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Magnetically-responsive phase change thermal storage materials:Mechanisms,advances,and beyond

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Journal of Energy Chemistry 2025年第2期101卷 485-510页

作者： Yan Gao Yang Li Jinjie Lin Panpan Liu Xiao Chen Ge Wang beijing advanced innovation center for materials genome engineering Beijing Key Laboratory of Function Materials for Molecule & Structure Construction School of Materials Science and Engineering University of Science and Technology Beijing School of Physics and Astronomy Beijing Normal University Shunde Graduate School University of Science and Technology Beijing

Rapid advances in thermal management technology and the increasing need for multi-energy conversion have placed stringent energy efficiency requirements on next-generation shape-stable composite phase change materials(PCMs).Magnetically-responsive phase change thermal storage materials are considered an emerging concept for energy storage systems,enabling PCMs to perform unprecedented functions(such as green energy utilization,magnetic thermotherapy,drug release,etc.).The combination of multifunctional magnetic nanomaterials and PCMs is a milestone in the creation of advanced multifunctional composite ***,a timely and comprehensive review of composite PCMs based on magnetic nanoparticle modification is still ***,we furnish an exhaustive exposition elucidating the cutting-edge advancements in magnetically responsive composite *** delve deeply into the multifarious roles assumed by distinct nanoparticles within composite PCMs of varying dimensions,meticulously scrutinizing the intricate interplay between their architectures and thermophysical ***,we prognosticate future research trajectories,delineate alternative stratagems,and illuminate prospective *** review is intended to stimulate broader academic interest in interdisciplinary fields and provide valuable insights into the development of next-generation magnetically-responsive composite PCMs.

关键词： Magnetic nanoparticles Magnetic-thermal conversion Phase change materials Response mechanism Thermal energy storage

Research status and prospects of the fractal analysis of metal material surfaces and interfaces

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International Journal of Minerals,Metallurgy and materials 2025年第1期32卷 20-38页

作者： Qinjin Dai Xuefeng Liu Xin Ma Shaojie Tian Qinghe Cui beijing advanced innovation center for materials genome engineering University of Science and Technology BeijingBeijing 100083China beijing Laboratory of Metallic materials and Processing for Modern Transportation University of Science and Technology BeijingBeijing 100083China Laboratory for advanced materials Processing of Ministry of Education University of Science and Technology BeijingBeijing 100083China School of Mechanical and Electrical engineering Xinjiang Institute of EngineeringUrumqi 830023China

As a mathematical analysis method,fractal analysis can be used to quantitatively describe irregular shapes with self-similar or self-affine *** analysis has been used to characterize the shapes of metal materials at various scales and *** methods make it difficult to quantitatively describe the relationship between the regular characteristics and properties of metal material surfaces and ***,fractal analysis can be used to quantitatively describe the shape characteristics of metal materials and to establish the quantitative relationships between the shape characteristics and various properties of metal *** the perspective of two-dimensional planes and three-dimensional curved surfaces,this paper reviews the current research status of the fractal analysis of metal precipitate interfaces,metal grain boundary interfaces,metal-deposited film surfaces,metal fracture surfaces,metal machined surfaces,and metal wear *** relationship between the fractal dimensions and properties of metal material surfaces and interfaces is *** from three perspectives of fractal analysis,namely,research scope,image acquisition methods,and calculation methods,this paper identifies the direction of research on fractal analysis of metal material surfaces and interfaces that need to be *** is believed that revealing the deep influence mechanism between the fractal dimensions and properties of metal material surfaces and interfaces will be the key research direction of the fractal analysis of metal materials in the future.

关键词： metal material surfaces and interfaces fractal analysis fractal dimension homogeneity

Taming of trinitromethyl-oxadiazole to access high density and high oxygen balance via a dual modulation strategy

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Defence Technology(防务技术) 2025年第1期43卷 142-149页

作者： Jinya Zhang Teng Fei Jingwei Meng Jinxiong Cai Lei Zhang Siping Pang Chunlin He School of materials Science&engineering Beijing Institute of TechnologyBeijing 100081China Experimental center of advanced materials School of Materials Science&EngineeringBeijing Institute of TechnologyBeijing 100081China hongqing innovation center Beijing Institute of TechnologyChongqing 401120China

Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense *** this work,an effective dual modulation strategy involving both molecular isomerization and crystal morphology control was employed to design and optimize trinitromethyl-oxadiazole with improved comprehensive *** this dual strategy,3,5-bis(trinitromethyl)-1,2,4-oxadiazole(3)was synthesized,resulting in the formation of two distinct crystal morphologies(needle and sheet)corresponding to two crystal forms(3-a and3-b).Encouragingly,while maintaining ultra-high oxygen balance(21.73%),3 achieves impressive densities(1.97-1.98 g/cm^(3)).To our knowledge,the density of 1.98 g/cm^(3)for 3-a sets a new record among that of nitrogen-rich monocyclic ***,practical crystal morphology prediction was creatively introduced to guide the experimental crystallization conditions of 3,increasing the impact sensitivity and friction sensitivity from 1 J to 80 N(3-a)to 10 J and 240 N(3-b),***,the crystal structural analyses and theoretical calculations were conducted to elucidate the reasons of differences between 3-a and 3-b in density and *** work provides an efficient strategy to enhance performance of trinitromethyl derivatives,broadening the path and expanding the toolbox for energetic materials.

关键词： Energetic materials High oxygen balance High density Dual modulation Trinitromethyl group

Reverse modulation of defect density of Ce-MOF-808 by solventassisted ligand exchange for dicyclopentadiene hydrogenation

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Science China Chemistry 2025年

作者： Danfeng Zhao Fajie Hu Rushuo Li Xinmeng Xu Zhaokun Wang Zuoshuai Xi Jun Tong Xiubing Huang Ge Wang advanced innovation center for materials genome engineering Beijing Key Laboratory of Function Materials for Molecule & Structure Construction School of Materials Science and Engineering University of Science and Technology Beijing

Defect engineering is a pivotal strategy for tailoring the electronic structure and physicochemical properties of catalysts, yet the straightforward manipulation of defect density in porous materials presents a current challenge. In this work, we achieved precise control over the coordination unsaturated site（CUS） content and pore architecture of Ce-MOF-808 by employing 2-fluorobenzoic acid（2-FBA） as a modifier. Leveraging the p Kadisparities among three ligands（1,3,5-tricarboxylic benzoic acid,formic acid, and 2-FBA）, we preserved the spn topology of Ce-MOF within an aqueous system, while realizing partial substitution of the auxiliary ligands and saturation of the CUS. The amount of 2-FBA was negatively correlated with the number of ligand defects, and the consequent decrease in Ce3+content and the increase in the number of ligand linkages also induced crystal structure transformation. The modulation of the defect structure was correlated with the catalytic performance of dicyclopentadiene（DCPD） hydrogenation reaction, in which Ce-MMF0.15, constructed by the modulation of 0.15 mol amount of 2-fluorobenzoic acid, exhibited an optimal ligand defect density and micro-mesoporous structure, enabling almost complete conversion of DCPD at 100 ℃ and 2 MPa. This article also elucidates the correlation between the regulation of defect density and the accessibility of frustrated Lewis pair（FLP） active sites, guiding the application of novel porous intrinsic FLP materials in hydrogenation catalysis.

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Unraveling the significance of cobalt on transformation kinetics,crystallography and impact toughness in high-strength steels

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International Journal of Minerals,Metallurgy and materials 2025年第2期32卷 380-390页

作者： Yishuang Yu Jingxiao Zhao Xuelin Wang Hui Guo Zhenjia Xie Chengjia Shang Collaborative innovation center of Steel Technology University of Science and Technology BeijingBeijing 100083China School of materials Science and engineering Shanghai Jiao Tong UniversityShanghai 200240China State Key Laboratory for advanced Metals and materials University of Science and Technology BeijingBeijing 100083China

This work reveals the significant effects of cobalt(Co)on the microstructure and impact toughness of as-quenched highstrength steels by experimental characterizations and thermo-kinetic *** results show that the Co-bearing steel exhibits finer blocks and a lower ductile-brittle transition temperature than the steel without ***,the Co-bearing steel reveals higher transformation rates at the intermediate stage with bainite volume fraction ranging from around 0.1 to *** improved impact toughness of the Co-bearing steel results from the higher dense block boundaries dominated by the V1/V2 variant ***,the addition of Co induces a larger transformation driving force and a lower bainite start temperature(BS),thereby contributing to the refinement of blocks and the increase of the V1/V2 variant *** findings would be instructive for the composition,microstructure design,and property optimization of high-strength steels.

关键词： high-strength steel cobalt transformation kinetics crystallography impact toughness

Recent advances in metal-loaded MOFs photocatalysts:From single atom,cluster to nanoparticle

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Chinese Chemical Letters 2025年第1期36卷 68-79页

作者： Shenglan Zhou Haijian Li Hongyi Gao Ang Li Tian Li Shanshan Cheng Jingjing Wang Jitti Kasemchainan Jianhua Yi Fengqi Zhao Wengang Qu advanced innovation center for materials genome engineering Beijing Key Laboratory of Function Materials for Molecule&Structure ConstructionSchool of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijing 100083China National Key Laboratory of Energetic materials Xi’an Modern Chemistry Research InstituteXi’an 710065China Shunde innovation School University of Science and Technology BeijingShunde 528399China School of materials Science and engineering Suzhou University of Science and TechnologySuzhou 215009China Department of Chemical Technology Chulalongkorn UniversityBangkok 10330Thailand

Photocatalysis is widely regarded as a highly promising sustainable technique for addressing the challenges posed by environmental pollution and energy *** recent years,metal-loaded MOFs has become a rising star within the domain of photocatalysis due to its high specific surface area and porosity,adjustable structure,diverse and abundant catalytic components,which has exhibited excellent photocatalytic activity and exhibit great potential in a range of *** this paper,the principles for evaluating the photocatalytic performance of MOFs-based materials were firstly introduced,and some typical examples were also listed *** with this,particular emphasis is paid to the main factors affecting the photocatalytic performance of metal-loaded *** the synthesis and design strategies of MOFs loaded metal entities of varying sizes(single atoms,nanoclusters,and nanoparticles),and their applications in photocatalytic CO_(2)reduction,hydrogen production,photooxidation and photocatalytic hydrogenation were summarized and ***,the opportunities and challenges faced in this kind of MOFs-based composites were analyzed from different *** report is expected to help researchers design and develop high-performance MOFs-based photocatalytic materials.

关键词： Metal-loaded MOFs Photocatalysis Single atom catalysts Nanoclusters Nanoparticles

Designing the counter pressure casting gating system for a large thin-walled cabin by machine learning

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China Foundry 2025年

作者： Xiao-long Zhang Hua Hou Xiao-long Pei Zhi-qiang Duan Yu-hong Zhao School of materials Science and engineering Collaborative Innovation Center of Ministry of Education and Shanxi Province for High-performance Al/Mg Alloy Materials North University of China beijing advanced innovation center for materials genome engineering University of Science and Technology Beijing Institute of materials Intelligent Technology Liaoning Academy of Materials

The design of casting gating system directly determines the solidification sequence, defect severity,and overall quality of the casting. A novel machine learning strategy was developed to design the counter pressure casting gating system of a large thin-walled cabin casting. A high-quality dataset was established through orthogonal experiments combined with design criteria for the gating system. Spearman's correlation analysis was used to select high-quality features. The gating system dimensions were predicted using a gated recurrent unit(GRU) recurrent neural network and an elastic network model. Using EasyCast and ProCAST casting software, a comparative analysis of the flow field, temperature field, and solidification field can be conducted to demonstrate the achievement of steady filling and top-down sequential solidification. Compared to the empirical formula method, this method eliminates trial-and-error iterations, reduces porosity, reduces casting defect volume from 11.23 cubic centimeters to 2.23 cubic centimeters, eliminates internal casting defects through the incorporation of an internally cooled iron, fulfilling the goal of intelligent gating system design.

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Status analysis on sputtering and erosion evaluation methods of ion optic systems

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Chinese Journal of Aeronautics 2025年第1期38卷 254-270页

作者： Long MIAO Tongxun YANG Zhengxi ZHU Chang LU Zhiwen WU Ningfei WANG School of Aerospace engineering Beijing Institute of TechnologyBeijing 100081China Chongqing innovation center Beijing Institute of TechnologyChongqing 404100China advanced Aerospace Power and Energy Research center Beijing Institute of TechnologyZhuhai 519088China

In the past few decades,ion engines have been widely used in deep-space propulsion and satellite *** aim of extending the thruster lifetime is still one of the most important parts during the design stage of ion *** one of the core components of ion engine,the grid assembly of ion optic systems may experience long-term ion sputtering in extreme electro-thermal environments,which will eventually lead to its structural and electron-backstreaming *** this paper,the current studies of the grid assembly erosion process are systematically analyzed from the aspects of sputtering damage process of grid materials,numerical simulations,and measurements of erosion characteristics of grid *** advantages and disadvantages of various erosion prediction models are highlighted,and the key factors and processes affecting the prediction accuracy of grid assembly erosion patterns are *** different types of experimental methods of grid assembly erosion patterns are *** analysis in this paper is of great importance for selecting the sputter-resistant grid materials,as well as establishing the erosion models and measurement methods to accurately determine the erosion rate and failure modes of grid ***,the working conditions and structure parameters of ion optic systems could be optimized based on erosion models to promote the ion engine lifetime.

关键词： Electric propulsion Ion optic systems Sputtering yield Erosion characteristics Erosion pattern measurement Lifetime evaluation

Encapsulating perovskite quantum dots into 3D COF for visible light-driven CO2 reduction

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Science China Chemistry 2025年

作者： Xinxin Wang Yucheng Jin Xiya Yang Qingyu Luan Tianyu Wang Dongdong Qi Kang Wang Jianzhuang Jiang College of Chemistry and materials Science Anhui Normal University beijing advanced innovation center for materials genome engineering Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological EngineeringUniversity of Science and Technology Beijing

Lead halide perovskite quantum dots（LHP QDs） have been revealed to possess great potential in photocatalytic applications including CO2reduction, which however suffer from poor stability. Herein, a high crystalline hydrazine-linked three-dimensional（3D） covalent organic framework, USTB-17, was fabricated from the reaction between 12-connected building block and 4-connected 3,5,7-tetrakis（4-aldophenyl）-adamantane. Post-modification with Ni2+affords the metallic framework USTB-17（Ni）followed by sequential deposition of the CH3NH2PbI3（MAPbI3） perovskite QDs into its pores, generating the USTB-17（Ni）@MAPbI3composite. Powder X-ray diffraction analysis together with theoretical simulations and transmission electron microscopy discloses the crystalline nature of USTB-17, USTB-17（Ni）, and USTB-17（Ni）@MAPbI3with an unprecedented noninterpenetrated hpt topology. The close contact of QDs inside the COF pores with the Ni catalytic site locating at the pore surface of COF allows a rapid transfer of the photogenerated electrons in QDs to the Ni catalytic sites, enhancing the photocatalytic activity for CO2reduction. This endows USTB-17（Ni）@MAPbI3with efficient photocatalysis performance for photocatalytic CO2reduction with CO generation rate of 365 μmol g-1h-1and CO selectivity up to 96% under visible-light irradiation, 7 times higher than that of USTB-17（Ni）. After four cycles of reactions, the photocatalytic CO generation rate remains almost unchanged, demonstrating its excellent cycle stability.

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