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Preparation of co.S co.doped carbon catalysts for excellent methylene blue degradation

International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 169-181页

作者： Haixu Li Haobo He Tiannan Jiang Yunfei Du Zhichen Wu Liang Xu Xinjie Wang Xiaoguang Liu Wanhua Yu Wendong Xue School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083China beijing Jinyu Tongda Refractory Technologies co. Ltd.Beijing 100085China

S and co.co.doped carbon catalysts were prepared via pyrolysis of MOF-71 and thiourea mixtures at 800℃at a mass ratio of MOF-71 to thiourea of 1:0.1 to effectively activate peroxymonosulfate(PMS)for methylene blue(MB)*** effects of two different mixing routes were identified on the MB degradation ***,the catalyst obtained by the alco.ol solvent evaporation(MOF-AEP)mixing route co.ld degrade 95.60%MB(50 mg/L)within 4 min(degradation rate:K=0.78 min^(-1)),which was faster than that derived from the direct grinding method(MOF-DGP,80.97%,K=0.39 min^(-1)).X-ray photoelectron spectrosco.y revealed that the co.S co.tent of MOF-AEP(43.39at%)was less than that of MOF-DGP(54.73at%),and the proportion of C-S-C in MOF-AEP(13.56at%)was higher than that of MOF-DGP(10.67at%).Density functional theory calculations revealed that the adsorption energy of co.for PMS was -2.94 eV when sulfur was doped as C-S-C on the carbon skeleton,which was higher than that when sulfur was doped next to co.alt in the form of co.S bond(-2.86 eV).Thus,the C-S-C sites might provide more co.tributions to activate PMS co.pared with ***,the degradation parameters,including pH and MOF-AEP dosage,were ***,radical quenching experiments and electron paramagnetic resonance(EPR)measurements revealed that ^(1)O_(2)might be the primary catalytic species,whereas·O~(2-)might be the seco.dary one in degrading MB.

关键词： advanced oxidation process alco.ol solvent evaporation hydrogen bond S and co.co.doped carbon catalysts wastewater remediation

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SensFL:Privacy-Preserving Vertical Federated Learning with Sensitive Regularization

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co.puter Modeling in Engineering & Sciences 2025年第1期142卷 385-404页

作者： Chongzhen Zhang Zhichen Liu Xiangrui Xu Fuqiang Hu Jiao Dai Baigen Cai Wei Wang School of Automation and Intelligence Beijing Jiaotong UniversityBeijing100044China Shuohuang Railway Development co. Ltd.National Energy GroupCangzhou062350China beijing Key Laboratory of Security and Privacy in Intelligent Transportation School of Computer Science and TechnologyBeijing Jiaotong UniversityBeijing100044China

In the realm of Intelligent Railway Transportation Systems,effective multi-party co.laboration is crucial due to co.cerns over privacy and data *** Federated Learning(VFL)has emerged as a promising approach to facilitate such co.laboration,allowing diverse entities to co.lectively enhance machine learning models without the need to share sensitive training ***,existing works have highlighted VFL’s susceptibility to privacy inference attacks,where an honest but curious server co.ld potentially reco.struct a client’s raw data from embeddings uploaded by the *** vulnerability poses a significant threat to VFL-based intelligent railway transportation *** this paper,we introduce SensFL,a novel privacy-enhancing method to against privacy inference attacks in ***,SensFL integrates regularization of the sensitivity of embeddings to the original data into the model training process,effectively limiting the information co.tained in shared *** reducing the sensitivity of embeddings to the original data,SensFL can effectively resist reverse privacy attacks and prevent the reco.struction of the original data from the *** experiments were co.ducted on four distinct datasets and three different models to demonstrate the efficacy of *** results show that SensFL can effectively mitigate privacy inference attacks while maintaining the accuracy of the primary learning *** results undersco.e SensFL’s potential to advance privacy protection technologies within VFL-based intelligent railway systems,addressing critical security co.cerns in co.laborative learning environments.

关键词： Vertical federated learning privacy defenses

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Study on the hydrogen absorption properties of a YGdTbDyHo rare-earth high-entropy alloy

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 127-135页

作者： Tongyue Li Ziliang Xie Wenjiao Zhou Huan Tong Dawen Yang Anjia Zhang Yuan Wu Xiping Song State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing 100083China Whole Win(beijing)Materials Sci.&Tech.co. Ltd.Beijing 100083China

This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),*** indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with the alloy elements distributed *** hydrogen absorption,the phase structure of the HEA changed from a solid solution with an hexagonal-close-packed(HCP)structure to a high-entropy hydride with an faced-centered-cubic(FCC)structure without any seco.dary phase *** alloy demonstrated a maximum hydrogen storage capacity of 2.33 H/M(hydrogen atom/metal atom)at 723 K,with an enthalpy change(ΔH)of-141.09 kJ·mol^(-1)and an entropy change(ΔS)of-119.14 J·mol^(-1)·K^(-1).The kinetic mechanism of hydrogen absorption was hydride nucleation and growth,with an apparent activation energy(E_(a))of 20.90 kJ·mol^(-1).Without any activation,the YGdTbDyHo alloy co.ld absorb hydrogen quickly(180 s at 923 K)with nearly no incubation period *** reason for the obtained value of 2.33 H/M was that the hydrogen atoms occupied both tetrahedral and octahedral *** results demonstrate the potential application of HEAs as a high-capacity hydrogen storage material with a large H/M ratio,which can be used in the deuterium storage field.

关键词： rare-earth high-entropy alloy hydrogen absorption capacity pressure–co.position–temperature curves kinetics

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Bending Stiffness of co.crete-Filled Steel Tube and Its Influence on co.crete Placement Timing of co.posite Beam-String Structure

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Structural Durability & Health Monitoring 2025年第1期19卷 55-75页

作者： Zhenyu Zhang Quan Jin Haitao Zhang Zhao Liu Yuyang Wu Longfei Zhang Renzhang Yan CCCC Third Highway Engineering co. Ltd.Beijing101300China School of Civil Engineering Chongqing Jiaotong UniversityChongqing400074China

When the upper chord beam of the beam-string structure(BSS)is made of co.crete-filled steel tube(CFST),its overall stiffness will change greatly with the co.struction of co.crete placement,which will have an impact on the design of the tensioning plans and selection of co.trol measures for the *** order to accurately obtain the bending stiffness of CFST beam and clarify its impact on the mechanical properties of co.posite BSS during co.struction,the influence of some factors such as height-width ratio,wall thickness of steel tube,elasticity modulus of co.crete,and friction co.fficient on the bending stiffness are analyzed parametrically by the numerical simulation technology based on an actual *** calculation formula of the equivalent bending stiffness of CFST is also established through mathematical statistical ***,the equivalent bending stiffness is introduced into the co.struction and use stages of the co.posite BSS,respectively,and the mechanical properties such as prestress-tensioning co.trol value,structural deformation,and internal force of key members are co.paratively analyzed when adopting two different co.struction ***,the optimal co.struction plan of co.crete placement first and then prestress-tensioning is proposed.

关键词： co.crete panels freeze-thaw damage co.pression-shear crack tension-shear crack

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Knowledge Map Mining of Financial Data

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Tsinghua Science and Technology 2013年第1期18卷 68-76页

作者： Wenhui Shou Wenhui Fan Boyuan Liu Yuyang Lai the Department of Automation Tsinghua University the soyotec Technologies co. Ltd.

The Knowledge Map （KM） co.cept, which was derived to describe and manage knowledge. KM provides insight into the from the Fuzzy co.nitive Map （FCM）, is used interdependencies and uncertainties co.tained in the system. This paper uses a model-free method to mine KMs in historical data to analyze co.ponent stock co.porations of the Shanghai Stock 50 index. The analyses use static and time-domain analyses. The results indicate that a knowledge map is useful for representing knowledge and for monitoring the health of co.panies. Furthermore, sudden changes of the key features of the KMs should be taken seriously by policymakers as an alarm of a crisis.

关键词： Knowledge Map (KM) data mining health monitoring crisis warning

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The Mechanism of Heating Rate on the Seco.dary Recrystallization Evolution in Grain Oriented Silico. Steel

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期 275-282页

作者：高倩 LI Jun WANG Xianhui CAO Laifu GONG Jian LI Bo Central Iron and Steel Research Institute Group Shougang Zhixin Electromagnetic Material R&D (beijing) co. Ltd. beijing Shougang co. Ltd.

Grain-oriented silico. steels were prepared at different heating rates during high temperature annealing, in which the evolution of magnetic properties, grain orientations and precipitates were studied. To illustrate the Zener factor, the diameter and number density of precipitates of interrupted testing samples were statistically calculated. The effect of precipitate ripening on the Goss texture and magnetic property was investigated. Data indicated that the trend of Zener factor was similar under different heating rates, first increasing and then decreasing, and that the precipitate maturing was greatly inhibited as the heating rate increased. Seco.dary recrystallization was developed at the temperature of 1 010 ℃ when a heating rate of 5 ℃/h was used, resulting in Goss, Brass and {110} oriented grains growing abnormally and a magnetic induction intensity of 1.90T. Furthermore, increasing the heating rate to 20 ℃/h would inhibit the development of undesirable oriented grains and obtain a sharp Goss texture. However, when the heating rate was extremely fast, such as 40 ℃/h, poor seco.dary recrystallization was developed with many island grains, co.responding to a decrease in magnetic induction intensity to 1.87 T. At a suitable heating rate of 20 ℃/h, the sharpest Goss texture and the highest magnetic induction of 1.94 T with an onset seco.dary recrystallization temperature of 1 020 ℃ were found among the experimental variables in this study. The heating rate affected the initial temperature of seco.dary recrystallization by co.trolling the maturation of precipitates, leading to the deviation and dispersion of Goss texture, thereby reducing the magnetic properties.

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Boosting bidirectional sulfur co.version enabled by introducing boron-doped atoms and phosphorus vacancies in Ni2P for lithium-sulfur batteries

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Journal of Energy Chemistry 2025年第1期100卷 760-769页

作者： Lin Peng Yu Bai Hang Li Meixiu Qu Zhenhua Wang Kening Sun Advanced Research Institute of Multidisciplinary Science Beijing Institute of Technology beijing Key Laboratory of Chemical Power Source and Green Catalysis School of Chemistry and Chemical Engineering Beijing Institute of Technology

Lithium-sulfur （Li-S） batteries have gained great attention due to the high theoretical energy density and low co.t,yet their further co.mercialization has been obstructed by the notorious shuttle effect and sluggish redox ***,we supply a strategy to optimize the electron structure of Ni2P by co.currently introducing B-doped atoms and P vacancies in Ni2P （Vp-B-Ni2P）,thereby enhancing the bidirectional sulfur *** study indicates that the simultaneous introduction of B-doped atoms and P vacancies in Ni2P causes the redistribution of electron around Ni atoms,bringing about the upward shift of d-band center of Ni atoms and effective d-p orbital hybridization between Ni atoms and sulfur species,thus strengthening the chemical anchoring for lithium polysulfides （LiPSs） as well as expediting the bidirectional co.version kinetics of sulfur ***,theoretical calculations reveal that the inco.poration of B-doped atoms and P vacancies in Ni2P selectively promotes Li2S dissolution and nucleation ***,the Li-S batteries with Vp-B-Ni2P-separators present outstanding rate ability of 777 m A h g-1at 5 C and high areal capacity of 8.03 mA h cm-2under E/S of 5μL mg-1and sulfur loading of 7.20 mg *** work elucidates that introducing heteroatom and vacancy in metal phosphide co.laboratively regulates the electron structure to accelerate bidirectional sulfur co.version.

关键词： Lithium sulfur batteries

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T cell interactions with microglia in immune-inflammatory processes of ischemic stroke

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Neural Regeneration Research 2025年第5期20卷 1277-1292页

作者： Yuxiao Zheng Zilin Ren Ying Liu Juntang Yan co.gai Chen Yanhui He Yuyu Shi Fafeng Cheng Qingguo Wang Changxiang Li Xueqian Wang School of Traditional Chinese Medicine Beijing University of Chinese MedicineBeijingChina Library Beijing University of Chinese MedicineBeijingChina Dongzhimen Hospital Beijing University of Chinese MedicineBeijingChina

The primary mechanism of seco.dary injury after cerebral ischemia may be the brain inflammation that emerges after an ischemic stroke,which promotes neuronal death and inhibits nerve tissue *** the first immune cells to be activated after an ischemic stroke,microglia play an important immunomodulatory role in the progression of the *** an ischemic stroke,peripheral blood immune cells(mainly T cells)are recruited to the central nervous system by chemokines secreted by immune cells in the brain,where they interact with central nervous system cells(mainly microglia)to trigger a seco.dary neuroimmune *** review summarizes the interactions between T cells and microglia in the immune-inflammatory processes of ischemic *** found that,during ischemic stroke,T cells and microglia demonstrate a more pronounced synergistic ***1,Th17,and M1 microglia can co.secrete proinflammatory factors,such as interferon-γ,tumor necrosis factor-α,and interleukin-1β,to promote neuroinflammation and exacerbate brain ***2,Treg,and M2 microglia jointly secrete anti-inflammatory factors,such as interleukin-4,interleukin-10,and transforming growth factor-β,to inhibit the progression of neuroinflammation,as well as growth factors such as brain-derived neurotrophic factor to promote nerve regeneration and repair brain *** interactions between microglia and T cells influence the direction of the subsequent neuroinflammation,which in turn determines the prognosis of ischemic stroke *** trials have been co.ducted on the ways to modulate the interactions between T cells and microglia toward anti-inflammatory co.munication using the immunosuppressant fingolimod or overdosing with Treg cells to promote neural tissue repair and reduce the damage caused by ischemic ***,such studies have been relatively infrequent,and clinical experience is still *** summary,in ischemic stroke,T cell subsets and activated micro

关键词： brain immune inflammation interaction ischemic stroke mechanism microglia neuron seco.dary injury T cells

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Data Driven Uncertainty Evaluation for co.plex Engineered System Design

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Chinese Journal of Mechanical Engineering 2016年第5期29卷 889-900页

作者： LIU Boyuan HUANG Shuangxi FAN Wenhui XIAO Tianyuan James HUMANN LAI Yuyang JIN Yan State CIMS Engineering Research Center Tsinghua University Beijing 100084 China University of Southern California Los Angeles California USA soyotec Technologies co. Ltd. Beijing 100081 China

co.plex engineered systems are often difficult to analyze and design due to the tangled interdependencies among their subsystems and co.ponents. co.ventional design methods often need exact modeling or accurate structure deco.position, which limits their practical application. The rapid expansion of data makes utilizing data to guide and improve system design indispensable in practical engineering. In this paper, a data driven uncertainty evaluation approach is proposed to support the design of co.plex engineered systems. The co.e of the approach is a data-mining based uncertainty evaluation method that predicts the uncertainty level of a specific system design by means of analyzing association relations along different system attributes and synthesizing the information entropy of the co.ered attribute areas, and a quantitative measure of system uncertainty can be obtained acco.dingly. Monte Carlo simulation is introduced to get the uncertainty extrema, and the possible data distributions under different situations is discussed in detail The uncertainty values can be normalized using the simulation results and the values can be used to evaluate different system designs. A prototype system is established, and two case studies have been carded out. The case of an inverted pendulum system validates the effectiveness of the proposed method, and the case of an oil sump design shows the practicability when two or more design plans need to be co.pared. This research can be used to evaluate the uncertainty of co.plex engineered systems co.pletely relying on data, and is ideally suited for plan selection and performance analysis in system design.

关键词： co.plex engineered system design uncertainty data-driven evaluation Monte Carlo simulation

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Multiphysics simulation and optimization of the in-situ beneficiation process of ilmenite minerals from lunar regolith

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Science China Earth Sciences 2025年第1期 195-207页

作者： Peng ZHANG Xin LIU Guanghui LIU Wei DAI Hanzhe YANG Haibo ZHENG Zhi WANG Ran NIU Yifan BAI Yang ZHANG Chengbao LIU Ge YANG Junwei YANG Guang ZHANG Technology and Engineering Center for Space Utilization Chinese Academy of Sciences beijing Hegong Simulation co. Ltd

The exploration and utilization of lunar resources have beco.e the major objectives of future lunar exploration missions. The classified co.lection and processing of lunar minerals is the basic prerequisite for the in-situ exploration and utilization of lunar resources. In this study, we propose a scheme for in-situ separation of magnetic minerals from lunar soils using the dry magnetic separation method. The scheme can realize the purpose of separating magnetic minerals from lunar regolith by altering the motion trajectory of lunar regolith particles with different magnetic properties. Detailed modeling of the dry magnetic separation device is co.ducted, and the three-dimensional distribution of magnetic parameters is calculated and analyzed. Based on the characterization and analysis of the Chang E-5's samples, the morphologies and physical parameters of lunar regolith particles are modeled and simulated. A discrete element simulation of the motion process of lunar regolith particles under multi-physical field co.ditions is performed, and the influences of key parameters on the beneficiation performance of lunar magnetic minerals are investigated. Our results indicate that optimal separation and beneficiation of lunar regolith particles can be achieved under specific co.ditions of magnetic field strength and drum speed. Additionally, we analyze the effects of lunar weak gravity co.ditions and the charged nature of lunar particles on the beneficiation process, showing that these factors can obviously enhance the beneficiation process of lunar ilmenites. This study demonstrates the feasibility of using the dry magnetic separation method for the beneficiation of magnetic minerals from lunar regolith, providing a theoretical basis for the scientific tasks of co.lecting, processing, and utilizing lunar mineral resources.

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