检索结果-南通市图书馆

High toughness and CMAS resistance of REAlO_(3)/RE_(2)Zr_(2)O_(7)(RE=La,Nd,Sm,Eu,Gd,and Dy)composites with eutectic composition for thermal barrier coatings

引用

Journal of advanced ceramics 2024年第6期13卷 800-809页

作者： Zijian Zhang Jian Sun Guanghua Liu Yi Han Wei Liu Yi Li Wei Wang Xiangyang Liu Peng Zhang Wei Pan Chunlei Wan State Key laboratory of New ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China China United Gas Turbine Technology Co. Ltd.Beijing 100015China College of Mathematics and Physics Beijing University of Chemical TechnologyBeijing 100029China College of Materials Science and Engineering Beijing University of TechnologyBeijing 100124China

Although rare earth zirconates(RE_(2)Zr_(2)O_(7))have garnered attention as viable candidates for thermal barrier coatings(TBCs),they suffer from low fracture toughness and accelerated calcium–magnesium–alumina–silicate(CMAS)melt corrosion at high service temperatures,which impedes their practical *** this work,we developed a series of REAlO_(3)/RE_(2)Zr_(2)O_(7)(RE=La,Nd,Sm,Eu,Gd,and Dy)composites with a eutectic composition that not only significantly enhanced the fracture toughness by more than 40%relative to that of RE_(2)Zr_(2)O_(7)but also exhibited improved resistance to CMAS *** increase in toughness arises from multiple mechanisms,such as ferroelastic toughening,fine-grain strengthening,and residual stress toughening,all of which trigger more crack defects and energy ***,the CMAS penetration depth of the REAlO_(3)/RE_(2)Zr_(2)O_(7)composites is approximately 36%lower than that of RE_(2)Zr_(2)O_(7).Al–O constituents in composites can capture CaO,SiO_(2),and MgO in CMAS melts and increase their viscosity,resulting in enhanced CMAS corrosion *** thermophysical properties of the REAlO_(3)/RE_(2)Zr_(2)O_(7)composites were also investigated,and their coefficient of thermal expansion and thermal conductivity are comparable to those of 7–8 wt%Y_(2)O_(3)partially stabilized ZrO2(YSZ),indicating their potential as TBC materials.

关键词： fracture toughness thermal property calcium-magnesium-alumina-silicate(CMAS)corrosion REAlO_(3)/RE_(2)Zr_(2)O_(7) eutectic composition

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO_(3)-based lead-free ceramics for high-efficiency large-capacitive energy storage

引用

Chinese Chemical Letters 2024年第7期35卷 465-469页

作者： Shuangliang Xie Yuyue Chen Qing He Liang Chen Jikun Yang Shiqing Deng Yimei Zhu He Qi School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083China Beijing advanced Innovation Center for Materials Genome Engineering Department of Physical ChemistryUniversity of Science and Technology BeijingBeijing 100083China School of Mathematics and Physics University of Science and Technology BeijingBeijing 100083China Department of Condensed Matter Physics and Materials Science Brookhaven National LaboratoryUptonNew York 11973United States

Relaxor ferroic dielectrics have garnered increasing attention in the past decade as promising materials for energy *** them,relaxor antiferroelectrics(AFEs)and relaxor ferroelectrics(FEs)have shown great promise in term of high energy storage density and efficiency,*** this study,a unique phase transition from relaxor AFE to relaxor FE was achieved for the first time by introducing strong-ferroelectricity BaTiO_(3)into NaNbO_(3)-BiFeO_(3)system,leading to an evolution from AFE R hierarchical nanodomains to FE polar nanoregions.A novel medium state,consisting of relaxor AFE and relaxor FE,was identified in the crossover of 0.88NaNbO_(3)–0.07BiFeO_(3)–0.05BaTiO_(3)ceramic,exhibiting a distinctive core-shell grain structure due to the composition *** harnessing the advantages of high energy storage density from relaxor AFE and large efficiency from relaxor FE,the ceramic showcased excellent overall energy storage *** achieved a substantial recoverable energy storage density W_(rec)~13.1 J/cm^(3)and an ultrahigh efficiencyη~88.9%.These remarkable values shattered the trade-off relationship typically observed in most dielectric capacitors between W_(rec)andη.The findings of this study provide valuable insights for the design of ceramic capacitors with enhanced performance,specifically targeting the development of next generation pulse power devices.

关键词： Relaxor ferroelectric Antiferroelectric Core-shell Energy storage High efficiency

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Designing highly transparent cerium doped Y2O3 ceramics with high mechanical and thermal properties for UV-shielding in extreme conditions

引用

Journal of advanced ceramics 2024年第7期13卷 1032-1042页

作者： Cong Zhang Jianqi Qi Xiaolan Zhou Zhonghua Lu Tiecheng Lu College of Physics Sichuan UniversityChengdu 610064China Key laboratory of High Energy Density Physics of Ministry of Education Sichuan UniversityChengdu 610064China Key laboratory of Radiation Physics and Technology of the Ministry of Education Sichuan UniversityChengdu 610064China

Ultraviolet(UV)radiation poses risks to both human health and *** response to the urgent demand for UV-shielding across various applications,extensive endeavors have been dedicated to developing UV-shielding materials spanning from wide-bandgap semiconductors to organo-inorganic composite ***,existing UV shielding materials,though suitable for daily use,cannot meet the demands of extreme *** this work,we incorporated CeO_(2)as a UV absorber into Y_(2)O_(3)transparent ceramics for *** effect of CeO_(2)concentration on the optical,mechanical,and thermal properties of Y_(2)O_(3)ceramics was systematically *** findings indicate that CeO_(2)serves not only as a UV absorber but also as an effective sintering aid for Y_(2)O_(3)transparent *** 5 at%Ce-doped Y_(2)O_(3)transparent ceramics exhibit the optimal optical quality,with in-line transmittance of~77%at 800 *** introduction of Ce shifted the UV cutoff edge of Y_(2)O_(3)transparent ceramics from 250 to 375 nm,which was attributed to the visible band absorption of Ce^(4+).This shift grants UV shielding capabilities to Y_(2)O_(3)transparent ceramics,resulting in 100%shielding for ultraviolet C(UVC,100-280 nm)and ultraviolet B(UVB,280-320 nm)and~95%shielding for ultraviolet A(UVA,320-400 nm).The service stability(optical properties)under various corrosive conditions(acid,alkali,UV irradiation,and high temperature)was investigated,confirming the excellent stability of this transparent ceramic UV-shielding material.A comparison of the performance parameters of transparent ceramics with those of traditional UV shielding materials such as glasses,films,and coatings was *** work provides innovative design concepts and an effective solution for UVshielding materials for extreme conditions.

关键词： ultraviolet(UV)-shielding transparent ceramics bandgap engineering thermal properties optical properties

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Two-dimensional ultrathin vanadium oxide nanosheets as catalytic bactericide

引用

Science China Materials 2024年第9期67卷 2965-2976页

作者： Zhimin Zhang Zhao Guo Zesong Ruan Min Ge Shibo Cao Jiayi Yuan Zhen Xu Lieying Fan Ming Zong Han Lin Jianlin Shi State Key laboratory of High Performance ceramics and Superfine Microstructures Shanghai Institute of Ceramics Chinese Academy of SciencesResearch Unit of Nanocatalytic Medicine in Specific Therapy for Serious DiseaseChinese Academy of Medical SciencesShanghai200050China Department of Orthopedic Surgery Shanghai Institute of Microsurgery on ExtremitiesShanghai Sixth People’s Hospital Affiliated to Shanghai Jiao Tong University School of MedicineShanghai200233China Department of Clinical laboratory Shanghai East HospitalTongji University School of MedicineShanghai200120China Department of Electrical and Electronic Engineering The University of Hong KongHong KongChina Shanghai Tenth People’s Hospital Shanghai Frontiers Science Center of Nanocatalytic MedicineSchool of MedicineTongji UniversityShanghai200331China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing100049China

Infectious diseases caused by pathogenic bacteria are a serious threat to global public ***,antibiotics and other clinical drugs suffer from some fundamental disadvantages such as narrow-spectrum antibacterial effect and the risk to induce drug resistance,while inorganic functional nanomaterials with biological catalytic activities have been developed as novel antibacterial *** this study,we prepared two-dimensional ultrathin vanadium oxide nanosheets(VO_(x)NSs)with mixed valence states from the oxidised layer of vanadium powder(bulk V)by ultrasonically assisted liquid *** conveniently switching between V^(IV)and V^(V),VO_(x)NSs can efficiently catalyse H_(2)O_(2)enriched in bacterially infected areas to generate hydroxyl radicals(·OH),which induce bacterial oxidative stress and *** process can occur in both weakly alkaline and acidic environments,thus being independent of the pH value in infection *** addition,contributed by the intrinsic characteristics of vanadium,two-dimensional morphology and reasonable valence state ratios,VO_(x)NSs exhibit the advantages of broad antibacterial spectrum,high catalytic activity and non-toxic *** novel nanosheet offers a new strategy to heal infected wounds and extends the application of nanocatalytic medicine towards anti-infection.

关键词： ultrathin nanosheet vanadium oxide Fenton-like reaction antibacterial

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Enhanced thermoelectric and mechanical properties of Bi_(0.5)Sb_(1.5)Te_(3) alloy with dispersed yttrium oxide ceramic nanoparticles

引用

Rare Metals 2024年第4期43卷 1758-1768页

作者： Cun-Cheng Li Ming-Wei Zhang Ji-Wu Xin Lei Wei Wen-Yu Zhao School of Materials Science and Engineering Shandong University of TechnologyZibo255000China School of Electrical and Electronic Engineering Nanyang Technological UniversitySingapore639798Singapore State Key laboratory of advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China

Reducing thermal conductivity while avoiding adverse interfacial reactions during sintering is crucial for improving the thermoelectric performance of Bi_(2)Te_(3)based *** ceramic nanoparticles are good candidates for achieving this *** this study,we designed and prepared a series of p-type Bi_(0.5)Sb_(1.5)Te_(3)nanocomposites decorated with Y_(2)O_(3)ceramic nanoparticles via ball-milling dispersion and spark-plasma *** to the chemical stability of the ceramics,no traces of atomic doping or interfacial reactions were *** measurements revealed that the Y_(2)O_(3)nanoparticles distributed along the grain boundaries acted as energy-dependent carrier-filtering centers to improve the scattering parameter and Seebeck coefficient,contributing to the elevated power factor even with a decreased electrical ***,the incorporated Y_(2)O_(3)nanoparticles and various defect structures they induced effectively strengthened the phonon scattering and suppressed the lattice thermal ***,a peak figure of merit(ZT)of 1.23 at 313 K was achieved for 0.4%Y_(2)O_(3)/Bi_(0.5)Sb_(1.5)Te_(3),which is 13%higher than that of the *** addition,the Vickers hardness of the composite material was 35%higher than that of the *** study demonstrates the effectiveness of ceramic nanoparticles in synergistic ally improving the thermoelectric and mechanical properties,which may be further extended to other thermoelectric systems.

关键词： Bi_(0.5)Sb_(1.5)Te_3 alloy Y_(2)O_(3) ceramic nanoparticles Microstructures Thermoelectric performance Mechanical properties

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Structural evolution and high-temperature sensing performance of polymer-derived SiAlBCN ceramics

引用

Journal of advanced ceramics 2024年第4期13卷 478-485页

作者： Chao Ma Kun Liu Pengfei Shao Daoyang Han Kang Wang Mengmeng Yang Rui Zhao Hailong Wang Rui Zhang Gang Shao School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China Zhongyuan Critical Metal laboratory Zhengzhou UniversityZhengzhou 450001China State Key laboratory of Structural Analysis Optimization and CAE Software for Industrial EquipmentZhengzhou UniversityZhengzhou 450002China

In situ temperature monitoring has become extremely imperative in high-temperature harsh environments and polymer-derived ceramics(PDCs)as sensing materials have attracted great ***,the stability and oxidation/corrosion resistance of PDCs cannot be simultaneously achieved at the moment,limiting their practical ***,polymer-derived SiAlBCN ceramics were synthesized via polymer conversion method under different pyrolysis *** microstructure evolution,high temperature sensing properties,and stability were investigated in *** results show that the amorphous SiAlBCN phase grows more orderly and the size of the free carbon phase enlarges with the increasing *** defect concentration displays a decreasing ***,the SiAlBCN ceramics as sensing materials exhibit a good temperature-resistance property from roo temperature to 1100℃.The fabricated SiAlBCN temperature sensor possesses excellent stability,repeatability,and ***,SiAlBCN ceramics exhibit distinguished oxidation/corrosion resistance after 100 h treatment at 1200℃in a water/oxygen environment,which is attributed to their low corrosive rate constant(0.57 mg/(cm^(2)·h))and oxidative rate constant(3.43 mg^(2)/(cm^(4)·h)).Therefore,polymer-derived SiAlBCN ceramics as sensing materials,which possess outstanding stability and oxidation/corrosion resistance,have great potential for in-situ monitoring of extreme environmental temperatures in the future.

关键词： polymer-derived SiAlBCN ceramics temperature sensor harsh environments oxidation and corrosion resistance

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Enhanced mechanical properties and thermal shock resistance of Si_2BC_3N ceramics with SiC coated MWCNTs

引用

Journal of advanced ceramics 2019年第1期8卷 121-132页

作者： Ning LIAO Dechang JIA Zhihua YANG Yu ZHOU Institute for advanced ceramics School of Materials Science and EngineeringHarbin Institute of Technology Key laboratory of advanced Structure-Function Integrated Materials and Green Manufacturing Technology Ministry of Industry and Information Technology

Bulk Si_2 BC_3 N ceramics were reinforced with SiC coated multi-walled carbon nanotubes(MWCNTs). The phase compositions, mechanical properties, and thermal shock resistance, as well as the oxidation resistance of the designed Si_2 BC_3 N ceramics were comparatively investigated. The results show that nano SiC coating can be formed on MWCNTs through pyrolyzing polysilazane, which improves the oxidation resistance of MWCNTs. A stronger chemical bonding is formed between the SiC coated MWCNTs and SiC particles, contributing to improved flexural strength(532.1 MPa) and fracture toughness(6.66 MPa m1/2). Besides, the 2 vol% SiC coated MWCNTs reinforced Si_2 BC_3 N ceramics maintains much higher residual strength(193.0 MPa) after thermal shock test at 1000 ℃.The enhanced properties should be attributed to:(1) the breaking of MWCNTs and the debonding between MWCNTs and SiC interfaces, which leads to more energy dissipation;(2) the rough surfaces of SiC coated MWCNTs increase the adhesion strength during the "pull out" of MWCNTs.

关键词： Si2BC3N ceramics SiC coated MWCNTs mechanical properties thermal shock resistance

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Green State Joining ZrO_2/Al_2O_3 ceramics by Metal Interlayer

引用

Journal of Rare Earths 2005年第S1期23卷 194-196页

作者：张君娣刘家臣叶浩门荣磊 Key laboratory for advanced ceramics and Machining Technology of Ministry of Education School of Materials Science & Engineering Tianjin University Tianjin 300072 China

Green bodies of Al_2O_3 and ZrO_2 ceramics were joined without applying pressure by using metal slurries of Al as an interlayer according to the mechanism of volume expansion in the oxidation process of Al+O_2→Al_2O_3. The microstructure of the joints was investigated. The results shows that interface cracks are easily produced. With addition of Al_2O_3 and ZrO_2 into the interlayer composition, fine joints could be obtained without obvious cracks, pores and other defects. Under the experimental conditions, the grain size of the particles grown in the joint is smaller than that in the parent material. Therefore, the addition of Al_2O_3 or ZrO_2 can buffer the defect resulting from the volume expansion in the oxidation process. And in the existence of Al_2O_3 or ZrO_2 in the interlayer, active Al_2O_3 can boost the interface reaction.

关键词： joining interface slurry green body

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Microstructures and mechanical properties of SiBCNAl ceramics produced by mechanical alloying and subsequent hot pressing

引用

Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2010年第10期11卷 761-765页

作者： Dan YE De-chang JIA Zhi-hua YANG Zhen-lin SUN Peng-fei ZHANG Institute for advanced ceramics Harbin Institute of Technology Harbin 150001 China

Amorphous SiBCNAl powders were prepared via a mechanical alloying (MA) technique using crystalline silicon (Si), hexagonal boron nitride (h-BN), graphite (C), and aluminum (Al) as starting materials. SiBCNAl powders were consolidated by a hot pressing (HP) technique at 1800 °C under a pressure of 30 MPa in argon and nitrogen. The sintering atmosphere had a great influence on the microstructures and mechanical properties of the ceramics. The two ceramics had different phase compositions and fracture surface morphologies. For the ceramics sintered in argon, flexural strength, fracture toughness, elastic modulus and Vickers hardness were 421.90 MPa, 3.40 MPa·m1/2, 174.10 GPa, and 12.74 GPa, respectively. For the ceramics sintered in nitrogen, the mechanical properties increased, except for the Vickers hardness, and the values of the above properties were 526.80 MPa, 5.25 MPa·m1/2, 222.10 GPa, and 11.63 GPa, respectively.

关键词： SiBCNAl ceramics Hot pressing (HP) Mechanical properties Microstructure Mechanical alloying (MA)

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Effect of Different Rare-Earth on Microstructure and Properties of α-Sialon ceramics

引用

Journal of Materials Science & Technology 2008年第6期24卷 878-882页

作者： Chunfeng LIU Feng YE Yu ZHOU Yongliang WANG Jiancun RAO Institute for advanced ceramics Harbin Institute of Technology Harbin 150001 China

Densified Yb-, Y-, Dy-, Sin- and Nd-α-Sialon ceramics were prepared by two-step hot sintering. The variation of microstructure and properties with different rare-earth was investigated. The ceramics doped with smaller cations （Yb3＋, y3＋ and Dy3＋） are fully composed of α-Sialon, while in the larger cations （Sm3＋ and Nd3＋） doped ceramics also exist a few intergranular phase Mt （Re2Si3-xAlxO3＋xN4-x） in triple-point pockets. With increasing the radius of the rare-earth cations, the elongated α-Sialon grains form instead of the equiaxed grains in Yb-α-Sialon, and the aspect ratio of grains increases. All the ceramics possess high hardness, and the value of 21 GPa is achieved for Yb- and Y-α-Sialon. With increasing the ionic size of rare-earth, the hardness decreases slightly but the toughness tends to increase. Nd-α-Sialon possesses the highest toughness with the value of 5.4 MPa·m^1/2.

关键词： α-Sialon Rare-earth Microstructure Mechanical properties

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：