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In situ synthesis of porous Pt-Pd bimetallic structures for sweat glucose biosensing using dynamic hydrogen bubble template method

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Rare metals 2024年第7期43卷 3408-3414页

作者： Yi-Wen Guo Qian-Hui Wei Fei Wei Hao Liu Hong-Bin Zhao Dong Wang Hai-Ling Tu State Key Laboratory of advanced Materials for Smart Sensing China GRINM Group Co.Ltd. Department of advanced Electronic Materials GRIMAT Engineering Institute Co.Ltd. General research Institute for Nonferrous metals GRINM (Guangdong) Institute for advanced Materials and Technology School of Chemical Engineering Northeast Electric Power University

For the practical application of sweat glucose biosensors,it is crucial to develop a method for modifying the working electrode with noble metals that ensures strong *** this study,we synthesized porous Pt-Pd bimetall... 详细信息

关键词： Hydrogen

Hydrogen and nitrogen absorption properties of Ce-added Zr_(2)(Fe_(1-x)Ni_(x)) alloys

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Journal of Rare Earths 2024年第6期42卷 1136-1141,I0005页

作者： Kai Yin Xiaopeng Liu State Key Laboratory of advanced Materials for Smart Sensing GRINM Group Co.Ltd.Beijing10088China GRIMAT Engineering Institute Co. Ltd.Beijing101407China General research Institute of Nonferrous metals Beijing100088China

To improve the nitriding resistance of Zr_(2)Fe alloy,the Ce-added Zr_(2)(Fe_(1-x)Ni_(x))(x=0,0.15,0.3,0.5)alloys were prepared by magnetic levitation melting *** effects of Ni substitution for Fe on the phase structure,hydrogen and nitrogen absorption properties of the alloys were investigated by X-ray diffraction,scanning electron microscopy and p-c isotherm *** experimental results show that Ni substitution can effectively inhibit the formation of both α-Zr and ZrFe_(2) phases and promote the formation of C16 structure Zr_(2)(Fe,Ni)phase,causing Ni-substituted alloys to exhibit low nitrogen absorption rate and *** 623 K under 0.5 MPa nitrogen pressure,the nitrogen absorption capacity of Ce-added Zr_(2)(Fe_(0.5)Ni_(0.5))alloy reaches to 0.8 mL/g,much lower than that of Zr_(2)Fe alloy(1.5 mL/g).Ni substitution decreases the crystal cell volume of the C_(16)Zr_(2)(Fe,Ni)phase,resulting in an increase in the hydrogen absorption equilibrium *** 623 K under 0.05 MPa hydrogen pressure,the hydrogen absorption capacity decreases from 1.46 wt%of Zr_(2)Fe alloy to 1.41 wt%of Ce-added Zr_(2)(Fe_(0.5)Ni_(0.5))alloy.

关键词： Zr_(2)Fe alloy Ce Pressure-composition isotherm Hydrogen absorption Nitrogen absorption Rare earths

A novel high-Cr CoNi-based superalloy with superior high-temperature microstructural stability, oxidation resistance and mechanical properties

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International Journal of Minerals,Metallurgy and Materials 2024年第6期31卷 1373-1381页

作者： Xiaorui Zhang Min Zou Song Lu Longfei Li Xiaoli Zhuang Qiang Feng Beijing advanced Innovation Center for Materials Genome Engineering State Key Laboratory for Advanced MetalsUniversity of Science and Technology BeijingBeijing 100083China

A novel multicomponent high-Cr CoNi-based superalloy with superior comprehensive performance was prepared,and the evaluation of its high-temperature microstructural stability,oxidation resistance,and mechanical properties was conducted mainly using its cast polycrystalline *** results disclosed that the morphology of theγ′phase remained stable,and the coarsening rate was slow during the long-term aging at 900–1000℃.The activation energy forγ′precipitate coarsening of alloy 9CoNi-Cr was(402±51)kJ/mol,which is higher compared with those of CMSX-4 and some other Ni-based and Co-based ***,there was no indica-tion of the formation of topologically close-packed phases during this *** these factors demonstrated the superior microstructural stability of the *** mass gain of alloy 9CoNi-Cr was 0.6 mg/cm^(2) after oxidation at 1000℃ for 100 h,and the oxidation resistance was comparable to advanced Ni-based superalloys CMSX-4,which can be attributed to the formation of a continuous Al_(2)O_(3) protective ***,the compressive yield strength of this cast polycrystalline alloy at high temperatures is clearly higher than that of the conventional Ni-based cast superalloy and the compressive minimum creep rate at 950℃ is comparable to that of the conventional Ni-based cast superalloy,demonstrating the alloy’s good mechanical properties at high *** is partially because high Cr is bene-ficial in improving theγandγ′phase strengths of alloy 9CoNi-Cr.

关键词： CoNi-based superalloys microstructure coarsening oxidation mechanical properties

Extraction and recycling technologies of cobalt from primary and secondary resources:A comprehensive review

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International Journal of Minerals,Metallurgy and Materials 2024年第4期31卷 628-649页

作者： Yukun Huang Pengxu Chen Xuanzhao Shu Biao Fu Weijun Peng Jiang Liu Yijun Cao Xiaofeng Zhu ZhongYuan Critical metals Laboratory Zhengzhou UniversityZhengzhou 450001China State Key Laboratory of advanced Processing and Recycling of Nonferrous metals Lanzhou University of TechnologyLanzhou 730050China

Cobalt has excellent electrochemical,magnetic,and heat *** a strategic resource,it has been applied in many hightech ***,the recent rapid growth of the battery industry has substantially depleted cobalt resources,leading to a crisis of cobalt resource *** paper examines cobalt ore reserves and distribution,and the recent development and consumption of cobalt resources are summarized as *** addition,the principles,advantages and disadvantages,and research status of various methods are discussed *** can be concluded that the use of diverse sources(Cu-Co ores,Ni-Co ores,zinc plant residues,and waste cobalt products)for cobalt production should be enhanced to meet developmental ***,in recovery technology,the pyro-hydrometallurgical process employs pyrometallurgy as the pretreatment to modify the phase structure of cobalt minerals,enhancing its recovery in the hydrometallurgical stage and facilitating high-purity cobalt ***,it represents a promising technology for future cobalt ***,based on the above conclusions,the prospects for cobalt are assessed regarding cobalt ore processing and sustainable cobalt recycling,for which further study should be conducted.

关键词： cobalt recovery copper-cobalt ore nickel-cobalt ore zinc plant residue waste cobalt products

Performance improvements in complementary metal oxide semiconductor devices and circuits based on fin field-effect transistors using 3-nm ferroelectric Hf0.5Zr0.5O2

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Rare metals 2024年第7期43卷 3242-3249页

作者： Zhao-Hao Zhang Yan-Na Luo Gao-Bo Xu Jia-Xin Yao Zhen-Hua Wu Hong-Bin Zhao Qing-Zhu Zhang Hua-Xiang Yin Jun Luo Wen-Wu Wang Hai-Ling Tu Integrated Circuit advanced R&D Center Institute of Microelectronics of Chinese Academy of Sciences School of Integrated Circuits University of Chinese Academy of Sciences State Key Laboratory of advanced Materials for Smart Sensing General Research Institute for Nonferrous Metals

In this work,a conventional HfO2gate dielectric layer is replaced with a 3-nm ferroelectric（Fe） HZO layer in the gate stacks of advanced fin field-effect transistors（FinFETs）.Fe-induced characteristics,e.g.,negative drain induced barrier lowering（N-DIBL） and negative differential resistance（NDR）,are clearly observed for both p-and n-type HZO-based *** characteristics are attributed to the enhanced ferroelectricity of the 3-nm hafnium zirconium oxide（HZO） film,caused by Al doping from the TiAlC capping *** mechanism is verified for capacitors with structures similar to the *** to the enhanced ferroelectricity and N-DIBL phenomenon,the drain current(IDS)of the HZO-FinFETs is greater than that of HfO2-FinFETs and obtained at a lower operating ***,circuits based on HZO-FinFET achieve higher performance than those based on HfO2-FinFET at a low voltage drain(VDD),which indicates the application feasibility of the HZO-FinFETs in the ultralow power integrated circuits.

关键词： FinFET Ferroelectric Hafnium zirconium oxide Subthreshold swing Low power

Microstructure and Shear Properties Evolution of Minor Fe-Doped SAC/Cu Substrate Solder Joint under Isothermal Aging

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Acta Metallurgica Sinica(English Letters) 2024年第7期37卷 1279-1290页

作者： Quanzhen Li Chengming Li Xiaojing Wang Shanshan Cai Jubo Peng Shujin Chen Jiajun Wang Xiaohong Yuan Jiangsu University of Science and Technology Zhenjiang212003China R&D Center Yunnan Tin Group(Holding)Co.LtdKunming650000China The 58 Research Institute of China Electronics Technology Group CorporationWuxi214100China Yunnan Precious metals Lab Sino-Platinum Metals Co.LtdKunming650156China

Different amounts of Fe(0.005,0.01,0.03,0.05,and 0.07 wt%)were added to SAC305 to study the shear behavior damage of Fe-doped SAC solder joints under thermal loading(170℃,holding time of 0,250,500,and 750 h).The results show that during isothermal aging at 170℃,the average shear force of all solder joints decreases with increasing aging time,while the average fracture energy first increases and then decreases,reaching a maximum at 500 *** Fe doping could both increase shear forces and related fracture energy,with the optimum Fe doping amount being 0.03 wt%within the entire aging *** is because the doping Fe reduces the undercooling of the SAC305 alloy,resulting in the microstructure refining of solder *** in turn causes the microstructure changing from network structure(SAC305 joint:eutectic network+β-Sn)to a single matrix structure(0.03Fe-doped SAC305 joint:β-Sn matrix+small compound particles).Specifically,Fe atoms can replace some Cu in Cu_(6)Sn_(5)(both inside the solder joint and at the interface),and then form(Cu,Fe)_(6)Sn_(5) compounds,resulting in an increase in the elastic modulus and nanohardness of the ***,the growth of Cu_(6)Sn_(5) and Cu_(3)Sn intermetallic compounds(IMC)layer are inhibited by Fe doping even after the aging time prolonging,and Fe aggregates near the interface compound to form FeSn_(2).This study is of great significance for controlling the growth of interfacial compounds,stabilizing the microstructures,and providing strengthening strategy for solder joint alloy design.

关键词： SAC305 solder Fe doping Shear mechanical behavior Isothermal aging Interfacial intermetallic compounds(IMC)

Microstructure evolution and strengthening mechanism of high -performance powder metallurgy TA15 titanium alloy by hot rolling

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International Journal of Minerals,Metallurgy and Materials 2024年第6期31卷 1426-1436页

作者： Ying Gao Ce Zhang Jiazhen Zhang Xin Lu Beijing advanced Innovation Center for Materials Genome Engineering State Key Laboratory for Advanced Metals and MaterialsInstitute for Advanced Ma-terials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China National Engineering research Center for advanced Rolling Technology National Engineering Research Center for Flat Rolling EquipmentInstitute of Engin-eering TechnologyUniversity of Science and Technology BeijingBeijing 100083China

Hot deformation of sintered billets by powder metallurgy(PM)is an effective preparation technique for titanium alloys,which is more significant for high-alloying *** this study,Ti–6.5Al–2Zr–Mo–V(TA15)titanium alloy plates were prepared by cold press-ing sintering combined with high-temperature hot *** microstructure and mechanical properties under different process paramet-ers were *** microscope,electron backscatter diffraction,and others were applied to characterize the microstructure evolution and mechanical properties strengthening *** results showed that the chemical compositions were uniformly dif-fused without segregation during sintering,and the closing of the matrix craters was accelerated by increasing the sintering *** block was hot rolled at 1200℃ with an 80%reduction under only two passes without *** strength and elongation of the plate at 20–25℃ after solution and aging were 1247 MPa and 14.0%,respectively,which were increased by 24.5%and 40.0%,respect-ively,compared with the as-sintered alloy at 1300℃.The microstructure was significantly refined by continuous dynamic recrystalliza-tion,which was completed by the rotation and dislocation absorption of the substructure surrounded by low-angle grain *** hot rolling combined with heat treatment,the strength and plasticity of PM-TA15 were significantly improved,which resulted from the dense,uniform,and fine recrystallization structure and the synergistic effect of multiple slip systems.

关键词： elemental powder powder metallurgy titanium alloy hot rolling strength and plasticity

Selective leaching of calcium from mechanically activated mixed rare earth concentrate

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Journal of Rare Earths 2024年第6期42卷 1149-1156,I0006页

作者： Jiang Liu Bingxue Chen Yuanqi Feng Yijun Cao Yukun Huang Yuan Shi Meng Li Zhongyuan Critical metals Laboratory School of Chemical EngineeringZhengzhou UniversityZhengzhou450001China State Key Laboratory of advanced Processing and Recycling of Nonferrous metals Lanzhou University of TechnologyLanzhou730050China

The loss of rare earths(REs)takes place during the pre-decalcification process of mixed rare earth *** an effort to reduce such RE loss,a novel idea to improve the leaching selectivity of Ca to REs by applying selective mechanical activation was ***,regarding the key minerals affecting the leaching selectivity of Ca to REs,the differences in the mechanical activation behaviors of CaF_(2) and REFCO_(3) were studied,and we find that the lattice strain of CaF_(2) increases from 0.21%to 0.42%,whereas that of REFCO_(3) increases from 0.31%to 0.40%.Notably,CaF_(2) demonstrates a larger lattice strain than REFCO_(3),indicating greater mechanical activation energy storage and higher leaching ***,the HCl leaching process was studied.A significant leaching selectivity of Ca to REs,from 21.6 to 35.1,is achieved through mechanical *** Ca leaching rate reaches 80.7%when the RE loss is 2.3%in the activated *** study provides an novel approach for achieving selective extraction of specific components via mechanical activation pretreatment.

关键词： Mixed rare earth concentrate Pre-decalcification Selective mechanical activation Selective leaching

The structure–activity relationships of Rh/CeO_(2)-ZrO_(2)catalysts based on Rh metal size effect in the three-way catalytic reactions

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Nano research 2024年第8期17卷 6870-6878页

作者： Dongming Chen Weixin Zhao Zihao Xu Zheng Zhao Juanyu Yang Yongke Hou Yongqi Zhang Zongyu Feng Meisheng Cui Xiaowei Huang National Engineering research Center for Rare Earth Grirem Advanced Materials Co.Ltd.Beijing 100088China Grirem Hi-Tech Co. Ltd.Sanhe 065201China General research Institute for Nonferrous metals Beijing 100088China

With the continuous tightening of automotive emission regulations and the increasing promotion of energy-efficient hybrid vehicles,new challenges have arisen for the low-temperature performance of three-way catalysts(TWCs).To guide the design of next-generation TWCs,it is essential to further develop our understanding of the relationships between microstructure and catalytic ***,Rh/CeO_(2)–ZrO_(2)catalysts were synthesized with different Rh metal dispersion by using a combination of the wet impregnation method and reduction *** catalysts included Rh single-atom catalysts,cluster catalysts,and nanoparticle *** results showed that the Rh nanoparticle catalyst,with an average size of 1.9 nm,exhibited superior three-way catalytic performance compared to the other *** on the catalytic activity in a series of simple reaction atmospheres such as CO+O_(2),NO+CO,and hydrocarbons(HCs)+O_(2)and operando infrared spectroscopy,we found that metallic Rh sites on Rh nanoparticles are the key factor responsible for the low-temperature catalytic performance.

关键词： Rh/CeO_(2)-ZrO_(2)catalyst Rh metal size effect Rh nanoparticles three-way catalytic performance