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Mechanochemical route to fabricate an efficient nitrate reduction electrocatalyst

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Nano Research 2024年第6期17卷 4889-4897页

作者： Yunliang Liu Zhiyu Zheng Sobia Jabeen Naiyun Liu Yixian Liu Yuanyuan Cheng Yaxi Li Jingwen Yu Xin Wu Nina Yan Lei Xu Haitao Li Institute for Energy Research School of Energy and Power EngineeringJiangsu UniversityZhenjiang 212013China Jiangsu Engineering Technology Research Center of Biomass Composites and Addictive Manufacturing Institute of Agricultural Facilities and EquipmentJiangsu Academy of Agricultural SciencesNanjing 210014China Key Laboratory for Protected Agricultural Engineering in the Middle and Lower Reaches of Yangtze River Ministry of Agriculture and Rural AffairsNanjing 210014China

The electrochemical nitrate reduction reaction(NO_(3)RR)to ammonia under ambient conditions is a promising approach for addressing elevated nitrate levels in water bodies,but the progress of this reaction is impeded by the complex series of chemical reactions involving electron and proton transfer and competing hydrogen evolution ***,it becomes imperative to develop an electro-catalyst that exhibits exceptional efficiency and remarkable selectivity for ammonia synthesis while maintaining long-term *** the magnetic biochar(Fe-C)has been synthesized by a two-step mechanochemical route after a pyrolysis treatment(450,700,and 1000℃),which not only significantly decreases the particle size,but also exposes more oxygen-rich functional groups on the surface,promoting the adsorption of nitrate and water and accelerating electron transfer to convert it into *** showed that the catalyst(Fe-C-700)has an impressive NH_(3)production rate of 3.5 mol·h^(−1)·gcat^(−1),high Faradaic efficiency of 88%,and current density of 0.37 A·cm^(−2)at 0.8 V *** hydrogen electrode(RHE).In-situ Fourier transform infrared spectroscopy(FTIR)is used to investigate the reaction intermediate and to monitor the *** oxygen functionalities on the catalyst surface activate nitrate ions to form various intermediates(NO_(2),NO,NH_(2)OH,and NH_(2))and reduce the rate determining step energy barrier(*NO_(3)→*NO_(2)).This study presents a novel approach for the use of magnetic biochar as an electro-catalyst in NO_(3)RR and opens the road for solving environmental and energy challenges.

关键词： mechanochemical route magnetic biochar electron transfer nitrate ammonia

Lutein-stevioside nanoparticle attenuates H_(2)O_(2)-induced oxidative damage in ARPE cells

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Food Science and Human Wellness 2024年第3期13卷 1628-1635页

作者： Zhuqing Dai Meimei Nie Ye Chen Jiangfeng Song Yayuan Xu Zhongyuan Zhang Guodong Zhang Shumo Yan Xing Zhang Dajing Li Institute of Agro-Product Processing Jiangsu Academy of Agricultural SciencesNanjing 210014China Jiangsu Key Laboratory for Food Quality and Safety-State Key Laboratory Cultivation Base Ministry of Science and TechnologyNanjing 210014China Jiangsu Aland Nutrition Co. Ltd.Taizhou 214500China Aland Nutrition Taizhou Co. Ltd.Taizhou 225300China

In order to improve the bioavailability of lutein(LUT),a novel lutein-stevio side nanoparticle(LUT-STE)were prepared previously,but the information about LUT-STE on protecting of eye health was *** study investigated the effect of LUT-STE on antioxidant activity of H_(2)O_(2)-induced human retinal pigment epithelial(ARPE)*** and LUT-STE(final concentration of 5μg/mL)significantly enhanced cell viability from(74.84±5.10)%to(81.92±10.01)%(LUT)and(89.33±4.34)%(LUT-STE),and inhibited the cell apoptosis(P<0.05).After pretreatment with LUT-STE in ARPE cells,the levels of superoxide dismutase(SOD),catalase(CAT)and glutathion peroxidase(GSH-Px)in ARPE cells were significantly increased(P<0.05),the contents of reactive oxygen species(ROS)and malondialdehyde(MDA)were *** addition,the vascular endothelial growth factor(VEGF)levels were inhibited by 13.61%and 17.39%,respectively,pretreatment with LUT and *** blotting results showed that the pretreatment with LUT-STE inhibited the expression of caspase-9 and caspase-3 and up-regulated Bcl-2/Bax pathway to inhibit H_(2)O_(2)-induced *** summary,the novel delivery LUT-STE had more pronounced inhibitory effect on H_(2)O_(2)-induced damage in human ARPE cells.

关键词： Lutein Stevioside Antioxidant Human retinal pigment epithelial cell Mechanism

Automatic Miscalibration Detection and Correction of LiDAR and Camera Using Motion Cues

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Chinese Journal of Mechanical Engineering 2024年第2期37卷 318-329页

作者： Pai Peng Dawei Pi Guodong Yin Yan Wang Liwei Xu Jiwei Feng School of Mechanical Engineering Southeast UniversityNanjing 211102China School of Mechanical Engineering Nanjing University of Science and TechnologyNanjing 210014China School of Mechanical and Aerospace Engineering Nanyang Technological UniversitySingaporeSingapore

This paper aims to develop an automatic miscalibration detection and correction framework to maintain accurate calibration of LiDAR and camera for autonomous vehicle after the sensor ***,a monitoring algorithm that can continuously detect the miscalibration in each frame is designed,leveraging the rotational motion each individual sensor ***,as sensor drift occurs,the projection constraints between visual feature points and LiDAR 3-D points are used to compute the scaled camera motion,which is further utilized to align the drifted LiDAR scan with the camera ***,the proposed method is sufficiently compared with two representative approaches in the online experiments with varying levels of random drift,then the method is further extended to the offline calibration experiment and is demonstrated by a comparison with two existing benchmark methods.

关键词： Autonomous vehicle LiDAR and camera Miscalibration detection and correction Sensor drift

The chromosome-level genome of double-petal phenotype jasmine provides insights into the biosynthesis of floral scent

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Horticultural Plant Journal 2024年第1期10卷 259-272页

作者： Xiangyu Qi Huadi Wang Shuyun Liu Shuangshuang Chen Jing Feng Huijie Chen Ziyi Qin Quanming Chen Ikram Blilou Yanming Deng Jiangsu Key Laboratory for Horticultural Crop Genetic Improvement Institute of Leisure AgricultureJiangsu Academy of Agricultural SciencesNanjingJiangsu 210014China School of Life Sciences Jiangsu UniversityZhenjiangJiangsu 212013China College of Horticulture Nanjing Agricultural UniversityNanjingJiangsu 210014China Shanghai Personal Biotechnology Company Limited Shanghai 200231China Biological and Environmental Sciences and Engineering King Abdullah University of Science and TechnologyThuwal 23955-6900Saudi Arabia

Jasmine(Jasminum sambac Aiton)is a well-known cultivated plant species for its fragrant flowers used in the perfume industry and ***,the genetic basis of its floral scent is largely *** this study,using PacBio,Illumina,10×Genomics and highthroughput chromosome conformation capture(Hi-C)sequencing technologies,a high-quality chromosome-level reference genome for *** was obtained,exploiting a double-petal phenotype cultivar‘Shuangbanmoli’(JSSB).The results showed that the final assembled genome of JSSB is 580.33 Mb in size(contig N50=1.05 Mb;scaffold N50=45.07 Mb)with a total of 39618 predicted protein-coding *** analyses revealed that the JSSB genome has undergone an ancient whole-genome duplication(WGD)event at 91.68 million years ago(Mya).It was estimated that *** diverged from the lineage leading to Olea europaea and Osmanthus fragrans about 28.8 *** the basis of a combination of genomic,transcriptomic and metabolomic analyses,a range of floral scent volatiles and genes were identified involved in the benzenoid/phenylpropanoid and terpenoid biosynthesis *** results provide new insights into the molecular mechanism of its fragrance biosynthesis in jasmine.

关键词： Jasminum sambac Aiton Oleaceae Genome evolution Floral scent Terpene synthase

Efficiency-first spraying mission arrangement optimization with multiple UAVs in heterogeneous farmland with varying pesticide requirements

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Information Processing in Agriculture 2024年第2期11卷 237-248页

作者： Yang Li Yanqiang Wu Xinyu Xue Xuemei Liu Yang Xu Xinghua Liu Nanjing Institute of Agricultural Mechanization Ministry of Agriculture and Rural AffairsNanjing 210014PR China College of Mechanical&Electronic Engineering Shandong Agricultural UniversityTai'an 271018PR China Key Laboratory of Modern Agricultural Equipment Ministry of Agriculture and Rural AffairsNanjing 210014PR China Shandong Provincial Key Laboratory of Horticultural Machinery and Equipment Tai’an 271018PR China Shandong Provincial Engineering Laboratory of Agricultural Equipment Intellectualization Tai’an 271018PR China

Combining multiple crop protection Unmanned Aerial Vehicles(UAVs)as a team for a scheduled spraying mission over farmland now is a common way to significantly increase ***,given some issues such as different configurations,irregular borders,and especially varying pesticide requirements,it is more important and more complex than other multi-Agent Systems(MASs)in common *** this work,we focus on the mission arrangement of UAVs,which is the foundation of other high-level cooperations,systematically propose Efficiency-first Spraying Mission Arrangement Problem(ESMAP),and try to construct a united problem framework for the mission arrangement of crop protection ***,to characterise the differences in sub-areas,the varying pesticide requirement per unit is well considered based on Normalized Difference Vegetation Index(NDVI).Firstly,the mathematical model of multiple crop-protection UAVs is established and ESMAP is ***,an acquisition method of a farmland’s NDVI map is proposed,and the calculation method of pesticide volume based on NDVI is ***,an improved Genetic Algorithm(GA)is proposed to solve ESMAP,and a comparable combination algorithm is *** simulations for algorithm analysis are carried out within MATLAB,and it is determined that the proposed GA is more efficient and accurate than the ***,a mission arrangement tested with three UAVs was carried out to validate the effectiveness of the proposed GA in spraying *** results illustrated that it performed well,which took only 90.6%of the operation time taken by the combination algorithm.

关键词： Efficiency-first optimization Mission arrangement Multi-UAVs Heterogeneous farmland

Development of the electric automatic steering system for agricultural vehicles

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International Journal of Agricultural and Biological Engineering 2024年第1期17卷 209-214页

作者： Guangshun An Chong Yu Juan Du Xiang Yin Youliang Ni Chengqian Jin School of Agricultural Engineering and Food Science Shandong University of TechnologyZibo 255000ShandongChina Nanjing Research Institute for Agricultural Mechanization of Ministry of Agriculture and Rural Affairs Nanjing 210014China

Automatic guidance of agricultural vehicles requires automatic execution of operation commands received from the navigation controller by using electronically controlled mechanisms for wheel steering,speed changing and work *** steering contributes as a prerequisite technique in automatic and semi-automatic agricultural *** research aimed to develop an electric automatic steering system that was compact in its structure and integrated into original steering mechanism in a simply and convenient way for aftermarket modification.A brushless motor and reducer assembly was utilized to provide an adequate steering torque instead of manual maneuver.A rapid assembling approach was proposed by passing the steering shaft through the hollow output shaft.A digital proportional-integral-differential(PID)algorithm was implemented to calculate the rotation speeds and directions by comparing the desired angle and the actual angle,which was implemented in a printed circuit board with a microcontroller unit(MCU)and interface *** unmanned wheeled tractor was applied as test platform to integrate the newly developed electric automatic steering *** were conducted to evaluate its performance in terms of stability and *** autonomous navigation system guided the tractor along target paths in the field by sending steering commands to the electric automatic steering *** results show that the steering angle error was less than 0.81°when desired steering angle was less than 10°.The lateral error difference was no more than 4.76 cm when repeating following the same target path,which indicated that the electric automatic steering system responded accurately and robustly to steering commands.

关键词： automatic steering automatic navigation agricultural vehicles

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一种PMSM位置伺服系统的动态建模与控制

仪器仪表学报 2024年第4期45卷 226-233页

作者：王禹智吴志强徐世超南京理工大学中法工程师学院南京210014 南京理工大学机械工程学院南京210014

本文根据永磁同步电机(PMSM)的基本电磁关系及其动态数学模型建立了位置伺服控制模型,按照闭环负反馈控制原理,设计了具有电流、速度、位置三闭环的位置控制系统。首先,根据PMSM矢量控制的特性,利用3S/2S和2S/2R的坐标变换理论,建立了... 详细信息

本文根据永磁同步电机(PMSM)的基本电磁关系及其动态数学模型建立了位置伺服控制模型,按照闭环负反馈控制原理,设计了具有电流、速度、位置三闭环的位置控制系统。首先,根据PMSM矢量控制的特性,利用3S/2S和2S/2R的坐标变换理论,建立了位置伺服系统在同步坐标系下的动态数学模型,同时给出了按照转子磁场定向的位置控制策略和算法;其次,研究了基于空间矢量脉宽调制(SVPWM)的数字实现,并根据电机的数学模型,在MATLAB/Simulink环境中构建了三环模型,同时搭建了基于DSP实验样机。在仿真和实验中直轴、交轴以及速度和位置均采用PI控制,在控制参数的整定过程中,遵循先内环(电流环),后速度环,再位置环的增量调试原理,实现了同步电机的位置闭环控制;最后,对仿真结果和试验结果进行了对比分析,说明了模型的正确性和有效性。

关键词：永磁同步电机位置伺服系统空间矢量脉宽调制矢量控制增量调试原理

Development status and prospect of cold chain logistics of fruits,vegetables,and agricultural products based on intelligent technology

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智能化农业装备学报（中英文） 2024年第3期5卷 63-74页

作者： ZHANG Ruizhi LIU Qianyuan HUANG Yuying LIU Bing CHANG Zhiguang WANG Jiaoling Zhongnong Guoke(Nanjing)Planning and Design Co.Ltd. Nanjing 210014China Nanjing Institute of Agricultural Mechanization Ministry of Agriculture and Rural AffairsNanjing 210014China Key Laboratory of Agro-Products Processing and Storage Ministry of Agriculture and Rural AffairsNanjing 210014China

The cold chain in the production area of fruits and vegetables is the primary link to reduce product loss and improve product quality,but it is also a weak *** the application of big data technology in cold chain logistics,intelligent devices,and technologies have become important carriers for improving the efficiency of cold chain logistics in fruit and vegetable production areas,extending the shelf life of fruits and vegetables,and reducing fruit and vegetable *** have many advantages in fruit and vegetable pre-cooling,sorting and packaging,testing,warehousing,transportation,and other *** article summarizes the rapidly developing and widely used intelligent technologies at home and abroad in recent years,including automated guided vehicle intelligent handling based on electromagnetic or optical technology,intelligent sorting based on sensors,electronic optics,and other technologies,intelligent detection based on computer vision technology,intelligent transportation based on perspective imaging technology,*** analyses and studies the innovative research and achievements of various scholars in applying intelligent technology in fruit and vegetable cold chain storage,sorting,detection,transportation,and other links,and improves the efficiency of fruit and vegetable cold chain ***,applying intelligent technology in fruit and vegetable cold chain logistics also faces many *** challenges of high cost,difficulty in technological integration,and talent shortages have limited the development of intelligent technology in the field of fruit and vegetable cold *** solve the current problems,it is proposed that costs be controlled through independent research and development,technological innovation,and other means to lower the entry threshold for small *** integrating intelligent technology and cold chain logistics systems to improve data security and system *** the same time,the government

关键词： fruits and vegetables cold chain logistics automated guided vehicle intelligent handling computer vision spectral detection

Improving the electrical performances of InSe transistors by interface engineering

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Chinese Physics B 2024年第4期33卷 153-158页

作者：曹天俊郝松吴晨晨潘晨戴玉頔程斌梁世军缪峰 Institute of Brain-Inspired Intelligence National Laboratory of Solid State MicrostructuresSchool of PhysicsCollaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210093China Institute of Interdisciplinary Physical Sciences School of PhysicsNanjing University of Science and TechnologyNanjing 210014China

InSe has emerged as a promising candidate for next-generation electronics due to its predicted ultrahigh electrical ***,the efficacy of the InSe transistor in meeting application requirements is hindered due to its sensitivity to *** this study,we have achieved notable enhancement in the electrical performance of InSe transistors through interface *** engineered an InSe/h-BN heterostructure,effectively suppressing dielectric layer-induced ***,we successfully established excellent metal-semiconductor contacts using graphene ribbons as a buffer *** a methodical approach to interface engineering,our graphene/InSe/h-BN transistor demonstrates impressive on-state current,field-effect mobility,and on/off ratio at room temperature,reaching values as high as 1.1 mA/μm,904 cm^(2)·V^(-1)·s^(-1),and>10~6,*** computations corroborate that the graphene/InSe heterostructure shows significant interlayer charge transfer and weak interlayer interaction,contributing to the enhanced performance of InSe *** research offers a comprehensive strategy to elevate the electrical performance of InSe transistors,paving the way for their utilization in future electronic applications.

关键词： two-dimensional materials InSe van der Waals heterostructure electrical performances charge density difference