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Low‑Temperature Fabrication of Stable Black‑Phase CsPbI_(3) Perovskite Flexible Photodetectors Toward Wearable Health Monitoring

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Nano-Micro Letters 2025年第3期17卷 232-245页

作者： Yingjie Zhao Yicheng Sun Chaoxin Pei Xing Yin Xinyi Li Yi Hao Mengru Zhang Meng Yuan Jinglin Zhou Yu Chen Yanlin Song College of Chemistry and Pingyuan laboratory Zhengzhou UniversityZhengzhou 450001People’s Republic of China key laboratory of Green Printing Institute of ChemistryChinese Academy of SciencesBeijing 100190People’s Republic of China key laboratory of bio‑inspired materials and interfacial Science Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190People’s Republic of China Institute of High Energy Physics Chinese Academy of SciencesBeijing 100049People’s Republic of China

Flexible wearable optoelectronic devices fabricated fromorganic–inorganic hybrid perovskites significantly accelerate the developmentof portable energy,biomedicine,and sensing fields,but their poor thermal stabilityhinders further ***,all-inorganic perovskites possessexcellent thermal stability,but black-phase all-inorganic perovskite filmusually requires high-temperature annealing steps,which increases energy consumptionand is not conducive to the fabrication of flexible wearable *** this work,an unprecedented low-temperature fabrication of stable blackphaseCsPbI3perovskite films is demonstrated by the in situ hydrolysis reactionof diphenylphosphinic chloride *** released diphenyl phosphateand chloride ions during the hydrolysis reaction significantly lower the phasetransition temperature and effectively passivate the defects in the perovskitefilms,yielding high-performance photodetectors with a responsivity of 42.1 AW−1 and a detectivity of 1.3×10^(14)***,high-fidelity imageand photoplethysmography sensors are demonstrated based on the fabricated flexible wearable *** work provides a newperspective for the low-temperature fabrication of large-area all-inorganic perovskite flexible optoelectronic devices.

关键词： In situ hydrolyzation Low-temperature processing All-inorganic perovskite Flexible photodetectors Health monitoring

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biomimetic proton pocket and effective interfacial modulation for zinc metal anodes

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Science China Chemistry 2025年第2期68卷 526-535页

作者： Qi Dong Qingshun Nian Xuan Luo Jiajia Fan Jinyu Jiang Zhuangzhuang Cui Digen Ruan Xiaodi Ren Hefei National Research Center for Physical sciences at the Microscale CAS Key Laboratory of Materials for Energy ConversionDepartment of Materials Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China

Rechargeable aqueous zinc batteries(RAZBs)offer a promising solution for large-scale energy storage due to the abundance,low cost,and safety of ***,practical applications are hindered by Zn anode instability,dendrite growth,and hydrogen evolution reactions(HER).Chaotropic Zn(ClO_(4))2 electrolytes are favorable for low-temperature operations but exacerbate these issues due to their high acidity,leading to severe Zn corrosion and layered double hydroxide *** propose a biomimetic strategy using methylguanidoacetic acid(creatine)as a low-cost,eco-friendly additive to address these *** acts as a proton pocket to finely tune the pH of acidic Zn(ClO_(4))2 electrolytes for suppressing HER and stabilizing the Zn ***,the formed creatinine cations adsorb on the Zn surface,promoting highly controlled Zn deposition with a preferred(002)*** approach significantly enhances battery cycling performance,with Zn||Zn cells demonstrating extended cycling stability at both low and high current ***||Cu cells exhibited improved Coulombic efficiency over thousands of cycles,indicating highly reversible Zn plating/***,stable cell operations were realized at the temperature as low as−35℃ without electrolyte *** findings highlight the potential of biomimetic proton regulation and interfacial modulation for improving the stability and reversibility of Zn plating/stripping in RAZBs.

关键词： zinc metal anode dendrite suppression interfacial modulation proton-triggered cyclization Zn(ClO_(4))2 electrolyte

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Recent progress on photoactive nonprecious transition-metal complexes

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Science China Chemistry 2025年第1期68卷 46-95页

作者： Zhong-Liang Gong Hong-Jie Zhang Yan Cheng Jianxun Liu Yuhan Ai Yaqin Li Zhihui Feng Qiong Zhang Shaolong Gong Yong Chen Chang-Jiang Yao Yuan-Yuan Zhu Liang-Jin Xu Yu-Wu Zhong cas key laboratory of Photochemistry Institute of ChemistryChinese Academy of SciencesBeijing 100190China State key laboratory of Structural Cemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China School of Chemistry and Chemical Engineering Anhui Key Laboratory of Advanced Catalytic Materials and Reaction EngineeringHefei University of TechnologyHefei 230009China State key laboratory of Explosion Science and Safety Protection School of Mechatronical EngineeringBeijing Institute of TechnologyBeijing 100081China College of Chemistry and Molecular sciences Hubei Key Lab on Organic and Polymeric Optoelectronic MaterialsWuhan UniversityWuhan 430072China School of Chemistry and Chemical Engineering Anhui UniversityHefei 230601China key laboratory of Photochemical Conversion and Optoelectronic materials&cas-HKU Joint laboratory on New materials Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China

Photoactive complexes of nonprecious transition metals,mainly including those in the first-row and partially the second-row of the Periodic table of elements,have received increasing attention in view of their low cost and long-term *** are recognized as promising alternatives to noble transition metal complex congeners that have been extensively studied in optoelectronic devices,artificial photosynthesis,photocatalysis,biodiagnostics,and therapeutics,*** review is devoted to a comprehensive summary on the classical and recent advances on photoactive nonprecious transition metal complexes,including photoactive Zr,V,Cr,Mo,and W complexes,Mn complexes and hybrids,Fe,Co,Ni,and Cu complexes,and Zn and Cd complexes and hybrids.A particular focus is given on the molecular design,modulation of photophysical and photochemical properties,and applications of the representative and lately-developed nonprecious metal *** addition,a perspective on the future development in this field is provided at the end of this review.

关键词： photoactive metal complexes earth-abundant metals nonprecious metal complexes luminescence photochemistry

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Molecular dynamics simulation of quartz deformation under slow earthquake background

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Science China Earth sciences 2025年第2期68卷 598-610页

作者： Jingxian SUN Qianqian GUO Quanlin HOU College of Earth and Planetary sciences University of Chinese Academy of SciencesKey Laboratory of Computational GeodynamicsCASBeijing 100049China

Slow earthquakes are the primary mechanism of slow energy release,and research on the focal mechanism has been *** have primarily focused on the friction law based on physical mechanisms and have suggested that slow earthquakes are caused by brittle ***,the focal strength and structural characteristics of slow earthquakes in subduction zones provide evidence of plastic *** is the role of plastic deformation in the focal mechanisms of slow earthquakes?Mechanochemical study have shown that mechanical forces can directly affect chemical *** this study,we examine the storage and release of chemical energy during plastic deformation and consider a mechanochemical process in the focal mechanism of slow *** with the Tersoff potential,molecular dynamics simulation on the shear deformation process of twoα-quartz crystals show that the shear modulus ofα-quartz is 18 GPa,and that the crystal model primarily exhibits atoms flowing and changing in the direction of chemical bonds during the steady-state flow *** molecular potential energy and stress vary in an oscillating up-and-down curve during shear,indicating that chemical energy can be stored and released during plastic *** is consistent with the energy variation during slow *** the initial simple-shear loading condition,α-quartz crystals undergo general shear deformation instead of plane strain and the angle between the longest instantaneous stretching axis(ISA_(1))and the shearing direction is approximately 30°,not 45°.Both the deformation type and direction of ISA_(1)are contrary to basic deformation theory,which may provide clues for future *** study reveals the process of quartz elastic-plastic shear deformation on an atomic *** information is useful for understanding focal mechanisms of slow *** study is part of a series of investigations on tectonic stress chemistry.

关键词： Slow earthquake α-quartz Plastic strain energy Tectonic stress chemistry Tersoff potential

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Bifunctional bridging capping layer enables 24.5%efficiency of perovskite solar cells with polymer-based hole transport materials

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Science China Chemistry 2025年第1期68卷 350-359页

作者： Can Zhu Yiyang Wang Lei Meng Beibei Qiu Jing Li Shucheng Qin Ke Hu Xin Jiang Wenbin Lai Minchao Liu Zhe Liu Chenxing Lu Jinyuan Zhang Yongfang Li Beijing National laboratory for Molecular sciences CAS Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China School of Chemical Science University of Chinese Academy of SciencesBeijing 100049China key laboratory of Solid State Optoelectronic Devices of Zhejiang Province College of Physics and Electronic Information EngineeringZhejiang Normal UniversityJinhua 321004China key laboratory of Photochemical Conversion and Optoelectronic materials Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China laboratory of Advanced Optoelectronic materials College of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China

Developing a bridge capping layer between perovskite and hole transport layer materials(HTMs)in the n-i-p perovskite solar cells(pero-SCs)is an effective approach to modify the morphology of HTMs and passivate the perovskite ***,we select the quinoxaline-based bifunctional passivation agent,quinoxalin-6-yl-methylamine hydrochloride(Qx MACl),as the bridging layer,and a D-A copolymer PBQ12 containing the same quinoxaline unit as an HTM for the n-i-p *** to theπ-πstacking among the common quinoxaline units in the bridge layer and HTM,Qx MACl induces theπ-πstacking of the PBQ12 film and improves the film morphology of HTMs with better ***,Qx MACl can effectively passivate the perovskite surface,and PBQ12 possesses appropriate energy levels and high hole *** pero-SCs based on FAPbI_(3)with PBQ12/Qx MACl treatment showed a higher power conversion efficiency(PCE)of 24.05%and outstanding stability,maintaining 95.4%and 92.1%of its initial PCE after 750 h of storage and after over 800 h of thermal annealing at 85℃,*** further enhance the PCE of the PBQ12/Qx MACl-based devices,we developed a non-metal ion dopant for the PBQ12 *** trace doping of PBQ12 HTM by the non-metal ion dopant,the PCE of the PBQ12/Qx MACl-based devices reached 25.24%(the calibrated PCE of 24.55%by the National Institute of Metrology,China).

关键词： D-A copolymer hole transport materials bifunctional bridge capping layer passivation perovskite solar cells

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Failure mechanisms of AlGaN/GaN HEMTs irradiated by high-energy heavy ions with and without bias

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Nuclear Science and Techniques 2025年第1期36卷 49-58页

作者： Pei-Pei Hu Li-Jun Xu Sheng-Xia Zhang Peng-Fei Zhai Ling Lv Xiao-Yu Yan Zong-Zhen Li Yan-Rong Cao Xue-Feng Zheng Jian Zeng Yuan He Jie Liu Institute of Modern Physics Chinese Academy of Sciences(CAS)Lanzhou 730000China key laboratory of Wide Band‑gap Semiconductor materials Ministry of EducationXidian UniversityXi’an 710071China University of Chinese Academy of sciences(Ucas) Beijing 100049China

Gallium nitride(GaN)-based devices have significant potential for space ***,the mechanisms of radiation damage to the device,particularly from strong ionizing radiation,remains *** study investigates the effects of radiation on p-gate AlGaN/GaN high-electron-mobility transistors(HEMTs).Under a high voltage,the HEMT leakage current increased sharply and was accompanied by a rapid increase in power density that caused"thermal burnout"of the *** addition,a burnout signature appeared on the surface of the burned devices,proving that a single-event burnout effect ***,degradation,including an increase in the on-resistance and a decrease in the breakdown voltage,was observed in devices irradiated with high-energy heavy ions and without *** latent tracks induced by heavy ions penetrated the heterojunction interface and extended into the GaN ***,a new type of N_(2)bubble defect was discovered inside the tracks using Fresnel *** accumulation of N_(2)bubbles in the heterojunction and buffer layers is more likely to cause leakage and *** study indicates that electrical stress accelerates the failure rate and that improving heat dissipation is an effective reinforcement method for GaN-based devices.

关键词： GaN HEMTs Heavy ions Single-event burnout Latent tracks Degradation

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Na_(2)B_(6)SO_(13) with unprecedented [B_(6)SO_(13)]_(∞) double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B_(3)O_(7)] units

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Science China Chemistry 2025年第2期68卷 475-480页

作者： Jinbin Fan Ziting Yan Zilong Chen Huimin Li Zhihua Yang Fangfang Zhang Shilie Pan Research Center for Crystal materials State Key Laboratory of Functional Materials and Devices for Special Environmental ConditionsXinjiang Key Laboratory of Functional Crystal MaterialsXinjiang Technical Institute of Physics and ChemistryChinese Academy of SciencesUrumqi 830011China Center of materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

Birefringence is crucial for birefringent crystals to modulate polarized light and nonlinear optical crystals to enable *** is closely related to the arrangement of advantageous functional groups with large microcosmic polarizability anisotropy in the ***,designing crystals with large birefringence by modulating the arrangement of advantageous functional groups is still a *** this work,the arrangement of the advantageous[B_(3)O_(7)]groups is optimized by introducing rigid tetrahedral[SO_(4)]groups,resulting in a novel boron-rich borosulfate,Na_(2)B_(6)SO_(13) ,which exhibits unprecedented[B_(6)SO_(13)]_(∞)double chain and an enhanced birefringence(Δn=0.07 at 589.3 nm)against the borate parent *** calculations confirm that the birefringence is mainly attributable to the uniform alignment of[B_(3)O_(7)]***_(2)B_(6)SO_(13) also possesses a deep ultraviolet(DUV)cutoff edge(λ<185 nm).This work provides a feasible method to design DUV birefringent crystals with large birefringence by inducing the arrangement of advantageous functional groups.

关键词： borosulfate deep ultraviolet birefringence modulated groups

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Enhanced oxygen reduction reaction on La-Fe bimetal in porous N-doped carbon dodecahedra with CNTs wrapping

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Chinese Chemical Letters 2025年第1期36卷 618-622页

作者： Yi Zhou Yanzhen Liu Yani Yan Zonglin Yi Yongfeng Li Cheng-Meng Chen College of biomedical Engineering Taiyuan University of TechnologyTaiyuan 030024China cas key laboratory of Carbon materials Institute of Coal ChemistryChinese Academy of SciencesTaiyuan 030001China College of materials sciences and Opto-Electronic Technology University of Chinese Academy of SciencesBeijing 100049China

The oxygen reduction reaction(ORR)is a crucial process in Zn-air systems,and the catalyst plays a significant role in this ***,reported catalysts often suffer from poor durability and stability during the ORR ***,we synthesized La-Fe bimetallic nanoparticles encapsulated in a N-doped porous carbon dodecahedron(La-Fe/NC)originated from ZIF-8 by a simple direct *** La-Fe/NC catalyst had a numerous mesopores and dendritic outer layer generated by carbon nanotubes(CNTs),forming a high conductivity network that helped to optimize electron transfer and mass transport in the ORR *** effect of different doping transition metals and metal ratios on the ORR activity of Zn-air batteries was *** alkaline media,the La-Fe/NC showed the highest ORR catalytic activity,with a half-wave potential(E_(1/2))of 0.879 V(***,Pt/C 0.845 V).After 5000 cycles,the E_(1/2)of the La-Fe/NC catalyst only decreased by 7 m V,and its performance in stability tests and methanol tolerance tests was superior to Pt/*** used as the air electrode in a Zn-air battery,the La-Fe/NC catalyst demonstrated an excellent specific capacity of 755 m Ah/g and a peak power density of179.8 m W/cm~*** results provide important insights for the development of high-performance Zn-air batteries and new directions for the design of ORR catalysts.

关键词： Electrocatalyst ORR Bimetallic nanoparticle Dendritic CNTs Zn-air battery

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Impact of Startup Strategy and Buffer Tank Volume on the Compressor Inlet State for a 3-MW sCO_(2)Brayton Cycle

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Journal of Thermal Science 2025年第1期34卷 159-175页

作者： ZHAO Decai WANG Bo key laboratory of Advanced Energy and Power Institute of Engineering Thermophysics(IET)Chinese Academy of Sciences(CAS)Beijing 100190China University of Chinese Academy of sciences Beijing 100049China

The supercritical carbon dioxide(sCO_(2))Brayton cycle system has become an emerging and highly promising method of thermal power conversion due to its efficiency advantage,system compactness,and excellent adaptability of the heat *** the low carbon sCO_(2)Brayton cycle testbed with cycle output power approaching 3 MW,a relatively detailed dynamic simulation model of the entire system is constructed to explore the dynamic response characteristics of the system with different startup strategies and different buffer tank volumes during the startup *** simulation results indicate that the smaller the volume of the buffer tank,the more rapid and obvious the parameter fluctuation in the buffer tank during the *** the allowable relative deviation limit of density is 5%,then the ratio of the buffer tank volume to the volume of the entire closed loop should not be lower than 36.80%.The strategy of simultaneous temperature and speed increase during turbine bypass start can effectively reduce the fluctuation of compressor inlet parameters and reach the steady-state more *** paper provides the recommended matching table for the opening of the turbine bypass valve(TBV)and the main regulating valve(MGV)to reduce the parameter fluctuation during the bypass *** effectiveness of the proposed turbine bypass and bypass switching startup strategy is verified by simulation,which may be used as a reference for test bench's future debugging and operation.

关键词： sCO_(2)Brayton cycle dynamic model buffer tank startup strategy dynamic characteristic

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Boosting characteristic emissions of lanthanide in Cs_(2)Ag_(0.6)Na_(0.4)InCl_(6-x)Br_(x) double perovskites via mixing halide

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Journal of Rare Earths 2025年第1期43卷 39-46,I0002页

作者： Shujian Wang Dejian Chen Jie Hu Sisi Liang Kunyuan Xu Maochun Hong Haomiao Zhu University of Science and Technology of China Hefei230026China Ganjiang Innovation Academy Chinese Academy of SciencesGanzhou341000China cas key laboratory of Design and Assembly of Functional Nanostructures and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou350002China Xiamen key laboratory of Rare Earth Photoelectric Functional materials Xiamen Research Center of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen361021China

Lanthanide ions(Ln^(3+))doping provides a potential strategy to control over the luminescent properties of lead-free halide double perovskite nanocrystals(DP NCs).However,due to the low energy transfer efficiency between self-trapped exciton(STE)and Ln^(3+)ions,the characteristic emissions of Ln^(3+)ions are not ***,the energy transfer mechanism between STE and Ln^(3+)ions is also elusive and requires in-depth *** chose trace Bi^(3+)-doped Cs_(2)Ag_(0.6)Na_(0.4)InCl_(6-x)Br_(x) as a representative DP matrix to demonstrate that by tuning the bromide concentration,the Ln^(3+)emission can be greatly *** enhanced STE and Ln^(3+)ions energy transfer originates from the high covalency of Ln-Br bond,which contributes to improve ment of the characteristic emission of Ln^(3+)*** re,optical spectroscopy reveals that the energy transfer mechanism from DP to Eu^(3+)ions is different from all the other doped Ln^(3+)*** energy transfer from DP to Eu^(3+)ions is mostly through Eu-Br charge transfer while the other Ln^(3+)ions are excited by energy transfer from *** distinct energy transfer mechanism has resulted from the energy separation between the excited energy level of Ln^(3+)ions and the bottom of conduction band of *** increasing the energy separation,the energy transfer from STE to Ln^(3+)ions is less efficient because of the generation of a larger number of phonons and finally becomes impossible for Eu^(3+)*** results provide new insight into tuning the energy transfer of Ln^(3+)-doped DP NCs.

关键词： Double perovskitenanocrystal Lead free Lanthanideions Energytransfer Rare earths

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