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Prediction model on hydrolysis kinetics of phthalate monoester:A density functional theory study

Journal of environmental Sciences 2024年第1期135卷 51-58页

作者： Tong Xu Jingwen Chen Deming Xia Weihao Tang Jiansheng Cui Chun Liu Shuangjiang Li College of environmental Science and Engineering Hebei University of Science and TechnologyShijiazhuang 050000China Key Laboratory of Industrial ecology and environmental Engineering(Ministry of Education) School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China National-Regional Joint Engineering research Center for Soil Pollution Control and Remediation in South China Guangdong Key Laboratory of Integrated Agro-environmental Pollution Control and ManagementInstitute of Eco-environmental and Soil SciencesGuangdong Academy of SciencesGuangzhou 510650China

As primary degradation products of phthalate esters,phthalate monoesters(MPEs)have been widely detected in various aquatic environments and drawn growing toxicological *** kinetics that is of importance for assessing environmental persistence of chemicals remain elusive for ***,kinetics of base-catalyzed and neutral hydrolysis for 18 MPEs with different leaving groups was investigated by density functional theory *** indicate that MPEs with leaving groups having p Kaof<10 prefer dissociative transition *** are more persistent than their parents,and their hydrolysis half-lives were calculated to vary from 3.4 min to 79.2 years(p H=7–9).A quantitative structure-activity relationship model was developed for predicting the hydrolysis kinetics *** was found that p Kaof the leaving groups and electronegativity of the MPEs are key factors determining the hydrolysis *** work may lay a theoretical foundation for better understanding the chemical process that governs MPE persistence in aquatic environments.

关键词： Phthalate monoesters Phthalate esters Hydrolysis Density functional theory Quantitative structure-activity relationship

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Lake microbiome composition determines community adaptability to warming perturbations

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Ecological Processes 2024年第2期13卷 177-191页

作者： Xiaotong Wu Qixing Zhou Hui Zeng Xiangang Hu Key Laboratory of Pollution Processes and environmental Criteria (Ministry of Education) Carbon Neutrality Interdisciplinary Science Centre/College of Environmental Science and Engineering Nankai University

Background Microbial communities are crucial for ecosystems. A central goal of microbial ecological research is to simplify the biodiversity in natural environments and quantify the functional roles to explore how the ecosystems respond under different environmental conditions. However, the research on the stability and dynamics of lake microbes in response to repeated warming stress is *** To exclude confounding environmental factors, we conducted a 20-day repeated warming simulation experiment to examine the composition and function dynamics of lake microbial *** Experimental warming significantly altered the community structure of bacteria instead of fungi. Microbial community structure, together with microbial biomass, jointly regulated the function of microbial communities. The plummeting of aerobic denitrifiers Pseudomonadaceae decreased by 99%(P < 0.001) after high temperature, leading to reduced microbial nitrogen metabolism on nitrogen respiration and nitrate respiration. Under warming conditions, the microbial community with higher adaptability showed more positive correlations and less competitive relationships in co-occurrence networks to acclimate to *** Microbiome composition controlled carbon and nitrogen metabolism, thus determining lake microbial communities' adaptability to heat stress. This study extended our insights on the lake microbial community response and adaptability under warming drivers.

关键词： Temperature environmental stress Bacteria Fungi Freshwater ecosystem

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Typhoon-and pollution-driven enhancement of reactive bromine in the mid-latitude marine boundary layer

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National Science Review 2024年第4期11卷 93-101页

作者： Shanshan Wang Qinyi Li Ruifeng Zhang Anoop Sharad Mahajan Swaleha Inamdar Nuria Benavent Sanbao Zhang Ruibin Xue Jian Zhu Chenji Jin Yan Zhang Xiao Fu Alba Badia Rafael P.Fernandez Carlos A.Cuevas Tao Wang Bin Zhou Alfonso Saiz-Lopez Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3) Department of Environmental Science and Engineering Fudan University Institute of Eco-Chongming(IEC) Department of Atmospheric Chemistry and Climate Institute of Physical Chemistry Blas CabreraCSIC Department of Civil and environmental Engineering The Hong Kong Polytechnic University Environment research Institute Shandong University centre for Climate Change research Indian Institute of Tropical MeteorologyMinistry of Earth Sciences Department of Chemistry University of Colorado Boulder Institute of Environment and ecology Tsinghua Shenzhen International Graduate SchoolTsinghua University Sostenipra research Group Institute of Environmental Science and Technology(ICTA)Universitat Autonoma de Barcelona(UAB) Institute for Interdisciplinary Science (ICB) National Research Council (CONICET)

Tropospheric reactive bromine is important for atmospheric chemistry,regional air pollution,and global *** studies have reported measurements of atmospheric reactive bromine species in different environments,and proposed their main sources,***-salt aerosol（SSA）,oceanic biogenic activity,polar snow/ice,and *** and other strong cyclonic activities（***） induce abrupt changes in different earth system processes,causing widespread destructive ***,the role of typhoons in regulating reactive bromine abundance and sources remains ***,we report field observations of bromine oxide（BrO）,a critical indicator of reactive bromine,on the Huaniao Island（HNI）in the East China Sea in July *** observed high levels of BrO below 500 m with a daytime average of9.7±4.2 pptv and a peak value of ～26 pptv under the influence of a *** field measurements,supported by model simulations,suggest that the typhoon-induced drastic increase in wind speed amplifies the emission of SSA,significantly enhancing the activation of reactive bromine from SSA *** also detected enhanced BrO mixing ratios under high NOxconditions（ppbv level） suggesting a potential pollution-induced mechanism of bromine release from *** elevated levels of atmospheric bromine noticeably increase ozone destruction by as much as ～40% across the East China *** the high frequency of cyclonic activity in the northern hemisphere,reactive bromine chemistry is expected to play a more important role than previously thought in affecting coastal air quality and atmospheric oxidation *** suggest that models need to consider the hitherto overlooked typhoon-and pollution-mediated increase in reactive bromine levels when assessing the synergic effects of cyclonic activities on the earth system.

关键词： reactive bromine atmospheric chemistry marine boundary layer atmospheric oxidation capacity marine emission

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Analyzing the spatiotemporal evolution and driving forces of gross ecosystem product in the upper reaches of the Chaobai River Basin

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Frontiers of environmental Science & Engineering 2024年第8期18卷 117-132页

作者： Jiacheng Li Qi Han Liqiu Zhang Li Feng Guihuan Liu Beijing Key Laboratory for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Engineering research Center for Water Pollution Source Control&Eco-remediation College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Center of Eco-compensation Chinese Academy of Environmental PlanningMinistry of Ecology of EnvironmentBeijing 100041China

The Chaobai River Basin,which is a crucial ecological barrier and primary water source area within the Beijing-Tianjin-Hebei region,possesses substantial ecological *** gross ecosystem product(GEP)in the Chaobai River Basin is a reflection of ecosystem conditions and quantifies nature’s contributions to humanity,which provides a basis for basin ecosystem service management and *** study investigated the spatiotemporal evolution of GEP in the upper Chaobai River Basin and explored the driving factors influencing GEP spatial *** patterns from 2005 to 2020 were analyzed,and GEP was calculated for 2005,2010,2015,and *** driving factors influencing GEP spatial differentiation were identified using the optimal parameter-based geographical detector(OPGD)*** key findings are as follows:(1)From 2005 to 2020,the main ecosystem types were forest,grassland,and *** areas experienced significant changes,and conversions mainly occurred among urban,water,grassland and agricultural ecosystems.(2)Temporally,the GEP in the basin increased from 2005 to 2020,with regulation services *** the county(district)scale,GEP exhibited a north-west-high and south-east-low pattern,showing spatial differences between per-unit-area GEP and county(district)GEP,while the spatial variations in per capita GEP and county(district)GEP were similar.(3)Differences in the spatial distribution of GEP were influenced by regional natural geographical and socioeconomic *** these factors,gross domestic product,population density,and land-use degree density contributed *** among different driving forces noticeably impacted GEP spatial *** findings underscore the necessity of incorporating factors such as population density and the intensity of land-use development into ecosystem management decision-making processes in the upper reaches of the Chaobai River *** policies

关键词： Ecosystem pattern Gross ecosystem product(GEP) Spatiotemporal evolution Optimal parameter-based geographical detector(OPGD) Chaobai River Basin

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Degradation behaviors of Nabumetone and its metabolite during UV/monochloramine process:Experimental and theoretical study

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Journal of environmental Sciences 2024年第8期142卷 103-114页

作者： Xiang Tu Yunsong Bai Qing Fu Sheng Chang Kunfeng Zhang Yang Pan Ruiyang Xiao Yifu Fu Qi Zhang State Key Laboratory of environmental Criteria and Risk Assessment State Environmental Protection Key Laboratory of Drinking Water Source ProtectionResearch Centre of Lake EnvironmentNational Engineering Laboratory for Lake Pollution Control and Ecological RestorationChinese Research Academy of Environmental SciencesBeijing 100012China School of environmental Science and Engineering Suzhou University of Science and TechnologySuzhou 215009China Institute of environmental Engineering School of Metallurgy and EnvironmentCentral South UniversityChangsha 410083China School of Forestry Northeast Forestry UniversityHarbin 150040China

This study investigated degradation behaviors of a nonsteroidal anti-inflammatory drug Nabumetone(NMT)and its major metabolite 6-methoxy-2-naphthylacetic acid(MNA)in the coupling process of ultraviolet and monochloramine(UV/NH2Cl).The second-order rate constants of the contaminants reacting with reactive radicals(HO·,Cl·,Cl_(2)·-,and CO_(3)·^(-))were determined by laser flash photolysis ***·and Cl·contributed predominantly with 52.3%and 21.7%for NMT degradation and 60.8%and 22.3%for MNA *** presence of chlorides retarded the degradation of NMT,while promoted the destruction of MNA,which was ascribed to the photosensitization effects of MNA under UV *** functional theory(DFT)calculations revealed that radical adduct formation(RAF)was dominant pathway for both HO·and Cl·reacting with the contaminants,and hydrogen atom transfer(HAT)preferred to occur on side chains of NMT and *** reacted with NO_(2)·through single electron transfer(SET)with the second-order rate constant calculated to be 5.35×10^(7)(mol/L)^(-1)sec^(-1),and the contribution of NO_(2)·was predicted to be 13.0%of the total rate constant of NMT in pure water,which indicated that NO_(2)·played a nonnegligible role in the degradation of *** acute toxicity and developmental toxicity of NMT were enhanced after UV/NH_(2)Cl treatment,while those of MNA were *** transformation products of both NMT and MNA exhibited higher mutagenicity than their parent *** study provides a deep understanding of the mechanism of radical degradation of NMT and MNA in the treatment of UV/NH2Cl.

关键词： UV/NH_(2)Cl Reactive species Degradation kinetics Reaction mechanism Degradation products

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Detecting the distribution of and public attitudes to charismatic alien species based on media coverage

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Avian research 2024年第3期15卷 379-384页

作者： Yuexuan Liu Ruichang Sun Bo Li Zhijun Ma Shanghai Institute of Infectious Disease and Biosecurity Ministry of Education Key Laboratory for Biodiversity Science and Ecological EngineeringNational Observations and Research Station for Wetland Ecosystems of the Yangtze Estuaryand Institute of Eco-Chongming(SIEC)School of Life SciencesFudan UniversityShanghai200433China Yunnan Key Laboratory of Plant Reproductive Adaptation and Evolutionary ecology and centre for Invasion Biology Institute of BiodiversitySchool of Ecology and Environmental ScienceYunnan UniversityKunming650504YunnanChina

Charismatic species are often reported by the media,providing information for detecting population status and public *** identify the number and distribution of free-living Black Swan(Cygnus atratus),a charismatic alien species in Chinese mainland and to detect the public and the media attitudes to the species,we analyzed the reports and emotional tendency from media coverage in 2000-2022 using manual reading,crawler extraction and latent Dirichlet allocation.A total of 6654 Black Swans were reported at 711 sites,including 147 individuals at 30 nature *** breeding was reported at one-fourth of the total sites,including five nature *** proportion of positive emotional tendency to Black Swans was overwhelming in the reports and was higher than that to alien species in general,suggesting that the public and the media are unaware of the risk of biological *** management of invasive species requires the media clarifies the invasion risk of charismatic alien *** the unity between the harmfulness of abstract concept of alien species and the charisma of a specific alien species among the public help effective management.

关键词： Alien species Biological invasion Cygnus atratus Emotional tendency Invasive species Media coverage Public perception

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Ratio of photosynthetically active radiation to global solar radiation above forest canopy in complex terrain: measurements and analyses based on Qingyuan Ker Towers

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Ecological Processes 2024年第2期13卷 204-217页

作者： Shuangtian Li Qiaoling Yan Tian Gao Xingchang Wang Qingwei Wang Fengyuan Yu Deliang Lu Huaqi Liu Jinxin Zhang Jiaojun Zhu CAS Key Laboratory of Forest ecology and Silviculture Institute of Applied Ecology Chinese Academy of Sciences Qingyuan Forest CERN National Observation and Research Station Chinese Academy of Sciences CAS-CSI Joint Laboratory of research and Development for Monitoring Forest Fluxes of Trace Gases and Isotope Elements Institute of Applied Ecology Chinese Academy of Sciences (CAS) University of Chinese Academy of Sciences Center for Ecological research Northeast Forestry University

Background Understanding of the ratio of photosynthetic photon flux density（Qp） to global solar radiation（Rs）(Qp/Rs) is crucial for applying Rsto ecology-related *** studies reported Qp/Rsand its variations based on measurements from a single observatory tower,instead of multi-site-based measurements over complex *** may neglect spatial heterogeneity in the terrain,creating a gap in an understanding of how terrain affects Qp/Rsand how this effect interacts with meteorological *** Here the Qingyuan Ker Towers（three towers in a valley with different terrains:T1,T2,and T3） were utilized to measure Qpand Rsover mountainous forests of Northeast *** airborne LiDAR system was used to generate a digital elevation model,and sky view factor of sectors（SVFs） divided from the field of view of tower's pyranometer was calculated as a topographic factor to explain the variations of Qp/*** The results identified significant differences in Qp/Rsof the three towers at both daily and half-hour scales,with larger differences on clear days than on overcast ***/Rswas positively correlated with SVFsof T1 and T3,while this correlation was negative with that of *** effect of SVFson Qp/Rsinteracted with clearness index,water vapor pressure and solar zenith *** forest-based importance assessment demonstrated that explanation（R2） on Qp/Rswas improved when SVFswas included in the predictor variable set,indicating that incorporating terrain effects enhances the prediction accuracy of Qp/*** improvement in the R2values was more pronounced on clear days than on overcast days,suggesting that the effect of terrain on Qp/Rsdepended on sky *** All findings suggested that Qp/Rsis affected by terrain,and integrating terrain information into existing Qp/Rsmodels is a feasible solution to improve Qp/Rsestimates in mountainous areas.

关键词： Photosynthetic photon flux density Clearness index Water vapor pressure Solar zenith angle Terrain Sky view factor

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Phosphorus limitation on CO_(2)fertilization effect in tropical forests informed by a coupled biogeochemical model

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Forest Ecosystems 2024年第4期11卷 502-515页

作者： Zhuonan Wang Hanqin Tian Shufen Pan Hao Shi Jia Yang Naishen Liang Latif Kalin Christopher Anderson Natural Resources ecology Laboratory Colorado State UniversityFort CollinsCO80523USA Center for Earth System Science and Global Sustainability Schiller Institute for Integrated Science and SocietyBoston CollegeChestnut HillMAUSA Department of Earth and environmental Sciences Boston CollegeChestnut HillMAUSA Department of Engineering Boston CollegeChestnut HillMAUSA research Center for Eco-environmental Sciences State Key Laboratory of Urban and Regional EcologyChinese Academy of SciencesBeijingChina Department of Natural Resource ecology and Management Oklahoma State UniversityStillwaterOKUSA Center for Global environmental research(CGER) National Institute for Environmental Studies(NIES)TsukubaIbaraki305-8506Japan College of Forestry Wildlife and EnvironmentAuburn UniversityAuburnALUSA

Tropical forests store more than half of the world's terrestrial carbon(C)pool and account for one-third of global net primary productivity(NPP).Many terrestrial biosphere models(TBMs)estimate increased productivity in tropical forests throughout the 21st century due to CO_(2)***,phosphorus(P)liaitations on vegetation photosynthesis and productivity could significantly reduce the CO_(2)fertilization ***,we used a carbon-nitrogen-phosphorus coupled model(Dynamic Land Ecosystem Model;DLEM-CNP)with heterogeneous maximum carboxylation rates to examine how P limitation has affected C fluxes in tropical forests *** model results showed that the inclusion of the P processes enhanced model performance in simulating ecosystem *** further compared the simulations from DLEM-CNP,DLEM-CN,and DLEMC and the results showed that the inclusion of P processes reduced the CO_(2)fertilization effect on gross primary production(GPP)by 25%and 45%,and net ecosystem production(NEP)by 28%and 41%,respectively,relative to CN-only and C-on ly *** the 1860s to the 2010s,the DLEM-CNP estimated that in tropical forests GPP increased by 17%,plant respiration(Ra)increased by 18%,ecosystem respiration(Rh)increased by 13%,NEP increased by 121%per unit area,***,factorial experiments with DLEM-CNP showed that the enhanced NPP benefiting from the CO_(2) fertilization effect had been offset by 135%due to deforestation from the 1860s to the *** study highlights the importance of P limitation on the C cycle and the weakened CO_(2)fertilization effect resulting from P limitation in tropical forests.

关键词： Tropical forests Carbon-nitrogen-phosphorus model Phosphorus limitation CO_(2)fertilization effect Terrestfial ecosy stem model

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Functional dissimilarity in mixed forests promotes stem radial growth by mitigating tree water deficit

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National Science Review 2024年第3期11卷 55-57页

作者：张宏图艾尤尔.亥热提白云旻郭焱培李珊 Bernhard Schmid Helge Bruelheide 马克平唐志尧 Institute of ecology College of Urban and Environmental Sciences and Key Laboratory for Earth Surface Processes of Ministry of EducationPeking University College of Geography and Tourism Xinjiang Normal University State Key Laboratory of Vegetation and environmental Change Institute of BotanyChinese Academy of Sciences Department of Geography Remote Sensing LaboratoriesUniversity of Zurich Institute of Biology/Geobotany and Botanical Garden Martin Luther University Halle-Wittenberg German centre for Integrative Biodiversity research(iDiv)Halle-Jena-Leipzig

Tree growth is a key component of forest ecosystem functioning and is wellknown to be limited by water availability[1]. It is acknowledged that composition and diversity of co-occurring tree species can mitigate the influence of drought on tree growth through the resource complementarity for water use via niche partitioning and facilitation between different species [2,3].

关键词： RESILIENCE

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research on ozone formation sensitivity based on observational methods:Development history,methodology,and application and prospects in China

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Journal of environmental Sciences 2024年第4期138卷 543-560页

作者： Wanghui Chu Hong Li Yuanyuan Ji Xin Zhang Likun Xue Jian Gao Cong An State Key Laboratory of environmental Criteria and Risk Assessment Chinese Research Academy of Environmental SciencesBeijing 100012China Environment research Institute Shandong UniversityQingdao 266237China

Observation-based method for O_(3)formation sensitivity research is an important tool to analyze the causes of ground-level O_(3)pollution,which has broad application potentials in determining the O_(3)pollution formation mechanism and developing prevention and control *** paper outlined the development history of research on O_(3)formation sensitivity based on observational methods,described the principle and applicability of the methodology,summarized the relative application results in China and provided recommendations on the prevention and control of O_(3)pollution in China based on relevant study results,and finally pointed out the shortcomings and future development prospects in this field in *** overview study showed that the O_(3)formation sensitivity in some urban areas in China in recent years presented a gradual shifting tendency from the VOC-limited regime to the transition regime or the NO_(x)-limited regime due to the implementation of the O_(3)precursors emission reduction policies;O_(3)pollution control strategies and precursor control countermeasures should be formulated based on local conditions and the dynamic control capability of O_(3)pollution control measures should be *** are still some current deficiencies in the study field in ***,it is recommended that a stereoscopic monitoring network for atmospheric photochemical components should be further constructed and improved;the atmospheric chemical mechanisms should be vigorously developed,and standardized methods for determining the O_(3)formation sensitivity should be established in China in the near future.

关键词： Observation-based method Ozone formation sensitivity Ozone pollution prevention and control VOCs NO_(x) OBM

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