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An all-biomaterials-based aqueous binder based on adsorption redox-mediated synergism for {1. lithium–sulfur batteries

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eScience 2024年第3期4卷 116-126页

作者： Wanyuan Jiang Tianpeng Zhang Runyue Mao Zihui Song Siyang Liu Ce Song Xigao Jian Fangyuan Hu State Key laboratory of Fine Chemicals Frontiers Science Center for Smart Materials Oriented Chemical EngineeringSchool of Chemical EngineeringTechnology Innovation Center of High Performance Resin Materials(Liaoning Province)Key Laboratory of Energy Materials and Devices(Liaoning Province)Dalian University of TechnologyDalian 116024China School of materials Science and Engineering State Key Laboratory of Fine ChemicalsFrontiers Science Center for Smart Materials Oriented Chemical EngineeringTechnology Innovation Center of High Performance Resin Materials(Liaoning Province)Key Laboratory of Energy Materials and Devices(Liaoning Province)Dalian University of TechnologyDalian 116024China

The complex multistep electrochemical reactions of lithium polysulfides and the solid–liquid–solid phase transformation involved in the S8 to Li2S reactions lead to slow redox kinetics in lithium–sulfur batteries(Li–S batteries).However,some targeted researches have proposed strategies requiring the introduction of significant additional inactive components,which can seriously affect the energy *** polymer binders,proven to be effective in suppressing shuttle effects and constraining electrode volume expansion,also have promising potential in enhancing Li–S batteries redox ***,a novel aqueous polymer binder is prepared by convenient amidation reaction of fully biomaterials,utilizing its inherent rich amide groups for chemisorption and redox mediating ability of thiol groups to achieve adsorption redox-mediated synergism for efficient conversion of ***–S batteries based on N-Acetyl-L-Cysteine-Chitosan(NACCTS)binder exhibit high initial discharge specific capacity(1.60.1.mAhg−1.at 0.2C)and excellent cycling performance over 400 cycles(capacity decay rate of 0.01.%per cycle).In addition,the batteries exhibit great areal capacity and stable capacity retention of 83.6%over 80 cycles even under high sulfur loading of 8.4mgcm−*** work offers a novel perspective on the redox-mediated functional design and provides an environmentally friendly biomaterials-based aqueous binder for practical Li–S battery.

关键词： Li–S batteries Aqueous binder Biomaterials Adsorption redox-mediated synergism Hydrogen bonding

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Phase-field simulation of precipitation kinetics and creep properties of Ni-Al-Cr/Ta superalloys

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Science China(Technological Sciences) 2024年第4期67卷 1139-1150页

作者： YANG ShuaiGe ZHANG Zan ZHUO JiCheng LONG HongLi LI YongSheng National Key laboratory of {1. Casting Technologies MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials TechnologyEngineering Research Center of Materials Behavior and DesignMinistry of EducationNanjing University of Science and TechnologyNanjing 210094China

The precipitation kinetics ofγ'-Ni_(3)(Al,Ta)phase and creep properties of Ni-1.Al-x Ta at.%superalloys are investigated by the crystal plasticity phase-field *** results show that the high Ta content brings a lower creep strain for the deceleration and steady creep stage,while the creep lifetime is *** large external strain intensifies the creep damage and shortens the creep life of Ni-1.Al-3Ta at.%*** kinetics evolution and elements distribution are revealed in the quaternary Ni-1.Al-8.5Cr-xT a(x=1.5 at.%,2.0 at.%,2.5 at.%)superalloys by the multi-component phase-field *** anti-phase boundary(APB)changes the coarsening mechanism ofγ'phase,and Ta promotes the precipitation ofγ'phase with an increasing volume fraction and particle *** composition difference betweenγ'andγphases increases with the rising of Ta content,the strong partitioning of Ta toγ'phase strengthens the partitioning of Ni and Cr toγmatrix,and Ta shows a superiority than Al in the lattice site occupation of L1.(2)-Ni_(3)(Al,X)*** an importantγ'phase forming element,the optimization of Ta content is essential for improving the mechanical properties of Ni-based superalloys.

关键词： Ni-Al-Ta alloys creep properties kinetics phase-field

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Micelle-directed self-assembly of single-crystal-like mesoporous stoichiometric oxides for high-performance lithium storage

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National Science Review 2024年第4期11卷 195-205页

作者： Yanhua Wan Changyao Wang Xingmiao Zhang Yang Yin Mengmeng Liu Bing Ma Linlin Duan Yuzhu Ma Wei Zhang Changlin Zheng Dongliang Chao Fei Wang Yongyao Xia Wei Li Department of Chemistry Laboratory of Advanced Materials Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials State Key Laboratory of Molecular Engineering of Polymers College of Chemistry and Materials ScienceFudan University State Key laboratory of Surface Physics and Department of Physics Fudan University

Due to their uncontrollable assembly and crystallization process,the synthesis of mesoporous metal oxide single crystals remains a formidable ***,we report the synthesis of single-crystal-like mesoporous Li2TiSiO5by using soft micelles as *** key lies in the atomic-scale self-assembly and step-crystallization processes,which ensure the formation of single-crystal-like mesoporous Li2TiSiO5microparticles via an oriented attachment growth mechanism under the confinement of an in-situ formed carbon *** mesoporous Li2TiSiO5anode achieves a superior rate capability(1.8 mAh g-1.t5.0 A g-1. and outstanding long-term cycling stability(1.8 mAh g-1.fter 3000 cycles at 2.0 A g-1. for lithium storage as a result of the ultrafast Li+diffusion caused by penetrating mesochannels and nanosized crystal frameworks（5-1. nm）.In comparison,bulk Li2TiSiO5exhibits poor rate capability and cycle performance due to micron-scale diffusion *** method is very simple and reproducible,heralding a new way of designing and synthesizing mesoporous single crystals with controllable frameworks and chemical functionalities.

关键词： mesoporous materials micelles single-crystal-like Li2TiSiO5 lithium-ion batteries

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Fundamental Understanding on Selenium Electrochemistry:From Electrolytic Cell to advanced Energy Storage

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Energy & Environmental materials 2024年第3期7卷 236-256页

作者： Jiguo Tu Cheng Chang Jingxiu Wang Haiping Lei R.Vasant Kumar Mingyong Wang Shuqiang Jiao State Key laboratory of {1. Metallurgy University of Science and Technology BeijingBeijing 100083China School of Chemical Engineering The University of AdelaideAdelaideSA 5005Australia School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China Department of materials Science and Metallurgy University of CambridgeCambridge CB30FSUK

Selenium(Se),as an important quasi-metal element,has attracted much attention in the fields of thin-film solar cells,electrocatalysts and energy storage applications,due to its unique physical and chemical ***,the electrochemical behavior of Se in different systems from electrolytic cell to battery are complex and not fully *** this article,we focus on the electrochemical processes of Se in aqueous solutions,molten salts and ionic liquid electrolytes,as well as the application of Se-containing materials in energy ***,the electrochemical behaviors of Se-containing species in different systems are comprehensively summarized to understand the complexity of the kinetic processes and guide the Se ***,the relationship between the deposition conditions and resulting structure and morphology of electrodeposited Se is discussed,so as to regulate the morphology and composition of the ***,the {1. energy storage applications of Se in thin-film solar cells and secondary batteries are reviewed,and the electrochemical reaction processes of Se are systematically comprehended in monovalent and multivalent metal-ion *** on understanding the fundamental electrochemistry mechanism,the future development directions of Se-containing materials are considered in view of the in-depth review of reaction kinetics and energy storage applications.

关键词： electrochemical behaviors electrodeposition electrolytes energy storage selenium

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Synthesis and characterization of high entropy(TiVNbTaM)_(2)AlC(M=Zr,Hf)ceramics

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Journal of advanced Ceramics 2024年第2期13卷 237-246页

作者： Lei Cao Qiqiang Zhang Lijing Du Shuai Fu Detian Wan Yiwang Bao Qingguo Feng Chunfeng Hu Key laboratory of {1. Technologies of materials Ministry of EducationSchool of Materials Science and EngineeringSouthwest Jiaotong UniversityChengdu 610031China State Key laboratory of Green Building {1. China Building Materials AcademyBeijing 100024China

The high-entropy design of MAX phases is expected to confer superior properties,but its study was hindered by the complex synthesis method and limited purity of *** this work,two noteworthy types of high-entropy MAX phase structural ceramics,high-entropy(TiVNbTaM)_(2)AlC(M=Zr,Hf),were designed and prepared by the in-situ synthesis using spark plasma sintering(SPS).The microstructure and lattice parameters of sintered samples were *** with the single-component MAX phases,the highly pure high-entropy(TiVNbTaZr)_(2)AlC sample had good physical and mechanical properties,including electrical conductivity of 0.96×1.6Ω^(-1.·m^(-1.,thermal expansion coefficient of 3.65×1.^(-6) K^(-1.,thermal conductivity of 8.98 W·m^(-1.·K^(-1.,Vickers hardness of 9.80 GPa,flexural strength of 507 MPa,fracture toughness of 5.62 MPa·m^(1.2),and compressive strength of 1.64 MPa,which exhibited the remarkable hardening-strengthening effect.

关键词： MAX phase high-entropy ceramic microstructure physical properties mechanical properties

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Effects of longitudinal magnetic field on primary dendrite spacing and segregation of directionally solidified single crystal superalloy

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Progress in Natural Science:materials International 2024年第1期34卷 26-36页

作者： Congjiang Zhang Yilin Zhou Chen Shen Weili Ren Xiaotan Yuan Biao Ding Haibiao Lu Zuosheng Lei Yunbo Zhong Ang Zhang State Key laboratory of {1. Special Steel College of Materials Science and Engineering Shanghai University National Engineering Research Center for Magnesium Alloys Natural Key Laboratory of Advanced Casting Technologies College of Materials Science and EngineeringChongqing University

The primary dendrite spacing(PDS) and segregation of directionally solidified single crystal(SC) superalloy under the longitudinal magnetic field(LMF) were investigated based on the analysis of the whole cross-sectional microstructure at different solidification distances. The results show that the PDS under the LMF remains basically unchanged at different solidification distances, and it is greater than that under no LMF. With the increase of magnetic field intensity, the PDS increases and the macrosegregation decreases. The increasing PDS and reducing segregation under the LMF can be attributed to the increase of solute boundary layer, which expands the non-equilibrium freezing temperature range and brings the effective partition coefficient closer to 1. The increase of the solute enrichment layer thickness could be caused by the downward secondary circulation generated by the thermoelectric magnetic convection(TEMC) near the interface, which drives the migration of solutes towards the interdendritic region. This work not only clarifies the mechanism of LMF controlling PDS and reducing segregation by TEMC, but also provides theoretical guidance for producing high-quality SC superalloys using magnetic fields.

关键词： Primary dendrite spacing Segregation Single crystal superalloy Directional solidification Magnetic field Thermoelectric magnetic convection

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Stabilizing semi-transparent perovskite solar cells with a polymer composite hole transport layer

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Nano Research 2024年第3期17卷 1500-1507页

作者： Yongbin Jin Huiping Feng Zheng Fang Liu Yang Kaikai Liu Bingru Deng Jingfu Chen Xueling Chen Yawen Zhong Jinxin Yang Chengbo Tian Liqiang Xie Zhanhua Wei Xiamen Key laboratory of Optoelectronic {1. and advanced Manufacturing Institute of Luminescent Materials and Information DisplaysCollege of Materials Science and EngineeringHuaqiao UniversityXiamen 361021China

Semi-transparent perovskite solar cells(ST-PSCs)have broad applications in building integrated ***,the stability of ST-PSCs needs to be improved,especially in n-i-p ST-PSCs since the doped 2,2',7,7'-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9'-spirobifluorene(Spiro-OMeTAD)is unstable at elevated temperatures and high *** this work,aπ-conjugated polymer poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1.2-b:4,5-b']dithiophene))-alt-(5,5-(1.,3'-di-2-thienyl-5',7'-bis(2-ethylhexyl)benzo[1.,2'-c:4',5'-c']dithiophene-4,8-dione)](PBDB-T)is selected to form a polymer composite hole transport layer(HTL)with *** sulfur atom of the thiophene unit and the carbonyl group of the polymer interact with the undercoordinated Pb2+at the perovskite surface,which stabilizes the perovskite/HTL interface and passivates the interfacial *** incorporation of the polymer also increases the glass transition temperature and the moisture resistance of *** a result,we obtain ST-PSCs with a champion efficiency of 1..71.and an average visible light transmittance of 36.04%.Therefore,a high light utilization efficiency of 4.94%can be ***,the encapsulated device can maintain 84%of the initial efficiency after 751.h under continuous one-sun illumination(at 30%relative humidity)at the open circuit and the unencapsulated device can maintain 80%of the initial efficiency after maximum power tracking for more than 1.50 h under continuous one-sun illumination.

关键词： semi-transparent solar cells π-conjugated polymer composite hole transport layer building integrated photovoltaics

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Ordered Bicontinuous Network Structures Regulated by Orientational Interactions in a Rod-Coil Block Copolymer

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Chinese Journal of Polymer Science 2024年第5期42卷 636-642,I0008页

作者： Xiao-Lin Lyu Shi-Chu Yang An-Qi Xiao Ping-Ping Hou Wei Zhang Hong-Bing Pan Zhi-Hao Shen Xing-He Fan Qi-Feng Zhou Beijing National laboratory for Molecular Sciences Key Laboratory of Polymer Chemistry and Physics of Ministry of EducationCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing100871China Key laboratory of {1. materials Technologies International(HongKong Macao and Taiwan)Joint Laboratory on Advanced Materials TechnologiesCollege of Materials Science and EngineeringFuzhou UniversityFuzhou350108China

The rich phase behavior of block copolymers(BCPs)has drawn great attention in recent ***,the double diamond(DD)phase is rarely obtained because of the competition between the minimization of interfacial energy and packing ***,a rod-coil BCP containing mesogen-jacketed liquid crystalline polymer is designed to acquire ordered bicontinuous network *** reduction of internal energy originating from the orientational interaction among the rod blocks can compensate for the free energy penalty of packing frustration to stabilize the DD *** resulting BCP can also experience lamellae-to-DD and double gyroid-to-lamellae transitions by changing the annealing *** results make the rod-coil BCP an excellent candidate for the self-assembly of ordered network structures,demonstrating great potential in nanopatterning and metamaterials.

关键词： Block copolymer Rod-coil Ordered bicontinuous phase Double diamond Double gyroid

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Core-shell mesoporous carbon hollow spheres as Se hosts for advanced Al-Se batteries

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International Journal of Minerals,Metallurgy and materials 2024年第5期31卷 899-906页

作者： Haiping Lei Tianwei Wei Jiguo Tu Shuqiang Jiao State Key laboratory of {1. Metallurgy University of Science and Technology BeijingBeijing 100083China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China

Incorporating a selenium(Se)positive electrode into aluminum(Al)-ion batteries is an effective strategy for improving the overall battery ***,the cycling stability of Se positive electrodes has challenges due to the dissolution of intermediate reaction *** this work,we aim to harness the advantages of Se while reducing its limitations by preparing a core-shell mesoporous carbon hollow sphere with a titanium nitride(C@TiN)host to load 63.9wt%Se as the positive electrode material for Al-Se *** the physical and chemical confinement offered by the hollow mesoporous carbon and TiN,the obtained core-shell mesoporous carbon hollow spheres coated with Se(Se@C@TiN)display superior utilization of the active material and remarkable cycling *** a result,Al-Se batteries equipped with the as-prepared Se@C@TiN composite positive electrodes show an initial discharge specific capacity of 377 mAh·g^(-1.at a current density of 1.00 mA·g^(-1.while maintaining a discharge specific capacity of 86.0 mAh·g^(-1.over 200 *** improved cycling performance is ascribed to the high electrical conductivity of the core-shell mesoporous carbon hollow spheres and the unique three-dimensional hierarchical architecture of Se@C@TiN.

关键词： aluminum-selenium batteries intermediate products core-shell mesoporous carbon hollow sphere cycling performance

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Defect engineered nickel hydroxide nanosheets for advanced pseudocapacitor electrodes

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Nano Research 2024年第6期17卷 5233-5242页

作者： Yaohang Gu Yuxuan Zhang Xuanyu Wang Ateer Bao Bo Ni Haijun Pan Xiaoyan Zhang Xiwei Qi School of materials Science and Engineering Northeastern UniversityShenyang 110189China College of Metallurgy and Energy North China University of Science and TechnologyTangshan 063210China Key laboratory of Dielectric and Electrolyte Functional Material Hebei Province School of Resources and MaterialsNortheastern University at QinhuangdaoQinhuangdao 066004China School of Resources and materials Northeastern University at QinhuangdaoQinhuangdao 066004China

While the past years have witnessed great achievement in pseudocapacitors,the inauguration of electrode materials of high-performance still remains a formidable ***,the capacity and rate capability of the electrode depends largely on its electrical conductivity,which ensures fast charge transfer kinetics in both the grain bulk and grain ***,nickel hydroxides with oxygen vacancies are facilely fabricated via a hydrothermal *** active materials exhibit a high specific capacitance of 3250 F·g^(−1.and a high areal of capacitance of 1..98 F·cm^(−2)at 4.6 mA·cm^(−2).The asymmetric supercapacitor device based on our material delivers a high energy density of~71.6 Wh·kg^(−1.and a power density of~1.,300 W·kg^(−1.and could retain~95%of their initial capacitance even after 30,000 *** addition,the defect-rich hydroxides demonstrate higher electrical conductivity as well as dielectric constant,which is responsible for the superior pseudocapacitive *** new scientific strategy in terms of taking the advantages of oxygen vacancies might open up new opportunities for qualified pseudocapacitive materials of overall high performances not only for nickel hydroxides but also for other metal hydroxides/oxides.

关键词： pseudocapacitors nickel hydroxides oxygen vacancies electrical conductivity

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