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Highly efficient through-space charge transfer TADF molecule employed in TADF-and TADF-sensitized organic light-emitting diodes

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Science China Chemistry 2024年第4期67卷 1270-1276页

作者： Jiasen Zhang Deli Li Wei Li Yujie Wu Xilin Mu Chunyu Liu Kaibo Fang Ziyi Ge Zhejiang Provincial Engineering research Center of Energy Optoelectronic materials and Devices Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China Center of materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China state key laboratory of Luminescent materials and Devices and Institute of Polymer Optoelectronic materials and Devices South China University of TechnologyGuangzhou 510640China

The inception and harnessing of excitons are paramount for the electroluminescence performance of organic light-emitting devices(OLEDs).Through-space charge transfer(TSCT)via intramolecular interaction has proved to be one of the most potent techniques employed to achieve 100% internal quantum ***,molecular strategies utilized to comprehensively enhance the electroluminescent performance of TSCT emitters regarding improving the photoluminescence quantum yield(PLQY)and elevating the light out-coupling efficiency remain *** surmount this challenge,we deliberately designed and synthesized a proof-of-concept TSCT emitter called CzO-TRZ by incorporating an extra carbazole donor into spiroheterocyclic *** introduction of rigid spiral fragments can immensely boost the horizontal orientation dipole ratio and establish an extra through-bond charge transfer(TBCT)radiative decay *** a result,a very high PLQY of 98.7%,fast kRISCof 2.2×10^(5)s^(-1)and high k_(r)^(s) of 2.2×10^(7)s^(-1),and an ultrahigh horizontal dipolar ratio of 90%were concurrently achieved for Cz O-TRZ blended ***,corresponding thermally activated delayed fluorescence(TADF)-and TADF-sensitized fluorescence(TSF)-OLEDs based on CzO-TRZ demonstrated external quantum efficiencies(EQEs)of 33.4% and 30.3%,respectively,highlighting its versatile applications as both an emitter and sensitized host.

关键词： organic electronics organic light-emitting diodes polycyclic aromatic hydrocarbons multiple-resonance

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Enhanced superelasticity and reversible elastocaloric effect in nano-grained NiTi alloys with low stress hysteresis

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Chinese Physics B 2024年第5期33卷 557-562页

作者：周敏王维苏浩健胡忠军李来风 key laboratory of Cryogenic Science and Technology Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China Songshan Lake materials laboratory Dongguan 523808China

Solid-state cooling technologies have been considered as potential alternatives for vapor compression cooling *** search for refrigeration materials displaying a unique combination of pronounced caloric effect,low hysteresis,and high reversibility on phase transformation was very active in recent ***,we achieved increase in the elastocaloric reversibility and decrease in the friction dissipation of martensite transformations in the superelastic nano-grained NiTi alloys obtained by cold rolling and annealing treatment,with very low stress hysteresis(6.3 MPa)under a large applied strain(5%).Large adiabatic temperature changes(△T_(max)=16.3 K atε=5%)and moderate COP_(mater)values(maximum COP_(mater)=11.8 atε=2%)were *** present nano-grained NiTi alloys exhibited great potential for applications as a highly efficient elastocaloric material.

关键词： elastocaloric effect stress hysteresis superelasticity NiTi alloy

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Asymmetrically coordinated main group atomic In-S_(1)N_(3)interface sites for promoting electrochemical CO_(2)reduction

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Nano research 2024年第6期17卷 5011-5021页

作者： Yan Gao Jinlong Ge Jingqiao Zhang Ting Cao Zhiyi Sun Wensheng Yan Yu Wang Jie Lin Wenxing Chen Zheng Liu Anhui Provincial Engineering laboratory of Silicon-based materials Bengbu UniversityBengbu 233030China state key laboratory of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental SciencesBeijing 100012China SEPA key laboratory of Eco-Industry Chinese Research Academy of Environmental SciencesBeijing 100012China Ningbo Institute of materials Technology and Engineering Chinese Academy of ScienceNingbo 315201China Energy&Catalysis Center School of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China National Synchrotron Radiation laboratory University of Science and Technology of ChinaHefei 230029China Shanghai Synchrotron Radiation Facilities Shanghai Institute of Applied PhysicsChinese Academy of ScienceShanghai 201204China

Designing catalysts with highly active,selectivity,and stability for electrocatalytic CO_(2)to formate is currently a severe ***,we developed an electronic structure engineering on carbon nano frameworks embedded with nitrogen and sulfur asymmetrically dual-coordinated indium active sites toward the efficient electrocatalytic CO_(2)reduction *** expected,atomically dispersed In-based catalysts with In-S_(1)N_(3)atomic interface with asymmetrically coordinated exhibited high efficiency for CO_(2)reduction reaction(CO_(2)RR)to *** achieved a maximum Faradaic efficiency(FE)of 94.3%towards formate generation at−0.8 V *** hydrogen electrode(RHE),outperforming that of catalysts with In-S2N2 and In-N4 atomic *** at a potential of−1.10 V ***,In-S_(1)N_(3)achieves an impressive Faradaic efficiency of 93.7%in flow *** catalytic performance of In-S_(1)N_(3)sites was confirmed to be enhanced through in-situ X-ray absorption near-edge structure(XANES)measurements under electrochemical *** discovery provides the guidance for performance regulation of main group metal catalysts toward CO_(2)RR at atomic scale.

关键词： indium single-site catalyst main group metal asymmetrical coordination CO_(2)reduction reaction structure-activity relationship

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Remarkable Wear Resistance in a Complex Concentrated Alloy with Nanohierarchical Architecture and Composition Undulation

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research 2024年第1期2023卷 403-416页

作者： Yushan Geng Wenyuan Chen Hui Tan Jun Cheng Shengyu Zhu Jun Yang Weimin Liu state key laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000PR China Center of materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049PR China Shandong laboratory of Yantai Advanced materials and Green Manufacturing Yantai 264000PR China

Sustained wear damages on the sliding surfaces of alloys are generally the culprit responsible for the failure of various mechanical *** by high-entropy effects,here we deliberately deploy nanohierarchical architecture with composition undulation in a Ni50(AlNbTiV)_(50) complex concentrated alloy,which yields ultralow wear rate within the order of 10^(−7) to 10^(−6) mm^(3)/Nm between room temperature and 800℃.Such remarkable wear resistance heretofore represents one of the highest wear resistance reported for the bulk alloys or composites,and originates from the multi-type adaptive friction interface protection governed by intrinsically nano-coupled grains and *** cooperative heterostructure releases gradient frictional stress in stages upon wear at room temperature through the coexistence of multiple deformation pathways while activating a dense nanocrystalline glaze layer upon wear at 800℃ to minimize adhesive and oxidative *** work uncovers a practical avenue for tailoring wear properties with multicomponent heterostructures over a wide temperature range.

关键词： wear alloys friction

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Effects of impregnation sequence on the NH_(3)-SCR activity and hydrothermal stability of a Ce-Nb/SnO_(2) catalyst

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Journal of Environmental sciences 2024年第4期138卷 450-457页

作者： Ying Zhu Wenpo Shan Zhihua Lian Jingjing Liu Yan Zhang Hong He Center for Excellence in Regional Atmospheric Environment and key laboratory of Urban Pollutant Conversion Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Zhejiang key laboratory of Urban Environmental Processes and Pollution Control Ningbo Urban Environment Observation and Research StationInstitute of Urban EnvironmentChinese Academy of SciencesNingbo 315800China state key Joint laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China University of Chinese academy of sciences Beijing 100049China

Hydrothermal stability is crucial for the practical application of deNO_(x)catalyst on diesel vehicles,for the selective catalytic reduction of NO_(x)with NH_(3)(NH_(3)-SCR).SnO_(2)-based materials possess superior hydrothermal stability,which is attractive for the development of NH_(3)-SCR *** this work,a series of Ce-Nb/SnO_(2)catalysts,with Ce and Nb loading on SnO_(2)support,were prepared by impregnation *** was found that,the NH_(3)-SCR activities and hydrothermal stabilities of the Ce-Nb/SnO_(2)catalysts significantly varied with the impregnation sequences,and the Ce-Nb(f)/SnO_(2) catalyst that firstly impregnated Nb and then impregnated Ce exhibited the best *** characterization results revealed that CeNb(f)/SnO_(2)possessed appropriate acidity and redox ***,the strong synergistic effect between Nb and Sn species stabilized the structure and maintained the dispersion of acid *** study may provide a new understanding for the effect of impregnation sequence on activity and hydrothermal stability and a new environmental-friendly NH_(3)-SCR catalyst with potential applications for NO_(x)removal from diesel and hydrogenfueled engines.

关键词： NO_(x)emission control NH_(3)-SCR Hydrothermal stability Ce-Nb/SnO_(2)catalyst Impregnation sequence

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Negligible normal fluid in superconducting state of heavily overdoped Bi_(2)Sr_(2)CaCu_(2)O_(8+δ) detected by ultra-low temperature angle-resolved photoemission spectroscopy

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Chinese Physics B 2024年第7期33卷 562-567页

作者：殷超辉汪清泓解于洋陈逸雯刘俊豪杨鉴刚贾俊杰张杏吕文凯闫宏涛戎洪涛张申金王志敏宗楠刘丽娟李如康王晓洋张丰丰杨峰彭钦军许祖彦刘国东毛寒青赵林李昕彤周兴江 National laboratory for Superconductivity Beijing National Laboratory for Condensed Matter PhysicsInstitute of PhysicsChinese Academy of SciencesBeijing 100190China University of Chinese academy of sciences Beijing 100049China Technical Institute of Physics and Chemistry Chinese Academy of SciencesBeijing 100190China Songshan Lake materials laboratory Dongguan 523808China

In high temperature cuprate superconductors,it was found that the superfluid density decreases with the increase of hole *** natural question is whether there exists normal fluid in the superconducting state in the overdoped *** this paper,we have carried out high-resolution ultra-low temperature laser-based angle-resolved photoemission measurements on a heavily overdoped Bi2212 sample with a T_(c) of 48 *** find that this heavily overdoped Bi2212 remains in the strong coupling regime with 2Δ_(0)/(k_(B)T_(c))=*** single-particle scattering rate is very small along the nodal direction(~5 meV) and increases as the momentum moves from the nodal to the antinodal regions.A hard superconducting gap opening is observed near the antinodal region with the spectral weight at the Fermi level fully suppressed to *** normal fluid is found to be negligibly small in the superconducting state of this heavily overdoped *** results provide key information to understand the high T_(c) mechanism in the cuprate superconductors.

关键词： cuprate superconductor angle-resolved photoemission spectroscopy electronic structure

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Hybrid ion/electron interfacial regulation stabilizes the cobalt/oxygen redox of ultrahigh-voltage lithium cobalt oxide for fast-charging cyclability

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Science Bulletin 2024年第13期69卷 2071-2079页

作者： Zhihong Bi Anping Zhang Gongrui Wang Cong Dong Pratteek Das Xiaoyu Shi Zhong-Shuai Wu state key laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China University of Chinese academy of sciences Beijing 100049China Dalian National laboratory of Clean Energy Chinese Academy of SciencesDalian 116023China

High-voltage and fast-charging LiCoO_(2)(LCO)is key to high-energy/power-density Li-ion ***,unstable surface structure and unfavorable electronic/ionic conductivity severely hinder its high-voltage fast-charging ***,we construct a Li/Na-B-Mg-Si-O-F-rich mixed ion/electron interface network on the 4.65 V LCO electrode to enhance its rate capability and long-term cycling ***,the resulting artificial hybrid conductive network enhances the reversible conversion of Co^(3+)/^(4+)/O_(2)/nredox by the interfacial ion–electron cooperation and suppresses interface side reactions,inducing an ultrathin yet compact cathode electrolyte ***,the derived near-surface Na+/Mg2+/Si^(4+)-pillared local intercalation structure greatly promotes the Li^(+)diffusion around the 4.55 V phase transition and stabilizes the cathode ***,excellent 3 C(1 C=274 mA g1)fast charging performance is demonstrated with 73.8%capacity retention over 1000 *** findings shed new insights to the fundamental mechanism of interfacial ion/electron synergy in stabilizing and enhancing fast-charging cathode materials.

关键词： High-voltage Fast-charging LiCoO_(2) Interfacial ion-electron cooperation Local intercalation

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An all-metallic nanovesicle for hydrogen oxidation

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National Science Review 2024年第6期11卷 233-242页

作者： Juntao Zhang Lujie Jin Hao Sun Xiaozhi Liu Yujin Ji Youyong Li Wei Liu Dong Su Xuerui Liu Zhongbin Zhuang Zhiwei Hu Qi Shao Xiaoqing Huang state key laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering Xiamen University Innovation laboratory for sciences and Technologies of Energy materials of Fujian Province(IKKEM) key laboratory for Special Functional materials of Ministry of Education National &Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology School of Materials Science and EngineeringCollaborative Innovation Center of Nano Functional Materials and Applications Henan University Institute of Functional Nano and Soft materials(FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials& Devices Soochow University state key laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences beijing National laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences state key Lab of Organic-Inorganic Composites Beijing University of Chemical Technology Max Planck Institute for Chemical Physics of Solids College of Chemistry and Chemical Engineering and materials Science Soochow University

Vesicle, a microscopic unit that encloses a volume with an ultrathin wall, is ubiquitous in ***, it remains a huge challenge to create its inorganic metal-based artificial counterparts. Here,inspired by the formation of biological vesicles, we proposed a novel biomimetic strategy of curling the ultrathin nanosheets into nanovesicles, which was driven by the interfacial strain. Trapped by the interfacial strain between the initially formed substrate Rh layer and subsequently formed RhRu overlayer, the nanosheet begins to deform in order to release a certain amount of strain. Density functional theory（DFT）calculations reveal that the Ru atoms make the curling of nanosheets more favorable in thermodynamics applications. Owing to the unique vesicular structure, the RhRu nanovesicles/C displays excellent hydrogen oxidation reaction（HOR） activity and stability, which has been proven by both experiments and DFT calculations. Specifically, the HOR mass activity of RhRu nanovesicles/C are 7.52 A mg（Rh+Ru）-1at an overpotential of 50 m V at the rotating disk electrode（RDE） level; this is 24.19 times that of commercial Pt/C(0.31 m A mgPt-1). Moreover, the hydroxide exchange membrane fuel cell（HEMFC） with RhRu nanovesicles/C displays a peak power density of 1.62 W cm-2in the H2-O2condition, much better than that of commercial Pt/C(1.18 W cm-2). This work creates a new biomimetic strategy to synthesize inorganic nanomaterials, paving a pathway for designing catalytic reactors.

关键词： biomimetic synthesis nanovesicle interfacial strain hydrogen oxidation reaction

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Significant enhancement in local thermal conductivity of erythritol at interface with nanoparticles due to their interaction

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Nano research 2024年第8期17卷 7726-7736页

作者： Ning Cao Yanhui Feng Kening Yan Zihan Liu Jiawei Wan Lin Qiu School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China state key laboratory of Biochemical Engineering Key Laboratory of Biopharmaceutical Preparation and DeliveryInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China

When nano-fillers are used to enhance the thermal conductivity of organic phase change materials(PCMs),the naturally formed interface is considered to hinder thermal transport of the composite ***,the effect of the interface on the thermal properties of surrounding PCM has not been fully *** this paper,three composite PCMs(Ery@SiC,Ery@SiO_(2) and Ery@Si_(3)N_(4))were prepared by melt-blending *** local thermal conductivity and reduced Young’s modulus(E^(*))of the erythritol at the interface and far away from the interface in the composite PCMs were simultaneously measured by scanning thermal microscopy(SThM).The results revealed significant enhancement in local thermal conductivity of erythritol at the interface and its obvious positive correlation with E^(*).For different composite PCMs,molecular dynamics(MD)simulations suggested that the increase in intrinsic thermal conductivity and E^(*)of erythritol is attributed to the increase in interaction energy between erythritol and nanoparticles,as more erythritol phonon vibrations transform from localized mode to delocalized mode and erythritol has a higher density at the *** findings will provide new ideas for the design of PCM for energy storage.

关键词： scanning thermal microscopy phase change materials thermal conductivity reduced Young’s modulus interaction energy phonon participation ratio

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Slicing of large-size single crystals by ultrafast laser with external stress assistance

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Chinese Optics Letters 2024年第8期22卷 100-105页

作者： Lifeng Wang Lili Liu Yinan Wang Xun Li Chenchen Li Ming Li state key laboratory of Transient Optics and Photonics Xi’an Institute of Optics and Precision MechanicsChinese Academy of SciencesXi’an 710119China University of Chinese academy of sciences Beijing 100049China

The existing single-crystal slicing techniques result in significant material wastage and elevate the production cost o premium-quality thin slices of *** we report(for the first time,to our knowledge)an approach for vertical slicin of large-size single-crystal gain materials by ultrafast *** employing aberration correction techniques,the optimi zation of the optical field distribution within the high-refractive-index crystal enables the achievement of a continuou laser-modified layer with a thickness of less than 10μm,oriented perpendicular to the direction of the laser direction The compressed focal spot facilitates crack initiation,enabling propagation under external forces,ultimately achievin the successful slicing of aΦ12 mm *** surface roughness of the sliced Yb:YAG is less than 2.5μ*** result illustrate the potential of low-loss slicing strategy for single-crystal fabrication and pave the way for the future develop ment of thin disk lasers.

关键词： single-crystal gain materials ultrafast laser slicing YAG aberration correction

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