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Particles attrition of binary mixtures in the coal-fueled chemical looping system based on fluidized bed

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Particuology 2024年第3期86卷 281-290页

作者： Heyu Li Zhe Sun Yan Cao Guangzhou institute of {1. Conversion Chinese Academy of SciencesGuangzhou 510640China University of Chinese Academy of Sciences Bejing 100049China CAS Key Laboratory of renewable {1. Guangzhou 510640China Guangdong Provincial Key Laboratory of New and renewable {1. Research and Development Guangzhou 510640China College of Chemistry and Chemical Engineering Anhui UniversityHefei230601China

In this work,a reactive air jet attrition device with auto-recording and collection of elutriated fines was *** established insights into the physiochemical interaction and further correlated attrition behaviors between char and oxygen carriers under various operation *** attrition rate increased by over 1.0% upon the introduced CO_(2),which brought in the significant effect of thermo-chemical stress,similarly in effects of the increased char addition ratio and the decreased sizes of char or hematite in different *** the char-hematite co-attrition process,the elutriated carbon loss of char with poor mechanical strength was found to be over 1.%,while the reactive iron loss of hematite was found to be 6.3%,and was enriched in elutriated *** reaction-derived thermochemical stress and the collision-derived mechanical stress jointly controls the particle attrition during the cyclic transformation of oxygen carrier particles in coal-fueled chemical looping fluidization,especially sig-nificant in its reduction stage.

关键词： Attrition Binary species Chemical looping Oxygen carrier CO_(2)capture

Highly selective and eco-friendly dihydroisoquinoline synthesis via Cu/Co synergistic catalysis in Cu NPs@MOFs catalyst under mild conditions

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Science China Chemistry 2024年第5期67卷 1561-1568页

作者： Peng-Fei Guo Ze-Long Liang Yue-E Jiao Hang Xu Bin Zhao Key Laboratory of Advanced energy Material Chemistry Renewable Energy Conversion and Storage CenterDepartment of ChemistryNankai UniversityTianjin 300071China

3,4-Dihydroisoquinoline(DHIQ)is an important precursor used in the production of drugs for treating cancer,HIV,Alzheimer's disease,*** studies on DHIQ synthesis show low catalytic selectivity due to the susceptible over-oxidation feedstock of1.2,3,4-tetrahydroisoquinoline(THIQ),which often requires alkali ***,it is desirable yet challenging to explore a highly selective and efficient oxydehydrogenation capacity for DHIQ synthesis under eco-friendly reaction ***,a novel framework 1.was synthesized,exhibiting 1. channels with the size of 4.6 A×9.6 A and high solvent/p H/thermal stability.A stable framework allows it to encapsulate Cu nanoparticles(NPs)to form Cu NPs@1.x(x=1.2,3,and 4)with varying loading amounts of Cu NPs at 2.0 wt%,3.0 wt%,4.0 wt%,and 6.0 wt%,*** NPs@1.3 could selectively catalyze the reaction from THIQ to DHIQ with a high selectivity of 98%and a recorded turnover frequency(TOF)of 22.1.h-1.nder eco-friendly mild *** corresponding catalytic activity can maintain at least five recyclings and can be further applied to gram-scale ***,the efficient preparation of DHIQ catalyzed by Cu NPs@1.3 could be realized even under air ***,the anticancer molecule precursor synthesis of 6,7-dimethoxy-3,4-dihydroisoquinoline was also selectively catalyzed by Cu NPs@*** investigations revealed that high catalytic performance can be attributed to the stable framework and the synergistic catalytic effect of the loaded Cu NPs and Co metal *** importantly,this work represents the first example of MOF catalysts for selectively thermo-catalytic DHIQ synthesis and demonstrates a simple approach to obtain efficient catalysts for selective oxydehydrogenation in the production of unsaturated compounds.

关键词： metal-organic frameworks Cu NPs@MOFs 3 4-dihydroisoquinoline selective oxydehydrogenation synergistic catalysis

General three-dimensional thermal illusion metamaterials

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Chinese Physics B 2024年第4期33卷 41-47页

作者：刘天丰王兆宸朱展胡润 China-EU institute for Clean and {1. energy Huazhong University of Science and TechnologyWuhan 430074China School of energy and Power Engineering Huazhong University of Science and TechnologyWuhan 430074China

Thermal illusion aims to create fake thermal signals or hide the thermal target from the background thermal field to mislead infrared observers,and illusion thermotics was proposed to regulate heat flux with artificially structured metamaterials for thermal *** theoretical and experimental works on illusion thermotics focus on two-dimensional materials,while heat transfer in real three-dimensional(3D)objects remains elusive,so the general 3D illusion thermotics is urgently *** this study,we propose a general method to design 3D thermal illusion metamaterials with varying illusions at different sizes and *** validate the generality of the 3D method for thermal illusion metamaterials,we realize thermal functionalities of thermal shifting,splitting,trapping,amplifying and *** addition,we propose a special way to simplify the design method under the condition that the size of illusion target is equal to the size of original heat *** 3D thermal illusion metamaterial paves a general way for illusion thermotics and triggers the exploration of illusion metamaterials for more functionalities and applications.

关键词： thermal illusion thermal metamaterials transformation thermotics

Layered double hydroxides functionalization toward rechargeable batteries Author links open overlay panel

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Particuology 2024年第8期91卷 138-154页

作者： Jianxiong Gao Bowen Jin Mingfei Shao State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing100029China renewable {1. Research institute Quzhou Institute for Innovation in Resource Chemical EngineeringQuzhou324000China

Layered double hydroxides(LDHs),known as typical two-dimensional materials with unique physicochemical properties,are regarded as promising candidates in energy storage ***,some inherent defects,such as poor conductivity and limited active sites,hinder the further development of ***,various functionalization strategies(e.g.,intercalation of guest molecules;metal ions doping and defect introduction of host layer;exfoliation to monolayer;hybridization with functional materials;construction of hierarchical structure;interface engineering and phase transformation)have been used to modify the characteristics of LDHs,which provides guidance for designing novel *** this review,we discuss how these strategies improve the properties of LDH-based materials,which are expected to possess high electronic and ionic conductivity,high specific surface area and high mechanical and chemical stability ***,the application of LDH-based materials in advanced energy conversion and storage techniques,including metal-ions batteries,lithium-sulfur batteries and metal-air batteries,have been comprehensively summarized.

关键词： Layered double hydroxide Functionalization strategy Rechargeable battery

Emergence of carbonaceous material for hydrogen storage:an overview

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Clean energy 2024年第4期8卷 147-168页

作者： Khemlata Soni Narayan Lal Panwar Pranay Rajendra Lanjekar Department of renewable {1. Engineering Maharana Pratap University of Agriculture and TechnologyUdaipurRajasthan313001India

Hydrogen has gained enormous relevance due to its lower carbon footprint and its potential role in balancing energy supply and de*** is being considered as a sustainable substitute for conventional *** generation of hydrogen using {1. energy sources is still in development,with a significant challenge lying in the efficient and safe storage of hydrogen due to its low energy *** challenge hinders the widespread adoption of *** and liquefaction methods of storage face issues of losses that reduce their *** technology for hydrogen storage has advanced significantly in the past few years,driven by recent enhancements in synthesizing carbonaceous materials with hydrogen storage *** article critically reviews novel carbonaceous materials for hydrogen storage,including biochar,activated carbon,carbon nanotubes,carbon nanocomposites,carbon aerogel,fullerenes,MXenes,graphite,graphene and its *** hydrogen adsorption using microporous materials,such as activated carbons,is crucial,sparking interest in economically viable options for hydrogen *** this,a significant amount of work still needs to be accomplished before the potential and advantages of the hydrogen economy can be fully realized and utilized by manufacturers and academics.

关键词： hydrogen clean energy hydrogen storage adsorption-desorption phenomenon carbonaceous materials

Defect Engineering in Earth-Abundant Cu_(2)ZnSnSe_(4) Absorber Using Efficient Alkali Doping for Flexible and Tandem Solar Cell Applications

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energy & Environmental Materials 2024年第2期7卷 249-256页

作者： Muhammad Rehan Ara Cho Inyoung Jeong Kihwan Kim Asmat Ullah Jun-Sik Cho Joo Hyung Park Yunae Jo Sung Jun Hong Seung Kyu Ahn SeJin Ahn Jae Ho Yun Jihye Gwak Donghyeop Shin Photovoltaics Research Department Korea Institute of Energy Research(KIER)152-Gajeong-roYuseong-guDaejeon 34129Korea Department of renewable {1. Engineering University of Science and Technology(UST)217-Gajeong-roYuseong-guDaejeon 34113Korea Korea institute of {1. Technology(KENTECH) 50772 Ujeong-roNaju Jeonnam 58217Korea

To demonstrate flexible and tandem device applications,a low-temperature Cu_(2)ZnSnSe_(4)(CZTSe)deposition process,combined with efficient alkali doping,was ***,high-quality CZTSe films were grown at 480℃by a single co-evaporation,which is applicable to polyimide(PI)*** of the alkali-free substrate,Na and K alkali doping were systematically studied and optimized to precisely control the alkali distribution in *** bulk defect density was significantly reduced by suppression of deep acceptor states after the(NaF+KF)*** the low-temperature deposition with(NaF+KF)PDTs,the CZTSe device on glass yields the best efficiency of 8.1.with an improved Voc deficit of 646 *** developed deposition technologies have been applied to *** the first time,we report the highest efficiency of 6.92%for flexible CZTSe solar cells on ***,CZTSe devices were utilized as bottom cells to fabricate four-terminal CZTSe/perovskite tandem cells because of a low bandgap of CZTSe(~1.0 eV)so that the tandem cell yielded an efficiency of 20%.The obtained results show that CZTSe solar cells prepared by a low-temperature process with in-situ alkali doping can be utilized for flexible thin-film solar cells as well as tandem device applications.

关键词： alkali doping Earth-abundant Cu_(2)ZnSnSe_(4) flexible solar cells four-terminal tandem cells low-temperature process

A review on the chemo-catalytic conversion of cellulose to bio-ethanol

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Green Chemical Engineering 2024年第3期5卷 276-289页

作者： Xiuzheng Zhuang Haiyong Wang Shugen Jiang Xiaohong Hu Tong Su Xinghua Zhang Longlong Ma Key Laboratory of energy Thermal Conversion and Control of Ministry of Education School of Energy and EnvironmentSoutheast UniversityNanjing210096China Key Laboratory of renewable {1. Guangzhou Institute of Energy ConversionChinese Academy of SciencesGuangzhou510640China Wuzhou Refrigeration Group Co.Ltd. Nanjing211100China

While the industry has produced sugar-derived ethanol from the conventional method of fermentation for hundreds of years,other effective routes involving the direct transformation of carbohydrates still remain extremely *** recently,an innovative chemo-catalytic method driven by the aqueous-phase catalysis was created for the synthesis of cellulosic ethanol,making a great breakthrough in the common ways as it can theoretically utilize all of the carbon atoms in sugars with faster kinetics;up to now,results from the relevant studies have been accumulated to a certain extent,but the periodic conclusions in this field are unfortunately *** this reason,this work tries to offer an overview of the cellulosic ethanol produced by chemo-catalytic routes,highlighting the present knowledge in relation to the technical efficiency,catalytic mechanisms as well as practical *** first,the advanced progress on the increasing efficiency from a varied type of catalytic systems are extensively discussed,which involves the specific functions of hybrid components from different strategies;meanwhile,the general influences of processing conditions,such as the hydrothermal severity and aqueous environments,are also ***,possible mechanisms behind the chemo-catalytic processes are widely elaborated by analyzing a number of experimental cases associated with the reaction network and its kinetic *** that,the actual effects of this technique on the real biomass are collected to identify the positive/negative interactions between multiple components,together with the potential solutions on the semi-continuous processes of pilot scale *** techno-economic analysis(TEA)is also calculated and compared with other similar methods,such as fermentation and ***,several proposals aimed at upgrading the whole chain of chemo-catalytic processes are clearly provided,which may function as a guideline for future studies on the pr

关键词： Cellulosic ethanol Chemo-catalytic method Influencing factors Catalytic mechanism Techno-economic analysis

Dynamic Modeling of Key Operating Parameters for Supercritical Circulating Fluidized Bed Units based on Data-Knowledge-Driven Method

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Journal of Thermal Science 2024年第3期33卷 1216-1230页

作者： YU Haoyang GAO Mingming ZHANG Hongfu CHEN Jiyu LIU Jizhen YUE Guangxi The State Key Laboratory of Alternate Electrical Power System with renewable {1. Sources School of Control and Computer EngineeringNorth China Electric Power UniversityBeijing102206China CHN energy New energy Technology Research institute Co. Ltd.Beijing102209China Department of energy and Power Engineering Tsinghua UniversityBeijing100084China

To address the pressing need for intelligent and efficient control of circulating fluidized bed(CFB)units,it is crucial to develop a dynamic model for the key operating parameters of supercritical circulating fluidized bed(SCFB)***,data-knowledge-driven dynamic model of bed temperature,load,and main steam pressure of the SCFB unit has been ***,a knowledge-driven method is employed to develop a dynamic model for key operating parameters of SCFB *** model parameters are determined based on the operating data of the unit and continuously optimized in real ***,Bidirectional Long Short-Term Memory combined with Convolutional Neural Network and Attention Mechanism is utilized to build the dynamic model of bed temperature,load,and main steam ***,a collaboration and integration method based on the critic weight method and the variation coefficient method is proposed to establish data-knowledge-driven model of key operating parameters for SCFB *** model displays great accuracy and fitting ability compared with other methods and effectively captures the dynamic characteristics,which can provide a research basis for the design of intelligent flexible control mode of SCFB unit.

关键词： circulating fluidized bed dynamic model data-knowledge-driven method deep learning power plant

Development of a novel signal restoration algorithm to eliminate the distorted components in space charge measurement excited by femtosecond laser irradiation

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High Voltage 2024年第3期9卷 659-673页

作者： Tianrun Qi Hanwen Ren Haoyu Gao Qingmin Li Yidan Ma Yiqun Ma Tao Xiao State Key Laboratory of Alternate Electrical Power System with renewable {1. Sources North China Electric Power UniversityBeijingChina

For the space charge measurement method with optical excitation for electrical insulation,the distortion of the excitation laser on the measurement signal and the accumulation of space charge have not been discussed *** experiment and simulation results show that three types of distorted components introduced by optical excitation can lead to distortion of the upper interface ***,the factors causing distortion of the measured signal and the formation mechanism are analysed.A virtual electrode potential compensation method and a distorted component extraction method are ***,an attenuation restoration and charge conversion correction factor is intro-duced,leading to a novel signal processing algorithm adapted to space charge optical measurement *** with the traditional algorithm,the novel algorithm has an error of less than 1.in the calculation of charge and electric field strength,with an increase in accuracy of 47.7%and 9.81.,*** applying the novel restoration algorithm,the comparison shows that the space charge accumulation does not change significantly under laser irradiation,verifying the reliability of the optical *** given algorithm can provide a theoretical and technical foundation for the realisation of the optical measurement method for space charge.

关键词： charge algorithm excitation