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Ln3+(Ln=Eu,Dy)-doped Sr2CeO4 fine phosphor particles:Wet chemical preparation,energy transfer and tunable luminescence

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Journal of Rare Earths 2020年第12期38卷 1273-1280页

作者： Na Gao Yanfei Yang Shikao Shi Jiye Wang Shuping Wang Jibiao Li Lianshe Fu Key Laboratory of Inorganic Nanomaterials of Hebei Province College of Chemistry and Materials ScienceHebei Normal UniversityShijiazhuang 050024China Physics Department and ciceco-aveiro institute of materials University of Aveiro3810-193AveiroPortugal

The Sr2 CeO4:Ln3+(Ln=Eu,Dy)fine phosphor particles were prepared by a facile wet chemical approach,in which the consecutive hydrothermal-combustion reaction was *** doping of Ln3+into Sr2 CeO4 has little influence on the structure of host,and the as-prepared samples display wellcrystallized spherical or elliptical shape with an average particle size at about 100-200 *** Eu3+ions-doped Sr2 CeO4,with the increase of Eu3+-doping concentration,the blue light emission band with the maximum at 468 nm originating from a Ce4+→O2-charge transfer of the host decreases obviously and the characteristic red light emission of Eu3+(5 D0→7 F2 transition at 618 nm)is enhanced ***,the fluorescent lifetime of the broadband emission of Sr2 CeO4 decreases with the doping of Eu3+,indicating an efficient energy transfer from the host to the doping Eu3+*** ene rgy transfer efficiency from the host to Eu3+was investigated in detail,and the emitting color of Sr2 CeO4:Eu3+can be easily tuned from blue to red by varying the doping concentration of Eu3+***,the luminescence of Dy3+-doped Sr2 CeO4 was also *** energy transfer pheno menon can be observed,and the incorporation of Dy3+into Sr2 CeO4 host leads to the characteristic emission of 4 F9/2→6 H15/2(488 nm,blue light)and 4 F9/2→6 H13/2(574 nm,yellow light)of Dy3+.The Sr2 CeO4:Ln3+fine particles with tunable luminescence are quite beneficial for its potential applications in the optoelectronic fields.

关键词： Wet chemistry preparation Sr2CeO4 Ln3+ion Phosphor Luminescence Energy transfer

Coating independent cytotoxicity of citrate-and PEG-coated silver nanoparticles on a human hepatoma cell line

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Journal of Environmental Sciences 2017年第1期29卷 191-201页

作者： Veronica Bastos Jose M.P.Ferreira-de-Oliveira Joana Carrola Ana L.Daniel-da-Silva Iola F.Duarte Conceicao Santos Helena Oliveira CESAM&Laboratory of Biotechnology and Cytomics Department of BiologyUniversity of Aveiro3810-193 AveiroPortugal ciceco-aveiro institute of materials Department of ChemistryUniversity of Aveiro3810-193 AveiroPortugal Department of Biology Faculty of SciencesUniversity of Porto4169-007 PortoPortugal

The antibacterial potential of silver nanoparticles（AgNPs） resulted in their increasing incorporation into consumer,industrial and biomedical ***,human and environmental exposure to AgNPs（either as an engineered product or a contaminant）supports the emergent research on the features conferring them different toxicity *** this study,30 ran AgNPs coated with citrate or poly（ethylene glycol）（PEG） were used to assess the influence of coating on the effects produced on a human hepatoma cell line（HepG2）,namely in terms of viability,apoptosis,apoptotic related genes,cell cycle and cyclins gene *** types of coated AgNPs decreased cell proliferation and viability with a similar toxicity *** the concentrations used（11 and 5 μg/mL corresponding to IC50 and-IC10 levels,respectively） the amount of cells undergoing apoptosis was not significant and the apoptotic related genes BCL2（anti-apoptotic gene）and BAX（pro-apoptotic gene） were both ***,both AgNPs affected HepG2 cell cycle progression at the higher concentration（11 μg/mL） by increasing the percentage of cells in S（synthesis phase） and G2（Gap 2 phase） *** the cell-cycle related genes,the expression of cyclin B1 and cyclin E1 genes were ***,this work has shown that citrate- and PEG-coated AgNPs impact on HepG2 apoptotic gene expression,cell cycle dynamics and cyclin regulation in a similar *** research is needed to determine the properties that confer AgNPs at lower toxicity,since their use has proved helpful in several industrial and biomedical contexts.

关键词： Silver nanoparticles(AgNPs) Citrate Polyethylene glycol)(PEG) HepG2 cells Cytotoxicity Nanotoxicology

Novel lanthanide coordination polymers based on mixed N,O-donor ligands and their visible-light-driven photocatalytic performance

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Journal of Rare Earths 2023年第1期41卷 85-90页

作者： Jun Chen Weizhi Kou Shunsheng He Chenlan Lin Xin Wang Lianshe Fu Ting-Hai Yang Jiangsu Laboratory of Precious Metals Processing Technology and Application School of Chemistry&Environmental EngineeringJiangsu University of TechnologyChangzhou 213001China Department of Physics CICECO-Aveiro Institute of MaterialsUniversity of Aveiro3810-193AveiroPortugal

In the present work,we prepared three isostructural lanthanide(Ln) coordination polymers(CPs).namely [Ln(Hhpc)(phen)(NO_(3))](Ln=Gd(1),La(2),Y(3),H_(3)hpc=5-hydroxy-1 H-pyrazole-3-carboxyIic acid,phen=1,10-phenanthroline) by hydrothermal *** structures were characterized by single crystal X-ray diffraction,Fourier transform infrared spectrum,elemental analysis,powder X-ray diffraction and thermal gravimetric *** 1-3 are isostrutural and exhibit two-dimensional(2 D)wavy layered structure constructed from inorganic chains,in which equivalent eight coordinated Ln^(3+) ions are linked through carboxylate *** three dimensional supramolecular structure is further formed by hydrogen *** photocatalytic experiments show that CPs 2 and 3 exhibit good photocatalytic performances under visible light in degradation of methylene blue organic *** photocatalytic degradation efficiencies in 90 min are about 86.19% and 93.60% for CPs 2 and 3,*** photocatalytic degradation mechanisms have been proposed through photoelectrochemical and trapping radical experiments.

关键词： Lanthanides Coordination polymers Photocatalytic degradation Pyrazole carboxylic acid Rare earths

Sticky-MARTINI as a reactive coarse-grained model for molecular dynamics simulations of silica polymerization

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npj Computational materials 2022年第1期8卷 467-479页

作者： AndréP.Carvalho Sérgio M.Santos Germán Pérez-Sánchez JoséD.Gouveia JoséR.B.Gomes Miguel Jorge ciceco-aveiro institute of materials Department of ChemistryUniversity of AveiroCampus Universitário de Santiago3810-193AveiroPortugal Department of Chemical and Process Engineering University of Strathclyde75 Montrose StreetGlasgowG11XJUK

We report a molecular modeling paradigm to describe silica polymerization reactions in aqueous solutions at conditions that are representative of realistic experimental processes like biosilicification or porous silica synthesis–*** close to ambient temperatures and over a wide range of *** key point is to describe the Si-O-Si chemical bond formation and breakage processes through a continuous potential with a balance between attractive and repulsive interactions between suitably placed virtual sites and sticky *** simplicity of the model,its applicability in standard parallelized molecular dynamics codes,and its compatibility with the widely used MARTINI coarse-grained force-field allows for the study of systems containing millions of atoms over microsecond time *** model is calibrated to match experimental results for the temporal evolution of silica polymerization in aqueous solution close to the isoelectric point,and can describe silica polymerization and self-assembly processes during encapsulation of a surfactant micelle.

关键词： silica polymerization dynamics

Hybrid Triboelectric-Electromagnetic Nanogenerators for Mechanical Energy Harvesting:A Review

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Nano-Micro Letters 2021年第12期13卷 163-220页

作者： Joao V.Vidal Vladislav Slabov Andrei L.Kholkin Marco P.Soares dos Santos Department of Physics and ciceco-aveiro institute of materials University of Aveiro3810-193 AveiroPortugal Department of Physics and I3N University of Aveiro3810-193 AveiroPortugal Laboratory of Functional Low-Dimensional Structures National University of Science and Technology MISISMoscowRussia Department of Mechanical Engineering Centre for Mechanical Technology and Automation(TEMA)University of Aveiro3810-193 AveiroPortugal

Motion-driven electromagnetictriboelectric energy generators(E-TENGs) hold a Hybrid triboelectric-electromagnetic generators C A Bgreat potential to provide higher voltages,higher currents and wider operating bandwidths than Cantilever generators1 μm both electromagnetic and triboelectric generators Rotating generatorsSliding generators standing alone. Therefore,they are promising solutions to autonomously supply a broad range of Flexible blade generators Magnetoelectric highly sophisticated devices. This paper provides generators a thorough review focused on major recent breakLinear generators Multidimensional generators throughs in the area of electromagnetic-triboelectric vibrational energy harvesting. A detailed Pendulum generators analysis was conducted on various architectures including rotational,pendulum,linear,sliding,cantilever,flexible blade,multidimensional and 1 cm magnetoelectric,and the following hybrid technologies. They enable highly e cient ways to harvest electric energy from many forms of vibrational,rotational,biomechanical,wave,wind and thermal sources,among others. Open-circuit voltages up to 75 V,short-circuit currents up to 60 mA and instantaneous power up to 144 mW were already achieved by these nanogenerators. Their transduction mechanisms,including proposed models to make intelligible the involved physical phenomena,are also overviewed here. A comprehensive analysis was performed to compare their respective construction designs,external excitations and electric outputs. The results highlight the potential of hybrid E-TENGs to convert unused mechanical motion into electric energy for both large-and small-scale ***,this paper proposes future research directions toward optimization of energy conversion e ciency,power management,durability and stability,packaging,energy storage,operation input,research of transduction mechanisms,quantitative standardization,system integration,miniaturization and multi-energy hybrid cells.

关键词： E-TENG Hybrid triboelectric-electromagnetic Nanogenerators Energy harvesting

As-cast and extruded Mg-Zn-Ca systems for biodegradable implants:Characterization and corrosion behavior

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Journal of Magnesium and Alloys 2023年第3期11卷 1102-1120页

作者： Lara Moreno Endzhe Matykina Kiryl A.Yasakau Carsten Blawert Raul Arrabal Marta Mohedano Departamento de Ingeniería Química y de Materiales Facultad de Ciencias QuímicasUniversidad Complutense de Madrid28040 MadridSpain Department of materials and Ceramic Engineering CICECO-Aveiro institute of materialsUniversity of Aveiro3810-193 AveiroPortugal institute of Surface Science Helmholtz-Zentrum HereonMax-Planck Strasse 1Geesthacht 21502Germany

The aim of the present study is to evaluate the effect of alloy processing and composition as well as the pH control and testing medium on the in vitro corrosion performance of Mg-Zn-Ca systems for biodegradable *** grain size and secondary phases were analyzed by optical microscopy,scanning electron microscopy,transmission electron microscopy,and X-ray *** kelvin probe force microscopy(SKPFM)was used to analyze the Volta potential values of the second *** corrosion performance of the three alloys was evaluated by electrochemical and hydrogen evolution methods inα-MEM with and without organic species(*** and inorganicα-MEM).Two strategies were followed to evaluate the influence of the pH on the corrosion behavior:daily solution replacement and CO_(2)flow based pH *** all the materials,the organic medium accelerates the corrosion *** pH maintained by CO_(2)flow through the medium results in considerably higher corrosion rates for all *** impact of pH is lesser on the as-cast alloys due to the barrier effect of the secondary phases,particularly pronounced in the Mg1Zn1Ca alloy which showed the lowest corrosion *** wrought Mg0.5Zn0.2Ca alloy that lacks the refined secondary phase network and exhibits high number of twins undergoes accelerated uniform corrosion under constant pH conditions.

关键词： MgZnCa Magnesium Biomaterials Characterization Corrosion

Natural and Eco-Friendly materials for Triboelectric Energy Harvesting

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Nano-Micro Letters 2020年第3期12卷 179-196页

作者： Vladislav Slabov Svitlana Kopyl Marco PSoares dos Santos Andrei L.Kholkin Department of Physics and ciceco‑aveiro institute of materials University of Aveiro3810‑193 AveiroPortugal Centre for Mechanical Technology and Automation(TEMA) University of Aveiro3810‑193 AveiroPortugal Department of Mechanical Engineering University of Aveiro3810‑193 AveiroPortugal School of Natural Sciences and Mathematics Ural Federal UniversityEkaterinburgRussia 620000 Laboratory of Functional Low‑Dimensional Structures National University of Science and Technology MISiSMoscowRussia 119049

Triboelectric nanogenerators(TENGs)are promising electric energy harvesting devices as they can produce renewable clean energy using mechanical excitations from the *** designs of triboelectric energy harvesters relying on biocompatible and eco-friendly natural materials have been introduced in recent *** ability to provide customizable self-powering for a wide range of applications,including biomedical devices,pressure and chemical sensors,and battery charging appliances,has been *** review summarizes major advances already achieved in the field of triboelectric energy harvesting using biocompatible and eco-friendly natural materials.A rigorous,comparative,and critical analysis of preparation and testing methods is also *** power up to 14 mW was already achieved for the dry leaf/polyvinylidene fluoride-based TENG *** findings highlight the potential of eco-friendly self-powering systems and demonstrate the unique properties of the plants to generate electric energy for multiple applications.

关键词： Natural and eco-friendly materials Energy harvesting Triboelectric nanogenerators Biocompatibility

A comparative study on emergent pollutants photo-assisted degradation using ruthenium modified titanate nanotubes and nanowires as catalysts

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Journal of Environmental Sciences 2020年第6期32卷 38-51页

作者： Beatriz Barrocas M.Conceicao Oliveira Helena I.S.Nogueira Sara Fateixa Olinda C.Monteiro Centro de Química Estrutural Faculdade de CienciasUniversidade de LisboaLisboa 1749-016Portugal Centro Química Estrutural Instituto Superior TécnicoUniversidade de LisboaLisboa 1049-001Portugal Department of Chemistry CICECO-Aveiro Institute of MaterialsUniversity of AveiroAveiro 3810-193Portugal

Several methods have been used to tailor nanomaterials structure and ***,slight changes in the structure outcomes expressive improvements in the optical and photocatalytic properties of semiconductor *** this context,the influence of the metal doping and the morphology on a catalyst performance was studied in this ***,ruthenium doped titanate nanotubes(RuTNT)were synthesised for the first time using an amorphous Ru-containing ***,the photocatalytic performance of this sample was compared to the one obtained for ruthenium titanate nanowires(RuTNW),recently *** samples,RuTNW and RuTNT,were produced using the same Ru-containing precursor but distinct hydrothermal *** powders were structural,morphological and optical characterized by X-ray diffraction and fluorescence,transmission electron microscopy,Raman,X-ray photoelectron and photoluminescence *** variations on the structural and optical properties of the RuTNT and RuTNW nanoparticles,due to ruthenium incorporation were *** potential use as photocatalysts was evaluated on the hydroxyl radical photo-assisted *** samples were catalytic for this reaction,presenting better performances than the pristine counterparts,being RuTNT the best ***,the degradation of two emergent pollutants,caffeine and sulfamethazine,was *** demonstrated to be better photocatalyst than RuTNW for caffeine but identical performances were obtained for *** both catalysts,the degradation mechanism of the pollutants was explored through the identification and quantification of the intermediate compounds produced and several differences were *** indicates the importance of the structural and morphological aspects of a material on its catalytic performance.

关键词： Titanate nanotubes and nanowires Ruthenium doping Ru-Ti replacement Emergent pollutants Photocatalytic degradation

Biocompatibility and biotoxicity of in-situ synthesized carboxylated nanodiamond-cobalt oxide nanocomposite

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Journal of materials Science & Technology 2017年第8期33卷 879-888页

作者： L.Syam Sundar Naser A.Anjum M.C.Ferro Eduarda Pereira Manoj K.Singh A.C.M.Sousa TEMA-Department of Mechanical Engineering University ofAveiroAveiroPortugal CESAM-Centrefor Environmental&Marine Studies and Department of Chemistry University of Aveiro3810-193AveiroPortugal ciceco Department of Material Engineering and CeramicsUniversity of AveiroPortugal

A nanocomposite that incorporates cobalt oxide（Co3O4） and nanodiamond（ND） can present both high magnetism（Co3O4） and high hardness（ND）. ND particles have potential applications in a variety of fields such as protein immobilization, biosensors, therapeutic molecule delivery and bio-imaging. However,limited information is available in literature on the in-situ synthesis of biocompatible magnetic materials and also on their potential biotoxicity as a result of their entry into environmental compartments and subsequent interaction with biota. In this work, a new kind of bio-compatible magnetic material –carboxylated nanodiamond（c ND） and Co3O4 was synthesized to obtain the c ND-Co3O4 *** synthesis procedure involved in-situ and chemical reduction of cobalt chloride（CoCl（26）H2O） and sodium borohydrate（NaBH4）. The synthesized cND-Co3O4 nanocomposite was characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and X-ray photoelectron spectroscopy. The cyto-genotoxicity of the synthesized nanocomposite material was studied by using onion（Allium cepa L.） as a test model with concentrations of 5, 10 and 20 μg/ml. The study was also extended to cND and Co3O4 materials for comparison purpose. Co3O4 and cND exhibited their contrasting effects on mitosis and other cyto-genotoxic indices studied herein. This work provided fundamental data on the synthesis and the bio-toxicity of the c ND-Co3O4 nanocomposite, which, in turn, can help to expand their multidisciplinary applications.

关键词： Nanodiamond Cobalt oxide Nanodiamond Nanocomposite Bio-toxicity Allium cepa