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Fabrication of MXene-Bi_(2)WO_(6)heterojunction by Bi_(2)Ti_(2)O_(7)hinge for extraordinary LED-light-driven photocatalytic performance

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Nano Research 2024年第6期17卷 4729-4736页

作者： Zhiwen Li Liangliang Xu Zaheer Ud Din Babar Ali Raza Yifei Zhang Xinrui Gu Yu-Xin Miao Zhen Zhao Gao Li institute of catalysis for Energy and Environment College of Chemistry and Chemical EngineeringShenyang Normal UniversityShenyang 110034China State Key Laboratory of catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China Scuola Superiore Meridionale(SSM) University of Naples Federico IILargo S.Marcellino1080138Italy Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology(KAIST)Daejeon 34141Republic of Korea University of Chinese Academy of Sciences Beijing 100049China

Heterojunction composites with intimate interfaces can shorten the diffusion distance,which leads to a shorter path for photogenerated carriers,thereby increasing photocatalytic ***,we report the fabrication of Ti_(3)C_(2)-Bi_(2)WO_(6)(TC-BW)heterojunctions hinged by Bi_(2)Ti_(2)O_(7)joints via an in situ hydrothermal reaction of Ti_(3)C_(2)in the presence of Na_(2)WO_(4)and Bi(NO_(3))_(3).The TC-BW was characterized using X-ray diffraction(XRD),scanning transmission electron microscopy(STEM),and Raman ***-BW showed superior photocatalytic activity(productivity over 15TC-WB reaches up to 5.0 mmolreacted BA·gcat.^(−1)·h^(−1))in the oxidation of benzyl alcohol using light-emitting diode(LED)light,arising from the surface defects and intimate heterojunction interface between the Ti_(3)C_(2)MXene and Bi_(2)WO_(6)***-BW heterojunctions provide an enhanced separation efficiency of photogenerated charges,which in turn yields superior photocatalytic ***,it is well substantiated by density functional theory(DFT)*** summary,this study elucidates the preparation of heterojunction composites with intimate interfaces for highly efficient photooxidation.

关键词： MXene-Bi_(2)WO_(6) heterojunction LED-light-driven photocatalysis Bi_(2)Ti_(2)O_(7) photooxidation

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The dynamic catalysis of Ga/ZSM-5 catalysts for propane-CO2 coupling conversion to aromatics and syngas

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Journal of Energy Chemistry 2024年第10期97卷 513-519页

作者： Yonggui Song Zhong-Pan Hu Haohao Feng Enze Chen Le Lv Yimo Wu Zhen Liu Yong Jiang Xiaozhi Su Feifei Xu Mingchang Zhu Jingfeng Han Yingxu Wei Svetlana Mintova Zhongmin Liu The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry Shenyang University of Chemical Technology National Engineering Research Center of Lower-Carbon catalysis Technology Dalian National Laboratory for Clean Energy iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Dalian Institute of Chemical Physics Chinese Academy of Sciences Shanghai Advanced Research institute Chinese Academy of Sciences Normandie University Laboratory of Catalysis and Spectrochemistry (LCS) ENSICAENUNICAEN CNRS

Alkane coupling with CO2by metal-containing zeolites catalysis is found to be a promising way to produce aromatics and syngas in recent years,but the real active sites and the role of CO2are still unclear owing to the quick evolution of the metallic active sites and the complex reaction processes including direct propane aromatization,CO2hydrogenation,reverse water-gas shift reaction,and propane-CO2coupling ***,Ga/ZSM-5 catalysts were constructed to study the dynamic evolution of the metallic active sites and the role of CO2during the propane and CO2coupling *** optimizing the reaction conditions,a notable propane conversion rate of 97.9% and an impressive aromatics selectivity of 80.6% in hydrocarbons can be achieved at the conditions of 550℃ and CO2/C3H8of 4.13CO2isotope experiments illustrate that C-atoms of CO2can enter into CO（86.5%） and aromatics（10.8%）during the propane-CO2coupling reaction *** situ XANES and FTIR spectroscopies at 550℃and H2/C3H8atmosphere reveal that GaOxspecies can be gradually dispersed into [GaH2]+/[GaH]2+on the Bronsted acid sites of ZSM-5 zeolite during H2and/or C3H8treatment,which are the real active sites for propane-CO2coupling *** situ CO2-FTIR experiments demonstrate that the [GaH2]+/[GaH]2+species can react with CO2and accelerate the propane and CO2coupling *** work not only presents a cost-effective avenue for CO2utilization,but also contributes to the active site design for improved alkane and CO2activation in coupling reaction system.

关键词： Carbon dioxide Ga/ZSM-5 Gallium hydride Propane aromatization Spectroscopy

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Hyperbranched polymer hollow-fiber-composite membranes for pervaporation separation of aromatic/aliphatic hydrocarbon mixtures

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Chinese Journal of Chemical Engineering 2024年第5期69卷 13-22页

作者： Tong Liu Hao Sun Xiangqiong Wang Jie Li Zhanquan Zhang Pei Wu Naixin Wang Quanfu An Beijing Key Laboratory for Green catalysis and Separation Department of Chemical EngineeringCollege of Materials Science and EngineeringBeijing University of TechnologyBeijing 100124China Petrochemical Research institute CNPCBeijing 102206China

The separation of aromatic/aliphatic hydrocarbon mixtures is crucial in the petrochemical *** is regarded as a promising approach for the separation of aromatic compounds from alkanes. Developing membrane materials with efficient separation performance is still the main task since the membrane should provide chemical stability, high permeation flux, and selectivity. In this study, the hyperbranched polymer(HBP) was deposited on the outer surface of a polyvinylidene fluoride(PVDF)hollow-fiber ultrafiltration membrane by a facile dip-coating method. The dip-coating rate, HBP concentration, and thermal cross-linking temperature were regulated to optimize the membrane *** obtained HBP/PVDF hollow-fiber-composite membrane had a good separation performance for aromatic/aliphatic hydrocarbon mixtures. For the 50%/50%(mass) toluene/n-heptane mixture, the permeation flux of optimized composite membranes could reach 1766 g·m^(-2)·h^(-1), with a separation factor of 4.1 at 60℃. Therefore, the HBP/PVDF hollow-fiber-composite membrane has great application prospects in the pervaporation separation of aromatic/aliphatic hydrocarbon mixtures.

关键词： Aromatic/aliphatic hydrocarbons Hyperbranched polymer Pervaporation Hollow fiber membrane Dip-coating

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Effect of yttrium on catalytic performance of Y-doped TiO_(2) catalysts for propane dehydrogenation

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Journal of Rare Earths 2024年第5期42卷 962-971,I0005页

作者： Liyu Hou Liming Xia Ruipeng Zhou Jianmei Li Renjie Li Zhen Zhao Guimei Yuan Aijun Duan State Key Laboratory of Heavy Oil Processing China University of PetroleumBeijing102249China institute of catalysis for Energy and Environment College of Chemistry and Chemical EngineeringShenyang Normal UniversityShenyang110034China

Defective bulk catalysts based on TiO_(2) have superior catalytic performance for propane dehydrogenation(PDH).The oxygen vacancy concentration and the number of active sites on the catalyst surface can be effectively tuned by doping metal in TiO_(2).Herein,yttrium(Y)-doped titanium dioxide(nY/TiO_(x))catalysts were in-situ synthesized via the coprecipitation method to study the effect of rare earth metal Y doping on the structure of TiO_(2) and the catalytic performance for *** results demonstrate that Ydoped TiO_(2) exhibits higher catalytic activity,propylene selectivity and stability than bare TiO_(2).Full characterizations with X-ray diffraction(XRD),high-resolution transmission electron microscope(HRTEM),X-ray photoelectron spectroscopy(XPS),infrared spectroscopy of pyridine adsorption(Py-IR),temperature-programmed desorption of ammonia(NH_(3)-TPD),H_(2) temperature-programmed reduction(H_2-TPR),and Raman techniques on these catalysts reveal that Y^(3+)can enter TiO_(2) lattice,and the lattice stability of the catalyst can be enhanced by replacing Ti^(4+)to form Y-O-Ti ***,the introduction of an appropriate amount of Y can obviously promote the PDH reaction by adjusting the acidity of the catalyst,improving the release capacity of TiO_(2) lattice oxygen and increasing the formation of active ***,excessive Y doping will lead to pore clogging,and the exposure of active sites will be reduced,resulting in the degradation of catalytic performance.

关键词： Propane dehydrogenation Anatase Lattice defects Coordinatively unsaturated Ti cations Oxygen vacancy Rare earths

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Research progress on preparation of cerium-based oxide catalysts with specific morphology and their application for purification of diesel engine exhaust

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Journal of Rare Earths 2024年第7期42卷 1187-1216,I0001页

作者： Chunlei Zhang Siyu Gao Di Yu Shengran Zhou Lanyi Wang Xuehua Yu Zhen Zhao institute of catalysis for Energy and Environment College of Chemistry and Chemical EngineeringShenyang Normal UniversityShenyang110034China State Key Laboratory of Heavy Oil Processing China University of PetroleumBejing102249China

The elimination of pollutants from diesel exhaust has received widespread research attention as they cause serious air pollution and pose a threat to human *** post-treatment technology is one of the most effective and universal technologies to treat diesel exhaust *** design and development of efficient and low-cost catalysts is the key factor to realize the wide application of catalytic post-treatment ***(Ce)-based oxides with specific morphologies are widely used to eliminate pollutants in diesel vehicle exhaust due to their unique physical and chemical properties,such as high catalytic activity,low cost and *** this review,the preparation methods of Cebased oxide materials with specific morphologies,such as nanoparticles,nanocubes,nanorods,nanofibers,and multi-stage pores,are introduced in detail,and the research progress on using these catalysts for the removal of carbon monoxide,hydrocarbons,soot particles,nitrogen oxides,and other pollutants from diesel exhaust is reviewed in ***,the unresolved issues associated with using Ce-based oxide catalysts with a specific morphology to catalytically remove pollutants from diesel exhaust are highlighted,and future application prospects and development directions are discussed.

关键词： Ce-based oxide catalysts Dies elexhaust pollutants Specific morphology Catalytic purification Rare earths

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Total Synthesis of Laurane and Guaiane Sesquiterpenoids via Oxidative Nazarov Reaction

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Chinese Journal of Chemistry 2024年第11期42卷 1267-1274页

作者： Yuye Chen Wenqing Chen Zhiting Zhang Jing Xu Shenzhen Grubbs institute and Department of Chemistry and Guangming Advanced Research institute and Guangdong Provincial Key Laboratory of catalysis and Shenzhen Key Laboratory of Small Molecule Drug Discovery and Synthesis Southern University of Science and TechnologyShenzhenGuangdong518055 China

As one of the most common structural motifs in natural products,cyclopentenones usually can be fabricated by Nazarov cyclization using divinyl ketones or functionalized tertiary divinyl carbinols(TDCs)as ***,straightforward method for transforming unfunctionalized TDCs to their corresponding cyclopentenones is currently ***,we wish to report the total syntheses of four structurally distinct terpenoids,namely laurane-type marine sesquiterpenoids isolaurene,debromoaplysin and aplysin,and guaiane sesquiterpenoid guaiadienone A,all using a novel synthetic method,named oxidative Nazarov cyclization,as the key *** work demonstrated our robust method is suitable for synthesizing various highly substituted cyclopentenones.

关键词： Total synthesis Synthetic methods Sesquiterpenoids Oxidative Nazarov reaction Electrocyclization Oxoammonium salt Pericyclic reaction Annulation

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Applying the Shearlet-Based Complexity Measure for Analyzing Mass Transfer in Continuous-Flow Microchannels

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Fluid Dynamics & Materials Processing 2024年第8期20卷 1743-1758页

作者： Elena Mosheva Ivan Krasnyakov institute of Continuous Media Mechanics UB ras Perm614013Russia Department of Applied Physics Perm National Research Polytechnic UniversityPerm614990Russia

Continuous-flow microchannels are widely employed for synthesizing various materials,including nanoparticles,polymers,and metal-organic frameworks(MOFs),to name a *** technology allows precise control over reaction parameters,resulting in purer,more uniform,and structurally stable products due to more effective mass transfer ***,continuous-flow synthesis processes may be accompanied by the emergence of spatial convective structures initiating convective *** the one hand,convection can accelerate reactions by intensifying mass *** the other hand,it may lead to non-uniformity in the final product or defects,especially in MOF microcrystal *** ability to distinguish regions of convective and diffusive mass transfer may be the key to performing higher-quality reactions and obtaining purer *** this study,we investigate,for the first time,the possibility of using the information complexity measure as a criterion for assessing the intensity of mass transfer in microchannels,considering both spatial and temporal non-uniformities of liquid’s distributions resulting from convection *** calculate the complexity using shearlet transform based on a local *** contrast to existing methods for calculating complexity,the shearlet transform based approach provides a more detailed representation of local *** analysis involves experimental images illustrating the mixing process of two non-reactive liquids in a Y-type continuous-flow microchannel under conditions of double-diffusive convection *** obtained complexity fields characterize the mixing process and structure formation,revealing variations in mass transfer intensity along the *** compare the results with cases of liquid mixing via a pure diffusive *** analysis,it was revealed that the complexity measure exhibits sensitivity to variations in the type of mass transfer,establishing its feasibility as an ind

关键词： Shearlet analysis complexity measure entropy measure convection microchannels double-diffusive instability

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A weakly-solvated ether-based electrolyte for fast-charging graphite anode

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Chinese Chemical Letters 2024年第8期35卷 526-532页

作者： Xiao Zhu Yanbing Mo Jiawei Chen Gaopan Liu Yonggang Wang Xiaoli Dong Department of Chemistry and Shanghai Key Laboratory of Molecular catalysis and Innovative Materials Institute of New EnergyiChEM(Collaborative Innovation Center of Chemistry for Energy Materials)Fudan UniversityShanghai 200433China

Weakly-solvated electrolytes(WSEs)utilizing solvents with weak coordination ability offer advantages for low-potential graphite anode owing to their facile desolvation process and anions-derived inorganic-rich solid electrolyte interphase(SEI)***,these electrolytes face challenges in achieving a balance between the weak solvation affinity and high ionic conductivity,as well as between rigid inorganic-rich SEI and flexible SEI for long-term ***,we introduce 1,3-dioxolane(DOL)and lithium bis(trifluoromethanesulfonyl)-imide(LiTFSI)as functional additives into a WSE based on nonpolar cyclic ether(1,4-dioxane).The well-formulated WSE not only preserves the weakly solvated features and anion-dominated solvation sheath,but also utilizes DOL to contribute organic species for stabilizing the SEI *** from these merits,the optimized electrolyte enables graphite anode with excellent fast-charging performance(210 mAh/g at 5 C)and outstanding cycling stability(600 cycles with a capacity retention of 82.0%at room temperature and 400 cycles with a capacity retention of 80.4%at high temper-ature).Furthermore,the fabricated LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)||graphite full cells demonstrate stable operation for 140 cycles with high capacity retention of 80.3%.This work highlights the potential of tailoring solvation sheath and interphase properties in WSEs for advanced electrolyte design in graphite-based lithium-ion batteries.

关键词： Weakly-solvated solvent Bisalt ether-based electrolyte Graphite anode NCM||graphite battery Interfacial optimization

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Applications of in-situ solid-state nuclear magnetic resonance (ssNMR) in methanol to olefins (MTO) reaction

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Science China Chemistry 2024年

作者： Jing Niu Shutao Xu Yingxu Wei Zhongmin Liu National Engineering Research Center of Lower-Carbon catalysis Technology Dalian Institute of Chemical PhysicsChinese Academy of Sciences State Key Laboratory of catalysis Dalian Institute of Chemical PhysicsChinese Academy of Sciences University of Chinese Academy of Sciences

The methanol-to-olefins (MTO) reaction offers an alternative pathway for the production of low-carbon olefins from non-oil *** research has been impeded by a lack of comprehensive understanding of its underlying mechanism,despite the significant progress made in ***-situ solid-state nuclear magnetic resonance (ssNMR) spectroscopy has emerged as a pivotal tool,offering crucial insights into key species under real-time operando ***,the host–guest interaction between zeolites or surface species residing on zeolites and the reactant/active intermediates is revealed by the combination of in-situ13C MAS NMR and 2D correlation ***,recent technological advancements in hyperpolarization (HP) methods,including HP129Xe NMR and dynamic nuclear polarization (DNP),have significantly improved the sensitivity of ssNMR,enabling detailed structural and kinetic analysis as well as the detection of trace *** this feature article,we summarized recent advancements in (in-situ) ssNMR spectroscopy applied to MTO reaction processes,encompassing mechanistic investigations at various stages and the intricate host–guest *** theoretical insights into the dynamic evolution of MTO reactions lay a solid foundation for the optimization of catalytic processes and the development of efficient catalysts,thereby advancing the techniques towards more sustainable and economical production route for olefins.

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Recent progress in online detection methods of bioaerosols

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Fundamental Research 2024年第3期4卷 442-454页

作者： Taicheng An Zhishu Liang Zhen Chen Guiying Li Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health Guangdong Key Laboratory of Environmental Catalysis and Health Risk ControlInstitute of Environmental Health and Pollution controlGuangdong University of TechnologyGuangzhou 510006China Guangzhou Key Laboratory of Environmental catalysis and Pollution Control Guangdong Key Laboratory of Environmental Catalysis and Health Risk ControlSchool of Environmental Science and EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China

The aerosol transmission of coronavirus disease in 2019,along with the spread of other respiratory diseases,caused significant loss of life and property;it impressed upon us the importance of real-time bioaerosol *** complexity,diversity,and large spatiotemporal variability of bioaerosols and their external/internal mixing with abiotic components pose challenges for effective online bioaerosol *** methods focus on directly capturing bioaerosols before subsequent time-consuming laboratory analysis such as culture-based methods,preventing the high-resolution time-based characteristics necessary for an online *** a comprehensive literature assessment,this review highlights and discusses the most commonly used real-time bioaerosol monitoring techniques and the associated commercially available *** applied in online bioaerosol monitoring,including adenosine triphosphate bioluminescence,laser/light-induced fluorescence spectroscopy,Raman spectroscopy,and bioaerosol mass spectrometry are *** working principles,characteristics,sensitivities,and efficiencies of these real-time detection methods are compared to understand their responses to known particle types and to contrast their *** developed to analyze the substantial data sets obtained by these instruments and to overcome the limitations of current real-time bioaerosol monitoring technologies are also ***,an outlook is proposed for future instrumentation indicating a need for highly revolutionized bioaerosol detection technologies.

关键词： Airborne microorganisms Real-time monitoring Adenosine triphosphate luminescence Laser/light-induced fluorescence Raman spectroscopy Bioaerosol mass spectrometry

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