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Steric hindrance modulation of hexaazatribenzanthraquinone isomers for high-capacity and wide-temperature-range aqueous proton battery

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National Science Review 2024年第4期11卷 271-282页

作者： Mingsheng Yang Yuxin Hao Bei Wang Yan Wang Liping Zheng Rui Li Huige Ma Xinyu Wang Xiaoming Jing Hongwei Li Mengxiao Li Zhihui Wang Yujie Dai Guangcun Shan Mingjun Hu Jun Luo Jun Yang School of Materials Science and Engineering Beihang University Beijing Institute of nanoenergy &Nanosystems Chinese Academy of Sciences center on nanoenergy research School of Physical Science & TechnologyGuangxi University School of Chemistry and Chemical Engineering Center on Nanoenergy Research Guangxi University School of Instrumentation Science and Opto-electronics Engineering Beihang University ShenSi Lab Shenzhen Institute for Advanced StudyUniversity of Electronic Science and Technology of China

Organic materials with rich active sites are good candidates of high-capacity anodes in aqueous batteries,but commonly low utilization of active sites limits their capacity.Herein,two isomers,symmetric and asymmetric hexaazatribenzanthraquinone（s-HATBAQ and a-HATBAQ）,with rich active sites have been synthesized in a controllable manner.It has been revealed for the first time that a sulfuric acid catalyst can facilitate the stereoselective formation of s-HATBAQ.Attributed to the reduced steric hindrance in favor of proton insertion as well as the amorphous structure conducive to electrochemical dynamics,s-HATBAQ exhibits 1.5 times larger specific capacity than a-HATBAQ.Consequently,the electrode of s-HATBAQ with50% reduced graphene oxide（s-HATBAQ-50%rGO） delivers a record high specific capacity of405 mAh g-1in H2SO4electrolyte.Moreover,the assembled MnO2//s-HATBAQ-50%rGO aqueous proton full batteries show an exceptional cycling stability at 25℃ and can maintain ～92% capacity after1000 cycles at 0.5 A g-1at-80℃.This work demonstrates the controllable synthesis of isomers,showcases a wide-temperature-range prototype proton battery and highlights the significance of precise mole cular structure modulation in organic energy storage.

关键词： stereoisomers steric effect aqueous battery super cycling stability ultra-low temperature proton battery

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Regulated polarization degree of upconversion luminescence and multiple anti-counterfeit applications

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Rare Metals 2024年第5期43卷 2172-2183页

作者： Dong-Ping Wen Ping Chen Yi Liang Xiao-Ming Mo Cao-Feng Pan center on nanoenergy research Guangxi Key Laboratory for Relativistic Astrophysics School of Physical Science and Technology Guangxi University Key Laboratory of Micronano Energy and Sensor CAS Center for Excellence in Nanoscience Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of Sciences

Polarization upconversion luminescence（PUCL） of lanthanide ions (Ln3+) has been widely used in single particle tracking,microfluidics detection,three-dimensional displays,and so on.However,no effective strategy has been developed for modulating PUCL.Here we report a strategy to regulate PUCL in Ho3+-doped NaYF4single nanorods based on the number of upconversion photons.By constructing a multiphoton upconversion system for Ho3+,we regulate the degree of polarization （DOP） of PUCL from 0.590 for two-photon luminescence to 0.929 for three-photon upconversion luminescence （UCL）.Furthermore,our strategy is verified from cross-relaxation between Ho3+and Yb3+,excitation wavelength,excitation power density,and local site symmetry.And this regulation strategy of PUCL has also been achieved in Tm3+,with the DOP ranging from 0.233 for two-photon luminescence to 0.925 for four-photon UCL Besides,multi-dimensional anti-counterfeiting display has been explored with PUCL.This work provides an effective strategy for regulating PUCL and also provides more opportunities for the development of polarization display optical encoding,anti-counterfeiting,and integrated optical devices.

关键词： Polarization upconversion luminescence Degree of polarization Population density of excited state Number of upconversion photons Polarization anti-counterfeiting display

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High precision patternable liquid metal based conductor and adhesive substrate enabled stretchable hybrid systems

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Nano research 2024年第6期17卷 5595-5603页

作者： Runhui Zhou Jiaoya Huang Zemin Li Yushu Wang Ziyu Chen Caofeng Pan CAS center for Excellence in Nanoscience Beijing Key Laboratory of Micro-nano Energy and SensorBeijing Institute of Nanoenergy and NanosystemsChinese Academy of SciencesBeijing 101400China School of Nanoscience and Engineering University of Chinese Academy of SciencesBeijing 100049China center on nanoenergy research School of Physical Science and TechnologyGuangxi UniversityNanning 530004China Institute of Atomic Manufacturing Beihang UniversityBeijing 100191China

Stretchable hybrid systems have been attracting tremendous attention for their essential role in soft robotics,on-skin electronics,and implantable devices.Both rigid and soft functional modules are typically required in those devices.Consequently,ensuring stable electrical contact between rigid and soft modules is a vital part.Here,we propose a simple,universal,and scalable strategy for the stretchable hybrid system through a highly precise printable liquid metal particle-based conductor and adhesive fluorine rubber substrate.The properties of liquid metal particle-based conductors could be easily tuned to realize high-precision patterning,large-scale printing,and the ability to print on various substrates.Additionally,the fluorine rubber substrate could form strong interfacial adhesion with various components and materials through simply pressing and heating,hence enabling stable electrical contact.Furthermore,we prepared a stretchable hybrid light-emitting diode(LED)display system and employed it in on-skin visualization of pressure levels,which perfectly combined rigid and soft modules,thus demonstrating the promising potential applications in complex multifunctional stretchable hybrid systems for emerging technologies.

关键词： stretchable hybrid systems liquid metal high precision interfacial adhesion

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Robust autofocusing propagation in turbulence

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Chinese Physics B 2024年第6期33卷 370-375页

作者：刘娜娜谭柳陈凯健洪佩龙莫小明邹炳锁任煜轩梁毅 Guangxi Key Laboratory for Relativistic Astrophysics Center on Nanoenergy ResearchSchool of Physical Science and TechnologyGuangxi UniversityNanning 530004China School of Mathematics and Physics Anqing Normal UniversityAnqing 246133China Institute for Translational Brain research MOE Frontiers Center for Brain ScienceFudan UniversityShanghai 200032China

Turbulence in complex environments such as the atmosphere and biological media has always been a great challenge to the application of beam propagation in optical communication, optical trapping and manipulation. To overcome this challenge, this study comprehensively investigates the robust propagation of traditional Gaussian and autofocusing beams in turbulent environments. In order to select stable beams that exhibit high intensity and high field gradient at the focal position in complex environments, Kolmogorov turbulence theory is used to simulate the propagation of beams in atmospheric turbulence based on the multi-phase screen method. We systematically analyze the intensity fluctuations, the variation of the coherence factor and the change in the scintillation index with propagation distance. The analysis reveals that the intensity fluctuations of autofocusing beams are significantly smaller than those of Gaussian beams, and the coherence of autofocusing beams is better than that of Gaussian beams under turbulence. Moreover, autofocusing beams exhibit less oscillation than Gaussian beams, indicating that autofocusing beams propagate in complex environments with less distortion and intensity fluctuation. Overall, this work clearly demonstrates that autofocusing beams exhibit higher stability in propagation compared with Gaussian beams, showing great promise for applications such as optical trapping and manipulation in complex environments.

关键词： propagation beams autofocusing turbulence

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Flexo-photocatalysis in centrosymmetric semiconductors

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Nano research 2024年第3期17卷 1173-1181页

作者： Kang Liu Tong Wu Luying Xu Zhuangzhuang Zhang Zhiyu Liu Longfei Wang Zhong Lin Wang center on nanoenergy research School of Physical Science&TechnologyGuangxi UniversityNanning 530004China Beijing Institute of nanoenergy and Nanosystems Chinese Academy of SciencesBeijing 101400China College of Nanoscience and Technology University of Chinese Academy of SciencesBeijing 100049China Georgia Institute of Technology AtlantaGA 30332-0245USA Yonsei Frontier Lab Yonsei UniversitySeoul 03722Republic of Korea

The separation of photogenerated electron–hole pairs is vitally important for photocatalysis,which can be effectively promoted by polarization field.However,it only manifests in piezoelectric/pyroelectric/ferroelectric materials that have a non-centrosymmetric structure.Here,we demonstrate that the polarization enhanced photocatalysis(with wide spectra from ultraviolet(UV)light to visible light)can be achieved in centrosymmetric semiconductors,such asδ-MnO_(2) and TiO_(2) nanosheets integrated nanoflowers,by using the strain-gradient-induced flexoelectric polarization that is always overlooked in polarization-enhanced catalysis.Under ultrasonic and illumination excitation,the organic pollutants(methylene blue(MB),etc.)can be effectively degraded within 30 min with excellent stability and repeatability.Compared with photocatalysis,the flexo-photocatalytic performance of above centrosymmetric semiconductors is substantially increased by 85%.Moreover,the factors related to flexo-photocatalysis such as material morphology,mechanical stimuli source,and adsorption are explored to deeply understand the mechanism of flexo-photocatalysis.This work opens up a way for high-performance photocatalysis in centrosymmetric semiconductors.

关键词： piezo-photocatalysis photocatalysis flexoelectricity polarization centrosymmetric semiconductor

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Intelligent Recognition Using Ultralight Multifunctional Nano‑Layered Carbon Aerogel Sensors with Human‑Like Tactile Perception

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Nano-Micro Letters 2024年第1期16卷 172-186页

作者： Huiqi Zhao Yizheng Zhang Lei Han Weiqi Qian Jiabin Wang Heting Wu Jingchen Li Yuan Dai Zhengyou Zhang Chris RBowen Ya Yang CAS center for Excellence in Nanoscience Beijing Key Laboratory of Micro‑Nano Energy and SensorBeijing Institute of Nanoenergy and NanosystemsChinese Academy of SciencesBeijing 101400People’s Republic of China Tencent Robotics X Shenzhen 518054People’s Republic of China School of Nanoscience and Technology University of Chinese Academy of SciencesBeijing 100049People’s Republic of China Department of Mechanical Engineering University of BathBath BA27AKUK center on nanoenergy research School of Physical Science and TechnologyGuangxi UniversityNanning 530004People’s Republic of China

Humans can perceive our complex world through multi-sensory fusion.Under limited visual conditions,people can sense a variety of tactile signals to identify objects accurately and rapidly.However,replicating this unique capability in robots remains a significant challenge.Here,we present a new form of ultralight multifunctional tactile nano-layered carbon aerogel sensor that provides pressure,temperature,material recognition and 3D location capabilities,which is combined with multimodal supervised learning algorithms for object recognition.The sensor exhibits human-like pressure(0.04–100 kPa)and temperature(21.5–66.2℃)detection,millisecond response times(11 ms),a pressure sensitivity of 92.22 kPa^(−1)and triboelectric durability of over 6000 cycles.The devised algorithm has universality and can accommodate a range of application scenarios.The tactile system can identify common foods in a kitchen scene with 94.63%accuracy and explore the topographic and geomorphic features of a Mars scene with 100%accuracy.This sensing approach empowers robots with versatile tactile perception to advance future society toward heightened sensing,recognition and intelligence.

关键词： Multifunctional sensor Tactile perception Multimodal machine learning algorithms Universal tactile system Intelligent object recognition

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A near-zero quiescent power breeze wake-up anemometer based on a rolling-bearing triboelectric nanogenerator

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Microsystems & Nanoengineering 2024年第2期10卷 241-249页

作者： Xianpeng Fu Zhichao Jiang Jie Cao Zefang Dong Guoxu Liu Meiling Zhu Chi Zhang CAS center for Excellence in Nanoscience Beijing Key Laboratory of Micro-nano Energy and SensorBeijing Institute of Nanoenergy and NanosystemsChinese Academy of SciencesBeijing101400China School of Nanoscience and Engineering University of Chinese Academy of SciencesBeijing100049China center on nanoenergy research Guangxi Colleges and Universities Key Laboratory of Blue Energy and Systems IntegrationSchool of Physical Science&TechnologyGuangxi UniversityNanning530004China Institute of Intelligent Flexible Mechatronics Jiangsu UniversityZhenjiang212013China College of Engineering Mathematics and Physical ScienceUniversity of ExeterExeterEX44QFUK

Wind sensors have always played an irreplaceable role in environmental information monitoring and are expected to operate with lower power consumption to extend service lifetime.Here,we propose a breeze wake-up anemometer(B-WA)based on a rolling-bearing triboelectric nanogenerator(RB-TENG)with extremely low static power.The B-WA consists of two RB-TENGs,a self-waking-up module(SWM),a signal processing module(SPM),and a wireless transmission unit.The two RB-TENGs are employed for system activation and wind-speed sensing.Once the ambient wind-speed exceeds 2 m/s,the wake TENG(W-TENG)and the SWM can wake up the system within 0.96 s.At the same time,the SPM starts to calculate the signal frequency from the measured TENG(M-TENG)to monitor the wind speed with a sensitivity of 9.45 Hz/(m/s).After the wind stops,the SWM can switch off the B-WA within 0.52 s to decrease the system energy loss.In quiescent on-duty mode,the operating power of the B-WA is less than 30 nW,which can greatly extend the service lifetime of the B-WA.By integrating triboelectric devices and rolling bearings,this work has realized an ultralow quiescent power and self-waked-up wireless wind-speed monitoring system,which has foreseeable applications in remote weather monitoring,IoT nodes,and so on.

关键词： generator power service

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Improvement in hydrogen storage performance of MgH2 by vanadium doped with ZIF-8 derived a single-atom catalyst V-N-C

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Rare Metals 2024年第6期43卷 2623-2635页

作者： Fei-Fan Hong Wei-Tao Shi Ruo-Lin Zhao Yi Fan Zi-Qi Liu Si-Zhi Ding Hai-Zhen Liu Wen-Zheng Zhou Jin Guo Zhi-Qiang Lan Guangxi Novel Battery Materials research center of Engineering Technology and center on nanoenergy research Guangxi Colleges and Universities Key Laboratory of Blue Energy and Systems IntegrationCarbon Peak and Neutrality Science and Technology Development InstituteSchool of Physical Science and TechnologyGuangxi University Nanning Engineering Technology research center for Power Transmission System of New Energy Vehicle Transportation CollegeNanning University

Herein,the successful preparation of a singleatom catalyst V-N-C using vanadium-doped zeolitic imidazolate framework（ZIF）-8 as a precursor is reported.The experimental results showed that the V-N-C had a good promoting effect on the hydrogen storage performance of MgH2,and the optimal addition amount of V-N-C was 10wt%.The hydrogenation and dehydrogenation apparent activation energies of 10 wt% V-N-C-catalyzed MgH2were reduced by 44.9 and 53.5 kJ·mol-1,respectively,compared to those of additive-free MgH2.The 10 wt% V-N-C-catalyzed MgH2could reabsorb 5.92 wt% of hydrogen in 50 min at 150℃,with a capacity retention rate of 99.1% after 30 cycles of hydrogen absorption and desorption.Mechanism analysis showed that V-N-C was partially transformed into VN and metallic V when it was milled with MgH2;the in-situ-formed VN and metallic V played an important role in improving the hydrogen storage performance of MgH2.This approach provides a potential solution for obtaining high-performance Mg-based hydrogen storage materials through synergistic interactions between V,N and C.

关键词： MgH 2 Hydrogen storage materials Catalyst Hydrogen storage perormance

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A columnar multi-layer sliding triboelectric nanogenerator for water wave energy harvesting independent of wave height and direction

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Nano research 2024年第4期17卷 3029-3034页

作者： Xue Miao Hanxiao Yang Zekun Li Meifei Cheng Yilin Zhao Lingyu Wan Aifang Yu Junyi Zhai center on nanoenergy research School of Physical Science and TechnologyGuangxi UniversityNanning 530004China Beijing Institute of Nano Energy and Nano Systems Chinese Academy of SciencesBeijing 101400China School of Nanoscience and Engineering University of Chinese Academy of ScienceBeijing 101408China

The ocean,with its highly variable and complex meteorological conditions,harbors enormous renewable resources.Triboelectric nanogenerators(TENGs),which possess unique advantages,show exciting prospects in water wave energy collection.How to design and optimize TENGs to cover all characteristic water wave energies and achieve efficient energy utilization is emergent.In this paper,we carefully designed and fabricated a columnar multi-layer sliding TENG(CMLS-TENG)that can harvest water wave energy independent of wave height and direction.Drive rods with a hollow acrylic spherical shell were introduced to deliver wave energy,ensuring that the CMLS-TENG can work in all directions from 0°to 360°.Based on the sliding structure,switching the optimized CMLS-TENG is independent of wave heights.The optimized CMLS-TENG can achieve a total power density of 730 mW/m^(3) at a wave height of only 4.8 cm regardless of wave direction,which can illuminate multiple light-emitting diodes(LEDs)to provide lighting and provide power to a watch and a hygrometer for temperature and humidity monitoring.This work provides new choices and hopes for the effective collection of full-range water wave energy.

关键词： triboelectric nanogenerator wave energy multi-direction columnar slide

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Optical trapping capability of tornado circular Pearcey beams

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Chinese Physics B 2024年第5期33卷 401-407页

作者：刘娜娜唐晓莹刘舜禹梁毅 Guangxi Key Laboratory for Relativistic Astrophysics Center on Nanoenergy ResearchGuangxi Colleges and Universities Key Laboratory of Blue Energy and Systems IntegrationSchool of Physical Science and TechnologyGuangxi UniversityNanning 530004China State Key Laboratory of Featured Metal Materials and Lifecycle Safety for Composite Structures Nanning 530004China

We systemically investigate optical trapping capability of a kind of tornado waves on Rayleigh particles.Such tornado waves are named as tornado circular Pearcey beams(TCPBs)and produced by combining two circular Pearcey beams with different radii.Our theoretical exploration delves into various aspects,including the propagation dynamics,energy flux,orbital angular momentum,trapping force,and torque characteristics of TCPBs.The results reveal that the orbital angular momentum,trapping force,and torque of these beams can be finely tuned through the judicious manipulation of their topological charges(l_(1)and l_(2)).Notably,we observe a precise control mechanism wherein the force diminishes with|l_(1)+l_(2)|and|l_(1)-l_(2)|,while the torque exhibits enhancement by decreasing solely with|l_(1)+l_(2)|or increasing with|l_(1)-l_(2)|.These results not only provide quantitative insights into the optical trapping performance of TCPBs but also serve as a valuable reference for the ongoing development of innovative photonic tools.

关键词： trapping capability tornado beams autofocusing

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