ABDUVALIEVA M.I.KHAN Department of Mathematics Namal University Department of Mathematics College of Science King Saud University Department of Mathematics Mohi-ud-Din Islamic University Department of Pure and applied Mathematics School of Mathematical SciencesSunway University Department of Mathematics Graphic Era (Deemed to be University) Department of Mathematics School of Chemical Engineering and Physical SciencesLovely Professional University Jadara University Research center Jadara University applied Science Research center Applied Science Private University Department of Mathematics and Information technologies Tashkent State Pedagogical University Department of Mechanics and Engineering Science Peking University

The thermal nanofluids have garnered widespread attention for their use in multiple thermal systems, including heating processes, sustainable energy, and nuclear reactions. Research on nanofluids has revealed that the thermal efficiencies of such materials are adversely affected by various thermal features. The purpose of the current work is to demonstrate the thermal analysis of Jeffrey nanofluids with the suspension of microorganisms in the presence of variable thermal sources. The variable effects of thermal conductivity, Brownian diffusivity, and motile density are utilized. The investigated model also reveals the contributions of radiation phenomena and chemical reactions. A porous, saturated, moving surface with a suction phenomenon promotes flow. The modeling of the problem is based on the implementation of the Cattaneo-Christov *** convective thermal constraints are used to promote the heat transfer features. A simplified form of the governing model is treated with the assistance of a shooting technique. The physical effects of different parameters for the problem are presented. The current problem justifies its applications in heat transfer, coating processes, heat exchangers, cooling systems in microelectronics, solar systems, chemical processes, etc.

关键词： Jeffrey nanofluid bioconvection effect variable thermal consequence chemical reaction numerical simulation O357 76Rxx

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Preparation of FeCoNi medium entropy alloy from Fe^(3+)-Co^(2+)-Ni^(2+)solution system

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 92-101页

作者： Zongyou Cheng Qing Zhao Mengjie Tao Jijun Du Xingxi Huang Chengjun Liu Key Laboratory for Ecological Metallurgy of Multimetallic Mineral(Ministry of Education) Northeastern UniversityShenyang 110819China School of Metallurgy Northeastern UniversityShenyang 110819China Engineering Research center of Frontier technologies for Low-carbon Steelmaking(Ministry of Education) Shenyang 110819China

In recent years,medium entropy alloys have become a research hotspot due to their excellent physical and chemical *** controlling reasonable elemental composition and processing parameters,the medium entropy alloys can exhibit similar properties to high entropy alloys and have lower *** this paper,a FeCoNi medium entropy alloy precursor was prepared via sol-gel and coprecipitation methods,respectively,and FeCoNi medium entropy alloys were prepared by carbothermal and hydrogen *** phases and magnetic properties of FeCoNi medium entropy alloy were *** showed that FeCoNi medium entropy alloy was produced by carbothermal and hydrogen reduction at 1500℃.Some carbon was detected in the FeCoNi medium entropy alloy prepared by carbothermal *** alloy prepared by hydrogen reduction was uniform and showed a relatively high ***,the hydrogen reduction product exhibited better saturation magnetization and lower coercivity.

关键词： medium entropy alloy sol-gel co-precipitation carbothermal hydrogen reduction

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Spin magnetization in unconventional antiferromagnets with collinear and non-collinear spins

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Science China(Physics,Mechanics & Astronomy) 2025年第04期Mechanics & Astronomy) .卷 165-174页

作者： Lun-Hui Hu Song-Bo Zhang center for Correlated Matter and School of Physics Zhejiang University Department of applied Physics School of Science Aalto University Hefei National Laboratory International center for Quantum Design of Functional Materials (ICQD) University of Science and Technology of China

Unconventional antiferromagnets(AFMs) with non-relativistic spin-splitting, such as the recently discovered altermagnet, have recently gained significant interest due to their potential for novel quantum phenomena and spintronic applications. The compensated magnetization in unconventional AFMs is protected by spin-space symmetries. In this work, we explore the symmetrybreaking effects and identify three distinct mechanisms for inducing net spin magnetizations in unconventional AFMs with collinear or non-collinear spins:(1) finite size effect,(2) extrinsic spin canting effect, and(3) irradiation with circularly polarized light. We show that the induced spin magnetizations are controllable and manifest as diverse intriguing phenomena. For the finite size system, the confined direction of a two-dimensional AM creates quantum-well-like subbands that determine the spin magnetization. This effect can be experimentally probed by measuring the spin density of states and the spin-polarization of Andreev-bound states within planar Josephson junctions. In the case of spin canting effect, it leads to peculiar anisotropic and non-monotonic behaviors in the superconducting proximity effect. Lastly, with circularly polarized light, spin magnetization is driven by the polarized light and the chirality of non-collinear magnetic order, thus offering a direct means of detecting the chirality of magnetic order in real materials. Our findings provide valuable insight into understanding and probing the spin magnetization in unconventional AFM materials.

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Physiological Variance of CD34 Marker’s Content in Twenty Tissues Determining Different Risks of Cardiovascular Diseases and Cancer in Them

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Open Journal of Biophysics 2025年第1期15卷 1-17页

作者： Aleksey N. Shoutko Marat A. Karamullin Department of Transplantation and Cells technologies A. M. Granov Russian Research Center for Radiology and Surgical Technologies Saint-Petersburg Russia Department of Battle-Field Therapy Military Medical Academy Saint-Petersburg Russia

The decreasing of hazard ratio for cancer incidence (HRCVD) in the range of twenty native tissues (lung, liver, brain, hematologic, neuroendocrine renal, pancreas, lymphoid, bladder, colon, lip-oral-head-neck, leukocytic, rectum and anus, thyroid, soft tissue, prostate, skin, ovarian, breast, uterine) as much, as decreasing of the level of cardiovascular pathology (CVD) in the host before malignization, have been described by C.F. Bell et al. in 2023. Earlier, in 2022, the decreasing of 5-year mortality from cancer in similar range of tissues discussed by us as the inverse dependence from the content of stem CD34 markers in tissues before malignization, with example of population in England. In present article we investigate the interrelation between both data more thoroughly, using accessible and more representative populations level of the data. The analysis shows that high level of HRCVD is able to predicts only high cancer death for tissue sites in the beginning of the range, being applied to the referent data of cancer cases and deaths in estimated population of USA 2024. Along with this, an increasing the content of CD34 stem marker in the native tissues of the same range was favorite for increasing of cancer’s cases at the end of the range, diminishing, in parallel, the signs of vasculo-endothelial pathology, i.e. HR CVD. Thus, the cases (incidence) of cancer depend directly rather from content of CD34, which preexisted in native sites, than that from HRCVD. Further analysis shows that CD34 content averaged over twenty cites dominates over that CD2 marker of total T-cells more than 7 times, in oppose to their ratio in the blood. The enhancement of stem CD34 marker in the range of tissues is accompanied by unidirectional rising of its maturing derivatives, vasculo-endothelial CD31 and total T-cells CD2 markers, which contents relate positively to increasing of cancer death in US population 2024. The increase of CD34 decreases cancer mortality (death: cases) in

关键词： Population Cardiovascular Pathology Cancers Interrelation Tissues CD Markers Prognostic Value Revision

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Generation,interrogation,and future applications of microglia-containing brain organoids

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Neural Regeneration Research 2025年第12期20卷 3448-3460页

作者： Julia Di Stefano Federica Di Marco Ilaria Cicalini Una FitzGerald Damiana Pieragostino Marleen Verhoye Peter Ponsaerts Elise Van Breedam Laboratory of Experimental Hematology Vaccine and Infectious Disease Institute(Vaxinfectio)University of AntwerpWilrijkBelgium Bio-Imaging Lab University of AntwerpWilrijkBelgium center for Advanced Studies and Technology(CAST) G.d’Annunzio University of Chieti-PescaraChietiItaly Department of Innovative technologies in Medicine and Dentistry University“G.d’Annunzio”of Chieti-PescaraChietiItaly CÚRAM Center for Research in Medical DevicesBiomedical EngineeringUniversity of GalwayIreland Galway Neuroscience center University of GalwayIreland μNEURO Research center of Excellence University of AntwerpWilrijkBelgium

Brain organoids encompass a large collection of in vitro stem cell–derived 3D culture systems that aim to recapitulate multiple aspects of in vivo brain development and ***,this review provides a brief introduction to the current state-of-the-art for neuroectoderm brain organoid development,emphasizing their biggest advantages in comparison with classical two-dimensional cell cultures and animal ***,despite their usefulness for developmental studies,a major limitation for most brain organoid models is the absence of contributing cell types from endodermal and mesodermal *** such,current research is highly investing towards the incorporation of a functional vasculature and the microglial immune *** this review,we will specifically focus on the development of immune-competent brain *** summarizing the different approaches applied to incorporate microglia,it is highlighted that immune-competent brain organoids are not only important for studying neuronal network formation,but also offer a clear future as a new tool to study inflammatory responses in vitro in 3D in a brainlike ***,our main focus here is to provide a comprehensive overview of assays to measure microglial phenotype and function within brain organoids,with an outlook on how these findings could better understand neuronal network development or restoration,as well as the influence of physical stress on microglia-containing brain ***,we would like to stress that even though the development of immune-competent brain organoids has largely evolved over the past decade,their full potential as a pre-clinical tool to study novel therapeutic approaches to halt or reduce inflammation-mediated neurodegeneration still needs to be explored and validated.

关键词： 3D cell culture brain organoids immune response immunocompetent model in vitro model microglia neural organoids neuroimmunology neuroinflammation

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