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MOF and its derivative materials modified lithium-sulfur battery separator:a new means to improve performance

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Rare Metals 2024年第6期43卷 2418-2443页

作者： Rong-Wei Huang Yong-Qi Wang Dan You Wen-Hao Yang Bin-Nan Deng Fei Wang Yue-Jin Zeng Yi-Yong Zhang Xue Li National Local Joint Engineering Research Center for Lithium-Ion Batteries and Materials Preparation technology Key Laboratory of Advanced Batteries Materials of Yunnan ProvinceFaculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunming 650093China State key {1. of Physical Chemistry of Solid Surfaces Collaborative Innovation Centre of Chemistry for Energy MaterialsState-Province Joint Engineering Laboratory of Power Source Technology for New Energy VehicleEngineering Research Center of Electrochemical TechnologyMinistry of EducationCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China

In recent years,lithium-sulfur batteries(LSBs)are considered as one of the most promising new generation energies with the advantages of high theoretical speeific capacity of sulfur(1.75 mAh·g^(-1.),abundant sulfur resources,and environmental friendliness storage technologies,and they are receiving wide attention from the ***,the problems of the shuttle effect and lithium dendrite growth in LSBs have limited their practical application,so there is a need to find ways to solve these *** is an excellent choice to use novel materials to modify battery *** those novel materials,the metal-organic framework(MOF)has the properties of regular pores and controllable *** applied as a positive electrode and diaphragm,it can restrain the shuttle effect and lithium dendrite growth,especially since it shows excellent performance in diaphragm ***,various design strategies and synthesis methods of MOF-modified separators are reviewed in this paper,and the applications of MOF in LSBs separators in different forms are introduced,including the composite of MOF and carbon-based materials,the compounding of MOF and polymer,self-carbonization to form MOF-derived *** the same time,different characterization techniques are systematically reviewed to obtain the physical and chemical properties of MOF particles and the working mechanism of MOF-modified diaphragm,which provides a basis for further research in this ***,some future research trends and directions are put forward to fully tap the future commercial potential of MOF-modified diaphragm in LSBs.

关键词： MOF Lithium-sulfur battery Modified diaphragms Design strategies Prospect Characterization

On the Intelligent Optimization of the Crevice Structure in a Rapid Compression Machine

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Journal of Thermal Science 2024年第3期33卷 1200-1215页

作者： GUO Qiang LIU Jie WU Yingtao WANG Hewu TANG Chenglong YU Ruiguang Department of power Mechanical Engineering Beijing Jiaotong UniversityBeijing100044China State key {1. of Multiphase Flow in power Engineering Xi’an Jiaotong UniversityXi’an710049China State key {1. of Automotive Safety and energy Tsinghua UniversityBeijing100084China Beijing key {1. of New energy Vehicle powertrain technology Beijing100044China National International Science and technology Cooperation Base Beijing Jiaotong UniversityBeijing100044China

In this study,the multi-objective intelligent optimization of the crevice structure in a rapid compression machine(RCM)is carried out based on the RCM simulation model modified with the KIVA-3V program.A multi-objective optimization simulation model of the crevice structure based on the large eddy simulation model coupled with the genetic algorithm NSGA-Ⅲis *** optimization parameters and seven optimization objectives are selected in the optimization *** results show that the genetic algorithm can quickly find the values of the optimized *** crevice volume ratio shows a trade-off relationship with the dimensionless temperature ratio T_(max)/T_(aver)and the tumble ratio.A larger crevice volume can reduce the flow of boundary layer cryogenic gas into the combustion chamber,thus improving the temperature *** addition,the crevice entrance width and the connecting channel length should be smaller,while the volume of the crevice main chamber should be larger,so as to sufficiently introduce the low-temperature gas of the boundary layer into the crevice and reduce their influence on the temperature field of the combustion *** the crevice volume accounts for1.%of the total volume,the temperature uniformity of the combustor is significantly enhanced,and when the crevice volume accounts for 30.4%,there is almost no low-temperature vortex in the combustion chamber.

关键词： rapid compression machine adiabatic core area ignition delay period crevice structure

A clean disposal method of carbide slag with carbon emission reduction:Used as a flux for iron ore sintering Author links open overlay panel

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Particuology 2024年第8期91卷 303-314页

作者： Hanxiao Meng Jiankang Wang Xiang Liu Kelang Jin Lei Zhang Hao Zhou State key {1. of Clean energy Utilization Institute for Thermal Power EngineeringZhejiang UniversityHangzhou310027China

Limestone or quicklime is a necessary flux in the iron ore sintering *** production and application process will cause CO_(2) emissions and various environmental pollution,but this has not attracted enough *** slag(CS)is a calcium-rich solid waste produced in acetylene production,the harmless disposal of which is still incomplete,resulting in soil and groundwater *** study investigated the granulation characteristics and sintering performance of the sintering mixture with different proportions of *** results show that replacing limestone with an appropriate proportion of CS is promising and beneficial to the formation of high-quality bonding *** CS accounts for 75%of the total mass of CS and limestone,the tumbler index increases by 8.1.%and the comprehensive index decreases only from 1.0 to 96.1.,which is within the acceptable *** application of CS in iron ore sintering can achieve a clean disposal of it and a considerable carbon emission reduction,as the main component of which is Ca(OH)_(2).

关键词： Ironore sintering Carbide slag Flux Carbon emission Comprehensive index

Experimental Investigation and X-Ray Computed Microtomography Simulation on Thermal Physical Properties of Foundation Materials after Molten Salt Leakage in the Storage Tank

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Journal of Thermal Science 2024年第2期33卷 591-601页

作者： WANG Zhaowen ZHOU Hao LUO Jiawei LI Yawei FANG Hao LIU Tianxiao State key {1. of Clean energy Utilization Institute for Thermal Power EngineeringZhejiang UniversityHangzhou310027China

This paper studied the thermal physical properties of foundation materials in the molten salt tank of thermal energy storage system after molten salt leakage by Transient plane source experiment and X-ray computed microtomography simulation *** microstructure,thermal properties and pressure resistance with different particle diameters were *** measured heat conductivities from Transient plane source experiment for three cases are 0.49 W/(m·K),0.48 W/(m·K),and 0.51.W/(m·K),and the porosity is 30.1.,30.7%,and 31.2% *** heat conductivity simulating results of three cases are 0.471.W/(m·K),0.482W/(m·K),and 0.51. W/(m·K).The ratio of difference between the results of simulation and Transient plane source measurement is as low as 1.2%,verifying the reliability of experimental and simulation results to a certain *** with the heat conductivity of 0.097-0.1.9 W/(m·K) and porosity of 71.6%-78.9% without leaking salt,the porosity is reduced by more than 50% while the heat conductivity increased by 4 to 5 times after molten salt *** significant increase in heat conductivity has a great impact on security operation,structure design,and modeling of the tank foundation for solar {1. plants.

关键词： heat conductivity X-ray computed microtomography foundation materials three-phase threshold algorithm molten salt leakage

Promoting effect of FeOx addition on the mechanochemically prepared vanadium-based catalyst for real PCDD/Fs removal and mechanism insight

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Journal of Environmental Sciences 2024年第3期137卷 478-487页

作者： Minghui Tang Ling Wang Hongxian Li Xinlei Huang Cuicui Du Shengyong Lu State key {1. for Clean energy Utilization Institute for Thermal Power EngineeringZhejiang UniversityHangzhou 310027China

Industrial-use VOx-based catalysts usually have a higher active temperature window (>250-300℃),which becomes a“bottleneck”for the practical application of PCDD/Fs catalytic degradation *** this work,VO_(x)-FeO_(x)/TiO_(2) catalyst prepared via mechanochemically method was investigated for the catalytic removal of PCDD/*** removal efficiency of 1.2-DCBz,pure PCDD/Fs gas generated in the lab,PCDD/Fs from actual fue gas,long-term were studied,and the degradation mechanism was explored using FTIR and *** degradation efficiency of 1.2-DCBz and PCDD/Fs on VO_(x)-FeO_(x)/TiO_(2) were higher than that of VO_(x)/TiO_(2)catalyst,and the optimal FeOx addition ratio was 3 wt.%.The characterization results show that the addition of FeOx can effectively improve the pore structure,surface acidity,and VOx dispersion of the catalyst,thus contributing to increasing the V^(5+)content and surface-active oxygen,which is conducive to the improvement of adsorption and redox performance of the *** the actual MSWI (municipal solid waste incineration)fue gas,the PCDD/Fs removal efficiency over VTi-3Fe-MC maintained long-term stability,higher than 85%for 240 *** result was not significantly reduced compared with the data obtained in the *** to the analysis results of intermediate products by FTIR and GC-TOFMS,it can be inferred that the epoxidation fracture of benzene ring is the rate-limiting step of dioxin catalytic degradation *** work gives an in-depth view into the PCDD/Fs removal over VO_(x)-FeO_(x)/TiO_(2) catalysts and could provide guidelines for the rational design of reliable catalysts for industrial applications.

关键词： PCDD/F removal MSWI fue gas VO_(x)-FeO_(x)/TiO_(2) Mechanochemical GC-TOFMS

Copper slag assisted coke reduction of phosphogypsum for sulphur dioxide preparation

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Chinese Journal of Chemical Engineering 2024年第1期65卷 43-53页

作者： Dong Ma Qinhui Wang State key {1. of Clean energy Utilization Institute for Thermal Power EngineeringZhejiang UniversityHangzhou 310027China

The reduction of phosphogypsum(PG)to lime slag and SO_(2)using coke can effectively alleviate the environmental problems caused by ***,the PG decomposition temperature remains high and the product yield remains *** adding additives,the decomposition temperature can be further reduced and PG decomposition rate and product yield can be ***,the use of current additives such as Fe_(2)O_(3)and SiO_(2)brings the problem of increasing economic ***,it is proposed to use solid waste copper slag(CS)as a new additive to reduce PG to prepare SO2,which can reduce the cost and meet the environmental benefits at the same *** effects of proportion,temperature and thermostatic time on PG decomposition are investigated by experimental and kinetic analysis combined with FactSage thermodynamic calculations to optimize the roasting ***,the reaction mechanism is *** is found that adding CS to the coke and PG system can increase the rate of PG decomposition and SO_(2)yield while lowering the PG decomposition *** example,when the CS/PG mass ratio increases from 0 to 1.PG decomposition rate increases from 83.38%to 99.35%,SO_(2)yield increases from 78.62%to 96.81.,and PG decomposition temperature decreases from 992.4℃to 949.6℃.The optimal reaction parameters are CS/PG mass ratio of 1.Coke/PG mass ratio of 0.06 at 1.00℃for 20 min with 99.35%PG decomposition rate and 96.81.SO_(2) *** process proceeds according to the following reactions:2CaSO_(4)+ 0.7C + 0.8Fe_(2)SiO_(4)→0.8Ca_(2)SiO_(4)+ 0.2Ca_(2)Fe_(2)O_(5)+ 0.4Fe_(3)O_(4)+2SO_(2)+ 0.7CO_(2)Finally,a process for decomposing PG with coke and CS is proposed.

关键词： Phosphogypsum Sulfur dioxide Copper slag Fluidized-bed Reduction Waste treatment

Effect of CO_(2) Opposing Multiple Jets on Thermoacoustic Instability and NO_(x) Emissions in a Lean-Premixed Model Combustor

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Journal of Thermal Science 2024年第1期33卷 207-221页

作者： ZHOU Hao HU Liubin Institute for Thermal power Engineering State Key Laboratory of Clean Energy UtilizationZhejiang UniversityHangzhou 310027China

This paper experimentally studied the effect of CO_(2) opposing multiple jets on the thermoacoustic instability and NO_(x) emissions in a lean-premixed model *** feasibility was verified from three variables:the CO_(2) jet flow rate,hole numbers,and hole diameters of the *** indicate that the control effect of thermoacoustic instability and NO_x emissions show a reverse trend with the increase of open area ratio on the whole,and the optimal jet flow rate range is 1.4 L/min with CO_(2) opposing multiple *** this flow rate range,the amplitude and frequency of the dynamic pressure and heat release signals CH~* basically decrease as the CO_(2) flow rate increases,which avoids high-frequency and high-amplitude thermoacoustic *** amplitude-damped ratio of dynamic pressure and CH*can reach as high as 98.75% and 93.64% with an optimal open area ratio of 3.72%.NO_(x) emissions also decrease as the jet flow rate increases,and the maximum suppression ratio can reach 68.1.%.Besides,the flame shape changes from a steep inverted "V" to a more flat "M",and the flame length will become shorter with CO_(2) opposing multiple *** research achieved the synchronous control of thermoacoustic instability and NO_(x) emissions,which could be a design reference for constructing a safer and cleaner combustor.

关键词： thermoacoustic instability lean-premixed model combustor CO_(2)opposing multiple jets open area ratio NO_(x)emissions

Rapid and stable calcium-looping solar thermochemical energy storage via co-doping binary sulfate and Al±Mn±Fe oxides

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Green energy & Environment 2024年第8期9卷 1290-1305页

作者： Changjian Yuan Xianglei Liu Xinrui Wang Chao Song Hangbin Zheng Cheng Tian Ke Gao Nan Sun Zhixing Jiang Yimin Xuan Yulong Ding School of energy and {1. Engineering Nanjing University of Aeronautics and Astronautics key {1. of Thermal Management and energy Utilization of Aviation Vehicles Ministry of Industry and Information Technology Birmingham Centre for energy Storage School of Chemical Engineering University of Birmingham

Solar thermochemical energy storage based on calcium looping（CaL） process is a promising {1. for next-generation concentrated solar power（CSP） systems. However, conventional calcium carbonate（CaCO3） pellets suffer from slow reaction kinetics, poor stability, and low solar absorptance. Here, we successfully realized high power density and highly stable solar thermochemical energy storage/release by synergistically accelerating energy storage/release via binary sulfate and promoting cycle stability, mechanical strength, and solar absorptance via Al±Mn±Fe oxides. The energy storage density of proposed CaCO3pellets is still as high as 1.55 kJ kg-1.ith only a slight decay rate of 4.91. over 1.0 cycles, which is higher than that of state-of-the-art pellets in the literature, in stark contrast to 69.9% of pure CaCO3pellets over 35cycles. Compared with pure CaCO3, the energy storage power density or decomposition rate is improved by 1.0% due to lower activation energy and promotion of Ca2+diffusion by binary sulfate. The energy release or carbonation rate rises by 1.% because of high O2-transport ability of molten binary sulfate. Benefiting from fast energy storage/release rate and high solar absorptance, thermochemical energy storage efficiency is enhanced by more than 50% under direct solar irradiation. This work paves the way for application of direct solar thermochemical energy storage techniques via achieving fast energy storage/release rate, high energy density, good cyclic stability, and high solar absorptance simultaneously.

关键词： Calcium looping (CaL) Solar thermochemical energy storage Binary sulfate Fast reaction kinetics

Electrospinning-hot pressing technique for the fabrication of thermal and electrical storage membranes and its applications

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International Journal of Minerals,Metallurgy and Materials 2024年第9期31卷 1945-1964页

作者： Panpan Che Baoshan Xie Penghui Cao Youfu Lv Daifei Liu Huali Zhu Xianwen Wu Zhangxing He Jian Chen Chuanchang Li key {1. of Renewable energy Electric-technology of Hunan Province School of Energy and Power EngineeringChangsha University of Science and TechnologyChangsha 410114China State key {1. of Disaster Prevention&Reduction for power Grid Changsha University of Science and TechnologyChangsha 410114China School of Chemistry and Chemical Engineering Jishou UniversityJishou 416000China School of Chemical Engineering North China University of Science and TechnologyTangshan 063009China

The combination of electrospinning and hot pressing,namely the electrospinning-hot pressing technique(EHPT),is an efficient and convenient method for preparing nanofibrous composite materials with good energy storage *** emerging composite membrane prepared by EHPT,which exhibits the advantages of large surface area,controllable morphology,and compact structure,has attracted immense *** this paper,the conduction mechanism of composite membranes in thermal and electrical energy storage and the performance enhancement method based on the fabrication process of EHPT are systematically ***,the state-of-the-art applications of composite membranes in these two fields are *** particular,in the field of thermal energy storage,EHPT-prepared membranes have longitudinal and transverse nanofibers,which generate unique thermal conductivity pathways;also,these nanofibers offer enough space for the filling of functional ***,EHPT-prepared membranes are beneficial in thermal management systems,building energy conservation,and electrical energy storage,e.g.,improving the electrochemical properties of the separators as well as their mechanical and thermal *** application of electrospinning-hot pressing membranes on capacitors,lithium-ion batteries(LIBs),fuel cells,sodium-ion batteries(SIBs),and hydrogen bromine flow batteries(HBFBs)still requires *** the future,EHPT is expected to make the field more exciting through its own technological breakthroughs or be combined with other technologies to produce intelligent materials.

关键词： electrospinning-hot pressing technique thermal storage electrical storage composite membranes nanofiber