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Development of a model to simulate soil heavy metals lateral migration quantity based on SWAT in Huanjiang watershed,China

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Journal of Environmental Sciences 2019年第3期31卷 115-129页

作者： Pengwei Qiao Mei Lei Sucai Yang Jun Yang Xiaoyong Zhou Nan Dong Guanghui Guo Institute of Geographic Sciences and Natural Resources Research Chinese Academy of Sciences Beijing Key Laboratory of Remediation of Industrial Pollution Sites Environmental Protection Research Institute of Light Industry Comprehensive Institute of Geotechnical Investigation and Surveying Ltd.

Lateral transportation of soil heavy metals in rainfall events could significantly increase the scope of pollution. Therefore, it is necessary to develop a model with high accuracy to simulate the migration quantity of heavy metals. A model for heavy metal migration simulation was developed based on the SWAT(Soil and Water Assessment Tool) model. This model took into consideration the influence of soil p H value, soil particle size, runoff volume, sediment amount,concentration of water-soluble heavy metals dissolved in runoff and insoluble absorbed to the soil particles. This model was reasonable in Huanjiang watershed, Guangxi Zhuang Autonomous Region, south China, covering an area of 273 km^2. The optimal drainage area threshold was determined by analyzing the effects of watershed subdivision on the simulation results to ensure the simulation accuracy. The main conclusions of this paper were:(1) watershed subdivision could affect simulation migration quantity of heavy metals;(2) the quantity of heavy metals transported by sediment accounted for 97%–99% of the total migration quantity in the study watershed. Therefore, sediment played the most important role in heavy metal migration;(3) the optimal drainage area threshold percentage to ensure high simulation accuracy was determined to be 2.01% of the total watershed;(4) with the optimal threshold percentage, this model could simulate the migration quantity of As, Pb and Cd accurately at the total watershed and subwatershed level. The results of this paper were useful for identifying the key regions with heavy metal migration.

关键词： Soil heavy metal migration Simulation model Watershed subdivision Optimal drainage area threshold percentage Simulation accuracy

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Identifying factors that influence soil heavy metals by using categorical regression analysis:A case study in beijing,China

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Frontiers of Environmental Science & Engineering 2020年第3期14卷 1-14页

作者： Jun Yang Jingyun Wang Pengwei Qiao Yuanming Zheng Junxing Yang Tongbin Chen Mei Lei Xiaoming Wan Xiaoyong Zhou Center for Environmental remediation Institute of Geographic Sciences and Natural Resources ResearchChinese Academy of SciencesBeijing 100101China University of Chinese Academy of Sciences Beijing 100049China Research Center for Eco-Environmental Sciences Chinese Academy of SciencesBeijing 100085China Beijing Key Laboratory of Remediation of Industrial Pollution Sites Environmental Protection Research Institute of Light IndustryBeijing 100048China

Identifying the factors that influence the heavy metal contents of soil could reveal the sources of soil heavy metal pollution.In this study,a categorical regression was used to identify the factors that influence soil heavy metals.First,environmental factors were associated with soil heavy metal data,and then,the degree of influence of different factors on the soil heavy metal contents in beijing was analyzed using a categorical regression.The results showed that the soil parent material,soil type,land use type,and industrial activity were the main influencing factors,which suggested that these four factors were important sources of soil heavy metals in beijing.In addition,population density had a certain influence on the soil Pb and Zn contents.The distribution of soil As,Cd,Pb,and Zn was markedly influenced by interactions,such as traffic activity and land use type,industrial activity and population density.The spatial distribution of soil heavy metal hotspots corresponded well with the influencing factors,such as industrial activity,population density,and soil parent material.In this study,the main factors affecting soil heavy metals were identified,and the degree of their influence was ranked.A categorical regression represents a suitable method for identifying the factors that influence soil heavy metal contents and could be used to study the genetic process of regional soil heavy metal pollution.

关键词： Soil Heavy metal Influencing factor Categorical regression Identification method

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Source-specific risk assessment for cadmium in wheat and maize:Towards an enrichment model for China

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Journal of Environmental Sciences 2023年第3期125卷 723-734页

作者： Zhong Zhuang Qiqi Wang Siyu Huang Andrea Giovanna NinoSavala Yanan Wan Huafen Li Andreas H.Schweiger Andreas Fangmeier Jürgen Franzaring beijing key laboratory of Farmland Soil pollution Prevention and remediation Key Laboratory of Plant-Soil Interactions of the Ministry of EducationCollege of Resources and Environmental SciencesChina Agricultural UniversityBeijing 100193China State key laboratory of North China Crop Improvement and Regulation Hebei Agricultural UniversityBaoding 071001China Institute of Landscape and Plant Ecology University of Hohenheim70599 StuttgartGermany

Cadmium (Cd) pollution of agricultural soil is of public concern due to its high potential toxicity and mobility.This study aimed to reveal the risk of Cd accumulation in soil and wheat/maize systems,with a specific focus on the source-specific ecological risk,human health risk and Cd enrichment model.For this we investigated more than 6100 paired soil and grain samples with 216 datasets including soil Cd contents,soil pH and grain Cd contents of 85 sites from China.The results showed that mining activities,sewage irrigation,industrial activities and agricultural practices were the critical factors causing Cd accumulation in wheat and maize cultivated sites.Thereinto,mining activities contributed to a higher Cd accumulation risk in the southwest China and Middle Yellow River regions;sewage irrigation influenced the Cd accumulation in the North China Plain.In addition,the investigated sites were classified into different categories by comparing their soil and grain Cd contents with the Chinese soil screening values and food safety values,respectively.Cd enrichment models were developed to predict the Cd levels in wheat and maize grains.The results showed that the models exhibited a good performance for predicting the grain Cd contents among safe and warning sites of wheat (R2=0.61 and 0.72,respectively);while the well-fitted model for maize was prone to the overestimated sites (R2=0.77).This study will provide national viewpoints for the risk assessments and prediction of Cd accumulation in soil and wheat/maize systems.

关键词： Ecological risk Enrichment models Cadmium Health risk assessment pollution sources

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Simultaneous removal of NO and dichloromethane(CH_(2)Cl_(2)) over Nb-loaded cerium nanotubes catalyst

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Journal of Environmental Sciences 2022年第1期34卷 175-184页

作者： Weilong Ouyang Yi Zhou Xiaoqi Fei Yarong Bai Haiqiang Wang Zhongbiao Wu key laboratory of Environment remediation and Ecological Health Ministry of EducationCollege of Environmental and Resources ScienceZhejiang UniversityHangzhou 310058China Zhejiang Provincial Engineering Research Center of industrial Boiler and Furnace Flue Gas pollution Control Hangzhou 310058China

Herein,a series of niobium oxide supported cerium nanotubes(Ce NTs)catalysts with different loading amount of Nb_(2)O_(5)(0–10 wt.%)were prepared and used for selective catalytic reduction of NOxwith NH_(3)(NH_(3)-SCR)in the presence of CH_(2)Cl_(2).Commercial V_(2)O_(5)-WO_(3)-TiO_(2) catalyst was also prepared for comparison.The physcial properties and chemical properties of the Nb_(2)O_(5) loaded cerium nanotubes catalysts were investigated by X-ray diffractometer,Transmission electron microscope,Brunauer-Emmett-Teller specific surface area,H_(2)-temperature programmed reduction,NH_(3)-temperature programmed desorption and Xray photoelectron spectroscopy.The experiment results showed that the loading amount of Nb_(2)O_(5) had a significant effect on the catalytic performance of the catalysts.10 wt.%Nb-Ce NTs catalyst presented the best NH_(3)-SCR performance and degradation efficiency of CH_(2)Cl_(2) among the prepared catalysts,due to its superior redox capability,abundant surface oxygen species and acid sites,the interaction between Nb and Ce,higher ratio of Nb^(4+)/(Nb^(5+)+Nb^(4+))and Ce^(3+)/(Ce^(3+)+Ce^(4+)),as well as the special tubular structure of cerium nanotube.This study may provide a practical approach for the design and synthesis of SCR catalysts for the simultaneously removal NOxand chlorinated volatile organic compounds(CVOCs)emitted from the stationary industrial sources.

关键词： Cerium nanotubes Niobium oxide Selective catalytic reduction Nitrogen oxides CH_(2)Cl_(2) Simultaneous removal

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Biomineralized nanoparticles for the immobilization and degradation of crude oil-contaminated soil

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Nano Research 2023年第10期16卷 12238-12245页

作者： Daoqing Liu Qianwei Li Enhui Liu Miao Zhang Jicheng Liu Chunmao Chen key laboratory of Water and Sediment Sciences(Ministry of Education) College of Environmental Sciences and EngineeringPeking UniversityBeijing 100871China State key laboratory of Heavy Oil Processing State Key Laboratory of Petroleum Pollution ControlChina University of Petroleum(Beijing)Beijing 102249China

Accidental oil leaks and spills often cause server soil pollution,and in situ remediation is a powerful and economical treatment technology.While during in situ remediation process,unpredicted migration of petroleum hydrocarbon in heterogeneous soil will lead to a long-term source of persistent aquifer contamination.To reduce the migration of petroleum hydrocarbon and effectively improve the in situ remediation efficiency,herein,fungal biomineralization strategy was proposed for the immobilization of petroleum contaminants.A ureolytic fungi strain with crude oil-degradation ability was screened and identified as Chaetomium globosum.When incubated in medium containing Ca2+and crude oil,a mineral corona with spiny nanoparticles was formed at the edge of oil and the interface characters were analyzed using fluorescent pH and dissolved oxygen(DO)sensing films,respectively.Results indicated that biominerals preferred to aggregate around the edge of crude oil,providing favorable microenvironment for fungal growth and then leading to the increase of pH in the microenvironment,eventually accompanied by the formation of mineral corona.The mineral corona with numerous nanoparticles may act as a solid and stable shell,limiting or reducing the mobility of crude oil,and providing enough time for fungal biodegradation.After 28 days incubation,oilcontaminated soil treated with fungal biomineralization showed better immobilization ability for total petroleum hydrocarbon(TPH)under simulated acid-rain condition and higher TPH removal efficiency.This is the first demonstration for the immobilization of oil through fungal biomineralized nanoparticles,thus providing a novel strategy for the in situ remediation of oilcontaminated sites.

关键词： biomineralization degradation nanomineral nanoaggregates immigration

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In-situ construction of abundant active centers on hierarchically porous carbon electrode toward high-performance phosphate electrosorption: Synergistic effect of electric field and capture sites

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Green Energy & Environment 2024年第1期9卷 126-137页

作者： Peng Zhang Fukuan Li Mingming He Silu Huo Xueli Zhang Benqiang Cen Dezhi Fang Kexun Li Hao Wang College of Environmental Science and Engineering Nankai UniversityTianjin300350China MOE key laboratory of pollution Processes and Environmental Criteria Tianjin Key Laboratory of Environmental Remediation and Pollution ControlTianjin Key Laboratory of Environmental Technology for Complex Trans-Media PollutionNankai UniversityTianjin300350China State key laboratory of Simulation and Regulation of Water Cycles in River Basins China Institute of Water Resources and Hydropower ResearchBeijing100038China

Phosphate removal is crucial for eutrophication control and water quality improvement.Electro-assisted adsorption,an eco-friendly elec-trosorption process,exhibited a promising potential for wastewater treatment.However,there are few works focused on phosphate electro-sorption,and reported electrodes cannot attach satisfactory removal capacities and rates.Herein,electro-assisted adsorption of phosphate via in-situ construction of La active centers on hierarchically porous carbon(LaPC)has been originally demonstrated.The resulted LaPC composite not only possessed a hierarchically porous structure with uniformly dispersed La active sites,but also provided good conductivity for interfacial electron transfer.The LaPC electrode achieved an ultrahigh phosphate electrosorption capability of 462.01 mg g^(-1) at 1 V,outperforming most existing electrodes.The superior phosphate removal performance originates from abundant active centers formed by the coupling of electricﬁeld and capture sites.Besides,the stability and selectivity toward phosphate capture were maintained well even under comprehensive conditions.Moreover,a series of kinetics and isotherms models were employed to validate the electrosorption process.This work demonstrates a deep understanding and promotes a new level of phosphate electrosorption.

关键词： Electro-assisted adsorption Electrosorption Phosphate removal Active centers MOF-derived carbon

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Engineering practice of mechanical soil aeration for the remediation of volatile organic compound-contaminated sites in China： Advantages and challenges

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Frontiers of Environmental Science & Engineering 2016年第6期10卷 17-27页

作者： Yan Ma Xiaoming Du Yi Shi Deyi Hou Binbin Dong Zhu Xu Huiying Li Yunfeng Xie Jidun Fang Zheng Li Yunzhe Cao Qingbao Gu Fasheng Li School of Chemical and Environmental Engineering China University of Mining & Technology Beijing 100083 China Department of Soil pollution Control State Key Laboratory of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental Sciences Beijing 100012 China School of Environment Tsinghua University Beijing 100084 China beijing key laboratory for Risk Modeling and remediation of Contaminated sites Beijing Municipal Research Institute of Environmental Protection Beijing 100037 China Shandong key laboratory of Eco-Environmental Science for Yellow River Delta Binzhou University Binzhou 256600 China

In recent years, many industrial enterprises located in the urban centers of China have been relocated owing to the rapid increase in urban development. At the sites abandoned by these enterprises, volatile organic compounds have frequently been detected, sometimes at high concentrations, particularly at sites abandoned by chemical manufacturing enterprises. With the redevelopment of sites and changes in land-use tvpe associated with these sites, substantial amounts of contaminated soils now require remediation. ＂Since China is a developing country, soil remediation warrants the usage of techniques that are suitable for addressing the unique challenges faced in this country. Land shortage is a common problem in China; the large numbers of contaminated sites, tight development schedules, and limited financial resources necessitate the development of .cost-effective methods for land reclamation.Mechanical soil aeration is a simple, effective, and low-cost soil remediation tectm^que mat is particularly suitable for the remediation of large volatile organic compound-contaminated sites. Its effectiveness has been confirmed by conducting laboratory studies, pilot tests, and full-scale projects.This study reviews current engineei-ing practice and developmental trends of mechanical soil aeration and analyzes the advantages and disadvantages of this technology for application in China as an emerging soil remediation market. The findings of this study might aid technology development in China, as well as assist other developing countries in the assessment and implementation of costeffective hazardous waste site soil remediation programs.

关键词： Soil contamination Volatile organic compound Mechanical soil aeration Engineering practice China

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Catalytic destruction of chlorobenzene over K-OMS-2: Inhibition of high toxic byproducts via phosphate modification

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Journal of Environmental Sciences 2023年第5期127卷 844-854页

作者： Yunpeng Long Jiajia Liu Meiling Chen Renna Li Xiaole Weng Zhongbiao Wu key laboratory of Environment remediation and Ecological Health Ministry of EducationCollege of Environmental and Resource SciencesZhejiang UniversityHangzhou 310058China Zhejiang Provincial Engineering Research Center of industrial Boiler and Furnace Flue Gas pollution Control Zhejiang University-Hangzhou Global Scientific and Technological Innovation CenterHangzhou 311200China

In the process of catalytic destruction of chlorinated volatile organic compounds(CVOCs),the catalyst is prone to chlorine poisoning and produce polychlorinated byproducts with high toxicity and persistence,bringing great risk to atmospheric environment and human health.To solve these problems,this work applied phosphate to modify K-OMS-2 catalysts.The physicochemical properties of catalysts were determined by using X-ray powder diffraction(XRD),scanning electron microscope(SEM),X-ray photoelectron spectroscopy(XPS),hydrogen temperature programmed reduction(H_(2)-TPR),pyridine adsorption Fouriertransform infrared(Py-IR)and water temperature programmed desorption(H_(2)O-TPD),and chlorobenzene was selected as a model pollutant to explore the catalytic performance and byproduct inhibition function of phosphating.Experimental results revealed that 1 wt.%phosphate modification yielded the best catalytic activity for chlorobenzene destruction,with the 90%conversion(T90)at approximately 247℃.The phosphating significantly decreased the types and yields of polychlorinated byproducts in effluent.After phosphating,we observed significant hydroxyl groups on catalyst surface,and the active centerwas transformed into Mn(IV)-O…H,which promoted the formation of HCl,and enhanced the dechlorination process.Furthermore,the enriched Lewis acid sites by phosphating profoundly enhanced the deep oxidation ability of the catalyst,which promoted a rapid oxidation of reaction intermediates,so as to reduce byproducts generation.This study provided an effective strategy for inhibiting the toxic byproducts for the catalytic destruction of chlorinated organics.

关键词： Catalytic destruction Chlorinated organics Phosphoric modification K-OMS-2 Secondary pollution

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Photocatalytic fuel cell for simultaneous antibiotic wastewater treatment and electricity production by anatase TiO_(2) nanoparticles anchored on Ni foam

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Chinese Chemical Letters 2023年第2期34卷 311-316页

作者： Jinhan Li Xicheng Li Shaobin Yu Shuai Gao Yang Zhang Yan Li Changzheng Wang Qiang Wang beijing key laboratory of Functional Materials for Building Structure and Environment remediation Beijing University of Civil Engineering and ArchitectureBeijing 100044China College of Chemistry Beijing Normal UniversityBeijing 100875China laboratory for Micro-sized Functional Materials&College of Elementary Education Capital Normal UniversityBeijing 100048China

Photocatalytic fuel cell (PFC) holds great potential for the sustainable production of electricity and degradation of organic pollutants for solving global energy and environmental problems.However,the efficient photodegradation of organic dyes and antibiotic drugs,such as ciprofloxacin (CIP) and methylene blue(MB),remains challenging.Aiming at improving the separation efficiency of hole and electron for electricity generation in the PFC system,TiO_(2)-NPs@NF-x photoanode was fabricated by a cost-effective and laborsaving hydrothermal approach.The as-fabricated photoanode demonstrated abundant active sites,enhanced light harvesting capacity and photogenerated charge carrier separation.At a CIP-HCl concentration of 10 mg/L and p H value of about 7,85%of CIP-HCl can be efficiently removed after 3 h irradiation by 300 W Xe lamp.TiO_(2)-NPs@NF-20 photoelectrode based PFC system exhibited an impressed ability to simultaneously degrade ciprofloxacin and generate electricity under light irradiation with an open circuit voltage of 1.021 V,short circuit current density and maximum power density of 2.4 mA/cm^(2),0.357 mW/cm^(2),respectively.This work provided a cost-effective method for the treatment of organic waste and generation of electrical power.

关键词： Photocatalytic fuel cell TiO_(2) Ni foam Electricity production Antibiotic wastewater treatment

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Multiple effects of nitrate amendment on the transport, transformation and bioavailability of antimony in a paddy soil-rice plant system

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Journal of Environmental Sciences 2021年第2期33卷 90-98页

作者： Xiaofeng Zhang Tongxu Liu Fangbai Li Xiaomin Li Yanhong Du Huanyun Yu Xiangqin Wang Chuanpin Liu MiFeng Bing Liao Guangzhou Institute of Geochemistry Chinese Academy of SciencesGuangzhou 510640China Guangdong key laboratory of Ilntegrated Agro-environmental pollution Control and Management GuangdongInstitute of Eco-environmental Science&TechnologyGuangzhou 510650China National-Regional Joint Engineering Research Center for Soil pollution Control and remediation in South China Guangzhou 510650China University of Chinese Academy of Sciences Beijing 100049China SCNU Enuironmental Research Institute Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety&MOE Key Laboratory of Theoretical Chemistry of EnvironmentSouth China NormalUniversityGuangzhou 510006China

Nitrate(NO3^(-))is known to be actively involved in the processes of mineralization and heavy metal transformation;however,it is unclear whether and how it affects the bioavailability of antimony(Sb)in paddy soils and subsequent Sb accumulation in rice.Here,the effects of NO3^(-)on Sb transformation in soil-rice system were investigated with pot experiments over the entire growth period.Results demonstrated that NO3^(-)reduced Sb accumulation in brown rice by 15.6%compared to that in the control.After amendment with NO3^(-),the Sb content in rice plants increased initially and then gradually decreased(in roots by 46.1%).During the first 15 days,the soil p H increased,the oxidation of Sb(Ⅲ)and sulfides was promoted,but the reduction of iron oxide minerals was inhibited,resulting in the release of adsorbed and organic-bound Sb from soil.The microbial arsenite-oxidizing marker gene aox B played an important role in Sb(Ⅲ)oxidation.From days 15 to 45,after NO3^(-)was partially consumed,the soil p H decreased,and the reductive dissolution of Fe(Ⅲ)-bearing minerals was enhanced;consequently,iron oxide-bound Sb was transformed into adsorbed and dissolved Sb species.After day 45,NO3^(-)was completely reduced,Sb(V)was evidently reduced to Sb(Ⅲ),and green rust was generated gradually.Thus,the available Sb decreased due to its enhanced affinity for iron oxides.Moreover,NO3^(-)inhibited the reductive dissolution of iron minerals,which ultimately caused low Sb availability.Therefore,NO3^(-)can chemically and biologically reduce the Sb availability in paddy soils and alleviate Sb accumulation inrice.This study provides a potential strategy for decreasing Sb accumulation in rice in the Sb-contaminated sites.

关键词： Antimony Nitrate Microbial Sb(Ⅲ)oxidation Rice Paddy soil

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