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Mechanistic insight into the synergy between nickel single atoms and nanoparticles on N-doped carbon for electroreduction of CO2

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Journal of Energy Chemistry 2025年第1期100卷 327-336页

作者： Mingdong Sun Wenwen Guan Cailing Chen Chao Wu Xiaoling Liu Biao Meng Tao Chen Yu Han Jun Wang Shibo Xi Yu Zhou State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Advanced Membranes and Porous Materials center Physical Sciences and Engineering Division King Abdullah University of Science and Technology Institute of sustainability for Chemicals Energy and Environment A*STAR (Agency for Science Technology and Research) College of Materials Science and Engineering Sichuan University

The synergy of single atoms （SAs） and nanoparticles （NPs） has demonstrated great potential in promoting the electrocatalytic carbon dioxide reduction reaction （CO2RR）;however,the rationalization of the SAs/NPs proportion remains one challenge for the catalyst ***,a Ni2+-loaded porous poly（ionic liquids）(PIL) precursor synthesized through the free radical self-polymerization of the ionic liquid monomer,1-allyl-3-vinylimidazolium chloride,was pyrolyzed to prepare the Ni,N co-doped carbon materials,in which the proportion of Ni SAs and NPs could be facilely modulated by controlling the annealing *** catalyst Ni-NC-1000 with a moderate proportion of Ni SAs and NPs exhibited high efficiency in the electrocatalytic conversion of CO2into *** Ni K-edge X-ray absorption near-edge structure （XANES） spectra and theoretical calculations were conducted to gain insight into the synergy of Ni SAs and *** charge transfer from Ni NPs to the surrounding carbon layer and then to the Ni SAs resulted in the electron-enriched Ni SAs active *** the electroreduction of CO2,the coexistence of Ni SAs and NPs strengthened the CO2activation and the affinity towards the key intermediate of*COOH,lowering the free energy for the potential-determining*CO2→*COOH step,and therefore promoted the catalysis efficiency.

关键词： Single atom catalyst Synergy effect Carbon catalyst Electrocatalysis

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Interannual variability of boreal summer intraseasonal oscillation over the northwestern Pacific influenced by the Pacific Meridional Mode

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Atmospheric and Oceanic Science Letters 2025年第1期18卷 6-11页

作者： Haoyu Zhou Pang-Chi Hsu Lin Chen Yitian Qian Key Laboratory of Meteorological Disaster Ministry of Education/Joint International Research Laboratory of Climate and Environmental Change/Collaborative Innovation Center on Forecast and Evaluation of Meteorological DisastersNanjing University of Information Science and TechnologyNanjingChina

During the boreal summer,intraseasonal oscillations exhibit significant interannual variations in intensity over two key regions:the central-western equatorial Pacific(5°S-5°N,150°E-150°W)and the subtropical Northwestern Pacific(10°-20°N,130°E-175°W).The former is well-documented and considered to be influenced by the ENSO,while the latter has received comparatively less attention and is likely influenced by the Pacific Meridional Mode(PMM),as suggested by partial correlation analysis *** elucidate the physical processes responsible for the enhanced(weakened)intraseasonal convection over the subtropical northwestern Pacific during warm(cold)PMM years,the authors employed a moisture budget *** findings reveal that during warm PMM years,there is an increase in summer-mean moisture over the subtropical northwestern *** increase interacts with intensified vertical motion perturbations in the region,leading to greater vertical moisture advection in the lower troposphere and consequently resulting in convective *** a process is pivotal in amplifying intraseasonal convection *** observational findings were further verified by model experiments forced by PMM-like sea surface temperature patterns.

关键词： Boreal summer intraseasonal oscillation Interannual variability Pacific Meridional Mode Moisture budget analysis

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Influence of climate fluctuations on Pinus palustris growth and drought resilience

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Forest Ecosystems 2023年第6期10卷 681-689页

作者： Joao Campoa Joshua Puhlick cense–center for environmental and sustainability research CHANGE-Global Change and Sustainability InstituteDepartment of Environmental Sciences and EngineeringNOVA School of Science and TechnologyNOVA University LisbonCampus de Caparica2829-516 CaparicaPortugal The Jones center at Ichauway 3988 Jones Center Drive39870NewtonGAUSA

The longleaf pine(Pinus palustris Mill.)ecosystem is an endangered ecosystem in the southeastern USA,and efforts to restore the species are ***,in recent decades,the region has experienced drastic fluctuations between wet and dry growing season conditions from year to year,and it is not fully understood how these fluctuations have influenced the growth of *** address this topic,we cored *** trees in woodlands of southwest Georgia and used dendrochronology techniques to determine how climate fluctuations have influenced the growth and drought resilience of *** also cored slash pine(Pinus elliottii Engelm.)trees in the same woodlands to compare growth between *** *** growth was less impacted by adverse climate conditions compared to ***,the strength of correlations between *** growth and temperature,precipitation,and Palmer Drought Severity Index(PDSI)changed over *** recent decades,climate conditions during the growing season became more influential on *** growth than the previous year's *** is concerning given that drought severity during the growing season has been *** results also indicate that *** was less resilient to droughts during the 2000s and 2010s than to those of the *** this new climate paradigm,our results suggest that *** might be more susceptible to growth reductions and less resistant to droughts than once *** work highlights the importance of understanding the impact of novel climate conditions on *** and has implications for restoration efforts,such as using silvicultural treatments that reduce tree vulnerability to drought(e.g.,thinning)and promote other climate-adapted species in mixture with ***.

关键词： Longleaf pine Slash pine Pinus elliottii Climate change Dendrochronology Dendroclimatology Forest disturbances

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Multiple sclerosis is at a checkpoint: advancing the program

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Neural Regeneration research 2025年第3期20卷 811-812页

作者： Brandon C.Smith Jessica L.Williams Department of Neurosciences Lerner Research InstituteCleveland ClinicClevelandOHUSA Department of Biological Geologicaland Environmental SciencesCleveland State UniversityClevelandOHUSA

Multiple sclerosis(MS) is a chronic inflammatory and demyelinating disease of the central nervous system(CNS). Patients with MS experience sensory and motor function loss due to myelin and/or axon damage perpetuated b... 详细信息

关键词： Hauser sclerosis damage

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Surface embedded binary Co-Cu hydroxy phosphate over surface of oxy/hydroxides for efficient nitrate reduction to ammonia

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Nano research 2025年第1期18卷 195-207页

作者： Chun Zhu Yifei Yang Yike Jing Zhen Zeng Xuesong Yi Wei Sun Fei Yang Key Laboratory of Agro-Forestry environmental Processes and Ecological Regulation of Hainan Province School of Environmental Science and EngineeringHainan UniversityHaikou 570228China

Electrochemical nitrate reduction reaction(NO3RR)to ammonia is a promising approach to address excess Ncontamination in aqueous environment but suffers from a limited ammonia yield and selectivity due to the low concentration and sluggish *** work reports a three-dimensional porous electrode with binary Co_(2)Cu_(1)hydroxy phosphate embedded into the surface of Ni_(3)Co_(1)oxy/hydroxides(CoCu-PH@NiCo/Ni,“PH”means phosphate-hydroxide),which delivers a yield of 4.13 mg·h^(-1)·cm^(-2)with a high Faraday efficiency of 92.6%under a low nitrate concentration of 40 mM and provide an impressive *** embedded structure of the as-prepared catalyst exhibits unique metal coordination ligands and valence states different from the unitary *** electrochemical in situ infrared spectra and theoretical calculations revealed that the Co sites with the ability to dissociate water molecular to form adsorbed OH*can effectively provide the required protons for the deoxygenation and hydrogenation steps during NO3-conversion,thereby,effectively reducing the energy barrier of the key transition states in the NO3RR process to improve the intrinsic *** demonstrate that the rational design of binary components with the appropriate ability to activate water molecules as well as the threedimensional porous skeletal structure are expected to promote effectively the low-concentration nitrates conversion to ammonia.

关键词： nitrate reduction hydroxy phosphate surface embedded water dissociation active hydroxy adsorbed

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Electrochemical conversion of methane to bridge the gap in the artificial carbon cycle

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Journal of Energy Chemistry 2025年第1期100卷 286-308页

作者： Yuhao Peng Yuefeng Song Ihar Razanau Juanxiu Xiao Wei Xiao Di Hu Guoxiong Wang College of Chemistry and Molecular Sciences Hubei Key Laboratory of Electrochemical Power Sources Wuhan University State Key Laboratory of Catalysis Dalian National Laboratory for Clean Energy iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Dalian Institute of Chemical Physics Chinese Academy of Sciences Laboratory of Physical-Chemical Technologies SSPA Scientific and Practical Materials Research Centre of NAS of Belarus State Key Laboratory of Marine Resources Utilization in South China Sea Collaborative Innovation Center of Marine Science and Technology School of Marine Science and Engineering Hainan University Department of Chemical and environmental Engineering University of Nottingham Ningbo China

Methane, an abundant one-carbon（C1） resource, is extensively used in the industrial production of vital fuels and value-added chemicals. However, current industrial methane conversion technologies are energy-and carbon-intensive, mainly due to the high activation energy required to break the inert C–H bond, low selectivity, and problematic side reactions, including CO2emissions and coke deposition. Electrochemical conversion of methane（ECM） using intermittent renewable energy offers an attractive solution, due to its modular reactor design and operational flexibility across a broad spectrum of temperatures and pressures. This review emphasizes conversion pathways of methane in various reaction systems, highlighting the significance and advantages of ECM in facilitating a sustainable artificial carbon cycle. This work provides a comprehensive overview of conventional methane activation mechanisms and delineates the complete pathways of methane conversion in electrolysis contexts. Based on surface/interface chemistry, this work systematically analyzes proposed reaction pathways and corresponding strategies to enhance ECM efficiency towards various target products, including syngas, hydrocarbons, oxygenates, and advanced carbon materials. The discussion also encompasses opportunities and challenges for the ECM process, including insights into ECM pathways, rational electrocatalyst design, establishment of benchmarking protocols, electrolyte engineering, enhancement of CH4conversion rates, and minimization of CO2emission.

关键词： Methane Electrochemical conversion Reaction mechanism Catalyst design Electrode Electrocatalysis

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Characterization and reactivity of biogenic manganese oxides for ciprofloxacin oxidation

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Journal of environmental Sciences 2014年第5期26卷 1154-1161页

作者： Jinjun Tu Zhendong Yang Chun Hu Jiuhui Qu State Key Laboratory of environmental Aquatic Chemistry Research Center for Eco-Environmental SciencesResearch Center for Eco-Environmental Sciences

Biogenic manganese oxides （BioMnOx） were synthesized by the oxidation of Mn（II） with Mn- oxidizing bacteria Pseudomonas sp. G7 under different initial pH values and Mn（II） dosages, and were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, and UV-Vis absorption spectroscopy. The crystal structure and Mn oxidation states of BioMnOx depended on the initial pH and Mn（lI） dosages of the medium. The superoxide radical （O2） was observed in Mn-containing （III/IV） BioMnOx suspensions by electron spin resonance measurements. BioMnOx（0.4）-7, with mixed valence of Mn（II/III/IV） and the strongest O^- signals, was prepared in the initial pH 7 and Mn（II） dosage of 0.4 mmol/L condition, and exhibited the highest activity for ciproftoxacin degradation and no Mn（II） release. During the degradation of ciprofloxacin, the oxidation of the Mn（II） formed came from biotic and abiotic reactions in BioMnOx suspensions on the basis of the Mn（II） release and O2- formation from different BioMnOx. The degradation process of ciprofloxacin was shown to involve the cleavage of the hexatomic ring having a secondary amine and carbon-carbon double bond connected to a carboxyl group, producing several compounds containing amine groups as well as small organic acids.

关键词： Mn oxidation state Mn-oxidizing bacteria superoxide radicals ciprofloxacin degradation

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Comparison on Soil Carbon Stocks Between Urban and Suburban Topsoil in Beijing, China

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Chinese Geographical Science 2014年第5期24卷 551-561页

作者： LUO Shanghua MAO Qizheng MA Keming State Key Laboratory of Urban and Regional Ecology Research Center for Eco-Environmental Science Chinese Academy of Sciences center for Human-Environment System sustainability Beijing Normal University

The urban population and urbanized land in China have both increased markedly since the 1980 s. Urban and suburban developments have grown at unprecedented rates with unknown consequences for ecosystem functions. In particular, the effect of rapid urbanization on the storage of soil carbon has not been studied extensively. In this study, we compared the soil carbon stocks of different land use types in Beijing Municipality. We collected 490 top-soil samples(top 20 cm) from urban and suburban sites within the Sixth Ring Road of Beijing, which cover approximately 2400 km2, and the densities of soil organic carbon(SOC), soil inorganic carbon(SIC), and total carbon(TC) were analyzed to determine the spatial distribution of urban and suburban soil carbon characteristics across seven land use types. The results revealed significant differences in soil carbon densities among land use types. Additionally, urban soil had significantly higher SOC and SIC densities than suburban soil did, and suburban shelterbelts and productive plantations had lower SIC densities than the other land use types. The comparison of coefficients of variance(CVs) showed that carbon content of urban topsoil had a lower variability than that of suburban topsoil. Further findings revealed that soil carbon storage increased with built-up age. Urban soil built up for more than 20 years had higher densities of SOC, SIC and TC than both urban soil with less than 10 years and suburban soil. Correlation analyses indicated the existence of a significantly negative correlation between the SOC, SIC, and TC densities of urban soil and the distance to the urban core, and the distance variable alone explained 23.3% of the variation of SIC density and 13.8% of the variation of TC density. These results indicate that SOC and SIC accumulate in the urban topsoil under green space as a result of the conversion of agricultural land to urban land due to the urbanization in Beijing.

关键词： urban soil soil organic carbon (SOC) soil inorganic carbon (SIC) carbon stock land use change built-up age Beijing China

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Uncertainty analyses on the calculation of water environmental capacity by an innovative holistic method and its application to the Dongjiang River

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Journal of environmental Sciences 2014年第9期26卷 1783-1790页

作者： Qiuwen Chen Qibin Wang Zhijie Li Ruonan Li center for Eco-environmental research Nanjing Hydraulic Research Institute State Key Laboratory of environmental Aquatic Chemistry Research Center for Eco-Environmental SciencesChinese Academy of sciences

The estimation and allocation of water environmental capacity （WEC） are essential to water quality management and social-economic interests. However, there is inevitable uncertainty in the capacity estimation due to model conceptualization, data collection and parameter calibration. An innovative holistic approach was developed, which took both independence and relevance between parameters into account to analyze the uncertainties in WEC calculation and estimate the margin of safety. The Doniang River was taken as the case to demonstrate the method, focusing on the chemical oxygen demand and NH-N that were the two major water quality problems in the river. The results showed that the proposed holistic approach is very promising and applicable compared to traditional methods of uncertainty analysis.

关键词： Water environmental capacityModel uncertaintyHolistic approachDon^iang River

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Simultaneous denitrification and denitrifying phosphorus removal in a full-scale anoxic–oxic process without internal recycle treating low strength wastewater

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Journal of environmental Sciences 2016年第1期28卷 175-183页

作者： Qibin Wang Qiuwen Chen State Key Laboratory of environmental Aquatic Chemistry Research Center for Eco-Environmental Sciences Chinese Academy of Sciences center for Eco-environmental research Nanjing Hydraulic Research Institute

Performance of a full-scale anoxic-oxic activated sludge treatment plant（4.0×10-5 m-3/day for the first-stage project） was followed during a *** plant performed well for the removal of carbon,nitrogen and phosphorus in the process of treating domestic wastewater within a temperature range of 10.8℃ to 30.5℃.Mass balance calculations indicated that COD utilization mainly occurred in the anoxic phase,accounting for 88.2% of total COD *** nitrogen removal occurred 13.71% in the anoxic zones and 78.77% in the aerobic *** contribution of anoxic zones to total nitrogen（TN） removal was 57.41%.Results indicated that nitrogen elimination in the oxic tanks was mainly contributed by simultaneous nitrification and denitrification（SND）.The reduction of phosphorus mainly took place in the oxic zones,51.45% of the total *** phosphorus removal was achieved biologically by 11.29%.Practical experience proved that adaptability to gradually changing temperature of the microbial populations was important to maintain the plant overall *** changes in temperature did not cause paralysis of the system just lower removal efficiency,which could be explained by functional redundancy of microorganisms that may compensate the adverse effects of temperature changes to a certain ***-oxic process without internal recycling has great potential to treat low strength wastewater（i.e.,TN 〈 35 mg/L） as well as reducing operation costs.

关键词： Wastewater treatment Biological nutrient removal Simultaneous nitrification and denitrification Denitrifying phosphorus removal

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