检索结果-南通市图书馆

In situ seed layer bandgap engineering leading to the conduction band offset reversion and efficient Sb2Se3 solar cells with high open-circuit voltage

引用

Journal of Energy Chemistry 2025年第2期101卷 201-212页

作者： Yanting Jiang Weiyu Wang Zhirong Chen Zhenyu Fang Qiqiang Zhu Qiao Zheng Jionghua Wu Hui Deng Weihuang Wang Shuying Cheng Fuzhou University Institute of Micronano Devices & Solar Cells College of Physics & Information Engineering Jiangsu Collaborative Innovation Center for Photovoltaic Science and engineering

Sb2Se3solar cells have achieved a power conversion efficiency（PCE） of over 10%.However,the serious open-circuit voltage deficit(VOC-deificit),induced by the hard-to-control crystal orientation and heterojunction interface reaction,limits the PCE of vapor transport deposition（VTD） processed Sb2Se3solar *** overcome the VOC-deficit problem of VTD processed Sb2Se3solar cells,herein,an in-situ bandgap regulation strategy is innovatively proposed to prepare a wide band gap Sb2（S,Se）3seed layer（WBSL） at CdS/Sb2Se3heterojunction interface to improve the PCE of Sb2Se3solar *** analysis results show that the introduced Sb2（S,Se）3seed layer can enhance the [001] orientation of Sb2Se3thin films,broaden the band gap of heterojunction interface,and realize a "Spike-like" conduction band alignment withΔEc=0.11 *** addition,thanks to the suppressed CdS/Sb2Se3interface reaction after WBSL application,the depletion region width of Sb2Se3solar cells is widened,and the quality of CdS/Sb2Se3interface and the carrier transporting performance of Sb2Se3solar cells are significantly improved as ***,the harmful Se vacancy defects near the front interface of Sb2Se3solar cells can be greatly diminished by ***,the PCE of Sb2Se3solar cells is improved from 7.0% to 7.6%;meanwhile the VOCis increased to 466 mV which is the highest value for the VTD derived Sb2Se3solar *** work will provide a valuable reference for the interface and orientation regulation of antimony-based chalcogenide solar cells.

关键词： Band gap alignment Carrier transport Crystal orientation Open circuit voltage deficit Seed-layer

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

engineering nanoparticle structure at synergistic Ru-Na interface for integrated CO_(2)capture and hydrogenation

引用

Journal of Energy Chemistry 2025年第1期100卷 779-791页

作者： Hanzi Liu Ling Cen Xinlin Xie Lei Liu Zhao Sun Zhiqiang Sun Hunan engineering Research Center of Clean and Low-Carbon Energy Technology School of Energy Science and EngineeringCentral South UniversityChangsha 410083HunanChina

The development of dual functional material for cyclic CO_(2)capture and hydrogenation is of great significance for converting diluted CO_(2)into valuable fuels,but suffers from kinetic limitation and deactivation of adsorbent and ***,we engineered a series of RuNa/γ-Al_(2)O_(3)materials,varying the size of ruthenium from single atoms to clusters/*** coordination environment and structure sensitivity of ruthenium were quantitatively investigated at atomic *** findings reveal that the reduced Ru nanoparticles,approximately 7.1 nm in diameter with a Ru-Ru coordination number of 5.9,exhibit high methane formation activity and selectivity at 340°*** Ru-Na interfacial sites facilitate CO_(2)migration through a deoxygenation pathway,involving carbonate dissociation,carbonyl formation,and ***-situ experiments and theoretical calculations show that stable carbonyl intermediates on metallic Ru nanoparticles facilitate heterolytic C–O scission and C–H bonding,significantly lowering the energy barrier for activating stored CO_(2).

关键词： CO_(2)capture Hydrogenation Ru-Na interface Dual functional material Reaction mechanism

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Optimizing electronic structure through point defect engineering for enhanced electrocatalytic energy conversion

引用

Green Energy & Environment 2025年第1期10卷 109-131页

作者： Wei Ma Jiahao Yao Fang Xie Xinqi Wang Hao Wan Xiangjian Shen Lili Zhang Menggai Jiao Zhen Zhou Interdisciplinary Research Center for Sustainable Energy Science and engineering(IRC4SE2) School of Chemical EngineeringZhengzhou UniversityHenan450001China

Point defect engineering endows catalysts with novel physical and chemical properties,elevating their electrocatalytic *** introduction of defects emerges as a promising strategy,effectively modifying the electronic structure of active *** optimization influences the adsorption energy of intermediates,thereby mitigating reaction energy barriers,altering paths,enhancing selectivity,and ultimately improving the catalytic efficiency of *** elucidate the impact of defects on the electrocatalytic process,we comprehensively outline the roles of various point defects,their synthetic methodologies,and characterization ***,we consolidate insights into the relationship between point defects and catalytic activity for hydrogen/oxygen evolution and CO_(2)/O_(2)/N_(2) reduction reactions by integrating mechanisms from diverse *** underscores the pivotal role of point defects in enhancing catalytic *** last,the principal challenges and prospects associated with point defects in current electrocatalysts are proposed,emphasizing their role in advancing the efficiency of electrochemical energy storage and conversion materials.

关键词： Point defect engineering Doping Vacancy Electrocatalysis Electronic structure

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Kinked Rebar and engineering Structures Applying Kinked Materials:State-ofthe-Art Review

引用

Structural Durability & Health Monitoring 2025年第2期19卷 233-263页

作者： Chengquan Wang Lei Xu Xinquan Wang Yun Zou Kangyu Wang Boyan Ping Xiao Li Department of Civil engineering Hangzhou City UniversityHangzhou310015China Zhejiang engineering Research Center of Intelligent Urban Infrastructure Hangzhou310015China Department of Civil engineering Jiangnan UniversityWuxi214122China School of Civil engineering Zhejiang University of TechnologyHangzhou310014China Department of Civil engineering Tongji UniversityShanghai200092China

Kinked rebar is a special type of steel material,which is installed in beam column nodes and frame *** effectively enhances the blast resilience,seismic collapse resistance,and progressive collapse resistance of reinforced concrete(RC)structures without imposing substantial cost burdens,thereby emerging as a focal point of recent research *** the basis of explaining the working principle of kinked rebars,this paper reviews the research status of kinked rebars at home and abroad from three core domains:the tensile mechanical properties of kinked rebars,beam column nodes with kinked rebars,and concrete frame structures with kinked *** analysis underscores that the straightening process of kinked rebars does not compromise their ultimate strength but significantly bolsters structural ductility and enhances energy dissipation *** beam-column joints,the incorporation of kinked rebars facilitates the seamless transfer of plastic hinges,adhering to the design principle of“strong columns and weak beams.”In addition,kinked rebars can greatly improve the resistance of the beam;The seismic resistance,internal explosion resistance,and progressive collapse resistance of reinforced concrete frame structures with kinked rebar have significantly *** its primary application,the principle of kinked rebar was extended to other applications of kinked materials such as corrugated steel plates and origami structures,and the stress characteristics of related components and structures were ***,this paper also proposes the application of kinked rebars in bridge engineering,aiming to address the challenges of localized damage concentration and excessive residual displacement in RC bridge *** introduction of kinked rebars in piers is envisioned to mitigate these issues,with the paper outlining its advantages and feasibility,thereby offering valuable insights for future research on kinked reinforcement and seismic design strat

关键词： Structural engineering kinked rebar seismic performance explosion-resistant performance progressive collapse

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Quantile-based optimization under uncertainties for complex engineering structures using an active learning basis-adaptive PC-Kriging model

引用

Chinese Journal of Aeronautics 2025年第1期38卷 340-352页

作者： Yulian GONG Jianguo ZHANG Dan XU Ying HUANG School of Reliability and Systems engineering Beihang UniversityBeijing 100191China

The Reliability-Based Design Optimization(RBDO)of complex engineering structures considering uncertainties has problems of being high-dimensional,highly nonlinear,and timeconsuming,which requires a significant amount of sampling simulation *** this paper,a basis-adaptive Polynomial Chaos(PC)-Kriging surrogate model is proposed,in order to relieve the computational burden and enhance the predictive accuracy of a *** active learning basis-adaptive PC-Kriging model is combined with a quantile-based RBDO ***,five engineering cases have been implemented,including a benchmark RBDO problem,three high-dimensional explicit problems,and a high-dimensional implicit *** with Support Vector Regression(SVR),Kriging,and polynomial chaos expansion models,results show that the proposed basis-adaptive PC-Kriging model is more accurate and efficient for RBDO problems of complex engineering structures.

关键词： Reliability-based design optimization Quantile-based Basis-adaptive PC-Kriging Complex engineering structures Active learning Uncertainty

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Transforming waste particles into valuable adsorbents via amyloid-mediated molecular engineering

引用

Science China Chemistry 2025年第1期68卷 317-328页

作者： Qingmin Yang Jian Zhao Yujia Zhang Xingyu Zhou Hao Ren Bowen Hu Zhongli Lei Lixin Chen Peng Yang Key Laboratory of Applied Surface and Colloid Chemistry Ministry of EducationSchool of Chemistry and Chemical EngineeringShaanxi Normal UniversityXi’an 710119China School of Material and Chemical engineering Bengbu UniversityBengbu 233030China Anhui Provincial engineering Laboratory of Silicon-Based Materials Bengbu 233030China Xi’an Key Laboratory of Polymeric Soft Matter School of Chemistry and Chemical EngineeringShaanxi Normal UniversityXi’an 710119China International Joint Research Center on Functional Fiber and Soft Smart Textile School of Chemistry and Chemical EngineeringShaanxi Normal UniversityXi’an 710119China School of Chemistry and Chemical engineering Northwestern Polytechnical UniversityXi’an 710129China

The high-value utilization of industrial solid waste using a facile and eco-friendly process is of great interest and significance in reducing environmental pollution and developing a green circular ***,we propose an amyloid-mediated molecular engineering strategy to transform particulate waste into valuable adsorbents for metal *** method has the advantage of aqueous solution fabrication under mild conditions without the use of high-temperature hydrothermal methods and toxic chemical ***-mediated molecular engineering manipulates the phase transition of bovine serum albumin(BSA)on particulate waste surfaces,resulting in a remarkable~3.1 times improvement in the adsorption capacity of fly ash,a typical industrial solid waste for gold ions after modification with the phase-transitioned BSA(PTB).The resultant adsorption ability was 69–1,980 times higher than those of conventional and emerging adsorbent materials such as ion exchange resins,activated carbon(AC),covalent organic frameworks(COFs),and metal-organic frameworks(MOFs).We further demonstrated the application of our PTB-modified materials in the recovery of precious metals from low-grade gold ore and electronic waste ***,this strategy could increase the value of waste materials nearly 27 *** addition,this method is generally extendable to other conventional industrial adsorbents such as resin,clay,and Al_(2)O_(3),and enhances their adsorption capabilities at least ***,this work provides a simple and green approach for improving the adsorption performance of solid particles,and is expected to develop into a universal strategy for transforming waste particles into high-value-added products.

关键词： amyloid-like protein aggregates surface engineering fly ash solid waste adsorption

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Dynamic stress concentration in an infinitely long cylindrical cavity due to a point spherical source embedded within a fluid-saturated poroelastic formation of infinite extent

引用

Applied Mathematics and Mechanics(English Edition) 2025年第1期46卷 139-156页

作者： H.HOSSEINI O.BALILASHAKI Department of Mechanical engineering Faculty of EngineeringGolestan University

The effects of a harmonically exciting monopole source on an infinitely long cylindrical cavity embedded entirely within a fluid-saturated poroelastic formation of infinite extent are examined theoretically. It is assumed that the source is located outside the cavity at a specified distance from the borehole axis. The magnitudes of the hoop and radial stresses beside the pore pressures exerted on the interface and inside the porous medium surrounding the borehole are calculated and discussed. Biot's poroelastic modeling along with three types of boundary conditions for the cylindrical interface including the ideal fluid, empty borehole, and rigid inclusion with a hard boundary is employed for the analysis. Utilizing a proper translational addition theorem for expressing the incident spherical wave in terms of cylindrical wave expansions, the proposed boundary conditions at the interface are satisfied. Stresses are formulated by means of wave potential functions in a three-dimensional(3D) manner. The effects of the frequency and the radial distance between the source and borehole on the induced stresses are examined for the first cylindrical modes over frequency spectra. Two permeability conditions for the interface and three types of soils for the porous formation are considered throughout the analysis. To give an overall outline of the study, a numerical example is presented. The results clearly indicate that the distance is a key parameter and has considerable effects on the induced stress values. In addition, the interface permeability condition and soil characteristics play an important role in determining the dynamic response of the borehole. Finally,the obtained results are compared with the relevant analyses existing in the literature for some limit cases, and good agreement is achieved.

关键词： cylindrical cavity O353.4 point source porous medium stress concentration wave-field transformation

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

“One stone, two birds”: Salt template enabling porosity engineering and single metal atom coordinating toward high-performance zinc-ion capacitors

引用

Journal of Energy Chemistry 2025年第1期100卷 637-645页

作者： Chunliu Zhu Huanyu Liang Ping Li Chenglong Qiu Jingyi Wu Jingwei Chen Weiqian Tian Yue Zhu Zhi Li Huanlei Wang School of Materials Science and engineering Ocean University of ChinaQingdao 266100ShandongChina Department of Chemical and Materials engineering University of AlbertaAlberta T6G 2V4EdmontonCanada

Zinc-ion hybrid capacitors (ZIHCs) have received increasing attention as energy storage devices owing to their low cost,high safety,and environmental ***,their progress has been hampered by low energy and power density,as well as unsatisfactory long-cycle stability,mainly due to the lack of suitable electrode *** this context,we have developed manganese single atoms implanted in nitrogen-doped porous carbon nanosheets (MnSAs/NCNs) using a metal salt template method as cathodes for *** metal salt serves a dual purpose in the synthesis process:It facilitates the uniform dispersion of Mn atoms within the carbon matrix and acts as an activating agent to create the porous *** applied in ZIHCs,the MnSAs/NCNs electrode demonstrates exceptional performance,including a high capacity of 203 m Ah g^(-1),an energy density of 138 Wh kg^(-1)at 68 W kg^(-1),and excellent cycle stability with 91%retention over 10,000 *** calculations indicate that the introduced Mn atoms modulate the local charge distribution of carbon materials,thereby improving the electrochemical *** work demonstrates the significant potential of carbon materials with metal atoms in zinc-ion hybrid capacitors,not only in enhancing electrochemical performance but also in providing new insights and methods for developing high-performance energy storage devices.

关键词： Zinc ion hybrid capacitors Cathodes Carbon materials Heteroatoms Single atoms

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

16.48% Efficient solution-processed CIGS solar cells with crystal growth and defects engineering enabled by Ag doping strategy

引用

Journal of Energy Chemistry 2025年第1期100卷 59-65页

作者： Mengyu Xu Shaocong Yan Ting Liang Jia Jia Shengjie Yuan Dongxing Kou Zhengji Zhou Wenhui Zhou Yafang Qi Yuena Meng Litao Han Sixin Wu Key Laboratory for Special Functional Materials of MOE National&Local Joint Engineering Research Centre for High-efficiency Display and Lighting TechnologySchool of Nanoscience and Materials EngineeringHenan UniversityKaifeng 475004HenanChina

Solution-processed Cu(In,Ga)Se_(2)(CIGS) solar cells suffer from serious carrier recombination and power conversion efficiency(PCE) loss because of the poor film properties and easy formation of ***, we propose Ag&Se co-selenization strategy to enhance the crystallization and passivate harmful defects of the CIGS films. The formation of Ag-Se phase during the selenization process enables the formation of large grains and suppresses the deep level defects. It is found that Ag doping can enlarge the depletion region width, lower the Urbach energy and prolong the carrier lifetime. As a result, a champion solution-processed CIGS solar cell presents a high efficiency of 16.48% with the highly improved opencircuit voltage(VOC) of 662 m V and fill factor(FF) of 75.8%. This work provides an efficient strategy to prepare high quality solution-processed CIGS films for high-performance CIGS solar cells.

关键词： CIGS solarcells Solution-processedmethod Ag doping Crystal growth Defects engineering

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

A review of over-discharge protection through prelithiation in working lithium-ion batteries

引用

Journal of Energy Chemistry 2025年第2期101卷 437-452页

作者： Hanchen Wang Yingtian Liu Mingze Jiang Qiang Zhang School of Aerospace engineering National Engineering Research Center of Neuromodulation Tsinghua University Tsinghua Center for Green Chemical engineering Electrification Department of Chemical Engineering Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Tsinghua University

The demand for high safety and high reliability lithium-ion batteries(LIBs) is strongly considered for practical ***,due to their inherent self-discharge properties or abuse,LIBs face the threat of over-discharge,which induces premature end of life and increased risk of thermal *** addition,a strong demand for batteries with zero-volt storage is strongly considered for aerospace and implantable medical *** this review,we firstly introduce the necessity and the importance of over-discharge and zero-volt protection for *** mechanism of damage to the Cu current collectors and SEI induced by potential changes during over-discharge is *** current over-discharge protection strategies based on whether the zero-crossing potential of the electrodes is ***,the fresh insights into the material design of cathode prelithiation additives are presented from the perspective of over-discharge protection.

关键词： Electrode potential regulation Electrode prelithiation Li-ion batteries Over-discharge protection Zero-volt storage

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：