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Hydrologic Modeling Impacts of Post-mining Land Use Changes on Streamflow of Peace River, Florida

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Chinese Geographical Science 2015年第6期25卷 728-738页

作者： ZHANG Jing Mark ROSS key laboratory of resource environment and gis in beijing Capital Normal University Department of Civil and environmental Engineering University of South Florida

Whether mining activity results in reduced flow of surface water in the Peace River Watershed of Florida has been the subject of much debate. With increased dependence of downstream users on surface water flow of the Peace River as a source of drinking water for four coastal counties in Southwest Florida and problems of water security, the debate has been intensified. It is possible to assess relationships of mining with streamflow in the upper reaches of the Peace River Basin using hydrologic modeling and identify mined sub-basins. In this work, land-use change impacts were simulated by the Hydrological Simulation Program—Fortran(HSPF) model based on geographical information system(gis) tools, to compare pre- and post-mining streamflows at a study site of the Peace River in west-central Florida. The purpose of this study was to determine if land-use changes caused by mining have negatively impacted streamflow in the Peace River. Changes of land use were identified before and after mining activities. A coupled volume-water depth-discharge(V-h-Q) model based on stage/storage and stage/discharge was applied using HSPF for the pre-mining and post-mining models, respectively. Daily simulated post-mining hydrographs from HSPF were plotted with the calibrated pre-mining results and streamflow hydrographs from the 18 gauging stations, to compare timing of peaks, low flows and flow trends. Analyses of percent exceedances of flow frequency curves of the streams indicated that most streams had similar distributions for mined(reclaimed) and premining periods. In the streamflow change analysis, streamflows actually increased in mining-affected basins at nearly half the stations. Streamflows at other stations diminished. Overall from this comprehensive study, there were declines in streamflow at most gauging stations on the mainstem of the Peace River and its tributaries. The results of this study suggest that regional planning is urgently needed to propose reclamation schemes that enhance regional hydrology.

关键词：土地利用变化流域径流水文模拟采后安宁河佛罗里达州 FORTRAN 地理信息系统

Improving the quality of pollen-climate calibration-sets is the primary step for ensuring reliable climate reconstructions

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Science Bulletin 2018年第20期63卷 1317-1318页

作者： Xianyong Cao Fang Tian Wei Ding key laboratory of Alpine Ecology and Biogeography Institute of Tibetan Plateau Research Chinese Academy of Sciences Beijing Key Laboratory of Resource Environment and GIS College of Resource Environment and Tourism Capital Normal University Institute of Geological Sciences Palaeontology Free University of Berlin

Pollen-based climate reconstructions have been widely applied in China [1,2]as an essential way to investigate quantitatively past climate change,which is necessary to improve the reliability of future climate predictions [3].However,their usefulness is often doubted,particularly for those regions with a long history of civilization (e.g.East China),where both the modern and past vegetation are heavily disturbed by human activities [4-6].Which factors influence the integrity of pollen-based climate reconstructions and how to improve their reliability are rigorous challenges for palynologists.Previous work focusing on these two questions has used modern pollen data from China or eastern continental Asia and mainly concludes that past climate reconstruction is quite sensitive to the clualitv of the calibration-set [2,7].

关键词： pollen-climate

Electrochemical Removal of Chlorophenol Pollutants by Reactive Electrode Membranes: Scale-Up Strategy for Engineered Applications

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Engineering 2022年第2期8卷 77-84页

作者： Shuzhao Pei Yi Wang Shijie You Zhanguo Li Nanqi Ren State key laboratory of Urban Water resource and environment School of EnvironmentHarbin Institute of TechnologyHarbin 150090China State key laboratory of NBC Protection for Civilian Beijing 102205China

Chlorophenols(CPs)are significant refractory pollutants that are highly toxic to humans and other organ-isms.Reactive electrode membranes(REMs)show considerable potential in the electrochemical removal of refractory pollutants by allowing flow-through operations with convection-enhanced mass transfer.However,relevant studies are commonly performed on the laboratory scale,and there is no straightfor-ward method that guarantees success in scaling up engineered REM reactors.In this study,we demon-strated that a tubular concentric electrode(TCE)configuration with a titanium suboxide ceramic anode and a stainless-steel cathode is suitable for large-scale CPs removal.Both theoretical and experi-mental results showed that the TCE configuration not only allows the electrode surface to be orthogonal to electric field lines everywhere,but also has an ohmic resistance that is inversely proportional to the length of the electrode.In addition,the TCE configuration can be operated in either the anode-to-cathode(AC)or the cathode-to-anode(CA)mode based on the flow direction,creating adjustable condi-tions for selective degradation of CPs.This was confirmed by 98%removal of 2,4-dichlorophenol(2,4-DCP)and 72.5%removal of chemical oxygen demand(COD)in the CA mode,in which the kinetic constant was one order of magnitude higher than that for the AC mode under flow-through single-pass operations.This can be explained by the lower activation energy and free energy in the CA mode,as revealed by the-oretical calculations and experimental measurements.The TCE configuration is also suitable for a numbering-up strategy to scale up the electrochemical reactor without increasing the ohmic resistance or decreasing the specific electrode area,achieving 99.4%removal of 2,4-DCP with an energy consump-tion of 1.5 kW·h·m^(-3) when three TCE modules were employed.This study presents a suitable electrode design configuration for the REM reactor,offering effective strategies to bridge the“Valley of Death”encountered when scaling up the electrochemica

关键词： Chlorophenols Reactive electrode membrane Tubular concentric electrode Scale-up

Driving forces analysis of reservoir wetland evolution in beijing during 1984-2010

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Journal of Geographical Sciences 2013年第4期23卷 753-768页

作者：宫兆宁李洪赵文吉宫辉力 Base of the State laboratory of Urban environmental Processes and Digital Modeling key laboratory of 3D Information Acquisition and Application of Ministry key laboratory of resource environment and gis of beijing College of resource environment & Tourism Capital Normal University Beijing 100048 China

The reservoir wetland, which is the largest artificial wetland in beijing, constitutes one of the important urban ecological infrastructures. Considering two elements of natural environment and socio-economy, this paper established the driving factor indexing system of beijing reservoir wetland evolution. Natural environment driving factors include precipitation, temperature, entry water and groundwater depth; social economic driving factors include resident population, urbanization rate and per capita GDP. Using multi-temporal Landsat TM images from 1984 to 2010 in beijing, the spatial extent and the distribution of beijing reservoir wetlands were extracted, and the change of the wetland area about the three decade years were analyzed. Logistic regression model was used to explore for each of the three periods： from 1984 to 1998, from 1998 to 2004 and from 2004 to 2010. The results showed that the leading driving factors and their influences on reservoir wetland evolution were different for each period. During 1984-1998, two natural environment indices： average annual precipitation and entry water index were the major factors driving the increase in wetland area with the contribution rate of Logistic regression being 5.78 and 3.50, respectively, and caused the wetland growth from total area of 104.93 km 2 to 219.96 km 2 . From 1998 to 2004, as the impact of human activities intensified the main driving factors were the number of residents, groundwater depth and urbanization rate with the contribution rate of Logistic regression 9.41, 9.18, and 7.77, respectively, and caused the wetland shrinkage rapidly from the total area of 219.96 km 2 to 95.71 km 2 . During 2004-2010, reservoir wetland evolution was impacted by both natural and socio-economic factors, and the dominant driving factors were urbanization rate and precipitation with the contribution rate of 6.62 and 4.22, respectively, and caused the wetland total area growth slightly to 109.73 km 2 .

关键词： reservoir wetland driving force Logistic regression model beijing

Genotypic variations in the accumulation of Cd exhibited by different vegetables

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Journal of environmental Sciences 2010年第8期22卷 1246-1252页

作者： Junxing Yang Haitao Guo Yibing Ma Liqun Wang Dongpu Wei Luo Hua Ministry of Agriculture key laboratory of Plant Nutrition and Nutrient Cycling Institute of Agricultural Resources and Regional Planning Chinese Academy of Agricultural Sciences Beijing 100081 China The key laboratory of resource environment and gis College of Resource Environment and Tourism Capital Normal University Beijing 100037 China

It is an important approach to use the Cd-contaminated soils properly by growing low accumulator or excluder plants for Cd to produce safe foods. To find the suitable vegetable species for growing in Cd-contaminated soils, in the present study the variations in the Cd accumulation for twenty eight vegetable species and several cultivars of five common vegetables （cowpea, kidney pea, bitter gourd, cucumber and squash） were investigated in two soil Cd levels （1 and 2 mg/kg Cd）. Experimental results showed that highly significant differences in Cd concentration were evident among 28 vegetables. For example, spinach Cd concentrations were 110-fold and 175-fold higher than that of sweet pea under the 1 and 2 mg/kg Cd exposures, respectively. For Cd accumulation, the order of vegetable species was： leafy vegetables solanaceous vegetables kale vegetables root vegetables allimus melon vegetables legumes. Distinctive differences were also identified when comparing different cultivars of the five common vegetables with an average range of 0.003–0.094 mg/kg Cd. Our results indicated that a large genotypic variation existed among vegetable species or cultivars when subjected to Cd exposure. Therefore, it is important and feasible to elect/breed vegetable species/cultivars with low accumulation of Cd, especially in mildly Cd-contaminated soils.

关键词： vegetables cadmium accumulation genotypic variations

A combined evaluation of the characteristics and antibiotic resistance induction potential of antibiotic wastewater during the treatment process

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Journal of environmental Sciences 2024年第4期138卷 626-636页

作者： Sun Miao Yanyan Zhang Cong Men Yiou Mao Jiane Zuo State key Joint laboratory of environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing 100084China School of Energy and environmental Engineering Beijing Key Laboratory of Resource-Oriented Treatment of Industrial PollutantsUniversity of Science and Technology BeijingBeijing 100083China High School Affiliated to Renmin University of China Beijing 100080China Tsinghua Shenzhen International Graduate School Shenzhen 518055China

Antibiotic wastewater contains a variety of pollutant stressors that can induce and promote antibiotic resistance(AR)when released into the environment.Although these substances are mostly in concentrations lower than those known to induce AR individually,it is possible that antibiotic wastewater discharge might still promote the AR transmission risk via additive or synergistic effects.However,the comprehensive effect of antibiotic wastewater on AR development has rarely been evaluated,and its treatment efficiency remains unknown.Here,samples were collected from different stages of a cephalosporin production wastewater treatment plant,and the potential AR induction effect of their chemical mixtures was explored through the exposure of the antibiotic-sensitive Escherichia coli K12 strain.Incubation with raw cephalosporin production wastewater significantly promoted mutation rates(3.6×10^(3)-9.3×10^(3)-fold)and minimum inhibition concentrations(6.0-6.7-fold)of E.coli against ampicillin and chloramphenicol.This may be attributed to the inhibition effect and oxidative stress of cephalosporin wastewater on E.coli.The AR induction effect of cephalosporin wastewater decreased after the coagulation sedimentation treatment and was completely removed after the full treatment process.A Pearson correlation analysis revealed that the reduction in the AR induction effect had a strong positive correlation with the removal of organics and biological toxicity.This indicates that the antibiotic wastewater treatment had a collaborative processing effect of conventional pollutants,toxicity,and the AR induction effect.This study illustrates the potential AR transmission risk of antibiotic wastewater and highlights the need for its adequate treatment.

关键词： Antibiotic wastewater treatment plant Antibiotic resistance Antibiotic resistance induction effect Correlation analysis Biological toxicity

Performance of a completely autotrophic nitrogen removal over nitrite process for treating wastewater with different substrates at ambient temperature

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Journal of environmental Sciences 2013年第4期25卷 688-697页

作者： Xiaoyan Chang Dong Li Yuhai Liang Zhuo Yang Shaoming Cui Tao Liu Huiping Zeng Jie Zhang key laboratory of beijing for Water Quality Science and Water environment Recovery Engineering Beijing University of Technology State key laboratory of Urban Water resource and environment Harbin Institute of Technology

The stability and parameters of a bio-ceramic filter for completely autotrophic nitrogen removal were investigated. The completely autotrophic nitrogen removal over nitrite （CANON） reactor was fed with different concentrations of ammonia （400, 300, and 200 mg N/L） but constant influent ammonia load. The results showed that the CANON system can achieve good treatment performance at ambient temperature （15-23℃）. The average removal rate and removal loading of NH4＋-N and TN was 83.90%, 1.26 kg N/（m3.day）, and 70.14%, 1.09 kg N/（m3.day）, respectively. Among the influencing factors like pH, dissolved oxygen and alkalinity, it was indicated that the pH was the key parameter of the performance of the CANON system. Observing the variation of pH would contribute to better control of the CANON system in an intuitive and fast way. Denaturing gradient gel electrophoresis analysis of microorganisms further revealed that there were some significant changes in the community structure of ammonium oxidizing bacteria, which had low diversity in different stages, while the species of anaerobic ammonium oxidizing （anammox） bacteria were fewer and the community composition was relatively stable. These observations showed that anaerobic ammonia oxidation was more stable than the aerobic ammonia oxidation, which could explain that why the CANON system maintained a good removal efficiency under the changing substrate conditions.

关键词： completely autotrophic nitrogen removal over nitrite bio-filter anammox pH dissolved oxygen alkalinity

Real-world emission characteristics of carbonyl compounds from agricultural machines based on a portable emission measurement system

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Journal of environmental Sciences 2023年第2期124卷 846-859页

作者： Wenhan Yu Xianbao Shen BoboWu Lei Kong Kaijie Xuan Cheng Zhao Xinyue Cao Xuewei Hao Xin Li Hanyu Zhang Zhiliang Yao School of Ecology and environment Beijing Technology and Business UniversityBeijing 100048China State environmental Protection key laboratory of Food Chain Pollution Control Beijing Technology and Business UniversityBeijing 100048China key laboratory of Cleaner Production and Integrated resource Utilization of China National Light Industry Beijing Technology and Business UniversityBeijing 100048China

Emissions of carbonyl compounds from agricultural machines cannot be ignored.Carbonyl compounds can cause the formation of ozone(O3)and secondary organic aerosols,which can cause photochemical smog to form.In this study,20 agricultural machines were tested using portable emission measurement system(PEMS)under real-world tillage processes.The exhaust gases were sampled using 2,4-dinitrophenylhydrazine cartridges,and 15 carbonyl compounds were analyzed by high-performance liquid chromatography.Carbonyl compound emission factors for agricultural machines were 51.14–3315.62 mg/(kg-fuel),and were 2.58±2.05,0.86±1.07 and 0.29±0.20 g/(kg-fuel)for China 0,China II and China III emission standards,respectively.Carbonyl compound emission factor for sowing seeds of China 0 agricultural machines was 3.32±1.73 g/(kg-fuel).Formaldehyde,acetaldehyde and acrolein were the dominant carbonyl compounds emitted.Differences in emission standards and tillage processes impact ozone formation potential(OFP).The mean OFP was 20.15±16.15 g O3/(kg-fuel)for the China 0 emission standard.The OFP values decreased by 66.9% from China 0 to China II,and 67.4%from China II to China III.The mean OFP for sowing seeds of China 0 agricultural machines was 25.92±13.84 g O3/(kg-fuel).Between 1.75 and 24.22 times more ozone was found to be formed during sowing seeds than during other processes for China 0 and China II agricultural machines.Total carbonyl compound emissions from agricultural machines in China was 19.23 Gg in 2019.The results improve our understanding of carbonyl compound emissions from agricultural machines in China.

关键词： Agricultural machines Carbonyl compounds Emission characteristics Tillage process PEMS

A cellphone-based colorimetric multi-channel sensor for water environmental monitoring

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Frontiers of environmental Science & Engineering 2022年第12期16卷 67-78页

作者： Yunpeng Xing Boyuan Xue Yongshu Lin Xueqi Wu Fang Fang Peishi Qi Jinsong Guo Xiaohong Zhou State key laboratory of Urban Water resource and environment School of EnvironmentHarbin Institute of TechnologyHarbin150090China State key Joint laboratory of ESPC Center for Sensor Technology of Environment and HealthSchool of EnvironmentTsinghua UniversityBeijing100084China key laboratory of the Three Gorges Reservoir Region’s Eco-environments of MOE Chongqing UniversityChongqing400030China

The development of colorimetric analysis technologies for the commercial cellphone platform has attracted great attention in environmental monitoring due to the low cost,high versatility,easy miniaturization,and widespread ownership of cellphones.This work demonstrates a cellphone-based colorimetric multi-channel sensor for quantifying multiple environmental contaminants simultaneously with high sensitivity and stability.To improve the sensitivity of the sensor,a delicate optical path system was created by using a diffraction grating to split six white beams transmitting through the multiple colored samples,which allows the cellphone CMOS camera to capture the diffracted light for image analysis.The proposed sensor is a universal colorimetric detection platform for a variety of environmental contaminants with the colorimetry assay in the range of 400–700 nm.By introducing the diffraction grating for splitting light,the sensitivity was improved by over six folds compared with a system that directly photographed transmitted light.As a successful proof-of-concept,the sensor was used to detect turbidity,orthophosphate,ammonia nitrogen and three heavy metals simultaneously with high sensitivity(turbidity:detection limit of 1.3 NTU,linear range of 5–400 NTU;ammonia nitrogen:0.014 mg/L,0.05–5 mg/L;orthophosphate:0.028 mg/L,0.1–10 mg/L;Cr(VI):0.0069 mg/L,0.01–0.5 mg/L;Fe:0.025 mg/L,0.1–2 mg/L;Zn:0.032 mg/L,0.05–2 mg/L)and reliability(relative standard deviations of six parallel measurements of 0.37%–1.60%and recoveries of 95.5%–106.0%in surface water).The miniature sensor demonstrated in-field sensing ability in environmental monitoring,which can be extended to point-of-care diagnosis and food safety control.

关键词： Colorimetric analysis Multi-channel sensor Cellphone Water quality indexes environmental monitoring