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Chinese Journal of Structural Chemistry 2022年第2期41卷 23-33,I0007页

作者： PAN Meng-Qi YANG Run-Qi MUHAMMAD Yaseen CAI Kun-Tong HAN Feng ZHANG Hao-Chen NIU Yuan-Qing WANG Hao beijing key Lab of special elastomer composite materials College of New Materials and Chemical EngineeringBeijing Institute of Petrochemical TechnologyBeijing 102617China Institute of Chemical Sciences University of PeshawarPeshawar 25120Pakistan

A new lanthanide metal-organic framework (MOF)[Eu(BTB)(phen)(DMF)]·DMF (1,DMF=N,N-dimethylformamide) was synthesized using H_(3)BTB (1,3,5-tri(4-carboxyphenyl)benzene) and phen(1,10-phenanthroline) under solvothermal *** structure of the prepared MOF was characterized by single-crystal X-ray diffraction analyses,elemental analysis,fluorescence spectrum,FT-IR spectroscopy,powder X-ray diffraction and thermogravimetric *** structure of 1 can be viewed as a 3-D supramolecular network,which is formed by the stacking of 2D layers throughπ-π*** luminescence explorations revealed that 1 possesses favorable selectivity and sensitivity for testing Fe^(3+).Additionally,color tuning was achieved by varying Eu^(3+):Tb^(3+)ratios in the reaction mixtures.

关键词： lanthanide metal-organic frameworks sensing luminescence Fe^(3+) color tuning

Auxiliary Ligand-tuned Structural Variation of Cd(Ⅱ)Coordination Polymers:Synthesis,Crystal Structures and Luminescent Properties

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Chinese Journal of Structural Chemistry 2016年第11期35卷 1797-1804页

作者：赵帅王浩刘洋伍一波王亚飞郭文莉 beijing key Lab of special elastomer composite materials College of Materials Science and EngineeringBeijing Institute of Petrochemical Technology College of materials Science and Engineering Beijing University of Chemical Technology College of Mechanical Engineering Beijing Institute of Petrochemical Technology

Two new Cd（Ⅱ） coordination polymers, [Cd（PT）（1,4-BDC）0.5]n （1） and [Cd（PT）（1,3-BDC）0.5]n （2）（HPT = 3-（pyridin-2-yl）-1,2,4-triazole, 1,4-H2BDC = 1,4-benzenedicarboxylic acid, 1,3-H2BDC = 1,3-benzenedicarboxylic acid）, have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction as well as elemental analysis and IR. Complexes 1 and 2 are both three-dimensional coordination polymers with two-dimensional sheet structures bridged by the deprotonated carboxylate ligands. In 1, 1,4-BDC2- bridges the layered network to generate a quadrangular framework, and 2 owns a sexangular framework, which was caused by the different steric hindrance between 1,4-BDC^2- and 1,3-BDC^2-. Their thermal stabilities and photoluminescent properties have been also investigated.

关键词： 3-(pyridin-2-yl)-1,2,4-triazole cadmium complex crystal structure

Synthesis,Crystal Structure and Fluorescent Properties of a 1D Europium Coordination Polymer with 2,5-Furandicarboxylic Acid

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Chinese Journal of Structural Chemistry 2022年第3期41卷 92-99,I0009页

作者： ZHANG Han LI Xiang MUHAMMAD Yaseen XIE Hui-Feng ZANG Yi-Han FANG Ming-Lu LIU Shao-Jie WANG Hao beijing key Lab of special elastomer composite materials College of New Materials and Chemical EngineeringBeijing Institute of Petrochemical TechnologyBeijing 102617China Institute of Chemical Sciences University of PeshawarPeshawar 25120KPPakistan

By using solvothermal method,a one-dimensional chain compound[KEu_(2)(FDCA)_(3)(H_(2)O)_(9)·0.5(FDCA)](1)was ***-crystal X-ray diffraction data reveal that 1 crystallizes in monoclinic system,space group P21/n with a=12.1996(1),b=18.6454(2),c=17.7123(2)Å,β=98.8460(10)°,Dc=1.753 g/cm3,Z=2,V=3981.03(7)Å3,R=0.0544 and wR=0.1511 for 7886 observed reflections with I>2σ(I).In 1,three FDCA2–ligands construct a“23-crown-9-like”structure as the second building units(SBUs)to further form an infinite 1D ***,the fluorescent result reveals that compound 1 can selectively and sensitively sense Fe^(3+)by the fluorescence quenching.

关键词： 2,5-furandicarboxylic acid solvothermal synthesis Fe^(3+) fluorescence quenching

Endowing low fatigue for elastocaloric effect by refined hierarchical microcomposite in additive manufactured NiTiCuCo alloy

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International Journal of Extreme Manufacturing 2024年第4期6卷 307-322页

作者： Bo Feng Helong Liu Ying Yang Hui Shen Yang Ren Yinong Liu Lishan Cui Bingmin Huang Shijie Hao College of New Energy and materials China University of PetroleumBeijing 102249People's Republic of China College of Chemical Engineering and Environment China University of PetroleumBeijing 102249People's Republic of China Department of Physics City University of Hong Kong83 Tat Chee AvenueKowloonHong Kong Special Administrative Region of ChinaPeople's Republic of China Department of Mechanical Engineering The University of Western AustraliaPerthWA 6009Australia Jiangsu Smart Advanced Material Tech Co. LtdXuzhou 221000People's Republic of China

NiTiCu-based shape memory alloys have been considered as ideal materials for solid-state refrigeration due to their superb cycling stability for elastocaloric ***,the embrittlement and deterioration caused by secondary phase and coarse grains restrict their applications,and it is still challenging since the geometric components are ***,bulk NiTiCuCo parts with excellent forming quality were fabricated by laser powder bed fusion(LPBF)*** as-fabricated alloy exhibits refined three-phases hierarchical microcomposite formed based on the rapid cooling mode of LPBF,composed of intricate dendritic Ti2Ni–NiTi composite and nano Ti2Cu embedded inside the *** configuration endows far superior elastocaloric stability compared to the as-cast *** low fatigue stems from the strong elastic coupling between the interphases with reversible martensite transformation,revealed by in-situ synchrotron high-energy x-ray *** fabrication of NiTiCuCo alloy via LPBF fills the bill of complex geometric structures for elastocaloric NiTiCu *** understanding of interphase micro-coupling could provide the guide for designing LPBF fabricated shape memory-based composites,enabling their applications for special demands on other functionalities.

关键词： NiTiCuCo shape memoryalloy microcomposite high-energyx-raydiffraction laser powderbedfusion

Promoting electrocatalytic alcohols oxidation coupled with H_(2) production via ligand intercalation strategy

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Nano Research 2023年第4期16卷 4596-4602页

作者： Li Li Zhiyuan Zhang Haotong Chen Fei Chen College of New materials and Chemical Engineering Beijing Key Lab of Special Elastomeric Composite MaterialsBeijing Institute of Petrochemical TechnologyBeijing 102617China

Electrochemical alcohol oxidation,the alternate of oxygen evolution reaction,has been recognized as an effective way to produce value-added chemicals coupled with H2 ***,the current researches still suffer from the low reaction rate and Faradaic efficiency(FE)that limits the overall ***,we report a ligand intercalation strategy to enhance the current density of alcohol electrooxidation by intercalating sodium dodecyl sulfonate(SDS)in the interlayer of Co(OH)_(2)catalyst(Co(OH)_(2)-SDS).For instance,the Co(OH)_(2)-SDS shows obviously enhanced current density for glycerol electrooxidation than that of pure Co(OH)_(2).The corresponding glycerol conversion rate and H2 production rate reach 0.35 mmol·cm^(−2)·h^(−1)and 9.1 mL·cm^(−2)·h^(−1)at 1.42 V *** hydrogen electrode,which are 2.2-and 1.9-fold higher than that of Co(OH)_(2).The yield of formate reaches 86.6%with selectivity of 95.3%at high glycerol conversion of 95.1%(with FE of 83.3%for glycerol oxidation).The Co(OH)_(2)-SDS is demonstrated efficient for different alcohols with enhanced *** confirmed that the intercalation of SDS in Co(OH)_(2)can promote the generation and exposure of CoOOH reactive sites,and also facilitate the adsorption of alcohol,thus enabling high reaction rate.

关键词： electrocatalysis alcohol oxidation hydrogen cobalt hydroxide ligand intercalation

Synthesis and Properties of Hydroxytelechelic Polyisobutylenes by End Capping with tert-Butyl-dimethyl-(4-methyl-pent-4-enyloxy)-silane

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Chinese Journal of Polymer Science 2019年第9期37卷 936-942页

作者： Jing Li Kang-Da Wu Huang Shan Jing-Han Zhang Ming Zhao Guang-Bi Gong Wen-Li Guo Yi-Bo Wu College of materials Science & Engineering Beijing Institute of Petrochemical Technology Beijing 102617 China Lanzhou Petrochemical Research Center Petrochina Lanzhou 730060 China beijing key laboratory of specialty elastomer composite materials Beijing Institute of Petrochemical Technology Beijing 102617 China

The low-activity cationic monomer tert-butyl-dimethyl-(4-methyl-pent-4-enyloxy)-silane was synthesized by Grignard reaction and hydroxyl-protection reaction. Living polyisobutylene chains were initially synthesized by controlled cationic polymerization and then capped with tert-butyl-dimethyl-(4-methyl-pent-4-enyloxy)-silane. The hydrolysis of these polyisobutylenes end capped with tert-butyl-dimethyl-(4-methyl-pent-4-enyloxy)-silane gave rise to hydroxytelechelic polyisobutylene. NMR analysis confirmed that the hydrolysis was complete. Results also showed that a low polymerization temperature favored the participation of tert-butyl-dimethyl-(4- methyl-pent-4?enyloxy)-silane in the end-capping reaction. Moreover, polyisobutylene-based polyurethane exhibited greater acid resistance than commercial polyurethane.

关键词： Carbocationic polymerization Polyisobutylene Hydrolysis Polyisobutylene-based polyurethane

Regulating the formation ability and mechanical properties of high-entropy transition metal carbides by carbon stoichiometry

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Journal of materials Science & Technology 2022年第26期121卷 181-189页

作者： Juntao Song Guiqing Chen Huimin Xiang Fuzhi Dai Shun Dong Wenbo Han Xinghong Zhang Yanchun Zhou Science and Technology on Advanced composite in special Environments laboratory Harbin Institute of TechnologyHarbin150080China Science and Technology on Advanced Functional composite laboratory Aerospace Research Institute of Materials&Processing TechnologyBeijing100076China

Tremendous efforts have been dedicated to promote the formation ability of high-entropy transition metal ***,the majority of methods for the synthesis of high-entropy transition metal carbides still face the challenges of high temperature,low efficiency,additional longtime post-treatment and uncontrollable *** cope with these challenges,high-entropy transition metal carbides with regulatable carbon stoichiometry(HE TMC)were designed and synthesized,achieving improved ability for single phase solid solutions formation,promoting of sintering and controllable mechanical *** typical composition series,i.e.,easily synthesized(ZrHfTaNb)C(ZHTNC)and difficultly synthesized(Zr_(0.25)Hf_(0.25)Ta_(0.25)Ti_(0.25))C(ZHTTC)are selected to demonstrate the promoting formation ability of single phase solid solutions from carbon stoichiometry *** phase high-entropy ZHTTC,which has been proven difficult in forming a single phase solid solution,can be prepared with the decrease of C/TM ratio under 2000℃;while the high-entropy ZHTNC,which has been proven easy in forming a single phase solid solution,can be synthesized at lower temperatures with the decrease of C/TM *** synergistic effect of entropy stabilization and reduced chemical bond strength gaining from carbon stoichiometry deviations is responsible for the formation of single phase solid solutions and the promoted sintering of HE *** example,the relative density of bulk(ZrHfTaNb)C(SPS-ZHTNC)increases from 90.98%to 94.25%with decreasing the C/TM atomic ratio from 0.9 to *** importantly,the room temperature flexural strength,fracture toughness and brittleness index of SPS-ZHTNCcan be tuned in the range of 384 MPa–419 MPa,4.41 MPam–4.73 MPamand 3.679μm–4.083μm,***,the HE TMCprepared by adjusting the ratio of carbon to refractory transition metal oxides have great potential for achieving low temperature synthesis,promoted sintering and tunable properties.

关键词： Carbon stoichiometry High-entropy ceramics Transition metal carbide Low temperature synthesis Tunable mechanical properties

Medium and high-entropy transition mental disilicides with improved infrared emissivity for thermal protection applications

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Journal of materials Science & Technology 2023年第5期136卷 149-158页

作者： Juntao Song Yuan Cheng Huimin Xiang Fu-Zhi Dai Shun Dong Guiqing Chen Ping Hu Xinghong Zhang Wenbo Han Yanchun Zhou Science and Technology on Advanced composite in special Environments laboratory Harbin Institute of TechnologyHarbin 150080China Science and Technology on Advanced Functional composite laboratory Aerospace Research Institute of Materials&Processing TechnologyBeijing 100076China

Transition metal disilicides are widely used as heating elements and infrared emission ***,the limited intrinsic infrared emissivity and high thermal conductivity are the main limitations to their applications as infrared emission coatings in the thermal protection *** cope with these prob-lems,four medium and high-entropy transition metal disilicides,i.e.,(V_(0.25)Ta_(0.25)Mo_(0.25)W_(0.25))Si_(2)(ME-1),(Nb_(0.25)Ta_(0.25)Mo_(0.25)W_(0.25))Si_(2)(ME-2),(V_(0.2)Nb_(0.2)Ta_(0.2)Mo_(0.2)W_(0.2))Si_(2)(HE-1),and(Cr_(0.2)Nb_(0.2)Ta_(0.2)Mo_(0.2)W_(0.2))Si_(2)(HE-2),were designed and synthesized by spark plasma sintering method using transition metal binary disilicides as *** introduction of multi-elements into transition metal disilicides not only im-proved the infrared emissivity but also reduced the electrical and thermal *** them,(Cr_(0.2)Nb_(0.2)Ta_(0.2)Mo_(0.2)W_(0.2))Si_(2)(HE-2)had the lowest electrical conductivity of 3789 S cm-1,which is over one order of magnitude lower than that of MoSi_(2)(50000 S cm^(-1)),and total infrared emissivity of 0.42 at room temperature,which is nearly double of that of TaSi_(2).Benefiting from low electrical conductivity and phonon scattering due to lattice distortion,the medium and high-entropy transition metal disilicides also demonstrated a significant decline in thermal conductivity compared to their binary *** all samples,HE-2 exhibited the lowest thermal conductivity of 6.4 W m^(−1)K^(−1).The high-entropy tran-sition metal disilicides also present excellent oxidation resistance at high *** improved infrared emissivity,reduced thermal conductivity,excellent oxidation resistance,and lower densities of these medium and high-entropy transition metal disilicides portend that they are promising as infrared emission coating materials for applications in thermal protection systems.

关键词： High-entropy ceramics Transition metal disilicides Electrical conductivity Infrared emissivity Thermal conductivity

Enhanced dielectric properties of polypropylene based composite using Bi2S3 nanorod filler

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Progress in Natural Science:materials International 2011年第3期21卷 216-220页

作者： Yu DANG,Yao WANG,Yuan DENG,Mao LI,Ye ZHANG,Zhi-wei ZHANG beijing key laboratory of special Functional materials and Film,School of Chemistry and Environment, Beihang University,beijing 100191,China beijing key laboratory of special Functional materials and Film School of Chemistry and Environment Beihang University Beijing 100191 China

A novel two-phase composite system using polypropylene(PP) as matrix and semiconductor bismuth sulfide(Bi2S3) as filler,was prepared by a simple *** KH550 was chosen to modify the interface between inorganic fillers and organic PP *** variations of dielectric properties of the Bi2S3/PP composites with the volume fraction of Bi2S3,frequency and temperature were *** results reveal a percolative behavior of the composites with the threshold of *** composite is demonstrated to have good dielectric *** thermal stability of dielectric property and high breakdown strength of the composites show their potential application in film capacitor.

关键词： composite materials dielectric properties interface

Methods of configuration test and deformation analysis for large airship

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Journal of Systems Engineering and Electronics 2022年第4期33卷 951-960页

作者： ZHAI Yutao SHEN Yongzheng YAN Xiangbin TAN Huifeng School of Management Harbin Institute of TechnologyHarbin 150001China State key laboratory of special Environmental composite materials Technology Harbin Institute of TechnologyHarbin 150001China beijing Institute of Telemetry Technology China Aerospace Science and Technology CorporationBeijing 100071China

In recent years, high-altitude aerostats have been increasingly developed in the direction of multi-functionality and large size. Due to the large size and the high flexibility, new challenges for large aerostats have appeared in the configuration test and the deformation analysis. The methods of the configuration test and the deformation analysis for large airship have been researched and discussed. A tested method of the configuration,named internal scanning, is established to quickly obtain the spatial information of all surfaces for the large airship by the three-dimensional(3D) laser scanning technology. By using the surface wrap method, the configuration parameters of the large airship are calculated. According to the test data of the configuration, the structural dimensions such as the distances between the characteristic sections are measured. The method of the deformation analysis for the airship contains the algorithm of nonuniform rational B-splines(NURBS) and the finite element(FE)method. The algorithm of NURBS is used to obtain the reconfiguration model of the large airship. The seams are considered and the seam areas are divided. The FE model of the middle part of the large airship is established. The distributions of the stress and the strain for the large airship are obtained by the FE method. The position of the larger deformation for the airship is found.

关键词： large airship deformation analysis three-dimensional(3D)laser scanning technology non-uniform rational B-splines(NURBS) system engineering