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Micromechanism and mathematical model of stress sensitivity in tight reservoirs of binary granular medium

petroleum Science 2024年第3期21卷 1780-1795页

作者： Jian-Bang Wu Sheng-Lai Yang Qiang Li Kun Yang Can Huang Dao-Ping Lv Wei Zhou State key {1. of petroleum resources and Engineering China University of Petroleum(Beijing)Beijing2249China Laboratoire de G eologie Ecole Normale Sup erieure/CNRS UMR8538PSL Research UniversityParis75005France research Institute of Exploration and Development Xinjiang Oilfield CompanyKaramay834000XinjiangChina

research on reservoir rock stress sensitivity has traditionally focused on unary granular structures,neglecting the binary nature of real reservoirs,especially tight *** the stresssensitive behavior and mathematical characterization of binary granular media remains a challenging *** this study,we conducted online-NMR experiments to investigate the permeability and porosity evolution as well as stress-sensitive control mechanisms in tight sandy conglomerate *** results revealed stress sensitivity coefficients between 0.042 and 0.098 and permeability damage rates ranging from 65.6%to 90.9%,with an average pore compression coefficient of 0.01.8—0.0208 MPa ***-scale compression occurred in three stages:filling,compression,and compaction,with matrix pores playing a dominant role in pore *** stress sensitivity of binary granular media was found to be influenced by the support structure and particle *** stress sensitivity was associated with small fine particle size,high fines content,high uniformity coefficient of particle size,high plastic deformation,and low Young's ***-supported samples exhibited a high irreversible permeability damage rate(average=74.2%)and stress sensitivity coefficients(average=0.089),with pore spaces more *** contrast,grain-supported samples showed low stress sensitivity coefficients(average=0.021.at high stress *** on the experiments,we developed a mathematical model for stress sensitivity in binary granular media,considering binary granular properties and nested interactions using Hertz contact deformation and Poiseuille *** describing the change in activity content of fines under stress,we characterized the non-stationary state of compressive deformation in the binary granular structure and classified the reservoir into three *** model was applied for production prediction using actual data from the Mahu reservoir in China,showing that the e

关键词： Stress sensitivity Binary granular medium Tight reservoir Online-NMR Reservoir energy retention rate

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Volcanically Driven Terrestrial Environmental Perturbations during the Carnian Pluvial Episode in the Eastern Tethys

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Acta Geologica Sinica(English Edition) 2024年第3期98卷 753-770页

作者： Naveed Ur RAHMAN XIAN Benzhong FANG Linhao CHEN Sirui CHEN Peng Zaheen ULLAH WANG Pengyu National key {1. of petroleum resources and Engineering Beijing 102249China College of Geosciences China University of PetroleumBeijing 102249China Centre for Earth and Space Sciences University of SwatSwat 19120Pakistan

The Carnian Pluvial Episode(CPE)fingerprints global environmental perturbations and biological extinction on land and oceans and is potentially linked to the Wrangellia Large Igneous Province(LIP).However,the correlation between terrestrial environmental changes and Wrangellia volcanism in the Ordos Basin during the CPE remains poorly *** of negative carbon isotopic excursions(NCIEs),mercury(Hg),Hg/TOC,and Hg enrichment factor(HgEF)from oil shales in a large-scale terrestrial Ordos Basin in the Eastern Tethys were correlated with marine and other terrestrial *** three significant NCIEs in the study section were consistently correlated with those in the CPE successions of Europe,the UK,and South and North *** U-Pb geochronology indicates a Ladinian-Carnian age for the Chang 7 Member.A comprehensive overview of the geochronology,NCIE correlation,and previous bio-and chronostratigraphic frameworks shows that the Ladinian-Carnian boundary is located in the lower part of Chang 7 in the Yishicun *** may be a more reliable proxy for tracing volcanic eruptions than the Hg/TOC ratio because the accumulation rates of TOC content largely vary in terrestrial and marine *** records of Hg,Hg/TOC,HgEF,and NCIEs in the Ordos Basin aligned with Carnian successions worldwide and were marked by similar anomalies,indicating a global response to the Wrangellia LIP during the ***,a warm-humid climate,enhancement of detrital input,and NCIEs are synchronous with the CPE interval in the Ordos Basin,which suggests that the CPE combined with the regional Qinling Orogeny should dominate the enhanced rate of terrigenous input and paleoenvironmental evolution in the Ordos Basin.

关键词： Chang 7 Member oil shale Carnian Pluvial Episode volcanism environmental perturbations

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Geophysical prediction of organic matter abundance in source rocks based on geochemical analysis:A case study of southwestern Bozhong Sag,Bohai Sea,China

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petroleum Science 2024年第1期21卷 31-53页

作者： Xiang Wang Guang-Di Liu Xiao-Lin Wang Jin-Feng Ma Zhen-Liang Wang Fei-Long Wang Ze-Zhang Song Chang-Yu Fan State key {1. of petroleum resources and Prospecting China University of Petroleum(Beijing)Beijing102249China College of Geosciences China University of Petroleum(Beijing)Beijing102249China State key {1. of Continental Dynamics Northwest UniversityXi'an710069ShaanxiChina Department of Geology Northwest UniversityXi'an710069ShaanxiChina CNOOC Tianjin Branch Company Tianjin300459China

The Bozhong Sag is the largest petroliferous sag in the Bohai Bay Basin,and the source rocks of Paleogene Dongying and Shahejie Formations were buried *** of the drillings were located at the structural high,and there were few wells that met good quality source rocks,so it is difficult to evaluate the source rocks in the study area precisely by geochemical analysis *** on the Rock-Eval pyrolysis,total organic carbon(TOC)testing,the organic matter(OM)abundance of Paleogene source rocks in the southwestern Bozhong Sag were evaluated,including the lower of second member of Dongying Formation(E_(3)d2L),the third member of Dongying Formation(E_(3)d_(3)),the first and second members of Shahejie Formation(E_(2)s_(1.2)),the third member of Shahejie Formation(E_(2)s_(3)).The results indicate that the E_(2)s_(1.2)and E_(2)s_(3)have better hydrocarbon generative potentials with the highest OM abundance,the E_(3)d_(3)are of the second good quality,and the E_(3)d2L have poor to fair hydrocarbon generative ***,the well logs were applied to predict TOC and residual hydrocarbon generation potential(S_(2))based on the sedimentary facies classification,usingΔlogR,generalizedΔlogR,logging multiple linear regression and BP neural network *** various methods were compared,and the BP neural network method have relatively better prediction *** on the pre-stack simultaneous inversion(P-wave impedance,P-wave velocity and density inversion results)and the post-stack seismic attributes,the three-dimensional(3D)seismic prediction of TOC and S_(2)was carried *** results show that the seismic near well prediction results of TOC and S_(2)based on seismic multi-attributes analysis correspond well with the results of well logging methods,and the plane prediction results are identical with the sedimentary facies map in the study *** TOC and S_(2)values of E_(2)s_(1.2)and E_(2)s_(3)are higher than those in E_(3)d_(3)and E_(3)d_(2)L,basicall

关键词： Total organic carbon(TOC) Residual hydrocarbon generation potential(S_(2)) Geophysical prediction Seismic attribute Bozhong Sag Bohai Bay Basin

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Morphology effect on catalytic performance of ebullated-bed residue hydrotreating over Ni-Mo/Al_(2)O_(3)catalyst:a kinetic modeling study

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Green Chemical Engineering 2024年第1期5卷 60-67页

作者： Zhe Liu Juncong Yuan Zongzhuang Sun Xiang Feng Yibin Liu Huihong Zhu Chong Peng Chaohe Yang State key {1. of Heavy Oil Processing China University of PetroleumQingdao266580China Dalian research Institute of {1. and Petrochemicals SINOPECDalian116045China State key {1. of Fine Chemicals Dalian University of TechnologyDalian116024China

Upgrading of vacuum residue is of prime industrial significance due to the increasing demand for light *** the effect of catalyst morphology on vacuum residue hydrotreating performance by kinetic modeling is therefore of great ***,kinetic analysis of hydrodemetallization(HDM)and hydrodeconradsoncarbon-residue(HDCCR)performances on industrial Ni-Mo/Al_(2)O_(3)catalysts with spherical and cylindrical morphologies in ebullated-bed were evaluated for more than 1.00 *** was found that the percentage of light impurities easier to be removed on spherical catalysts were 78.20%and 39.43%in HDM and HDCCR reactions,respectively,higher than 65.20%and 1..50%on cylindrical *** suggests that catalyst morphology affects the impurity removal ability and the impurity properties,resulting in better hydrotreating performance of spherical *** work not only combines catalyst morphology with impurity removal capability through kinetic modeling,but also provides new insights into the design of efficient hydrotreating catalysts.

关键词： Morphology effect Kinetic analysis Vacuum residue Hydrotreating

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Proppant transport in rough fracture networks using supercritical CO_(2)

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petroleum Science 2024年第3期21卷 1852-1864页

作者： Yong Zheng Meng-Meng Zhou Ergun Kuru Bin Wang Jun Ni Bing Yang Ke Hu Hai Huang Hai-Zhu Wang School of petroleum Engineering Xi'an Shiyou UniversityXian710065ShaanxiChina Shaanxi key {1. of Carbon Dioxide Sequestration and Enhanced Oil Recovery Xi'an710075ShaanxiChina State key {1. of petroleum resources and Engineering China University of Petroleum(Beijing)Beijing2249China School of Mining and petroleum Engineering University of AlbertaEdmontonTG2W2AlbertaCanad Shaanxi Yanchang petroleum(Group)Co. Ltd.Xi'an710075ShaanxiChina

Proppant transport within fractures is one of the most critical tasks in oil,gas and geothermal reservoir stimulation,as it largely determines the ultimate performance of the operating *** transport in rough fracture networks is still a relatively new area of research and the associated transport mechanisms are still *** this study,representative parameters of rough fracture surfaces formed by supercritical CO_(2) fracturing were used to generate a rough fracture network model based on a spectral synthesis *** fluid dynamics(CFD)coupled with the discrete element method(DEM)was used to study proppant transport in this rough fracture *** reveal the turning transport mechanism of proppants into branching fractures at the intersections of rough fracture networks,a comparison was made with the behavior within smooth fracture networks,and the effect of {1. pumping parameters on the proppant placement in a secondary fracture was *** results show that the transport behavior of proppant in rough fracture networks is very different from that of the one in the smooth fracture *** turning transport mechanisms of proppant into secondary fractures in rough fracture networks are gravity-driven sliding,high velocity fluid suspension,and fracture structure *** the same injection conditions,supercritical CO_(2)with high flow Reynolds number still has a weaker ability to transport proppant into secondary fractures than *** of the supercritical CO_(2)needs to be increased beyond a certain value to have a significant effect on proppant carrying,and under the temperature and pressure conditions of this paper,it needs to be increased more than 20 times(about 0.94 m Pa s).Increasing the injection velocity and decreasing the proppant concentration facilitates the entry of proppant into the branching fractures,which in turn results in a larger stimulated reservoir *** results help to understand the pro

关键词： Reservoir stimulation CCUS Rough fracture network Supercritical CO_(2) Proppanttransport

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Fracture identification of carbonate reservoirs by deep forest model:An example from the D oilfield in Zagros Basin

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Energy Geoscience 2024年第3期5卷 339-350页

作者： Chunqiu Ji Shaoqun Dong Lianbo Zeng Yuanyuan Liu Jingru Hao Ziyi Yang National key {1. of petroleum resources and Engineering China University of Petroleum(Beijing)Beijing102249China College of Geosciences China University of Petroleum(Beijing)Beijing102249China College of Science China University of Petroleum(Beijing)Beijing102249China

Identifying fractures along a well trajectory is of immense significance in determining the subsurface fracture network ***,conventional logs exhibit responses in fracture zones,and almost all wells have such ***,detecting fractures through logging responses can be challenging since the log response intensity is weak and *** address this problem,we propose a deep learning model for fracture identification using deep forest,which is based on a cascade structure comprising multi-layer random *** forest can extract complex nonlinear features of fractures in conventional logs through ensemble learning and deep *** proposed approach is tested using a dataset from the Oligocene to Miocene tight carbonate reservoirs in D oilfield,Zagros Basin,Middle East,and eight logs are selected to construct the fracture identification model based on sensitivity analysis of logging curves against *** log package includes the gamma-ray,caliper,density,compensated neutron,acoustic transit time,and shallow,deep,and flushed zone resistivity *** have shown that the deep forest obtains high recall and accuracy(>92%).In a blind well test,results from the deep forest learning model have a good correlation with fracture observation from *** to the random forest method,a widely used ensemble learning method,the proposed deep forest model improves accuracy by approximately 4.6%.

关键词： Fracture identification Conventional log Deep forest Deep learning Tight carbonate reservoir

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A study on the temperature sensitivity of NMR porosity in porous media based on the intensity of magnetization Dedicated to the special issue “Magnetic Resonance in Porous Media”

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Magnetic Resonance Letters 2024年第1期4卷 28-39页

作者： Lu Zhang Lizhi Xiao Wensheng Wu Guangzhi Liao Yan Zhang Sihui Luo Xinglong Lei National key {1. of petroleum resources and Engineering China University of PetroleumBeijing102249China College of Geophysics China University of PetroleumBeijing102249China PetroChina Huabei Oilfield Company China National Petroleum CorporationRenqiu062552China

The measurement of nuclear magnetic resonance(NMR)porosity is affected by *** considering the impact of NMR logging tools,this phenomenon is mainly caused by variations in magnetization intensity of the measured system due to temperature fluctuations and difference between the temperature of the porous medium and calibration *** this study,the effect of temperature was explained based on the thermodynamic theory,and the rules of NMR porosity responses to temperature changes were identified through core physics *** addition,a method for correcting the influence of temperature on NMR porosity measurement was proposed,and the possible factors that may affect its application were also discussed.

关键词： NMR porosity Temperature Porous media Intensity of magnetization

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Paleoenvironmental Characteristics of Paleogene Lacustrine Source Rocks in the Western Bozhong Sag,Bohai Bay Basin,China:Evidence from Biomarkers,Major and Trace Elements

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Acta Geologica Sinica(English Edition) 2024年第1期98卷 220-240页

作者： WANG Xiang LIU Guangdi SONG Zezhang SUN Mingliang WANG Xiaolin WANG Feilong CHEN Rongtao GENG Mingyang LI Yishu State key {1. of petroleum resources and Prospecting China University of PetroleumBeijing 102249China College of Geosciences China University of PetroleumBeijing 102249China China National Offshore Oil Co. Ltd.(CNOOC)Tianjin Branch CompanyTianjin 300459China CNOOC research Institute Beijing 100028China

The organic matter(OM)enrichment mechanisms and depositional environment characteristics of lacustrine source rocks in the western Bozhong Sag,Bohai Bay Basin in Northeast China remain *** address these issues,based on Rock-Eval pyrolysis,kerogen macerals,H/C and O/C ratios,GC-MS,major and trace elements,the Dongying Formation Member(Mbr)3(E_(3)d_(3)),the Shahejie Formation mbrs 1.and 2(E_(2)s_(1.2)),and the Shahejie Mbr 3(E_(2)s_(3))source rocks in the western Bozhong Sag were *** above methods were used to reveal their geochemical properties,OM origins and depositional environments,all of which indicate that E_(2)s_(1.2)and E_(2)s_(3)are excellent source rocks,and that E_(3)d_(3)is of the second good quality.E_(3)d_(3)source rocks were formed under a warm and humid climate,mainly belong to fluvial/delta facies,the E_(3)d_(3)sediments formed under weakly oxidizing and freshwater ***,the depositional environments of E_(2)s_(1.2)source rocks were arid and cold climate,representing saline or freshwater lacustrine facies,and the sediments of E_(2)s_(1.2)belong to anoxic or suboxic settings with large evaporation and *** the period of E_(2)s_(3),the climate became warm and humid,indicating the freshwater lacustrine facies,and E_(2)s_(3)was characterized by freshwater and abundant ***,compared with other intervals,the OM origin of E_(3)d_(3)source rocks has noticeable terrestrial *** OM origin of the E_(2)s_(1.2)and E_(2)s_(3)are mainly plankton and *** subsidence and climate change have affected the changes of the depositional environment in the western Bozhong Sag,thus controlling the distribution of the source rocks,the geochemical characteristics in the three intervals of lacustrine source rocks have distinct ***,these factors are effective to evaluate the paleoenvironmental characteristics of source rocks by biomarkers,major and trace *** established models

关键词： petroleum geology source rocks depositional environments biomarkers major elements trace elements Bozhong Sag

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Multi-spherical interactions and mechanisms of hydrocarbon enrichment in the Southeast Asian archipelagic tectonic system

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Science China Earth Sciences 2024年第2期67卷 566-583页

作者： Rixiang ZHU Hongjun WANG Huajian WANG Xiaomei WANG Bo WAN Wang ZHANG Houqin ZHU Yuke LIU Junlai LIU Qingren MENG Fang HAO Zhijun JIN State key {1. of Lithospheric Evolution Institute of Geology and GeophysicsChinese Academy of SciencesBeijing100029China State key {1. of Enhanced Oil and Gas Recovery PetroChina Research Institute of Petroleum Exploration and DevelopmentBeijing100083China School of Earth Sciences and resources China University of GeosciencesBeijing100083China State key {1. of Deep Oil and Gas China University of Petroleum(East China)Qingdao266580China Institute of Energy Peking UniversityBeijing100871China

Global cooling began since 50 Ma,but a warm climate was maintained in the archipelagic tectonic system in Southeast Asia where a wealth of Cenozoic oil and gas resources was formed and *** the perspective of Earth system,this study analyzes Cenozoic tectonic activities,climatic and environmental evolution,and {1. enrichment in Southeast Asia,and provides the following insights:(1.Subduction of oceanic plates and the extension of overlying continental lithosphere resulted in widespread volcanic eruptions as well as the formation of rift basins and shallow marine shelves,leading to complex interactions between deep tectonic processes and Earth’s surface including mountains,basins,and seas.(2)Microcontinental accretion and prolonged stay in equatorial low-latitude regions have changed trade winds into monsoons,altered ocean current pathways and flow rates,and profoundly affected rainfall and climate.(3)The archipelagic tectonic system,coupled with a hot and rainy climate,fostered tropical rainforests,mangroves,and phytoplankton,providing abundant organic matter and promoting the development of {1. resources.(4)Combinations of rift basin development and marine transgression and regression led to an effective superposition of source-reservoir-seal combinations from multiple{1. *** deep burial of organic matter and high geothermal gradients facilitated the generation and large-scale accumulation of oil and gas.(5)Multi-spherical(such as atmosphere,biosphere,hydrosphere and lithosphere)interactions on the Earth,which resulted from the convergence of multiple tectonic plates,are believed as the primary driver for exceptional enrichments of Cenozoic oil and gas resources in Southeast *** understandings are significant for developing theories of oil and gas enrichment under the guidance of Earth System *** order to continue making significant oil and gas exploration discoveries in the deep-layers,deep-waters,and unconventio

关键词： Southeast Asia Archipelagic tectonic system Interactions of Earth’s spheres Oil and gas resources Cenozoic

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Effect of operating conditions on the performance of riser reactor for oxidative coupling of methane Author links open overlay panel

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Particuology 2024年第8期91卷 235-248页

作者： Min Cai Shuangzhu Kong Mengxi Liu Chunxi Lu State key {1. of Heavy Oil Processing China University of PetroleumBeijing102249China

Oxidative coupling of methane(OCM)is characterized by high temperature and strong heat released.A riser reactor is designed for the OCM process to improve gas-solid contacting and heat *** work illustrates the effect of hydrodynamic conditions and feed gas composition on the performance of an OCM riser *** findings suggest that oxidative reactions predominantly occur within the acceleration zone and developed flow ***,at the low superficial gas velocity accompanied by a high solid circulating rate,the C_(2)yield initially increases in the acceleration zone,followed by a decrease in the developed flow zone and deceleration *** optimal operating conditions are a specific region corresponding to the solids holdup ranges from 0.01. to ***,the C_(2)yield can be elevated using an appropriate feed mixture.

关键词： Oxidative coupling of methane Riser Hydrodynamics Solids holdup

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