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Optimized the vanadium electrolyte with sulfate-phosphoric mixed acids to enhance the stable operation at high-temperature

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Frontiers of Chemical science and Engineering 2024年第2期18卷 13-26页

作者： Ling Ge Tao Liu Yimin Zhang Hong Liu School of Resource and Environmental Engineering Wuhan University of Science and TechnologyWuhan 430081China state Environmental Protection {1. laboratory of Mineral Metallurgical Resources Utilization and Pollution control Wuhan University of Science and TechnologyWuhan 430081China Hubei Collaborative Innovation Center for High Efficient Utilization of Vanadium Resources Wuhan University of Science and TechnologyWuhan 430081China Hubei Provincial Engineering technology Research Center of High Efficient Cleaning Utilization for Shale Vanadium Resource Wuhan University of Science and TechnologyWuhan 430081China School of Resource and Environmental Engineering Wuhan University of TechnologyWuhan 430070China

Herein, the influence of the concentration design and comprehensive performance of the sulfate-phosphoric mixed acid system electrolyte is investigated to realize an electrolyte that maintains high energy density and stable operation at high temperatures. Static stability tests have shown that VOPO4 precipitation occurs only with vanadium(V) electrolyte. The concentration of vanadium ion of 2.0–2.2 mol·L^(–1., phosphoric acid of 0.1.–0.1. mol·L^(–1., and sulfuric acid of 2.5–3.0 mol·L^(–1. are suitable for a vanadium redox flow battery in the temperature range from –20 to 50 ℃. The equations for predicting the viscosity and conductivity of electrolytes are obtained by the response surface method. The optimized electrolyte overcomes precipitation generation. It has 2.8 times higher energy density than the non-phosphate electrolyte, and a coulomb efficiency of 94.0% at 50 ℃. The sulfate-phosphoric mixed acid system electrolyte promotes the electrode reaction process, increases the current density, and reduces the resistance. This work systematically optimizes the concentrations of composition of positive and negative vanadium electrolytes with mixed sulfate-phosphoric acid. It provides a basis for the different valence states and comprehensive properties of sulfate-phosphoric mixed acid system vanadium electrolytes under extreme environments, guiding engineering applications.

关键词： all vanadium redox flow battery mixed-acid vanadium electrolyte concentration optimization response surface methodology high-temperature stability

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Simulation of the Ecosystem Productivity Responses to Aerosol Diffuse Radiation Fertilization Effects over the Pan-Arctic during 2001.1.

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Advances in Atmospheric sciences 2024年第1期41卷 84-96页

作者： Zhiding ZHANG Xu YUE Hao ZHOU Jun ZHU Yadong LEI Chenguang TIAN Jiangsu key {1. of Atmospheric Environment Monitoring and Pollution control Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science&Technology(NUIST)Nanjing 210044China Climate Change Research Center Institute of Atmospheric Physics(IAP)Chinese Academy of Sciences(CAS)Beijing 100029China University of Chinese Academy of sciences Beijing 100049China state {1. laboratory of Severe Weather&{1. laboratory of Atmospheric Chemistry of CMA Chinese Academy of Meteorological SciencesBeijing 100081China

The pan-Arctic is confronted with air pollution transported from lower *** have shown that aerosols help increase plant photosynthesis through the diffuse radiation fertilization effects(DRFEs).While such DRFEs have been explored at low to middle latitudes,the aerosol impacts on pan-Arctic ecosystems and the contributions by anthropogenic and natural emission sources remain less ***,we perform regional simulations at 0.2o×0.2ousing a well-validated vegetation model(Yale Interactive terrestrial Biosphere,YIBs)in combination with multi-source of observations to quantify the impacts of aerosol DRFEs on the net primary productivity(NPP)in the pan-Arctic during *** show that aerosol DRFEs increase pan-Arctic NPP by 2.1. Pg C(1..8%)yr^(-1.under clear-sky conditions,in which natural and anthropogenic sources contribute to 8.9% and 3.9%,*** all-sky conditions,such DRFEs are largely dampened by cloud to only 0.26 Pg C(1.24%)yr^(-1.,with contributions of 0.65% by natural and 0.59% by anthropogenic *** aerosols cause a positive NPP trend of 0.022% yr^(-1.following the increased fire activities in the *** contrast,anthropogenic aerosols induce a negative trend of-0.01. yr^(-1.due to reduced emissions from the middle *** trends in aerosol DRFEs show a turning point in the year of 2007 with more positive NPP trends by natural aerosols but negative NPP trends by anthropogenic aerosols *** affected by modeling uncertainties,this study suggests a likely increasing impact of aerosols on terrestrial ecosystems in the pan-Arctic under global warming.

关键词： diffuse radiation fertilization effects anthropogenic aerosols natural aerosols pan-Arctic net primary productivity

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Parameter estimation in n-dimensional massless scalar field

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Chinese Physics B 2024年第3期33卷 231-237页

作者：杨颖荆继良 Hunan Provincial key {1. of Intelligent Sensors and Advanced Sensor Materials School of Physics and ElectronicsHunan University of Science and TechnologyXiangtan 411201China Department of Physics Key Laboratory of Low Dimensional Quantum Structures and Quantum Control of Ministry of Educationand Synergetic Innovation Center for Quantum Effects and ApplicationsHunan Normal UniversityChangsha 410081Chin

Quantum Fisher information(QFI)associated with local metrology has been used to parameter estimation in open quantum *** this work,we calculated the QFI for a moving Unruh-DeWitt detector coupled with massless scalar fields in n-dimensional spacetime,and analyzed the behavior of QFI with various parameters,such as the dimension of spacetime,evolution time,and Unruh *** discovered that the QFI of state parameter decreases monotonically from 1.to 0 over ***,we noted that the QFI for small evolution times is several orders of magnitude higher than the QFI for long evolution *** also found that the value of QFI decreases at first and then stabilizes as the Unruh temperature *** was observed that the QFI depends on initial state parameterθ,and Fθis the maximum forθ=0 orθ=π,Fφis the maximum forθ=π/*** also obtain that the maximum value of QFI for state parameters varies for different spacetime dimensions with the same evolution time.

关键词： quantum Fisher information parameter estimation open quantum systems

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Modulation of zeolite surface realizes dynamic copper species redispersion

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Chinese Journal of Structural Chemistry 2024年第6期43卷 6-7页

作者： Guoliang Liu Zhiqiang Liu Anmin Zheng Interdisciplinary Institute of NMR and Molecular sciences School of Chemistry and Chemical EngineeringThe State Key Laboratory of Refractories and MetallurgyWuhan University of Science and TechnologyWuhan430081PR China state {1. laboratory of Magnetic Resonance and Atomic and Molecular Physics Innovation Academy for Precision Measurement Science and TechnologyChinese Academy of SciencesWuhan430071PR China

Zeolite-based metal nanoparticles(NPs)catalysts have shown promising applications in fuel production,petro-and fine-chemical manufacture,biomass refinery,and so *** of hydroxyl groups on the zeolite surface has proven to be effective in boosting catalytic reactions over metal-zeolite *** example,modifying the wettability of ZSM-5 and titanium silicalite-1.TS-1.crystals by surface hydrophobization drastically enhances catalytic performance of zeolites encapsulated AuPd[1.and Pt[2]NPs in methane oxidation and aldehydes/ketones hydrogenation,*** fact,two kinds of hydroxyl groups are present in zeolite materials,which refers to bridged hydroxyls[Si-O(H)-Al]and silanols[Si-O(H)].Both hydroxyl groups are defects of zeolite framework structures,which provides anchor points in dispersing metals[3].The former hydroxyl group is tunable to control acidity by adjusting Si/Al ratio in zeolite,whereas the role of silanols is not fully understood[4],particularly in the dispersion of metal NPs.

关键词： zeolite dispersion aldehydes

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Synergistic effects of peroxydisulfate on UV/O_(3) process for tetracycline degradation:Mechanism and pathways

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Chinese Chemical Letters 2024年第10期35卷 408-413页

作者： Fengrui Yang Debing Wang Xinying Zhang Jie Zhang Zhichao Wu Qiaoying Wang state {1. laboratory of Pollution control and Resource Reuse Shanghai Institute of Pollution Control and Ecological SecuritySchool of Environmental Science and EngineeringTongji UniversityShanghai 200092China Fujian Provincial Engineering Research Center of Rural Waste Recycling technology College of Environment&Safety EngineeringFuzhou University.Fuzhou 350108China

Tetracycline(TC)as a typical emerging pollutant is becoming a serious threat to the environment and human health.A combined advanced oxidation technology of UV/Ozone(O_(3))/peroxydisulfate(PDS)process was developed to explore an efficient and economic treatment process of TC in ***,the reactive sites and transformation pathways of TC were explored and the toxicity of the intermediates was quantified with a quantitative structure-activity relationship(QSAR)*** degradation performance of TC was substantially enhanced in UV/O_(3)/PDS process with a kobsof 0.0949 min-1.which was 2.3 times higher than UV/O_(3)and 3.2 times than sole *** results demonstrated that there was a superior synergistic effect of PDS on UV/O_(3)processes for the degradation of *** paramagnetic resonance(EPR)analysis and quenching experiments show that·OH,SO_(4)·-,O_(2)·-and1._(2)all contributed to TC degradation in the UV/O_(3)/PDS process and exhibited a synergistic effect,which inhibited the generation of harmful *** addition,the UV/O_(3)/PDS system can effectively degrade TC in a wide range of substrate concentrations and pH,and also showed excellent adaptability to various concentrations of anions(Cl-and HCO_(3)-).This study proves the feasibility of UV/O_(3)/PDS process for treating TC contaminated wastewater with complicated water matrix.

关键词： UV/ozonation/peroxydisulfate Synergistic effect Tetracycline Degradation Wastewater

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Docosahexaenoic acid-acylated astaxanthin monoester enhances microglial autophagy for ameliorating amyloid-β load and cognitive deficits in models of Alzheimer’s disease

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Food science and Human Wellness 2024年

作者： Xiaoxu Wang Bo Dong Yu Song Zhigao Wang Yuming Wang Jie Xu Changhu Xue state {1. laboratory of Marine Food Processing & Safety control， College of Food science and Engineering， Ocean University of China College of Marine Life sciences， Ocean University of China Qingdao National laboratory for Marine {1. and technology

Autophagy directly regulates the amyloid-peptides （Aβ） clearance， and its dysfunction occurs in the early pathogenesis of Alzheimer’s disease （AD）. We previously reported that docosahexaenoic acid-acylated astaxanthin monoester （AST-DHA） showed neuroprotection against AD pathology. However， its in-depth mechanism and autophagic responses in AD brains are poorly understood. Herein， SH-SY5Y cells overexpressing the APP gene were established to preliminarily evaluate the actions of AST-DHA on reducing Aβ1.42levels and regulating autophagy. In microglial BV2 cells， AST-DHA and free astaxanthin （F-AST） recovered p62 and LC3II/I levels， and restored autophagy flux by rescuing the late phase of microglial autophagy. Notably， autophagic inhibitor bafilomycin A1.blunted the abilities of AST-DHA to reduce Aβ1.42and fibral Aβ， suggesting that AST-DHA probably promoted Aβ clearance in a microglial autophagy-dependent manner. Further studies in APP/PS1.mice verified that dietary AST-DHA and F-AST promoted Aβ phagocytosis via microglial autophagy. Significant decreases of Iba1.and p62 levels were observed around Aβ plaque in the hippocampus and cortex using triple fluorescence staining. Furthermore， AST-DHA exhibited superior performance over F-AST in restoring autophagic dysfunction， ameliorating Aβ burden and cognitive deficit. Our findings suggest a possible mechanism of AST-DHA in improving AD by which it restores microglial autophagy to facilitate cerebral Aβ clearance. It supports the future application of AST-DHA as an autophagic regulator in maintaining brain function.

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Efficient photocatalytic NADH regeneration with Rh-loaded Z-scheme mediator-free system

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Chinese Chemical Letters 2024年第2期35卷 496-500页

作者： Yi Zhou Yiling He Ming Gao Ningkai Ding Juying Lei Yanbo Zhou state Environmental Protection {1. laboratory of Environmental Risk Assessment and control on Chemical Process East China University of Science and TechnologyShanghai 200237China National Engineering Research Center of Industrial Wastewater Detoxication and Resource Recovery East China University of Science and TechnologyShanghai 200237China Shanghai Engineering Research Center for Multi-media Environmental Catalysis and Resource Utilization East China University of Science and TechnologyShanghai 200237China Shanghai Institute of Pollution control and Ecological Security Shanghai 200092China

Nicotinamide adenine dinucleotide(NADH)regeneration is necessary for the sustainable application of enzymatic *** Rh-based complex[Cp^(*)Rh(bpy)(H)]+has been widely used as an important mediator in NADH regeneration systems,but it is limited by complexity and high ***,a Z-scheme was constructed by loading Rh onto carbon nitride nanosheets/carbon nitride quantum dots(CN-CNQD).The resultant catalyst achieved a high yield of NADH in a mediator-free(M-free)system of 0.283 mmol L^(−1. g^(−1. min^(−1.,which is 5.29 times that of pure *** enzyme introduction experiments confirmed that the enzyme active product 1.4-NADH could reach 34.21.selectivity in the M-free *** research revealed that the heterojunction between CNs and CNQDs improved the NADH regeneration activity in the traditional M-involved system,while Rh loading was proved to optimize the yield and selectivity of 1.4-NADH in M-free *** immobilized Rh shows more competitiveness than[Cp^(*)Rh(bpy)(H)]^(+).This study contributes to the construction of an M-free system for further application in greener,lower-cost enzymatic processes.

关键词： Photocatalysis NADH regeneration Mediator-free Carbon nitride Z-scheme

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Effects of different organic fertilizers on nitrous oxide and methane emissions from double-cropping rice fields

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Pedosphere 2024年第1期34卷 52-62页

作者： Mingcheng HU Andrew J.WADE Weishou SHEN Zhenfang ZHONG Chongwen QIU Xiangui LIN Jiangsu key {1. of Atmospheric Environment Monitoring and Pollution control Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjing 210044China Department of Geography and Environmental science University of ReadingReading RG66 DWUK Haina Research Institute of Guangdong Haina Agricultural Co. Ltd.Huizhou 516000China state {1. laboratory of Soil and Sustainable Agriculture Institute of Soil ScienceChinese Academy of SciencesNanjing 210008China

Rice fields are a major source of greenhouse gases,such as nitrous oxide (N_(2)O) and methane (CH_(4)).Organic fertilizers may potentially replace inorganic fertilizers to meet the nitrogen requirement for rice growth;however,the simultaneous effects of organic fertilizers on N_(2)O and CH_(4)emissions and crop yield in paddy fields remain poorly understood and *** this study,experimental plots were established in conventional double-cropping paddy fields in the Pearl River Delta,China,including an unfertilized control and five fertilizer treatments with fresh organic fertilizer (FOF),successively composted organic fertilizer (SOF),chemically composted organic fertilizer (COF),COF supplemented with inorganic fertilizer (COIF),and chemical fertilizers (CFs)(TFOF,TSOF,TCOF,TCOIF,and TCF,respectively).Paddy field soils behaved simultaneously as an N_(2)O sink (cumulative N_(2)O emission:-1.6 to-381.g N ha^(-1.) and as a CH_(4)source (cumulative CH_(4)emission:71. to 2 1.8 kg ha^(-1.).Compared to CFs,the effects of organic fertilizers on N_(2)O emission were not *** contrast,total annual CH_(4)emission increased by 1.7%,1.2%,1.5%,and 37%in TFOF,TCOF,TSOF,and TCOIF,respectively,compared to *** TCOIF,rice yield was maintained,while CH_(4)emission was not significantly increased from the paddy fields characterized by a prolonged flood *** important next step is to extend these field-based measurements to larger rice cultivation areas to quantify the regional and national-scale impacts on greenhouse gas emissions and to help determine the optimum practice for fertilizer use.

关键词： crop production global warming potential greenhouse gases manure paddy sustainable agriculture

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Boosting Peroxymonosulfate Activation via Co-Based LDH-Derived Magnetic Catalysts:A Dynamic and Static state Assessment of Efficient Radical-Assisted Electron Transfer Processes

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Energy & Environmental Materials 2024年第05期7卷 305-316页

作者： Wenhan Yang Junming Xia Fanfan Shang Ge Ge Yang Bin Wang Hairui Cai Lingyun Jing Hao Zhu Shengchun Yang Chao Liang Guosheng Shao MOE key {1. for Nonequilibrium Synthesis and Modulation of Condensed Matter School of Physics National Innovation Platform (Center) for Industry-Education Integration of Energy Storage Technology Xi’an Jiaotong University state {1. laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM) Nanjing University of Posts & Telecommunications College of Petroleum and Chemical Engineering Lanzhou University of Technology key {1. of Western China’s Environmental Systems (Ministry of Education) and Gansu Engineering Research Center of Fine Particles Pollution control technology and Equipment College of Earth and Environmental Sciences Lanzhou University state Center for International Cooperation on Designer Low-Carbon & Environmental Materials (CDLCEM) School of Materials Science and Engineering Zhengzhou University

Heterogeneous catalysts promoting efficient production of reactive species and dynamically stabilized electron transfer mechanisms for peroxomonosulfates （PMS） still lack systematic investigation. Herein, a more stable magnetic layered double oxides （CFLDO/N-C）, was designed using selfpolymerization and high temperature carbonization of dopamine. The CFLDO/N-C/PMS system effectively activated PMS to remove 99%(k=0.737 min-1. of tetracycline （TC） within 1. min. The CFLDO/N-C/PMS system exhibited favorable resistance to inorganic anions and natural organics, as well as satisfactory suitability for multiple pollutants. The magnetic properties of the catalyst facilitated the separation of catalysts from the liquid phase, resulting in excellent reproducibility and effectively reducing the leaching of metal ions. An electronic bridge was constructed between cobalt （the active platform of the catalyst） and PMS, inducing PMS to break the O-O bond to generate the active species. The combination of static analysis and dynamic evolution confirmed the effective adsorption of PMS on the catalyst surface as well as the strong radical-assisted electron transfer process. Eventually, we further identified the sites where the reactive species attacked the TC and evaluated the toxicity of the intermediates.

关键词： advanced oxidation process degradation mechanisms electron transport layered double hydroxide reactive species

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Halogenated Thienoacene Derivatives with Improved Emission Properties

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Chemical Research in Chinese Universities 2024年第4期40卷 699-703页

作者： ZHANG Jingmei MENG Zhihao ZHEN Yonggang HE Ping YU Panpan HU Wenping Advanced Innovation Center for Soft Matter science and Engineering State Key Laboratory of Organic-Inorganic CompositesBeijing University of Chemical TechnologyBeijing100029P.R.China Wuhan National laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan430074P.R.China state {1. laboratory of Fine Chemicals Dalian University of TechnologyDalian116024P.R.China Chemical Synthesis and Pollution control {1. laboratory of Sichuan Province China West Normal UniversityNanchong637000P.R.China key {1. of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education Jiangxi Normal UniversityNanchang330022P.R.China MOE key {1. of Organic Integrated Circuits&Tianjin key {1. of Molecular Optoelectronic sciences Department of ChemistrySchool of SciencesTianjin UniversityTianjin300072P.R.China

Thienoacenes is one of most important groups of semiconducting materials due to the high stability and superior ***,there are scarce studies on the emission properties of thienoacenes to ***,we synthesized fluorinated and chlorinated dibenzo[d,d’]thieno[3,2-b;4,5-b’]dithiophenes(DBTDTs)derivatives F6-DBTDT and Cl6-DBTDT by sulfoxide cyclization,significantly lowering the energy levels relative to the parent compound *** to single crystal structure analysis,F6-DBTDT molecules adopt one-dimensional slipped stacking with closeπ-πinteractions of 3.43Å(1.=0.1.nm),which is different from the parent compound DBTDT with herringbone stacking ***,the halogenated DBTDT derivatives exhibit enhanced emission properties both in solution and in the solid state,opening up possiblities to improve photoluminescence of thienoacences by halogenation.

关键词： Thienoacene Halogenation Photoluminescence Aggregation structure

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