检索结果-南通市图书馆

Carbon dots-enhanced pH-responsive lubricating hydrogel based on reversible dynamic covalent bondings

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第5期35卷 232-237页

作者： Jianye Kang Xinyu Yang Xuhao Yang Jiahui Sun Yuhang Liu Shutao Wang Wenlong Song State key laboratory of Supramolecular Structure and materials College of ChemistryJilin UniversityChangchun 130012China cas key laboratory of bio-inspired materials and interfacial Science CAS Center for Excellence in NanoscienceTechnical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China University of Chinese Academy of sciences Beijing 100049China

Due to the various pH liquid environment in nature,the pH-responsive lubricating hydrogel is widely investigated and developed for tissue interface substitute.However,the applied liquid environment will lead to poor mechanical property and weaken the pH-responsive capability.In this work,a carbon dotsenhanced pH-responsive lubricating hydrogel is developed by combining a pH-responsive section of dynamic PVA-borax network into a PAAm covalent polymer network.The formed hydrogel presents a partial gel-sol transition under controlled pH environments.At low pH environments(materials for soft lubricating actuator or robot.

关键词： pH-responsive Carbon dots Dynamic covalent bonding Lubrication

Structural Engineering of Hierarchical Magnetic/Carbon Nanocomposites via In Situ Growth for High-Efficient Electromagnetic Wave Absorption

在线全文

学校读者我要写书评

暂无评论

Nano-Micro Letters 2024年第9期16卷 262-278页

作者： Xianyuan Liu Jinman Zhou Ying Xue Xianyong Lu key laboratory of bio‑inspired Smart interfacial Science and Technology of Ministry of Education School of ChemistryBeihang UniversityBeijing 100191People’s Republic of China

materials exhibiting high-performance electromagnetic wave absorption have garnered considerable scientific and technological attention,yet encounter significant challenges.Developing new materials and innovative structural design concepts is crucial for expanding the application field of electromagnetic wave absorption.Particularly,hierarchical structure engineering has emerged as a promising approach to enhance the physical and chemical properties of materials,providing immense potential for creating versatile electromagnetic wave absorption materials.Herein,an exceptional multi-dimensional hierarchical structure was meticulously devised,unleashing the full microwave attenuation capabilities through in situ growth,selfreduction,and multi-heterogeneous interface integration.The hierarchical structure features a three-dimensional carbon framework,where magnetic nanoparticles grow in situ on the carbon skeleton,creating a necklace-like structure.Furthermore,magnetic nanosheets assemble within this framework.Enhanced impedance matching was achieved by precisely adjusting component proportions,and intelligent integration of diverse interfaces bolstered dielectric polarization.The obtain Fe_(3)O_(4)-Fe nanoparticles/carbon nanofibers/Al-Fe_(3)O_(4)-Fe nanosheets composites demonstrated outstanding performance with a minimum reflection loss(RLmin)value of−59.3 dB and an effective absorption bandwidth(RL≤−10 dB)extending up to 5.6 GHz at 2.2 mm.These notable accomplishments offer fresh insights into the precision design of high-efficient electromagnetic wave absorption materials.

关键词： Electromagnetic wave absorption Hierarchical structure In situ growth Self-reduction

Environment-adaptive phase-separation-porous fluorofilm for highperformance passive radiation cooling

在线全文

学校读者我要写书评

暂无评论

Nano Research 2024年第6期17卷 5636-5644页

作者： Weiming Tang Yong Li Xue Meng Shutao Wang Ziguang Zhao School of Future Technology University of Chinese Academy of SciencesBeijing 100049China cas key laboratory of bio-inspired materials and interfacial Science Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China cas key laboratory of Cryogenics Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China

Passive radiative cooling is widely recognized as an environmentally sustainable method for achieving significant cooling effects.However,the mechanical properties and environmental adaptability of current radiative cooling materials are not sufficient to maintain high cooling performance in external environments.Here we reported an environment-adaptive phase-separation-porous fluorofilm for high-performance passive radiation cooling.Compared to the homogenous fluoro-porous network with limited scattering efficiencies,we modulated the porous structure of the fluorofilm to achieve a strong emissivity of 95.2%(8-13μm)and a high reflectivity of 97.1%(0.3-2.5μm).The fluorofilm demonstrates a temperature drop of 10.5°C and an average cooling power of 81 W·m^(−2)under a sunlight power of 770 W·m^(−2).The high mechanical performance and environmental adaptability of fluorofilms are also exhibited.Considering its significant radiative cooling capability and robust environmental adaptability,the fluorofilm is expected to have a promising future in radiative temperature regulation.

关键词： fluorofilm passive radiation cooling porous optimization thermal regulation

The Nano Research Young Innovators Awards in bio-inspired nanomaterials

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第2期17卷 417-425页

作者： Jun Chen Shuotao Wang Department of bioengineering University of CaliforniaLos AngelesLos AngelesCA 90095USA key laboratory of bio-inspired materials and interfacial Science Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China

Nano Research Young Innovators(NR45)Awards are designed to acknowledge and celebrate the achievements of young researchers under 45 years of age.These individuals have made significant contributions to the field of nanoscience and nanotechnology.Since the inaugural NR45 Awards in 2018,the journal's editorial board has recognized over a hundred innovators specializing in nanobiotechnology,nano energy,two-dimensional materials,and nanocatalysis.The focus of the 2023 NR45 Awards is on bioinspired nanomaterials,acknowledging thirty-three outstanding young innovators for their extraordinary contributions in developing these materials with applications spanning clean energy,human healthcare,monitoring,and disease treatments,as shown in Fig.1.We extend our heartfelt congratulations to all the 33 NR45 Awardees in 2023!

关键词： journal materials contributions

Discontinuous phase diagram of amorphous carbons

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

National Science Review 2024年第4期11卷 164-171页

作者： YinBo Zhu ZhouYu Fang ZhongTing Zhang HengAn Wu cas key laboratory of Mechanical Behavior and Design of materials Department of Modern MechanicsUniversity of Science and Technology of China State key laboratory of Nonlinear Mechanics Institute of Mechanics Chinese Academy of Sciences

The short-range order and medium-range order of amorphous carbons demonstrated in experiments allow us to rethink whether there exist intrinsic properties hidden by atomic disordering. Here we presented six representative phases of amorphous carbons（0.1–3.4 g/cm3）, namely, disordered graphene network（DGN）, high-density amorphous carbon（HDAC）, amorphous diaphite（a-DG）, amorphous diamond（a-D）, paracrystalline diamond（p-D）, and nano-polycrystalline diamond（NPD）, respectively, classified by their topological features and microstructural characterizations that are comparable with experiments. To achieve a comprehensive physical landscape for amorphous carbons, a phase diagram was plotted in the sp3/sp2versus density plane, in which the counterintuitive discontinuity originates from the inherent difference in topological microstructures, further guiding us to discover a variety of phase transitions among different amorphous carbons. Intriguingly, the power law, log（sp3/sp2） ∝ ρn, hints at intrinsic topology and hidden order in amorphous carbons, providing an insightful perspective to reacquaint atomic disorder in non-crystalline carbons.

关键词： amorphous carbons disordered carbons phase diagram microstructural topology phase transition

Immune checkpoint inhibition mediated with liposomal nanomedicine for cancer therapy

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Military Medical Research 2024年第1期11卷 98-114页

作者： Guang-Long Ma Wei-Feng Lin Faculty of Medicine Centre for Cancer ImmunologyUniversity of SouthamptonSouthampton SO166YDUK Department of Molecular Chemistry and materials Science Weizmann Institute of Science76100 RehovotIsrael key laboratory of bio-inspired Smart interfacial Science and Technology of Ministry of Education School of ChemistryBeihang UniversityBeijing 100191China

Immune checkpoint blockade(ICB)therapy for cancer has achieved great success both in clinical results and on the market.At the same time,success drives more attention from scientists to improve it.However,only a small portion of patients are responsive to this therapy,and it comes with a unique spectrum of side effects termed immunerelated adverse events(irAEs).The use of nanotechnology could improve ICBs’delivery to the tumor,assist them in penetrating deeper into tumor tissues and alleviate their irAEs.Liposomal nanomedicine has been investigated and used for decades,and is well-recognized as the most successful nano-drug delivery system.The successful combination of ICB with liposomal nanomedicine could help improve the efficacy of ICB therapy.In this review,we highlighted recent studies using liposomal nanomedicine(including new emerging exosomes and their inspired nanovesicles)in associating ICB therapy.

关键词： Liposome Exosome Immune checkpoint blockade(ICB)

Fast prototype and rapid construction of three-dimensional and multi-scaled pitcher for controlled drainage by systematic biomimicry

在线全文

学校读者我要写书评

暂无评论

International Journal of Extreme Manufacturing 2024年第3期6卷 489-503页

作者： Tao Shen Ning Li Shijie Liu Cunlong Yu Chengqi Zhang Kang Yang Xingfei Li Ruochen Fang Lei Jiang Zhichao Dong  Research Institute for Frontier Science Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education BeijingSchool of ChemistryBeihang UniversityBeijing 100191People’s Republic of China cas key laboratory of bio-inspired materials and interfacial Science Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190People’s Republic of China cas Center for Excellence in Nanoscience Beijing Key Laboratory of Micro-nano Energy and SensorBeijing Institute of Nanoenergy and NanosystemsChinese Academy of SciencesBeijing 100083People’s Republic of China School of Future Technology&School of Nanoscience and Engineering University of Chinese Academy of SciencesBeijing 101407People’s Republic of China School of Chemistry and materials Science University of Science and Technology of China230026 HefeiAnhuiPeople’s Republic of China Suzhou Institute for Advanced Research University of Science and Technology of China215123 SuzhouJiangsuPeople’s Republic of China State key laboratory of Precision Measuring Technology and Instruments Tianjin University300072 TianjinPeople’s Republic of China

biomimetic materials that use natural wisdom to solve practical problems are developing rapidly.The trend for systematic biomimicry is towards in-situ characterization of naturalcreatures with high spatial resolutions.Furthermore,rapid reconstruction of digital twin models with the same complex features as the prototype is indispensable.However,it faces bottlenecks and limits in fast characterization and fabrication,precise parameter optimization,geometricdeviations control,and quality prediction.To solve these challenges,here,we demonstrate astate-of-the-art method taking advantage of micro-computed tomography and three-dimensional printing for the fast characterization of the pitcher plant Nepenthes x ventrata and fabrication of its biomimetic model to obtain a superior drainage controller with multiscale structures withprecise surface morphology optimization and geometric deviation control.Thefilm-rupture-based drainage dynamic and mechanisms are characterized by x-ray and high-speed videography,which determines the crucial structures for unique directionaldrainage.Then the optimized artificial pitchers are further developed into sustained drainage devices with novel applications,such as detection,reaction,and smoke control.

关键词： systematic biomimicry biomimetic materials Micro-CT drainage digital twin

Surface reconstruction of heterostructures in alkaline medium towards enhanced electrocatalytic hydrogen evolution

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2024年第6期43卷 2636-2647页

作者： Ming-Yang Yang Ji Yuan Xue-Lian Fu Jing-Jing Chen Jing Hu Zhou-Guang Lu Chen Liu Guangdong Research Center for interfacial Engineering of Functional materials Shenzhen Key Laboratory of Polymer Science and TechnologyShenzhen Key Laboratory of Energy Electrocatalytic MaterialsCollege of Materials Science and EngineeringShenzhen University Shenzhen key laboratory of interfacial Science and Engineering of materials Department of Materials Science and EngineeringSouthern University of Science and Technology

Constructing heterostructures has proved to be a successful strategy to fabricate electrocatalysts with high efficiency for water splitting.However,the structure evolution in alkaline hydrogen evolution reaction lacks investigation and the specific active center remains disputable.Herein,we take the well-designed Ni3S2@VO2heterostructures as a model to investigate the electrocatalytic activity and the surface reconstruction process of heterostructure catalysts in alkaline electrolyte.The Ni3S2@VO2heterostructures,with Ni3S2nanorods as the core and VO2nanoflakes as the shell,coupled with the high conductive Ni3S2,the hydrophilic VO2and modulated electronic structures at the interfaces,exhibited prominent activity and superior stability at various current densities.Further,the ex-situ characterizations confirmed that the surface reconstruction from Ni3S2@VO2into Ni3S2@amorphous-Ni（OH）2in alkaline media could optimize the water dissociation barrier and exposed large active area,thereby contributing to improved electrocatalytic performance.Our study not only introduces novel high-performance electrocatalysts for hydrogen evolution reaction（HER）,but also provides a new avenue for re-examining hetero-structural catalysts in alkaline solutions.

关键词： Heterostructures Ni 3 S 2 @VO 2 Surface reconstruction Water dissociation Alkaline hydrogen evolution

High MXene loading, nacre-inspired MXene/ANF electromagnetic interference shielding composite films with ultralong strain-tofailure and excellent Joule heating performance

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第3期17卷 2061-2069页

作者： Jiaen Wang Tianliang Song Wei Ming Moxi Yele Longfu Chen Hao Zhang Xiaojuan Zhang Benliang Liang Guangsheng Wang School of Physical Science and Engineering Beijing Jiaotong UniversityBeijing 100044China College of Chemistry and materials Engineering Beijing Technology and Business UniversityBeijing 100048China key laboratory of bio-inspired Smart interfacial Science and Technology of Ministry of Education School of ChemistryBeihang UniversityBeijing 100191China

The high power density and intelligence of next-generation flexible electronic devices bring many challenges to fabricate flexible composite films with electromagnetic interference(EMI)shielding effectiveness(SE)property and excellent toughness via a simple method.Herein,inspired by the layered structure and biopolymer matrix networks in natural nacre,nacre-like layered Ti_(3)C2TX(MXene)/aramid nanofiber(ANF)films were fabricated through sol-gel,vacuum-assisted filtration,and hot-pressing.Three-dimensional(3D)interconnected aramid nanofibers networks between adjacent layered MXene result in an ultralong strain-to-failure of the film.Even though the functional filler MXene contents are as high as 60 wt.%and 70 wt.%,the strain-to-failure of the films could reach astonishing values of 18.34%±1.86%and 14.43%±1.26%,respectively.And the tensile strength could maintain about 85 MPa.Excitingly,with such a high filler,the film can also withstand double folding and vigorous rubbing without damage,which could better adapt to a harsh application environment.The result means that this work provides a convenient way to prepare other high functional filler composite films with excellent mechanical performance.The EMI SE values could reach 45 and 52.15 dB at 60 wt.%and 70 wt.%MXene in 8.2–12.4 GHz.Meanwhile,the films have prominent Joule heating properties,high sensitivity(inspired MXene/ANF composite films in this work have ability to apply in many areas including communication technology,military,and aerospace.

关键词： bioinspired aramid nanofiber networks ultralong strain-to-failure toughening mechanism electromagnetic interference shielding